It was found for the first time that gramicidin D (GD) molecules can be incorporated into the ODM monolayer which is self-assembled on the surface of the gold electrode and form monovalent cation channels.
A synthetic cationic surfactant, 5,5-ditetradecyl-2-(2-trimethyl-ammonioethyl)-1,3-dioxane bromide (DTDB), was used to construct a supported bilayer lipid membrane (s-BLM) coated on an underlying glassy carbon electro...A synthetic cationic surfactant, 5,5-ditetradecyl-2-(2-trimethyl-ammonioethyl)-1,3-dioxane bromide (DTDB), was used to construct a supported bilayer lipid membrane (s-BLM) coated on an underlying glassy carbon electrode (GCE). Electrochemical impedance spectroscopy (EIS), small-angle X-ray diffraction (SAXD) and cyclic voltammetry were used to characterize the s-BLM. Both EIS and SAXD data indicated that the synthetic lipid exists as a well-oriented bilayer in the membrane. The voltammetric study showed that the lipid membrane can open ion channels in the presence of C1O4- stimulant with Ru(bpy)32+ as marker ions and give distinct channel currents. The channels can be closed and open up again many times by removing or introducing ClO4- anions.展开更多
A visualized investigation was carried out on the effect of the diverging angle on the bubble motion and interfacial behavior in a Venturi-type bubble generator.It was found two or three large vortexes formed in the d...A visualized investigation was carried out on the effect of the diverging angle on the bubble motion and interfacial behavior in a Venturi-type bubble generator.It was found two or three large vortexes formed in the diverging section,resulting in strong reentrant jet flow in the front of the bubbles or slugs rushing out of the throat.The jet flow in return bumps into the ongoing bubbles or slugs,leading to strong interaction between the gas and liquid phases.The diverging angle has significant influence on the reentrant flow process and the performance of the bubble generator as well.Increasing the diverging angle results in the reentrant flow moving further forward to the upstream and intensifies the interaction between the two phases.As a consequence,the breakup or collapse of bubbles becomes more violent,whereby finer bubbles are generated.As such,the reentrant flow strongly links to the performance of the Venturi channel taken as a bubble generator,and that a moderate increase in the diverging angle can improve its performance without additional increase in flow resistance like that by increasing liquid flow rate.展开更多
文摘It was found for the first time that gramicidin D (GD) molecules can be incorporated into the ODM monolayer which is self-assembled on the surface of the gold electrode and form monovalent cation channels.
基金Project supported by University of Science and Technology of China(Nos.ky1212 and ky2216).
文摘A synthetic cationic surfactant, 5,5-ditetradecyl-2-(2-trimethyl-ammonioethyl)-1,3-dioxane bromide (DTDB), was used to construct a supported bilayer lipid membrane (s-BLM) coated on an underlying glassy carbon electrode (GCE). Electrochemical impedance spectroscopy (EIS), small-angle X-ray diffraction (SAXD) and cyclic voltammetry were used to characterize the s-BLM. Both EIS and SAXD data indicated that the synthetic lipid exists as a well-oriented bilayer in the membrane. The voltammetric study showed that the lipid membrane can open ion channels in the presence of C1O4- stimulant with Ru(bpy)32+ as marker ions and give distinct channel currents. The channels can be closed and open up again many times by removing or introducing ClO4- anions.
基金supported by the National Natural Science Foundation of China (Grants 51709191, 51606130, and 51506099)
文摘A visualized investigation was carried out on the effect of the diverging angle on the bubble motion and interfacial behavior in a Venturi-type bubble generator.It was found two or three large vortexes formed in the diverging section,resulting in strong reentrant jet flow in the front of the bubbles or slugs rushing out of the throat.The jet flow in return bumps into the ongoing bubbles or slugs,leading to strong interaction between the gas and liquid phases.The diverging angle has significant influence on the reentrant flow process and the performance of the bubble generator as well.Increasing the diverging angle results in the reentrant flow moving further forward to the upstream and intensifies the interaction between the two phases.As a consequence,the breakup or collapse of bubbles becomes more violent,whereby finer bubbles are generated.As such,the reentrant flow strongly links to the performance of the Venturi channel taken as a bubble generator,and that a moderate increase in the diverging angle can improve its performance without additional increase in flow resistance like that by increasing liquid flow rate.
