1 Introduction Massive tungsten-tin,rare and rare earth metals ore deposits were formed with the widespread granite magmatic activity in early Yanshanian period in the eastern Nanling region.Recent studies indicate th...1 Introduction Massive tungsten-tin,rare and rare earth metals ore deposits were formed with the widespread granite magmatic activity in early Yanshanian period in the eastern Nanling region.Recent studies indicate that the Yanshanian highly differentiated-granite formation is closely related to the deposits of tungsten and tin,rare and rare earth metals mineralization in the region(Xiao展开更多
Development of graphene field effect transistors （GFETs） faces a serious challenge of graphene interface to the dielectric material. A single layer of intrinsic graphene has an average sheet resistance of the order ...Development of graphene field effect transistors （GFETs） faces a serious challenge of graphene interface to the dielectric material. A single layer of intrinsic graphene has an average sheet resistance of the order of 1-5 kΩ/□. The intrinsic nature of graphene leads to higher contact resistance yielding into the outstanding properties of the material. We design a graphene matrix with minimized sheet resistance of 0.185 kΩ/□ with Ag contacts. The developed matrices on silicon substrates provide a variety of transistor design options for subsequent fabrication. The graphene layer is developed over 400 nm nickel in such a way as to analyze hypersensitive electrical properties of the interface for exfoliation. This work identifies potential of the design in the applicability of few-layer GFETs with less process steps with the help of analyzing the effect of metal contact and post-process anneMing on its electrical fabrication.展开更多
Recur to multi-hole and better elastic characteristics of metal rubber （MR）, a new squeezed film damper with MR （SFD/MR） throttle ring installed on the end of MR and MR damping ring installed on the radial directi...Recur to multi-hole and better elastic characteristics of metal rubber （MR）, a new squeezed film damper with MR （SFD/MR） throttle ring installed on the end of MR and MR damping ring installed on the radial direction of MR is implemented. Based on the D＇alembert principle, a locomotion equation and the mathematical model of stationary response of SFD/MR system is put forward. It proves that the SFD/MR has better ability to resist unbalance loads than the traditional SFD after the stationary dynamic characteristics of the traditional SFD and the new SFD/MR are researched.展开更多
Due to rapid urbanization and industrialization, heavy metals in road-deposited sediments（RDSs） of parks are emitted into the terrestrial, atmospheric, and water environment, and have a severe impact on residents＇ ...Due to rapid urbanization and industrialization, heavy metals in road-deposited sediments（RDSs） of parks are emitted into the terrestrial, atmospheric, and water environment, and have a severe impact on residents＇ and tourists＇ health. To identify the distribution and characteristic of heavy metals in RDS and to assess the road environmental quality in Chinese parks, samples were collected from Beijing Olympic Park in the present study. The results indicated that particles with small grain size（〈150 μm） were the dominant fraction. The length of dry period was one of the main factors affecting the particle size distribution, as indicated by the variation of size fraction with the increase of dry days. The amount of heavy metal（i.e., Cu, Zn, Pb and Cd） content was the largest in particles with small size（〈150 μm） among all samples. Specifically, the percentage of Cu, Zn, Pb and Cd in these particles was 74.7%, 55.5%, 56.6% and 71.3%, respectively.Heavy metals adsorbed in sediments may mainly be contributed by road traffic emissions. The contamination levels of Pb and Cd were higher than Cu and Zn on the basis of the mean heavy metal contents. Specifically, the geoaccumulation index（I geo） decreased in the order：Cd〉Pb〉Cu〉Zn. This study analyzed the mobility of heavy metals in sediments using partial sequential extraction with the Tessier procedure. The results revealed that the apparent mobility and potential metal bioavailability of heavy metals in the sediments, based on the exchangeable and carbonate fractions, decreased in the order： Cd〉Zn≈Pb〉Cu.展开更多
This paper reviewed the effect of powder characteristics and additives including metals,rare earth oxides,and ZrO2 on nitridation of Si powder.The decrease of particle size of Si powder increased nitridation.Most of m...This paper reviewed the effect of powder characteristics and additives including metals,rare earth oxides,and ZrO2 on nitridation of Si powder.The decrease of particle size of Si powder increased nitridation.Most of metal additives inhibited nitridation,while some metal additives such as Fe,Cu,Cr,and Ca increased nitrida—tion.Otherwise,the addition of metals might lead to the degradation of physical and mechanical properties of Si3N4.All the rare earth oxides,especially CeO2 and Eu2O3,showed nitridation enhancing effect.In addition,ZrO2 with small particle size showed a stronger enhancing effect.展开更多
The partial least squares（PLS） method was employed to establish a quantitative ion characteristics-activity relationship（QICAR） model for metal ion toxicity（EC50 of 15 metal ions）. The ion characteristics includ...The partial least squares（PLS） method was employed to establish a quantitative ion characteristics-activity relationship（QICAR） model for metal ion toxicity（EC50 of 15 metal ions）. The ion characteristics included AN（the atomic number）, AIP（the change in ionization potential, eV）, Xm（the electronegativity, eV）, AW（the atomic weight）, Xm2r（the covalent index）, △E0（the absolute difference between electrochemical potential of the ion and that of its first stable reduced state, eV）, ｜lgKoH｜ （the absolute value of the lg of the first hydrolysis constant）, AR（the atomic radius, nm）, AR/AW（the ratio between atomic radius and atomic weight） and ap（the softness index） selected based on relative correlation analysis. The simulated and tested（with the other four metals） efficiency coefficients of the model are 0.88 and 0.96, respectively. The information revealed from the QICAR model indicates that the value of the metal ion toxicity was positively correlated with variables AN, AlP, Xm, AW and Xm2r; negatively correlated with variables AE0, ｜IgKoH｜, AR/AW, AR and ap, and ion characteristics △E0, Xm, σp and Xm2r were found to contribute more to the toxicity of metal ions via the accurate analysis method provided by PLS. The model could be used to predict the toxicity of the target metals and preliminary to assess combined pollution and environmental risk for heavy metals in the environments.展开更多
Urban mining is essential for continued natural resource extraction. The recovery of rare and precious metals （RPMs） from urban mines has attracted increasing attention from both academic and industrial sectors, bec...Urban mining is essential for continued natural resource extraction. The recovery of rare and precious metals （RPMs） from urban mines has attracted increasing attention from both academic and industrial sectors, because of the broad application and high price of RPMs, and their low content in natural ores. This study summarizes the distribution characteristics of various RPMs in urban mines, and the advantages and shortcomings of various technologies for RPM recovery from urban mines, including both conventional （pyrometallurgical, hydrometallurgical, and biometallurgical processing）, and emerging （electrochemical, supereritieal fluid, mechanochemical, and ionic liquids processing） technologies. Mechanical/physical technologies are commonly employed to separate RPMs from nonmetallic components in a pre-treatment process. A pyrometallurgical process is often used tbr RPM recovery, although the expensive equipment required has limited its use in small and medium-sized enterprises. Hydrometallurgical processing is effective and easy to operate, with high selectivity of target metals and high recovery efficiency of RPMs, compared to pyrometallurgy. Biometallurgy, though, has shown the most promise for leaching RPMs from urban mines, because of its low cost and environmental friendliness. Newly developed technologies electrochemical, supercritical fluid, ionic liquid, and mechanochemical have offered new choices and achieved some success in laboratory experiments, especially as efficient and environmentally friendly methods of recycling RPMs. With continuing advances in science and technology, more technologies will no doubt be developed in this field, and be able to contribute to the sustainability of RPM mining.展开更多
The electrochemical skeleton for the production of hydrogen production from water splitting consists of electrocatalysts,electrolytes,substrates,and standard electrodes.Metal selenides have been considered efficient e...The electrochemical skeleton for the production of hydrogen production from water splitting consists of electrocatalysts,electrolytes,substrates,and standard electrodes.Metal selenides have been considered efficient electrocatalysts due to their outstanding features.Moreover,electrolytes and employed substrates can significantly influence the electrocatalytic performance of the metal selenides for hydrogen evolution reaction(HER).Several studies of metal selenides for HERs have been carried out and summarized,but there are some severe limitations regarding the synchronization of the employed substrates,electrolytes,and electrocatalysts.Several experiments suggest that metal selenides deposited on carbon-based substrates inject and transport the charge carriers effectively in an acidic medium and boost the electrocatalytic performance.Meanwhile,the metal selenides deposited on materials other than carbon-based substrates inject and make the facile transportation of the charge carriers in an alkaline medium and promote the electrocatalytic performance.Herein,the fundamental characteristics,critical factors,and electrocatalytic performance of metal selenides deposited on carbon-based substrates in acidic electrolytes have been effectively summarized.The electrocatalytic performance of the metal selenides in an alkaline electrolyte and substrates like nickel foam have also been summarized to provide direction,challenges,and feedback about the electrocatalytic performance of metal selenides.展开更多
Experiments were carried out with bypass-current MIG welding–brazing of magnesium alloy to galvanized steel to investigate the effect of heat input on the microstructure and mechanical properties of lap joints. Exper...Experiments were carried out with bypass-current MIG welding–brazing of magnesium alloy to galvanized steel to investigate the effect of heat input on the microstructure and mechanical properties of lap joints. Experimental results indicated that the joint efficiency tended to increase at first and then to reduce with the increase of heat input. The joint efficiency reached its maximum of about 70% when the heat input was 155 J/mm. The metallurgical bonding between magnesium alloy and steel was a thin continuous reaction layer, and the intermetallic compound layer consisted of Mg–Zn and slight Fe–Al phases. It is concluded that bypass-current MIG welding–brazing is a stable welding process, which can be used to achieve defect-free joining of magnesium alloy to steel with good weld appearances.展开更多
基金supported by CGS grants(Item Number: 121201053303, 1212010881305, 1212011120811 and 1212011402450)
文摘1 Introduction Massive tungsten-tin,rare and rare earth metals ore deposits were formed with the widespread granite magmatic activity in early Yanshanian period in the eastern Nanling region.Recent studies indicate that the Yanshanian highly differentiated-granite formation is closely related to the deposits of tungsten and tin,rare and rare earth metals mineralization in the region(Xiao
文摘Development of graphene field effect transistors （GFETs） faces a serious challenge of graphene interface to the dielectric material. A single layer of intrinsic graphene has an average sheet resistance of the order of 1-5 kΩ/□. The intrinsic nature of graphene leads to higher contact resistance yielding into the outstanding properties of the material. We design a graphene matrix with minimized sheet resistance of 0.185 kΩ/□ with Ag contacts. The developed matrices on silicon substrates provide a variety of transistor design options for subsequent fabrication. The graphene layer is developed over 400 nm nickel in such a way as to analyze hypersensitive electrical properties of the interface for exfoliation. This work identifies potential of the design in the applicability of few-layer GFETs with less process steps with the help of analyzing the effect of metal contact and post-process anneMing on its electrical fabrication.
基金This project is supported by National Natural Science Foundation of China (No.50075017)
文摘Recur to multi-hole and better elastic characteristics of metal rubber （MR）, a new squeezed film damper with MR （SFD/MR） throttle ring installed on the end of MR and MR damping ring installed on the radial direction of MR is implemented. Based on the D＇alembert principle, a locomotion equation and the mathematical model of stationary response of SFD/MR system is put forward. It proves that the SFD/MR has better ability to resist unbalance loads than the traditional SFD after the stationary dynamic characteristics of the traditional SFD and the new SFD/MR are researched.
基金supported by the Beijing Municipal Natural Science Foundation (No. 8142013)the Philosophical and Social Science Planning Program of Beijing (No. 13CSC010)
文摘Due to rapid urbanization and industrialization, heavy metals in road-deposited sediments（RDSs） of parks are emitted into the terrestrial, atmospheric, and water environment, and have a severe impact on residents＇ and tourists＇ health. To identify the distribution and characteristic of heavy metals in RDS and to assess the road environmental quality in Chinese parks, samples were collected from Beijing Olympic Park in the present study. The results indicated that particles with small grain size（〈150 μm） were the dominant fraction. The length of dry period was one of the main factors affecting the particle size distribution, as indicated by the variation of size fraction with the increase of dry days. The amount of heavy metal（i.e., Cu, Zn, Pb and Cd） content was the largest in particles with small size（〈150 μm） among all samples. Specifically, the percentage of Cu, Zn, Pb and Cd in these particles was 74.7%, 55.5%, 56.6% and 71.3%, respectively.Heavy metals adsorbed in sediments may mainly be contributed by road traffic emissions. The contamination levels of Pb and Cd were higher than Cu and Zn on the basis of the mean heavy metal contents. Specifically, the geoaccumulation index（I geo） decreased in the order：Cd〉Pb〉Cu〉Zn. This study analyzed the mobility of heavy metals in sediments using partial sequential extraction with the Tessier procedure. The results revealed that the apparent mobility and potential metal bioavailability of heavy metals in the sediments, based on the exchangeable and carbonate fractions, decreased in the order： Cd〉Zn≈Pb〉Cu.
基金financially supported by Guangdong Innovative and Entrepreneurial Research Team Program ( No. 2013G061)the National Natural Science Foundation of China ( No. 51402055)
文摘This paper reviewed the effect of powder characteristics and additives including metals,rare earth oxides,and ZrO2 on nitridation of Si powder.The decrease of particle size of Si powder increased nitridation.Most of metal additives inhibited nitridation,while some metal additives such as Fe,Cu,Cr,and Ca increased nitrida—tion.Otherwise,the addition of metals might lead to the degradation of physical and mechanical properties of Si3N4.All the rare earth oxides,especially CeO2 and Eu2O3,showed nitridation enhancing effect.In addition,ZrO2 with small particle size showed a stronger enhancing effect.
文摘The partial least squares（PLS） method was employed to establish a quantitative ion characteristics-activity relationship（QICAR） model for metal ion toxicity（EC50 of 15 metal ions）. The ion characteristics included AN（the atomic number）, AIP（the change in ionization potential, eV）, Xm（the electronegativity, eV）, AW（the atomic weight）, Xm2r（the covalent index）, △E0（the absolute difference between electrochemical potential of the ion and that of its first stable reduced state, eV）, ｜lgKoH｜ （the absolute value of the lg of the first hydrolysis constant）, AR（the atomic radius, nm）, AR/AW（the ratio between atomic radius and atomic weight） and ap（the softness index） selected based on relative correlation analysis. The simulated and tested（with the other four metals） efficiency coefficients of the model are 0.88 and 0.96, respectively. The information revealed from the QICAR model indicates that the value of the metal ion toxicity was positively correlated with variables AN, AlP, Xm, AW and Xm2r; negatively correlated with variables AE0, ｜IgKoH｜, AR/AW, AR and ap, and ion characteristics △E0, Xm, σp and Xm2r were found to contribute more to the toxicity of metal ions via the accurate analysis method provided by PLS. The model could be used to predict the toxicity of the target metals and preliminary to assess combined pollution and environmental risk for heavy metals in the environments.
文摘Urban mining is essential for continued natural resource extraction. The recovery of rare and precious metals （RPMs） from urban mines has attracted increasing attention from both academic and industrial sectors, because of the broad application and high price of RPMs, and their low content in natural ores. This study summarizes the distribution characteristics of various RPMs in urban mines, and the advantages and shortcomings of various technologies for RPM recovery from urban mines, including both conventional （pyrometallurgical, hydrometallurgical, and biometallurgical processing）, and emerging （electrochemical, supereritieal fluid, mechanochemical, and ionic liquids processing） technologies. Mechanical/physical technologies are commonly employed to separate RPMs from nonmetallic components in a pre-treatment process. A pyrometallurgical process is often used tbr RPM recovery, although the expensive equipment required has limited its use in small and medium-sized enterprises. Hydrometallurgical processing is effective and easy to operate, with high selectivity of target metals and high recovery efficiency of RPMs, compared to pyrometallurgy. Biometallurgy, though, has shown the most promise for leaching RPMs from urban mines, because of its low cost and environmental friendliness. Newly developed technologies electrochemical, supercritical fluid, ionic liquid, and mechanochemical have offered new choices and achieved some success in laboratory experiments, especially as efficient and environmentally friendly methods of recycling RPMs. With continuing advances in science and technology, more technologies will no doubt be developed in this field, and be able to contribute to the sustainability of RPM mining.
基金financial support of the National Natural Science Foundation of China(grant no.22209150)the Zhejiang Normal University Scientific Research Foundation(grant nos.ZC304022926,YS304221906,and YS304022904)+1 种基金the Dalian Revitalization Talents Program(grant no.2022RG01)the Liaoning Binhai Laboratory Grant(grant no.LILBLB-2023-04).
文摘The electrochemical skeleton for the production of hydrogen production from water splitting consists of electrocatalysts,electrolytes,substrates,and standard electrodes.Metal selenides have been considered efficient electrocatalysts due to their outstanding features.Moreover,electrolytes and employed substrates can significantly influence the electrocatalytic performance of the metal selenides for hydrogen evolution reaction(HER).Several studies of metal selenides for HERs have been carried out and summarized,but there are some severe limitations regarding the synchronization of the employed substrates,electrolytes,and electrocatalysts.Several experiments suggest that metal selenides deposited on carbon-based substrates inject and transport the charge carriers effectively in an acidic medium and boost the electrocatalytic performance.Meanwhile,the metal selenides deposited on materials other than carbon-based substrates inject and make the facile transportation of the charge carriers in an alkaline medium and promote the electrocatalytic performance.Herein,the fundamental characteristics,critical factors,and electrocatalytic performance of metal selenides deposited on carbon-based substrates in acidic electrolytes have been effectively summarized.The electrocatalytic performance of the metal selenides in an alkaline electrolyte and substrates like nickel foam have also been summarized to provide direction,challenges,and feedback about the electrocatalytic performance of metal selenides.
基金financially supported by the National Natural Science Foundation of China(No.51005049)
文摘Experiments were carried out with bypass-current MIG welding–brazing of magnesium alloy to galvanized steel to investigate the effect of heat input on the microstructure and mechanical properties of lap joints. Experimental results indicated that the joint efficiency tended to increase at first and then to reduce with the increase of heat input. The joint efficiency reached its maximum of about 70% when the heat input was 155 J/mm. The metallurgical bonding between magnesium alloy and steel was a thin continuous reaction layer, and the intermetallic compound layer consisted of Mg–Zn and slight Fe–Al phases. It is concluded that bypass-current MIG welding–brazing is a stable welding process, which can be used to achieve defect-free joining of magnesium alloy to steel with good weld appearances.
