The study of liquid film characteristics in multiphase flow is a very important research topic, however,the characteristics of the liquid film around Taylor bubble structure in gas, oil and water three-phase flow are ...The study of liquid film characteristics in multiphase flow is a very important research topic, however,the characteristics of the liquid film around Taylor bubble structure in gas, oil and water three-phase flow are not clear. In the present study, a novel liquid film sensor is applied to measure the distributed signals of the liquid film in three-phase flow. Based on the liquid film signals, the liquid film characteristics including the structural characteristics and the nonlinear dynamics characteristics in three-phase flows are investigated for the first time. The structural characteristics including the proportion, the appearance frequency and the thickness of the liquid film are obtained and the influences of the liquid and gas superficial velocities and the oil content on them are investigated. To investigate the nonlinear dynamics characteristics of the liquid film with the changing flow conditions, the entropy analysis is introduced to successfully uncover and quantify the dynamic complexity of the liquid film behavior.展开更多
In continuous casting production,droplet characteristics are important parameters for evaluating the nozzle atomization quality,and have a significant impact on the secondary cooling effect and the slab quality.In ord...In continuous casting production,droplet characteristics are important parameters for evaluating the nozzle atomization quality,and have a significant impact on the secondary cooling effect and the slab quality.In order to study the behavior of atomized droplets after reaching the slab surface and to optimize the spray cooling effect,the influence of droplet diameter and droplet velocity on the migration behavior of droplets in the secondary cooling zone was analyzed by FLUENT software.Results show that the droplets in the spray zone and on the slab surface are mainly concentrated in the center,thus,the liquid volume fraction in the center is higher than that of either side.As the droplet diameter increases,the region of high liquid volume fraction on the slab surface becomes wider,and the liquid phase distribution in the slab width direction becomes uneven.Although increasing the droplet velocity at the nozzle exit has little effect on droplet diffusion in the spray zone,the distribution becomes more uneven due to more liquid reaches the slab surface per unit time.A prediction formula of the maximum water flow rate on the slab surface for specific droplet characteristics was proposed based on dimensionless analysis and validated by simulated data.A nozzle spacing of 210 mm was recommended under the working conditions in this study,which ensures effective coverage of the spray water over the slab surface and enhances the distribution uniformity of water flow rate in the transverse direction.展开更多
With a focus on the difficulty of quantitatively describing the degree of nonuniformity of temporal and spatial distributions of water resources, quantitative research was carried out on the temporal and spatial distr...With a focus on the difficulty of quantitatively describing the degree of nonuniformity of temporal and spatial distributions of water resources, quantitative research was carried out on the temporal and spatial distribution characteristics of water resources in Guangdong Province from 1956 to 2000 based on a cloud model. The spatial variation of the temporal distribution characteristics and the temporal variation of the spatial distribution characteristics were both analyzed. In addition, the relationships between the numerical characteristics of the cloud model of temporal and spatial distributions of water resources and precipitation were also studied. The results show that, using a cloud model, it is possible to intuitively describe the temporal and spatial distribution characteristics of water resources in cloud images. Water resources in Guangdong Province and their temporal and spatial distribution characteristics are differentiated by their geographic locations. Downstream and coastal areas have a larger amount of water resources with greater uniformity and stronger stability in terms of temporal distribution. Regions with more precipitation possess larger amounts of water resources, and years with more precipitation show greater nonuniformity in the spatial distribution of water resources. The correlation between the nonuniformity of the temporal distribution and local precipitation is small, and no correlation is found between the stability of the nonuniformity of the temporal and spatial distributions of water resources and precipitation. The amount of water resources in Guangdong Province shows an increasing trend from 1956 to 2000, the nonuniformity of the spatial distribution of water resources declines, and the stability of the nonuniformity of the spatial distribution of water resources is enhanced.展开更多
Overwhelming evidence reveals that concentrations of dissolved organic carbon (DOC) have increased in streams which brings negative environmental impacts. DOC in stream flow is mainly originated from soil-water solu...Overwhelming evidence reveals that concentrations of dissolved organic carbon (DOC) have increased in streams which brings negative environmental impacts. DOC in stream flow is mainly originated from soil-water solutions of watershed. Wetlands prove to be the most sensitive areas as an important DOC reserve between terrestrial and fluvial biogeosystems. This reported study was focused on the distribution characteristics and the controlling factors of DOC in soil-water solutions of annular wetland, i.e., a dishing wetland and a forest wetland together, in the Sanjiang Plain, Northeast China. The results indicate that DOC concentrations in soilwater solutions decreased and then increased with increasing soil depth in the annular wetland. In the upper soil layers of 0-10 cm and 10-20 cm, DOC concentrations in soil-water solutions linearly increased from edge to center of the annular wetland (R^2 = 0.3122 and R^2 = 0.443). The distribution variations were intimately linked to DOC production and utilization and DOC transport processes in annular wetland soil-water solutions. The concentrations of total organic carbon (TOC), total carbon (TC) and Fe(II), DOC mobility and continuous vertical and lateral flow affectext the distribution variations of DOC in soil-water solutions. The correlation coefficients between DOC concentrations and TOC, TC and Fe(II) were 0.974, 0.813 and 0.753 respectively. These distribution characteristics suggested a systematic response of the distribution variations of DOC in annular wetland soil-water solutions to the geometry of closed depressions on a scale of small catchments. However, the DOC in soil pore water of the annular wetland may be the potential source of DOC to stream flow on watershed scale. These observations also implied the fragmentation of wetland landscape could bring the spatial-temporal variations of DOC distribution and exports, which would bring negative environmental impacts in watersheds of the Sanjiang Plain.展开更多
Within the biofilm and scales Legionella is less far susceptible to the effects of the most frequently used biocides. The objective of this study was to evaluate the effect of a 4-months continuous injection of a gas ...Within the biofilm and scales Legionella is less far susceptible to the effects of the most frequently used biocides. The objective of this study was to evaluate the effect of a 4-months continuous injection of a gas mixture (CO2 and inert gas) in the hot water distribution system of a large hotel colonized by L. pneumophila sg3 on limiting biofilm formation and scales and in turn Legionella growth. Before the continuous injection of the gas mixture, out of the 15 sampling points examined every month 60% were colonized by Legionella (mean concentrations of 102 cfu/L in the boilers and the return loop, and 104 cfu/L in taps and showers). One week after the injection of the gas mixture and daily fluxing of the distal outlets, the level of colonization decreased (3 cfu/L). When it was decided to flux all the distal outlets only 1 day per week the mean concentration of Legionella increased again (>104 cfu/L) in all the sampling points. Thus, cleaning of the boilers was performed and distal outlets were again fluxed daily. One week after the level of contamination decreased again (2 cfu/L). Nonetheless, the colonization was not eliminated and when fluxing of the distal outlets was not performed every day the mean concentrations of Legionella raised up to >104 cfu/L. Results indicate that the gas mixture was able to reduce the level of colonization by Legionella only because associated to the fluxing of the distal outlets.展开更多
Abundance of total bacteria, heterotrophic bacteria, coliform and oil degradable bacteria and their relations with salinity and suspended matter in the frontal waters in the Hangzhou Bay are described. The results obt...Abundance of total bacteria, heterotrophic bacteria, coliform and oil degradable bacteria and their relations with salinity and suspended matter in the frontal waters in the Hangzhou Bay are described. The results obtained show that the highest abundances of total bacteria , heterotrophic bacteria are encountered around the front and near the northern shore of the Hangzhou Bay, where a positive correlation ( r =0. 70) between the total bacteria abundance and the total suspended matter (TSM) is persent. Moreover,the abundance of oil degradable bacteria being an indicator of oil pollution, is also high in that region.展开更多
Coal-formed gas generated from the Permo-Carboniferous coal measures has become one of the most important targets for deep hydrocarbon exploration in the Bohai Bay Basin,offshore eastern China.However,the proven gas r...Coal-formed gas generated from the Permo-Carboniferous coal measures has become one of the most important targets for deep hydrocarbon exploration in the Bohai Bay Basin,offshore eastern China.However,the proven gas reserves from this source rock remain low to date,and the distribution characteristics and accumulation model for the coal-formed gas are not clear.Here we review the coal-formed gas deposits formed from the Permo-Carboniferous coal measures in the Bohai Bay Basin.The accumulations are scattered,and dominated by middle-small sized gas fields,of which the proven reserves ranging from 0.002 to 149.4×108 m3 with an average of 44.30×108 m3 and a mid-point of 8.16×108 m3.The commercially valuable gas fields are mainly found in the central and southern parts of the basin.Vertically,the coal-formed gas is accumulated at multiple stratigraphic levels from Paleogene to Archaeozoic,among which the Paleogene and PermoCarboniferous are the main reservoir strata.According to the transporting pathway,filling mechanism and the relationship between source rocks and reservoir,the coal-formed gas accumulation model can be defined into three types:"Upward migrated,fault transported gas"accumulation model,"Laterally migrated,sandbody transported gas"accumulation model,and"Downward migrated,sub-source,fracture transported gas"accumulation model.Source rock distribution,thermal evolution and hydrocarbon generation capacity are the fundamental controlling factors for the macro distribution and enrichment of the coal-formed gas.The fault activity and the configuration of fault and caprock control the vertical enrichment pattern.展开更多
A large number of antibiotics have been discharged into rivers by human activities,posing a threat to aquatic ecosystems.The surface water of the Yellow River Basin also suffers antibiotic pollution,which hinders the ...A large number of antibiotics have been discharged into rivers by human activities,posing a threat to aquatic ecosystems.The surface water of the Yellow River Basin also suffers antibiotic pollution,which hinders the improvement in the aquatic ecological environment.This study investigated and analyzed the characteristics and assessed the ecological risks of antibiotic pollution in surface water bodies such as canals,rivers and fish ponds in Kaifeng,Henan Province,which is a key city along the lower reaches of the Yellow River.The test results are as follows.A total of 15 types of antibiotics were detected in the surface water.They had a total antibiotic concentration of 12.2-249.9μg/L,of which tetracyclines(TCs)and quinolones accounted for the highest percentages.Six types of quinolones had detection rates of up to 100%,and doxycycline(DC)and oxytetracycline(OTC)had average concentrations of 29.52μg/L1 and 13.71μg/L,respectively.The major canals with water diverted from the Yellow River had total concentrations of quinolones and TCs of 22.0μg/L and 14.9μg/L,respectively,which were higher than those in previous studies.This phenomenon may be related to the decrease in the water flow of the Yellow River during the dry season and the increase in the antibiotic consumption of residents in the context of the Covid-19 outbreak.The upper reaches of the Huiji River in the Xiangfu District had higher antibiotic content than other districts in Kaifeng.Specifically,TCs accounted for 72.38%-91.84%of all antibiotics,and the DC and OTC concentrations were significantly higher than other antibiotics in the upper reaches.As indicated by the ecological risk assessment results,TCs had the highest ecological risks to green algae.Among them,DC had medium-high risks;TC,OTC,and chlortetracycline(CTC)had medium-high risks;trimethoprim(TMP)and lomefloxacin(LOM)had low risks;other TC antibiotics had no risk.Compared with green algae,most antibiotics showed higher ecological risks to daphnia and lower ecological risks to fish.DC and OTC dominate antibiotic pollutants in the surface water in Kaifeng City,and especially in Xiangfu District,where DC and OTC have medium-high risks.The TCs in the major Yellow River showed medium risks to both green algae and daphnia.It can be speculated that the antibiotic pollution in the Yellow River might pose a certain threat to the ecological security of water in Kaifeng City.展开更多
Soil water retention characteristics are the key information required in hydrological modeling. Frac-tal models provide a practical alternative for indirectly estimating soil water retention characteristics frompartic...Soil water retention characteristics are the key information required in hydrological modeling. Frac-tal models provide a practical alternative for indirectly estimating soil water retention characteristics fromparticle-size distribution data. Predictive capabilities of three fractal models, i.e, Tyler-Wheatcraft model,Rieu-Sposito model, and Brooks-Corey model, were fully evaluated in this work using experimental datafrom an international database and literature. Particle-size distribution data were firstly interpolated into20 classes using a van Genuchten-type equation. Fractal dimensions of the tortuous pore wall and the poresurface were then calculated from the detailed particle-size distribution and incorporated as a parameter infractal water retention models. Comparisons between measured and model-estimated water retention cha-racteristics indicated that these three models were applicable to relatively different soil textures and pressurehead ranges. Tyler-Wheatcraft and Brooks-Corey models led to reasonable agreements for both coarse- andmedium-textured soils, while the latter showed applicability to a broader texture range. In contrast, Rieu-Sposito model was more suitable for fine-textured soils. Fractal models produced a better estimation of watercontents at low pressure heads than at high pressure heads.展开更多
Gas field water is the formation water produced together with natural gas in the process of natural gas exploitation.The gas field water treated is difficult to reach the standard due to its wide sources,numerous type...Gas field water is the formation water produced together with natural gas in the process of natural gas exploitation.The gas field water treated is difficult to reach the standard due to its wide sources,numerous types and complex composition.In addition,it can pollute soil,surface water and groundwater.In this study,the quality and pollution characteristics of gas field water in eastern Sichuan were studied by conventional water quality determination and GC-MS.The results show that the main components of gas field water in eastern Sichuan were chloride,COD Cr,SS,anionic surfactant,sulfide and other substances.The gas field water could be divided into two types according to the characteristics of water quality,of which one had high mineralization and high organic compounds,and the other had high sulfur and high organic compounds.There were 17 kinds of organic pollutants in the gas field water,mainly including alkanes,alcohols,esters and a small amount of acids.展开更多
Based on the field data obtained during summer cruises in 2006, the overall perspective of chemical and hydrographic characteristics of the Yellow Sea Cold Water Mass (YSCWM) are discussed through the cross- YSCWM t...Based on the field data obtained during summer cruises in 2006, the overall perspective of chemical and hydrographic characteristics of the Yellow Sea Cold Water Mass (YSCWM) are discussed through the cross- YSCWM transect profiles and horizontal distributions of hydrological and chemical variables, with emphasis on the differences between the northern Yellow Sea Cold Water Mass (NYSCWM) and the southern Yellow Sea Cold Water Mass (SYSCWM). The results show that YSCWM is characterized by low temperature (〈10℃) and dissolved oxygen (DO) concentration, high salinity (〉32.0) and nutrient concentrations. Compared to the SYSCWM, the NYSCWM possesses lower values of temperature, salinity and nutrient concentrations but higher values of DO. Also its smaller variation ranges of variables (except for temperature) demonstrate that NYSCWM is more uniform than that of SYSCWM. In addition, thermocline is more intensive in the SYSCWM than that of NYSCWM. Furthermore, DO and Chl a maxima appear at the depth of 30 m in the SYSCWM, while these phenomena are not obvious in the NYSCWM.展开更多
The distribution of precipitation field from the typhoon Haitang(2005) during its landing on Fujian province shows obvious asymmetric feature.Based on the NCEP/NCAR FNL(Final Analysis) data,this study reveals the cont...The distribution of precipitation field from the typhoon Haitang(2005) during its landing on Fujian province shows obvious asymmetric feature.Based on the NCEP/NCAR FNL(Final Analysis) data,this study reveals the contributions of atmospheric factor to the asymmetrical distribution characteristics of precipitation associated with the typhoon,through the analysis of water vapor condition,vertical ascending motion condition,the calculation of the dry Q vector and its decomposition,and adiabatic heating in the air column of 1000hPa-600hPa(lower atmosphere) and500hPa-100hPa(upper atmosphere).The results are as follows:(1) In the lower atmosphere,the humidity on both sides of typhoon path can be equivalent,while it is more wet on the right side than left in the upper atmosphere,which obviously presents asymmetric distribution characteristics.(2) Both range and intensity of the vertical motion on the right side are wider and stronger than counterparts on the left side no matter in the lower or upper atmosphere.(3) In the upper atmosphere,forcing role of atmosphere in vertical upward motion on the right side of typhoon path is the same as that on the left,while it is significantly different in the lower atmosphere,which is significantly broader in scope and stronger in the intensity,along with obvious asymmetric distribution characteristics.In addition,the further analysis of the Q vector decomposition indicates that the forcing effect of mesoscale weather systems on vertical upward motion is stronger than that of large scale weather systems in the lower atmosphere.(4) The adiabatic heating always exists on both lower and upper atmosphere,and the range and intensity of the adiabatic heating forcing showed asymmetric distribution on both lower and upper atmosphere.(5) In a summary,the upper atmosphere humidity conditions,the forcing role of lower atmosphere in vertical upward motion,especially,to mesoscale weather system,and adiabatic heating in the lower atmosphere,all show similar asymmetric distribution characteristics to that of precipitation field from the typhoon Haitang(2005),that is to say,the atmospheric factors as mentioned above are all contributed to genesis of the asymmetric distribution characteristics of precipitation.展开更多
The Paleogene and Neogene oil and gas in the western Qaidam basin have a regular distribution in three concentric zones from the edge to the center of the basin. Natural gas mainly occurs in the inner zone, and the ga...The Paleogene and Neogene oil and gas in the western Qaidam basin have a regular distribution in three concentric zones from the edge to the center of the basin. Natural gas mainly occurs in the inner zone, and the gas-oil ratio of the northern area of the basin is significantly higher than that of the southern area. Large amounts of carbon isotope data of natural gas, plotted in X- shaped and comprehensive identification diagrams for the southern area and northern area, respectively, were used to identify the types of natural gas. The large-scale distribution of natural gas is highly consistent with the Ro values of major source rocks, but is poorly correlated with the type of organic matter. This indicates that the main controlling factor of natural gas distribution is organic matter maturity, and the kerogen types act as the basis for the formation of different types of natural gas. Paleouplifts and squeezed anticlines near hydrocarbon generation depression centers, which are major natural gas-rich regions, control the migration directions of natural gas, while hydrocarbon migration pathways and fault systems connecting gas sources are the most important factors for natural gas reservoir formation in the inner basin. Therefore, favorable zones for natural gas distribution can be predicted on the basis of the distribution of thermal evolution and the gas generation intensity of major source rocks as well as the structural map. The Shizigou-Youshashan- Yingdong-Dawusi, Youquanzi -Kaitemilike - Youdunzi, and Xiaoliangshan - Nanyishan - Dafengshan structural belts are favorable zones for natural gas accumulation. This study has important theoretical and practical significance for future natural gas exploration.展开更多
Theflow behavior of shale gas horizontal wells is relatively complex,and this should be regarded as the main reason for which conventional pipeflow models are not suitable to describe the related dynamics.In this stud...Theflow behavior of shale gas horizontal wells is relatively complex,and this should be regarded as the main reason for which conventional pipeflow models are not suitable to describe the related dynamics.In this study,numerical simulations have been conducted to determine the gas-liquid distribution in these wells.In particular,using the measuredflow pressure data related to 97 groups of shale gas wells as a basis,9 distinct pipeflow models have been assessed,and the models displaying a high calculation accuracy for different water-gas ratio(WGR)ranges have been identified.The results show that:(1)The variation law of WGR in gas well satisfies a power function relation.(2)The well structure is the main factor affecting the gas-liquid distribution in the wellbore.(3)The Beggs&Brill,Hagedorn&Brown and Gray models exhibit a high calculation accuracy.展开更多
During the Pleistocene, the western Qaidam Basin has largely experienced strong structural reconstruction and strong erosion. First, the eroded thickness of Neogene strata was restored approximately by the stratigraph...During the Pleistocene, the western Qaidam Basin has largely experienced strong structural reconstruction and strong erosion. First, the eroded thickness of Neogene strata was restored approximately by the stratigraphic profile comparison method and plane trend surface restoring method; then, accurate calculation of erosion was recovered using vitrinite reflectance, and the erosion that was restored by the trend surface restoring method was corrected; finally, a distribution map of cumulative erosion was produced. This study marks an important achievement in that one of the most important parameters of basin tectonic evolution, sedimentary evolution, and oil and gas accumulation history has been obtained, and that a basic geological problem has been solved in the Qaidam Basin. The areas with high erosion and low erosion are shown in the map and a close relation between the distribution of oil and gas fields and erosion was recognized. Large and medium oil and gas fields are mainly distributed in areas with medium and low erosion. It is difficult to form large-scale oil and gas accumulation in areas in which erosion is more than 2000 m. The mechanism of the relation between oil and gas distribution and erosion is explained. This study will be of use in predicting the distribution of oil and gas.展开更多
This study analyzes the spatial and temporal distribution characteristics of seasonal precipitable water vapor (PWV) in China between 1979 and 2008. To achieve this, the observed temperature dew point difference and a...This study analyzes the spatial and temporal distribution characteristics of seasonal precipitable water vapor (PWV) in China between 1979 and 2008. To achieve this, the observed temperature dew point difference and atmospheric pressure at various altitudes of 102 radiosonde stations were utilized. The analysis involved calculating and examining the PWV variations across the different seasons in the study period. The results are illustrated as follows: 1) The annual mean and seasonal mean PWV over China is characterized by decreasing from southeast to northwest. The PWV has obvious seasonal features. It is the least in winter, which is mainly affected by latitude and altitude, and the most in summer, which is mainly affected by the monsoon. It is the medium in spring and autumn, with more in autumn than in spring. 2) The spatial distribution pattern of four seasonal PWV is approximately opposite to its variation coefficient distribution pattern, that is, the monsoon (non-monsoon) areas with more (less) PWV have a smaller (larger) variation amplitude. 3) The distribution pattern of four seasonal PWV shows a consistent distribution pattern in the whole region and the winter characteristics are the most significant. The abnormal variation of PWV shows consistent interdecadal oscillation, and it exhibits an obvious phase transition around 2002 when the PWV has an increasing shift in winter, spring, and summer, while it is more complicated in autumn.展开更多
The shapes and geometrical parameters of nozzles are key factors for fluidics. The relationship among the reaction thrust,flow rate pressure,diameter d0 and length L of a cylinder nozzle is analyzed theoretically. The...The shapes and geometrical parameters of nozzles are key factors for fluidics. The relationship among the reaction thrust,flow rate pressure,diameter d0 and length L of a cylinder nozzle is analyzed theoretically. The simulation of the flow field characteristics was conducted via the FLUENT computational fluid dynamics package. Effects of the inlet conditions and the nozzle dimensions on the reaction thrust of a water jet were addressed particularly. The reaction thrust experiments were performed on a custom-designed test apparatus. The experimental results reveal that a) the nozzle diameter and the inlet conditions exert great influence on the water jet reaction thrust; and b) for L≤4d0,where the nozzle is treated as a thin plate-orifice,the reaction thrust is independent of nozzle length; for L>4d0,where the nozzle is treated as a long orifice,the reaction thrust can reach maximum under the condition of a certain flow rate. These findings lay a theoretical foundation for the design of nozzles and have significant value,especially for the future development of high-pressure water-jet propulsion technology.展开更多
This study aimed to investigate the mechanism of mineral spontaneous combustion in an open pit. On the study of coal and mineral mixture in open pit mines, as well as through the specifc surface area and Search Engine...This study aimed to investigate the mechanism of mineral spontaneous combustion in an open pit. On the study of coal and mineral mixture in open pit mines, as well as through the specifc surface area and Search Engine Marketing (SEM) experiments, the specifc surface area and aperture characteristics of distribution of open pit coal sample and pit mineral mixture samples were analyzed. Thermal analysis experiments were used to divide the oxidation process was divided into three stages, and the thermal behavior characteristics of experimental samples were characterized. On the basis of the stage division, we explored the transfer law of the key active functional groups of the experimental samples. The apparent activation energy calculation of the key active groups, performed by combining the Achar diferential method with the Coats–Redfern integral method, microstructural and oxidation kinetic properties were revealed. The resulted showed that the mixed sample had high ash, the fxed carbon content was reduced, the specifc surface area was far lower than the raw coal, the large aperture distribution was slightly higher than the medium hole, the micropore was exceptionally low, the gas adsorption capacity was weaker than the raw coal, the pit coal sample had the exceedingly more active functional groups, easy to react with oxygen, more likely to occur naturally, and its harm was relatively large. The mixed sample contained the highest C–O–C functional group absorbance. The functional groups were mainly infuenced by the self-OH content, alkyl side chain, and fatty hydrocarbon in the sample. The main functional groups of the four-like mixture had the highest apparent activation energy, and the two reactions were higher in the low-temperature oxidation phase.展开更多
基金supported by the National Natural Science Foundation of China (42074142, 51527805, 41974139)China Postdoctoral Science Foundation (2020M680969, 2021T140099)the Fundamental Research Funds for the Central Universities (N2104013)。
文摘The study of liquid film characteristics in multiphase flow is a very important research topic, however,the characteristics of the liquid film around Taylor bubble structure in gas, oil and water three-phase flow are not clear. In the present study, a novel liquid film sensor is applied to measure the distributed signals of the liquid film in three-phase flow. Based on the liquid film signals, the liquid film characteristics including the structural characteristics and the nonlinear dynamics characteristics in three-phase flows are investigated for the first time. The structural characteristics including the proportion, the appearance frequency and the thickness of the liquid film are obtained and the influences of the liquid and gas superficial velocities and the oil content on them are investigated. To investigate the nonlinear dynamics characteristics of the liquid film with the changing flow conditions, the entropy analysis is introduced to successfully uncover and quantify the dynamic complexity of the liquid film behavior.
基金funded by the National Natural Science Foundation of China(Nos.51974213 and 52174324)。
文摘In continuous casting production,droplet characteristics are important parameters for evaluating the nozzle atomization quality,and have a significant impact on the secondary cooling effect and the slab quality.In order to study the behavior of atomized droplets after reaching the slab surface and to optimize the spray cooling effect,the influence of droplet diameter and droplet velocity on the migration behavior of droplets in the secondary cooling zone was analyzed by FLUENT software.Results show that the droplets in the spray zone and on the slab surface are mainly concentrated in the center,thus,the liquid volume fraction in the center is higher than that of either side.As the droplet diameter increases,the region of high liquid volume fraction on the slab surface becomes wider,and the liquid phase distribution in the slab width direction becomes uneven.Although increasing the droplet velocity at the nozzle exit has little effect on droplet diffusion in the spray zone,the distribution becomes more uneven due to more liquid reaches the slab surface per unit time.A prediction formula of the maximum water flow rate on the slab surface for specific droplet characteristics was proposed based on dimensionless analysis and validated by simulated data.A nozzle spacing of 210 mm was recommended under the working conditions in this study,which ensures effective coverage of the spray water over the slab surface and enhances the distribution uniformity of water flow rate in the transverse direction.
基金supported by the National Science and Technology Major Project of Water Pollution Control and Treatment(Grants No.2014ZX07405002,2012ZX07506007,2012ZX07506006,and 2012ZX07506002)the Natural Science Foundation of the Anhui Higher Education Institutions of China(Grant No.KJ2016A868)the Priority Academic Program Development of Jiangsu Higher Education Institutions
文摘With a focus on the difficulty of quantitatively describing the degree of nonuniformity of temporal and spatial distributions of water resources, quantitative research was carried out on the temporal and spatial distribution characteristics of water resources in Guangdong Province from 1956 to 2000 based on a cloud model. The spatial variation of the temporal distribution characteristics and the temporal variation of the spatial distribution characteristics were both analyzed. In addition, the relationships between the numerical characteristics of the cloud model of temporal and spatial distributions of water resources and precipitation were also studied. The results show that, using a cloud model, it is possible to intuitively describe the temporal and spatial distribution characteristics of water resources in cloud images. Water resources in Guangdong Province and their temporal and spatial distribution characteristics are differentiated by their geographic locations. Downstream and coastal areas have a larger amount of water resources with greater uniformity and stronger stability in terms of temporal distribution. Regions with more precipitation possess larger amounts of water resources, and years with more precipitation show greater nonuniformity in the spatial distribution of water resources. The correlation between the nonuniformity of the temporal distribution and local precipitation is small, and no correlation is found between the stability of the nonuniformity of the temporal and spatial distributions of water resources and precipitation. The amount of water resources in Guangdong Province shows an increasing trend from 1956 to 2000, the nonuniformity of the spatial distribution of water resources declines, and the stability of the nonuniformity of the spatial distribution of water resources is enhanced.
基金Project supported by the Knowledge Innovation Engineering Project of the Chinese Academy of Sciences(No. KSCX2-YW-N-46-06)the National Natural Science Foundation of China(No. 40501030).
文摘Overwhelming evidence reveals that concentrations of dissolved organic carbon (DOC) have increased in streams which brings negative environmental impacts. DOC in stream flow is mainly originated from soil-water solutions of watershed. Wetlands prove to be the most sensitive areas as an important DOC reserve between terrestrial and fluvial biogeosystems. This reported study was focused on the distribution characteristics and the controlling factors of DOC in soil-water solutions of annular wetland, i.e., a dishing wetland and a forest wetland together, in the Sanjiang Plain, Northeast China. The results indicate that DOC concentrations in soilwater solutions decreased and then increased with increasing soil depth in the annular wetland. In the upper soil layers of 0-10 cm and 10-20 cm, DOC concentrations in soil-water solutions linearly increased from edge to center of the annular wetland (R^2 = 0.3122 and R^2 = 0.443). The distribution variations were intimately linked to DOC production and utilization and DOC transport processes in annular wetland soil-water solutions. The concentrations of total organic carbon (TOC), total carbon (TC) and Fe(II), DOC mobility and continuous vertical and lateral flow affectext the distribution variations of DOC in soil-water solutions. The correlation coefficients between DOC concentrations and TOC, TC and Fe(II) were 0.974, 0.813 and 0.753 respectively. These distribution characteristics suggested a systematic response of the distribution variations of DOC in annular wetland soil-water solutions to the geometry of closed depressions on a scale of small catchments. However, the DOC in soil pore water of the annular wetland may be the potential source of DOC to stream flow on watershed scale. These observations also implied the fragmentation of wetland landscape could bring the spatial-temporal variations of DOC distribution and exports, which would bring negative environmental impacts in watersheds of the Sanjiang Plain.
文摘Within the biofilm and scales Legionella is less far susceptible to the effects of the most frequently used biocides. The objective of this study was to evaluate the effect of a 4-months continuous injection of a gas mixture (CO2 and inert gas) in the hot water distribution system of a large hotel colonized by L. pneumophila sg3 on limiting biofilm formation and scales and in turn Legionella growth. Before the continuous injection of the gas mixture, out of the 15 sampling points examined every month 60% were colonized by Legionella (mean concentrations of 102 cfu/L in the boilers and the return loop, and 104 cfu/L in taps and showers). One week after the injection of the gas mixture and daily fluxing of the distal outlets, the level of colonization decreased (3 cfu/L). When it was decided to flux all the distal outlets only 1 day per week the mean concentration of Legionella increased again (>104 cfu/L) in all the sampling points. Thus, cleaning of the boilers was performed and distal outlets were again fluxed daily. One week after the level of contamination decreased again (2 cfu/L). Nonetheless, the colonization was not eliminated and when fluxing of the distal outlets was not performed every day the mean concentrations of Legionella raised up to >104 cfu/L. Results indicate that the gas mixture was able to reduce the level of colonization by Legionella only because associated to the fluxing of the distal outlets.
文摘Abundance of total bacteria, heterotrophic bacteria, coliform and oil degradable bacteria and their relations with salinity and suspended matter in the frontal waters in the Hangzhou Bay are described. The results obtained show that the highest abundances of total bacteria , heterotrophic bacteria are encountered around the front and near the northern shore of the Hangzhou Bay, where a positive correlation ( r =0. 70) between the total bacteria abundance and the total suspended matter (TSM) is persent. Moreover,the abundance of oil degradable bacteria being an indicator of oil pollution, is also high in that region.
基金financial support from the National major projects (Item No.2016ZX05006-003)
文摘Coal-formed gas generated from the Permo-Carboniferous coal measures has become one of the most important targets for deep hydrocarbon exploration in the Bohai Bay Basin,offshore eastern China.However,the proven gas reserves from this source rock remain low to date,and the distribution characteristics and accumulation model for the coal-formed gas are not clear.Here we review the coal-formed gas deposits formed from the Permo-Carboniferous coal measures in the Bohai Bay Basin.The accumulations are scattered,and dominated by middle-small sized gas fields,of which the proven reserves ranging from 0.002 to 149.4×108 m3 with an average of 44.30×108 m3 and a mid-point of 8.16×108 m3.The commercially valuable gas fields are mainly found in the central and southern parts of the basin.Vertically,the coal-formed gas is accumulated at multiple stratigraphic levels from Paleogene to Archaeozoic,among which the Paleogene and PermoCarboniferous are the main reservoir strata.According to the transporting pathway,filling mechanism and the relationship between source rocks and reservoir,the coal-formed gas accumulation model can be defined into three types:"Upward migrated,fault transported gas"accumulation model,"Laterally migrated,sandbody transported gas"accumulation model,and"Downward migrated,sub-source,fracture transported gas"accumulation model.Source rock distribution,thermal evolution and hydrocarbon generation capacity are the fundamental controlling factors for the macro distribution and enrichment of the coal-formed gas.The fault activity and the configuration of fault and caprock control the vertical enrichment pattern.
基金jointly supported by the project of the China Geological Survey (DD20211309)the National Natural Science Foundation of China (41602273)the High-Level Talent Funding Program of Hebei province(A202101004).
文摘A large number of antibiotics have been discharged into rivers by human activities,posing a threat to aquatic ecosystems.The surface water of the Yellow River Basin also suffers antibiotic pollution,which hinders the improvement in the aquatic ecological environment.This study investigated and analyzed the characteristics and assessed the ecological risks of antibiotic pollution in surface water bodies such as canals,rivers and fish ponds in Kaifeng,Henan Province,which is a key city along the lower reaches of the Yellow River.The test results are as follows.A total of 15 types of antibiotics were detected in the surface water.They had a total antibiotic concentration of 12.2-249.9μg/L,of which tetracyclines(TCs)and quinolones accounted for the highest percentages.Six types of quinolones had detection rates of up to 100%,and doxycycline(DC)and oxytetracycline(OTC)had average concentrations of 29.52μg/L1 and 13.71μg/L,respectively.The major canals with water diverted from the Yellow River had total concentrations of quinolones and TCs of 22.0μg/L and 14.9μg/L,respectively,which were higher than those in previous studies.This phenomenon may be related to the decrease in the water flow of the Yellow River during the dry season and the increase in the antibiotic consumption of residents in the context of the Covid-19 outbreak.The upper reaches of the Huiji River in the Xiangfu District had higher antibiotic content than other districts in Kaifeng.Specifically,TCs accounted for 72.38%-91.84%of all antibiotics,and the DC and OTC concentrations were significantly higher than other antibiotics in the upper reaches.As indicated by the ecological risk assessment results,TCs had the highest ecological risks to green algae.Among them,DC had medium-high risks;TC,OTC,and chlortetracycline(CTC)had medium-high risks;trimethoprim(TMP)and lomefloxacin(LOM)had low risks;other TC antibiotics had no risk.Compared with green algae,most antibiotics showed higher ecological risks to daphnia and lower ecological risks to fish.DC and OTC dominate antibiotic pollutants in the surface water in Kaifeng City,and especially in Xiangfu District,where DC and OTC have medium-high risks.The TCs in the major Yellow River showed medium risks to both green algae and daphnia.It can be speculated that the antibiotic pollution in the Yellow River might pose a certain threat to the ecological security of water in Kaifeng City.
基金Project supported by the National Natural Science Foundation of China (No, 49971041), the National Key Basic Research Support Foundation (NKBRSF) of China (No. G1999011803) the Director Foundation of the Institute of Soil Science, CAS (No. ISSDF0004).
文摘Soil water retention characteristics are the key information required in hydrological modeling. Frac-tal models provide a practical alternative for indirectly estimating soil water retention characteristics fromparticle-size distribution data. Predictive capabilities of three fractal models, i.e, Tyler-Wheatcraft model,Rieu-Sposito model, and Brooks-Corey model, were fully evaluated in this work using experimental datafrom an international database and literature. Particle-size distribution data were firstly interpolated into20 classes using a van Genuchten-type equation. Fractal dimensions of the tortuous pore wall and the poresurface were then calculated from the detailed particle-size distribution and incorporated as a parameter infractal water retention models. Comparisons between measured and model-estimated water retention cha-racteristics indicated that these three models were applicable to relatively different soil textures and pressurehead ranges. Tyler-Wheatcraft and Brooks-Corey models led to reasonable agreements for both coarse- andmedium-textured soils, while the latter showed applicability to a broader texture range. In contrast, Rieu-Sposito model was more suitable for fine-textured soils. Fractal models produced a better estimation of watercontents at low pressure heads than at high pressure heads.
文摘Gas field water is the formation water produced together with natural gas in the process of natural gas exploitation.The gas field water treated is difficult to reach the standard due to its wide sources,numerous types and complex composition.In addition,it can pollute soil,surface water and groundwater.In this study,the quality and pollution characteristics of gas field water in eastern Sichuan were studied by conventional water quality determination and GC-MS.The results show that the main components of gas field water in eastern Sichuan were chloride,COD Cr,SS,anionic surfactant,sulfide and other substances.The gas field water could be divided into two types according to the characteristics of water quality,of which one had high mineralization and high organic compounds,and the other had high sulfur and high organic compounds.There were 17 kinds of organic pollutants in the gas field water,mainly including alkanes,alcohols,esters and a small amount of acids.
基金The National Natural Science Foundation of China under contract No.41106071the National Basic Research(973Program)of China under contract No.2010CB428703+1 种基金the Key Project of Young Marine Science Foundation of State Oceanic Administration of China under contract No.2012503the Key Project of Fundamental Research Funds for the First Institute of Oceanography,State Oceanic Administration under contract Nos GY02-2011T01 and GY02-2013T05
文摘Based on the field data obtained during summer cruises in 2006, the overall perspective of chemical and hydrographic characteristics of the Yellow Sea Cold Water Mass (YSCWM) are discussed through the cross- YSCWM transect profiles and horizontal distributions of hydrological and chemical variables, with emphasis on the differences between the northern Yellow Sea Cold Water Mass (NYSCWM) and the southern Yellow Sea Cold Water Mass (SYSCWM). The results show that YSCWM is characterized by low temperature (〈10℃) and dissolved oxygen (DO) concentration, high salinity (〉32.0) and nutrient concentrations. Compared to the SYSCWM, the NYSCWM possesses lower values of temperature, salinity and nutrient concentrations but higher values of DO. Also its smaller variation ranges of variables (except for temperature) demonstrate that NYSCWM is more uniform than that of SYSCWM. In addition, thermocline is more intensive in the SYSCWM than that of NYSCWM. Furthermore, DO and Chl a maxima appear at the depth of 30 m in the SYSCWM, while these phenomena are not obvious in the NYSCWM.
基金National Natural Science Foundation of China(40875025,41175050,41275021,41475039,41475041,41575048)Public Sector(Meteorology)Research of China(GYHY201306012,GYHY201506007)
文摘The distribution of precipitation field from the typhoon Haitang(2005) during its landing on Fujian province shows obvious asymmetric feature.Based on the NCEP/NCAR FNL(Final Analysis) data,this study reveals the contributions of atmospheric factor to the asymmetrical distribution characteristics of precipitation associated with the typhoon,through the analysis of water vapor condition,vertical ascending motion condition,the calculation of the dry Q vector and its decomposition,and adiabatic heating in the air column of 1000hPa-600hPa(lower atmosphere) and500hPa-100hPa(upper atmosphere).The results are as follows:(1) In the lower atmosphere,the humidity on both sides of typhoon path can be equivalent,while it is more wet on the right side than left in the upper atmosphere,which obviously presents asymmetric distribution characteristics.(2) Both range and intensity of the vertical motion on the right side are wider and stronger than counterparts on the left side no matter in the lower or upper atmosphere.(3) In the upper atmosphere,forcing role of atmosphere in vertical upward motion on the right side of typhoon path is the same as that on the left,while it is significantly different in the lower atmosphere,which is significantly broader in scope and stronger in the intensity,along with obvious asymmetric distribution characteristics.In addition,the further analysis of the Q vector decomposition indicates that the forcing effect of mesoscale weather systems on vertical upward motion is stronger than that of large scale weather systems in the lower atmosphere.(4) The adiabatic heating always exists on both lower and upper atmosphere,and the range and intensity of the adiabatic heating forcing showed asymmetric distribution on both lower and upper atmosphere.(5) In a summary,the upper atmosphere humidity conditions,the forcing role of lower atmosphere in vertical upward motion,especially,to mesoscale weather system,and adiabatic heating in the lower atmosphere,all show similar asymmetric distribution characteristics to that of precipitation field from the typhoon Haitang(2005),that is to say,the atmospheric factors as mentioned above are all contributed to genesis of the asymmetric distribution characteristics of precipitation.
基金supported financially by the National Science and Technology Major Project"Chinese large gasfields’formation conditions,accumulation and objective evaluation"(2011ZX05007)the Major Special Project of Chinese Petroleum Development Technologies"A study on comprehensive supporting technologies for building oil-gas field of ten million tons in Qaidam basin"(2011E-03)
文摘The Paleogene and Neogene oil and gas in the western Qaidam basin have a regular distribution in three concentric zones from the edge to the center of the basin. Natural gas mainly occurs in the inner zone, and the gas-oil ratio of the northern area of the basin is significantly higher than that of the southern area. Large amounts of carbon isotope data of natural gas, plotted in X- shaped and comprehensive identification diagrams for the southern area and northern area, respectively, were used to identify the types of natural gas. The large-scale distribution of natural gas is highly consistent with the Ro values of major source rocks, but is poorly correlated with the type of organic matter. This indicates that the main controlling factor of natural gas distribution is organic matter maturity, and the kerogen types act as the basis for the formation of different types of natural gas. Paleouplifts and squeezed anticlines near hydrocarbon generation depression centers, which are major natural gas-rich regions, control the migration directions of natural gas, while hydrocarbon migration pathways and fault systems connecting gas sources are the most important factors for natural gas reservoir formation in the inner basin. Therefore, favorable zones for natural gas distribution can be predicted on the basis of the distribution of thermal evolution and the gas generation intensity of major source rocks as well as the structural map. The Shizigou-Youshashan- Yingdong-Dawusi, Youquanzi -Kaitemilike - Youdunzi, and Xiaoliangshan - Nanyishan - Dafengshan structural belts are favorable zones for natural gas accumulation. This study has important theoretical and practical significance for future natural gas exploration.
基金supported by the company’s scientific research project“Study on Prediction Method of Liquid Carrying Capacity of Shale Gas Well with High Liquid-Gas Ratio”(Project No.20220303-05).
文摘Theflow behavior of shale gas horizontal wells is relatively complex,and this should be regarded as the main reason for which conventional pipeflow models are not suitable to describe the related dynamics.In this study,numerical simulations have been conducted to determine the gas-liquid distribution in these wells.In particular,using the measuredflow pressure data related to 97 groups of shale gas wells as a basis,9 distinct pipeflow models have been assessed,and the models displaying a high calculation accuracy for different water-gas ratio(WGR)ranges have been identified.The results show that:(1)The variation law of WGR in gas well satisfies a power function relation.(2)The well structure is the main factor affecting the gas-liquid distribution in the wellbore.(3)The Beggs&Brill,Hagedorn&Brown and Gray models exhibit a high calculation accuracy.
基金co-funded by the National Science and Technology Major Project "Chinese large gas fields' formation conditions,accumulation and objective evaluation"(grant No.2016ZX05007)the Major Special Project of Chinese Petroleum Development Technologies "A study on comprehensive supporting technologies for building oil-gas field of ten million tons in Qaidam Basin"(grant No.2016E-0102)
文摘During the Pleistocene, the western Qaidam Basin has largely experienced strong structural reconstruction and strong erosion. First, the eroded thickness of Neogene strata was restored approximately by the stratigraphic profile comparison method and plane trend surface restoring method; then, accurate calculation of erosion was recovered using vitrinite reflectance, and the erosion that was restored by the trend surface restoring method was corrected; finally, a distribution map of cumulative erosion was produced. This study marks an important achievement in that one of the most important parameters of basin tectonic evolution, sedimentary evolution, and oil and gas accumulation history has been obtained, and that a basic geological problem has been solved in the Qaidam Basin. The areas with high erosion and low erosion are shown in the map and a close relation between the distribution of oil and gas fields and erosion was recognized. Large and medium oil and gas fields are mainly distributed in areas with medium and low erosion. It is difficult to form large-scale oil and gas accumulation in areas in which erosion is more than 2000 m. The mechanism of the relation between oil and gas distribution and erosion is explained. This study will be of use in predicting the distribution of oil and gas.
文摘This study analyzes the spatial and temporal distribution characteristics of seasonal precipitable water vapor (PWV) in China between 1979 and 2008. To achieve this, the observed temperature dew point difference and atmospheric pressure at various altitudes of 102 radiosonde stations were utilized. The analysis involved calculating and examining the PWV variations across the different seasons in the study period. The results are illustrated as follows: 1) The annual mean and seasonal mean PWV over China is characterized by decreasing from southeast to northwest. The PWV has obvious seasonal features. It is the least in winter, which is mainly affected by latitude and altitude, and the most in summer, which is mainly affected by the monsoon. It is the medium in spring and autumn, with more in autumn than in spring. 2) The spatial distribution pattern of four seasonal PWV is approximately opposite to its variation coefficient distribution pattern, that is, the monsoon (non-monsoon) areas with more (less) PWV have a smaller (larger) variation amplitude. 3) The distribution pattern of four seasonal PWV shows a consistent distribution pattern in the whole region and the winter characteristics are the most significant. The abnormal variation of PWV shows consistent interdecadal oscillation, and it exhibits an obvious phase transition around 2002 when the PWV has an increasing shift in winter, spring, and summer, while it is more complicated in autumn.
基金Funded by the Natural Science Foundation of China (No. 50775081)the National High-tech R&D (863) Program No. 2006AA09Z238)the NCET-07-0330, State Education Ministry.
文摘The shapes and geometrical parameters of nozzles are key factors for fluidics. The relationship among the reaction thrust,flow rate pressure,diameter d0 and length L of a cylinder nozzle is analyzed theoretically. The simulation of the flow field characteristics was conducted via the FLUENT computational fluid dynamics package. Effects of the inlet conditions and the nozzle dimensions on the reaction thrust of a water jet were addressed particularly. The reaction thrust experiments were performed on a custom-designed test apparatus. The experimental results reveal that a) the nozzle diameter and the inlet conditions exert great influence on the water jet reaction thrust; and b) for L≤4d0,where the nozzle is treated as a thin plate-orifice,the reaction thrust is independent of nozzle length; for L>4d0,where the nozzle is treated as a long orifice,the reaction thrust can reach maximum under the condition of a certain flow rate. These findings lay a theoretical foundation for the design of nozzles and have significant value,especially for the future development of high-pressure water-jet propulsion technology.
基金Financial support for this study was kindly provided by the National Natural Science Foundation Project of China(5217-4202)Young Elite Scientists Sponsorship Program of China Association for Science,and Technology(2021QNRC001).
文摘This study aimed to investigate the mechanism of mineral spontaneous combustion in an open pit. On the study of coal and mineral mixture in open pit mines, as well as through the specifc surface area and Search Engine Marketing (SEM) experiments, the specifc surface area and aperture characteristics of distribution of open pit coal sample and pit mineral mixture samples were analyzed. Thermal analysis experiments were used to divide the oxidation process was divided into three stages, and the thermal behavior characteristics of experimental samples were characterized. On the basis of the stage division, we explored the transfer law of the key active functional groups of the experimental samples. The apparent activation energy calculation of the key active groups, performed by combining the Achar diferential method with the Coats–Redfern integral method, microstructural and oxidation kinetic properties were revealed. The resulted showed that the mixed sample had high ash, the fxed carbon content was reduced, the specifc surface area was far lower than the raw coal, the large aperture distribution was slightly higher than the medium hole, the micropore was exceptionally low, the gas adsorption capacity was weaker than the raw coal, the pit coal sample had the exceedingly more active functional groups, easy to react with oxygen, more likely to occur naturally, and its harm was relatively large. The mixed sample contained the highest C–O–C functional group absorbance. The functional groups were mainly infuenced by the self-OH content, alkyl side chain, and fatty hydrocarbon in the sample. The main functional groups of the four-like mixture had the highest apparent activation energy, and the two reactions were higher in the low-temperature oxidation phase.
基金Foundation item: Supported by the National Natural Science Foundation of China (11172241), and Northwestern Polytechnical University Foundation for Fundamental Research. (NPU-FFR- 1015)