A new kind of bittern-resisting cement (BRC) was introduced. This material is based on the ternary cementitious system of clinker containing C4A3 S phase, high-activity ground granulated blast-furnace slag (GGBFS)...A new kind of bittern-resisting cement (BRC) was introduced. This material is based on the ternary cementitious system of clinker containing C4A3 S phase, high-activity ground granulated blast-furnace slag (GGBFS) and fly ash (FA). The hydration process and the hydrated products of BRC were studied by means of XRD, TG-DTA and SEM, and the resistance to chemical attack of BRC in high-bittern environment was also examined. The corrosion experiment in seven kinds of brines proved that BRC exhibits an excellent resistance to chemical attack of bittern. The corrosion resistance factors were calculated and all of them were greater than 0.96. It showed that BRC totally controls the cement-based material corrosion in brines from four aspects: (1) making full use of the dominant complementation effect of mineral materials; (2) diminishing the hydrated products easy to be attacked; (3) improving the microstructure of hardened cement mortar; (4) degrading the chemical attack of bittern.展开更多
ZrO2 -containing refractories have been increasingly used for cement rotary kilns. This paper discusses how the properties and performance of ZrO2-containing refractories are improved in terms of chemical attack resis...ZrO2 -containing refractories have been increasingly used for cement rotary kilns. This paper discusses how the properties and performance of ZrO2-containing refractories are improved in terms of chemical attack resistance, thermal shock resistance , thermal conductivity and mechanical stress.展开更多
基金This work was financially supported by the Key Scientific and Technological Project of Qinghai Province (No.2002-G-103)
文摘A new kind of bittern-resisting cement (BRC) was introduced. This material is based on the ternary cementitious system of clinker containing C4A3 S phase, high-activity ground granulated blast-furnace slag (GGBFS) and fly ash (FA). The hydration process and the hydrated products of BRC were studied by means of XRD, TG-DTA and SEM, and the resistance to chemical attack of BRC in high-bittern environment was also examined. The corrosion experiment in seven kinds of brines proved that BRC exhibits an excellent resistance to chemical attack of bittern. The corrosion resistance factors were calculated and all of them were greater than 0.96. It showed that BRC totally controls the cement-based material corrosion in brines from four aspects: (1) making full use of the dominant complementation effect of mineral materials; (2) diminishing the hydrated products easy to be attacked; (3) improving the microstructure of hardened cement mortar; (4) degrading the chemical attack of bittern.
文摘ZrO2 -containing refractories have been increasingly used for cement rotary kilns. This paper discusses how the properties and performance of ZrO2-containing refractories are improved in terms of chemical attack resistance, thermal shock resistance , thermal conductivity and mechanical stress.