The importance of oxygen non-stoichiometry induced expansion, known as chemical expansion, for the mechanical properties of solid oxide fuel cells (SOFCs) is discussed. The methods used to measure chemical expansion...The importance of oxygen non-stoichiometry induced expansion, known as chemical expansion, for the mechanical properties of solid oxide fuel cells (SOFCs) is discussed. The methods used to measure chemical expansion and the defects responsible for its existence are introduced. Recent work demonstrating the origin of chemical expansion in fluorite structured oxides for SOFCs is presented. Models used to predict stress induced by chemical expansion in SOFCs, highlighting the necessity of considering electro-chemo-mechanical coupling relationships, are discussed.展开更多
In the present study,the chemical and mechanical properties and the thermal expansion of a carbon nanotube(CNT)-based crystalline nano-aluminum(nano Al) composite were reported.The properties of nanocomposites wer...In the present study,the chemical and mechanical properties and the thermal expansion of a carbon nanotube(CNT)-based crystalline nano-aluminum(nano Al) composite were reported.The properties of nanocomposites were tailored by incorporating CNTs into the nano Al matrix using a physical mixing method.The elastic moduli and the coefficient of thermal expansion(CTE) of the nanocomposites were also estimated to understand the effects of CNT reinforcement in the Al matrix.Microstructural characterization of the nanocomposite reveals that the CNTs are dispersed and embedded in the Al matrix.The experimental results indicate that the incorporation of CNTs into the nano Al matrix results in the increase in hardness and elastic modulus along with a concomitant decrease in the coefficient of thermal expansion The hardness and elastic modulus of the nanocomposite increase by 21%and 20%,respectively,upon CNT addition.The CTE of CNT/A1 nanocomposite decreases to 70%compared with that of nano Al.展开更多
BASF and Sinopec began the construction for the expansion of their joint venture,BASF-YPC Co.,Ltd. (BYC). BASF and Sinopec plan to jointly invest approximately $1.4 billion
基金support from I2CNER, supported by the World Premier International Research Center Initiative (WPI), MEXT, Japan
文摘The importance of oxygen non-stoichiometry induced expansion, known as chemical expansion, for the mechanical properties of solid oxide fuel cells (SOFCs) is discussed. The methods used to measure chemical expansion and the defects responsible for its existence are introduced. Recent work demonstrating the origin of chemical expansion in fluorite structured oxides for SOFCs is presented. Models used to predict stress induced by chemical expansion in SOFCs, highlighting the necessity of considering electro-chemo-mechanical coupling relationships, are discussed.
基金supported by the Defence Research and Development Organization, New Delhi (No.ARMREB/CDSW/2011/135)
文摘In the present study,the chemical and mechanical properties and the thermal expansion of a carbon nanotube(CNT)-based crystalline nano-aluminum(nano Al) composite were reported.The properties of nanocomposites were tailored by incorporating CNTs into the nano Al matrix using a physical mixing method.The elastic moduli and the coefficient of thermal expansion(CTE) of the nanocomposites were also estimated to understand the effects of CNT reinforcement in the Al matrix.Microstructural characterization of the nanocomposite reveals that the CNTs are dispersed and embedded in the Al matrix.The experimental results indicate that the incorporation of CNTs into the nano Al matrix results in the increase in hardness and elastic modulus along with a concomitant decrease in the coefficient of thermal expansion The hardness and elastic modulus of the nanocomposite increase by 21%and 20%,respectively,upon CNT addition.The CTE of CNT/A1 nanocomposite decreases to 70%compared with that of nano Al.
文摘BASF and Sinopec began the construction for the expansion of their joint venture,BASF-YPC Co.,Ltd. (BYC). BASF and Sinopec plan to jointly invest approximately $1.4 billion