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HELMHOLTZ FREE ENERGY IN A SYSTEM OF ANISOTROPIC CHAINLIKE MOLECULES AND ITS APPLICATIONS FOR NORMAL MONOHYDRIC ALCOHOLS AND NORMAL ALKANES
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作者 丛威 陆九芳 李以圭 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 1997年第2期91-100,共10页
1 INTRODUCTIONAfter Prausnitz et al.published the perturbed hard-sphere chain theory(PHCT),manymodified theories have been put forward,such as the perturbed soft-sphere chain theory(PSCT),the perturbed anisotropic cha... 1 INTRODUCTIONAfter Prausnitz et al.published the perturbed hard-sphere chain theory(PHCT),manymodified theories have been put forward,such as the perturbed soft-sphere chain theory(PSCT),the perturbed anisotropic chain theory(PACT)and the associated perturbedanisotropic chain theory(APACT).These theories are all concerned with the parameter3c.But,Wertheim in his work proved that the free energy of hard-sphere chain couldbe calculated without 3c.Induced by the work done by Wertheim,Chapman 展开更多
关键词 perturbation theory chainlike MOLECULES HELMHOLTZ free energy NORMAL monohydric alco-hol NORMAL ALKANE
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