Considering phase changes associated with a high-temperature molten material cooled down from the outside,this work presents an improvement of the modelling and the numerical simulation of such processes for an applic...Considering phase changes associated with a high-temperature molten material cooled down from the outside,this work presents an improvement of the modelling and the numerical simulation of such processes for an application pertaining to the safety of light water nuclear reactors.Postulating a core meltdown accident,the behaviour of the core melt(aka corium)into a steel vessel is of tremendous importance when evaluating the vessel integrity.Evaluating correctly the heat fluxes requires the numerical simulation of the interaction between the liquid material and its solid counterpart which forms during the solidification process,but also may melt back.To simulate this configuration,encoun-tered in various industrial applications,one considers a bi-phase model constituted by a liquid phase in contact and interaction with its solid phase.The liquid phase may solidify in presence of low energetic source,while the solid phase may melt due to an intense heat flux from the high-temperature liquid.In the frame of the in-house legacy code,several simplifying assumptions(0D multi-layer discretization,instantaneous heat transfer via a quadratic temperature profile in solids)are made for the modelling of such phase changes.In the present work,these shortcomings are illustrated and further overcome by solving a 2D heat conduction model in the solid by a mixed Raviart-Thomas finite element method coupled to the liquid phase due to heat and mass exchanges through Stefan condition.The liquid phase is modeled with a 0D multi-layer approach.The 0D-liquid and 2D-solid mod-els are coupled by a Stefan like phase change interface model.Several sanity checks are performed to assess the validity of the approach on 1D and 2D academical configurations for which exact or reference solutions are available.Then more advanced situations(genu-ine multi-dimensional phase changes and an"industrial-like scenario")are simulated to verify the appropriate behavior of the obtained coupled simulation scheme.展开更多
In this work, the easy to use, simple and direct equations were formulated and tested. These equations can be used to calculate the mean values of the heat transfer coefficients of inside tube flow during phase change...In this work, the easy to use, simple and direct equations were formulated and tested. These equations can be used to calculate the mean values of the heat transfer coefficients of inside tube flow during phase change. Analytical and experimental methods were used to correlate these equations. Two different forms were used, one for evaporation case and the other for condensation case. Carbon dioxide, CO2, was used as case study. Correlated values of the mean heat transfer coefficients (hcor,.) were compared with the experimental results (he^e) and with other published result, a good agreement was noticed. The resulted correlations can be used to simplify the design and performance studies of both condensers and evaporators.展开更多
In order to evaluate the feasibility of using phase change materials to reduce the inner temperature rise of mass concrete, the interior temperature of normal concrete specimen under semi-adiabatic curing condition wa...In order to evaluate the feasibility of using phase change materials to reduce the inner temperature rise of mass concrete, the interior temperature of normal concrete specimen under semi-adiabatic curing condition was measured. The effect of embedding phase change material(PCM) and replacing water with suspension of phase change material(SPCM) as cooling fluid were compared in the experiment. The cooling effect and the affecting factors were analyzed and calculated. The research results showed that the peak of inner temperature could be decreased obviously by the method of pre-embeding PCM in concrete, however, this method is only effective in the initial stage of cement hydration process. Besides, the volume of PCM is rather big and the PCM can not be used circularly, which means that this method can only be used under special condition and the feasibility is low. When SPCM was used as cooling fluid, the interior temperature rise of mass concrete was reduced more effectively, and the temperature grads peak around the cooling pipe was also reduced. Besides, both the SPCM consumption amount and the circulation time were decreased, and most important is that the SPCM is recyclable. The technical and economical feasibility of using SPCM to reduce the inner temperature rise of mass concrete is high.展开更多
The synthesis and characterization of meso-tetra (4-n-lauroyloxy phenyl) porphyrin with long ester chains are reported. The domains of stability and the structure of the liquid crystalline phases are determined by opt...The synthesis and characterization of meso-tetra (4-n-lauroyloxy phenyl) porphyrin with long ester chains are reported. The domains of stability and the structure of the liquid crystalline phases are determined by optical microscopy and differential scanning calorimerials (DSC).展开更多
A novel slow-down set waveform is proposed to improve the set performance and a 1 kb phase change random access memory chip fabricated with a 13nm CMOS technology is implemented to investigate the set performance by d...A novel slow-down set waveform is proposed to improve the set performance and a 1 kb phase change random access memory chip fabricated with a 13nm CMOS technology is implemented to investigate the set performance by different set programming strategies based on this new set pulse. The amplitude difference (I1 - I2) of the set pulse is proved to be a crucial parameter for set programming. We observe and analyze the cell characteristics with different I1 - I2 by means of thermal simulations and high-resolution transmission electron microscopy, which reveal that an incomplete set programming will occur when the proposed slow-down pulse is set with an improperly high I1 - I2. This will lead to an amorphous residue in the active region. We also discuss the programming method to avoid the set performance degradations.展开更多
As an important parameter in the single airborne passive locating system, the rate of phase difference change contains range information of the radio emitter. Taking single carrier sine pulse signals as an example, th...As an important parameter in the single airborne passive locating system, the rate of phase difference change contains range information of the radio emitter. Taking single carrier sine pulse signals as an example, this article illustrates the principle of passive location through measurement of rates of phase difference change and analyzes the structure of measurement errors. On the basis of the Cramér-Rao lower bound (CRLB), an algorithm associated with time-chips is proposed to determine the rates of pha...展开更多
Due to the deficiencies in the conventional multiple-receiver localization syste,.ns based on direction of arrival (DOA) such as system complexity of interferometer or array and ampli- tude/phase unbalance between m...Due to the deficiencies in the conventional multiple-receiver localization syste,.ns based on direction of arrival (DOA) such as system complexity of interferometer or array and ampli- tude/phase unbalance between multiple receiving channels and constraint on antenna configuration, a new radiated source localization method using the changing rate of phase difference (CRPD) measured by a long baseline interferometer (LBI) only is studied. To solve the strictly nonlinear problem, a two-stage closed-form solution is proposed. In the first stage, the DOA and its changing rate are estimated from the CRPD of each observer by the pseudolinear least square (PLS) method, and then in the second stage, the source position and velocity are found by another PLS minimiza- tion. The bias of the algorithm caused by the correlation between the measurement matrix and the noise in the second stage is analyzed. To reduce this bias, an instrumental variable (IV) method is derived. A weighted IV estimator is given in order to reduce the estimation variance. The proposed method does not need any initial guess and the computation is small. The Cramer-Rao lower bound (CRLB) and mean square error (MSE) are also analyzed. Simulation results show that the proposed method can be close to the CRLB with moderate Gaussian measurement noise.展开更多
基金funded by CEA,EDF and Framatomefinancial and scientific support of CEA Cadarache.
文摘Considering phase changes associated with a high-temperature molten material cooled down from the outside,this work presents an improvement of the modelling and the numerical simulation of such processes for an application pertaining to the safety of light water nuclear reactors.Postulating a core meltdown accident,the behaviour of the core melt(aka corium)into a steel vessel is of tremendous importance when evaluating the vessel integrity.Evaluating correctly the heat fluxes requires the numerical simulation of the interaction between the liquid material and its solid counterpart which forms during the solidification process,but also may melt back.To simulate this configuration,encoun-tered in various industrial applications,one considers a bi-phase model constituted by a liquid phase in contact and interaction with its solid phase.The liquid phase may solidify in presence of low energetic source,while the solid phase may melt due to an intense heat flux from the high-temperature liquid.In the frame of the in-house legacy code,several simplifying assumptions(0D multi-layer discretization,instantaneous heat transfer via a quadratic temperature profile in solids)are made for the modelling of such phase changes.In the present work,these shortcomings are illustrated and further overcome by solving a 2D heat conduction model in the solid by a mixed Raviart-Thomas finite element method coupled to the liquid phase due to heat and mass exchanges through Stefan condition.The liquid phase is modeled with a 0D multi-layer approach.The 0D-liquid and 2D-solid mod-els are coupled by a Stefan like phase change interface model.Several sanity checks are performed to assess the validity of the approach on 1D and 2D academical configurations for which exact or reference solutions are available.Then more advanced situations(genu-ine multi-dimensional phase changes and an"industrial-like scenario")are simulated to verify the appropriate behavior of the obtained coupled simulation scheme.
文摘In this work, the easy to use, simple and direct equations were formulated and tested. These equations can be used to calculate the mean values of the heat transfer coefficients of inside tube flow during phase change. Analytical and experimental methods were used to correlate these equations. Two different forms were used, one for evaporation case and the other for condensation case. Carbon dioxide, CO2, was used as case study. Correlated values of the mean heat transfer coefficients (hcor,.) were compared with the experimental results (he^e) and with other published result, a good agreement was noticed. The resulted correlations can be used to simplify the design and performance studies of both condensers and evaporators.
基金Funded by the National Basic Research Program of China(No.2009CB623203)the National Natural Science Foundation of China(No.50539040)the Scientific Research Foundation of Graduate School of Southeast University(No.YBJJ 0725)
文摘In order to evaluate the feasibility of using phase change materials to reduce the inner temperature rise of mass concrete, the interior temperature of normal concrete specimen under semi-adiabatic curing condition was measured. The effect of embedding phase change material(PCM) and replacing water with suspension of phase change material(SPCM) as cooling fluid were compared in the experiment. The cooling effect and the affecting factors were analyzed and calculated. The research results showed that the peak of inner temperature could be decreased obviously by the method of pre-embeding PCM in concrete, however, this method is only effective in the initial stage of cement hydration process. Besides, the volume of PCM is rather big and the PCM can not be used circularly, which means that this method can only be used under special condition and the feasibility is low. When SPCM was used as cooling fluid, the interior temperature rise of mass concrete was reduced more effectively, and the temperature grads peak around the cooling pipe was also reduced. Besides, both the SPCM consumption amount and the circulation time were decreased, and most important is that the SPCM is recyclable. The technical and economical feasibility of using SPCM to reduce the inner temperature rise of mass concrete is high.
文摘The synthesis and characterization of meso-tetra (4-n-lauroyloxy phenyl) porphyrin with long ester chains are reported. The domains of stability and the structure of the liquid crystalline phases are determined by optical microscopy and differential scanning calorimerials (DSC).
基金Supported by the Strategic Priority Research Program of Chinese Academy of Sciences under Grant No XDA09020402the National Key Basic Research Program of China under Grant Nos 2013CBA01900,2010CB934300,2011CBA00607,and 2011CB932804+2 种基金the National Integrate Circuit Research Program of China under Grant No 2009ZX02023-003the National Natural Science Foundation of China under Grant Nos 61176122,61106001,61261160500,and 61376006the Science and Technology Council of Shanghai under Grant Nos 12nm0503701,13DZ2295700,12QA1403900,and 13ZR1447200
文摘A novel slow-down set waveform is proposed to improve the set performance and a 1 kb phase change random access memory chip fabricated with a 13nm CMOS technology is implemented to investigate the set performance by different set programming strategies based on this new set pulse. The amplitude difference (I1 - I2) of the set pulse is proved to be a crucial parameter for set programming. We observe and analyze the cell characteristics with different I1 - I2 by means of thermal simulations and high-resolution transmission electron microscopy, which reveal that an incomplete set programming will occur when the proposed slow-down pulse is set with an improperly high I1 - I2. This will lead to an amorphous residue in the active region. We also discuss the programming method to avoid the set performance degradations.
基金Aeronautical Science Foundation of China (2007ZC53030)
文摘As an important parameter in the single airborne passive locating system, the rate of phase difference change contains range information of the radio emitter. Taking single carrier sine pulse signals as an example, this article illustrates the principle of passive location through measurement of rates of phase difference change and analyzes the structure of measurement errors. On the basis of the Cramér-Rao lower bound (CRLB), an algorithm associated with time-chips is proposed to determine the rates of pha...
基金co-supported by the Foundation of National Defense Key Laboratory of China (No. 9140C860304)the National High Technology Research and Development Program of China (No. 2011AA7072048)
文摘Due to the deficiencies in the conventional multiple-receiver localization syste,.ns based on direction of arrival (DOA) such as system complexity of interferometer or array and ampli- tude/phase unbalance between multiple receiving channels and constraint on antenna configuration, a new radiated source localization method using the changing rate of phase difference (CRPD) measured by a long baseline interferometer (LBI) only is studied. To solve the strictly nonlinear problem, a two-stage closed-form solution is proposed. In the first stage, the DOA and its changing rate are estimated from the CRPD of each observer by the pseudolinear least square (PLS) method, and then in the second stage, the source position and velocity are found by another PLS minimiza- tion. The bias of the algorithm caused by the correlation between the measurement matrix and the noise in the second stage is analyzed. To reduce this bias, an instrumental variable (IV) method is derived. A weighted IV estimator is given in order to reduce the estimation variance. The proposed method does not need any initial guess and the computation is small. The Cramer-Rao lower bound (CRLB) and mean square error (MSE) are also analyzed. Simulation results show that the proposed method can be close to the CRLB with moderate Gaussian measurement noise.