The major,trace,and rare earth elements of the Duanjiapo(DJP)section in the south of the Loess Plateau,the Jiaxian(JX)section in the north,and the Jiuzhoutai(JZT)section in the west are studied.The results show that t...The major,trace,and rare earth elements of the Duanjiapo(DJP)section in the south of the Loess Plateau,the Jiaxian(JX)section in the north,and the Jiuzhoutai(JZT)section in the west are studied.The results show that the main elemental characteristics of loess in three profiles are consistent with the upper continental crust(UCC).In terms of trace elements,Th,Nb,Zr,Hf,Y,Cs,W,Cr,V,Li,and Pb show relative enrichment compared with UCC;Rb,Ba,Sr and Be exhibit relative depletion.The average ofΣREE is 171.91ppm with a negative anomaly forδEu and essentially no anomaly forδCe.The results of K_(2)O/Na_(2)O,Rb/Sr ratios,as well as the leaching co-efficient from three profiles,indicate DJP>JX>JZT,suggesting that DJP experiences the strongest weathering leaching effect.The chemical index of alteration(CIA)reveals that all three profiles of loess are in the primary stage of Ca and Na depletion.DJP is generally in the early to moderate stage of chemical weathering,while JX and JZT are both in the early stage.展开更多
随着光伏产业和新能源汽车产业的蓬勃发展,国内外锂资源需求持续增加,黏土型锂矿逐渐成为矿产勘查的重点。经地质调查,南漳县西部梁山组黏土岩存在锂的超常富集现象,具备形成独立锂矿床的潜力,而梁山组富锂黏土岩物源特征、沉积环境和...随着光伏产业和新能源汽车产业的蓬勃发展,国内外锂资源需求持续增加,黏土型锂矿逐渐成为矿产勘查的重点。经地质调查,南漳县西部梁山组黏土岩存在锂的超常富集现象,具备形成独立锂矿床的潜力,而梁山组富锂黏土岩物源特征、沉积环境和成矿规律的研究仍为空白。因此,有必要研究南漳县西部梁山组富锂黏土岩物源特征,以进一步揭示其源区地质特征,为后续找矿工作提供有效指导。经测定,南漳县西部梁山组富锂黏土岩样品Al_(2)O_(3)/TiO_(2)比值为14.45~37.69,平均值为27.68;K_(2)O/Al_(2)O_(3)比值为0.0017~0.0206,平均值为0.0098;Cr/Zr比值为0.1449~0.3519,平均值为0.2775。结果表明,黏土岩物源区主要为长英质岩石。La/Sc-Th/Co图解、Zr-TiO_(2)图解中,所有样品点均落在长英质物源区,显示物源的单一性。大多数样品的化学蚀变指数(Chemical Index of Alteration,CIA)、化学风化指数(Chemical Index of Weathering,CIW)均在90以上,说明源岩经历强烈化学风化作用。展开更多
对岩石风化强度反应敏感的化学风化指标是定量评价岩石风化程度的重要参数。评述了包括帕克风化指数(weathering index of Parker,WIP)、风化势能指数(weathering potential index,WPI)、化学蚀变指数(chemical index of alteration,CIA...对岩石风化强度反应敏感的化学风化指标是定量评价岩石风化程度的重要参数。评述了包括帕克风化指数(weathering index of Parker,WIP)、风化势能指数(weathering potential index,WPI)、化学蚀变指数(chemical index of alteration,CIA)等12种在以往研究中被认为适合用于岩浆岩风化程度判定的化学风化指标的优点及其局限性。引入了岩石氧化因数X_(o)(X_(o)=Fe_(2)O_(3)/(FeO+Fe_(2)O_(3)))评价火山岩的风化程度,并使用该指标评价了12种化学风化指标在评价超基性岩和基性岩风化中的适用性。在黔西晚二叠世超基性岩和基性玄武岩的实际应用中,将X_(o)≤0.44和X_(o)≤0.55作为超基性岩和基性玄武岩未遭受风化的下限,结合定性分析结果,按风化程度将两种岩石分为新鲜岩石、微风化岩石、中风化岩石、强风化岩石和全风化岩石。X_(o)与12种化学风化指标散点交会的结果显示:BWI、A-FM、LOI这3种指标既适合于风化初期超基性岩和基性玄武岩风化程度的评价,也适合风化中后期超基性岩和基性玄武岩风化程度的评价,其余9种指标仅对风化中后期超基性岩和基性玄武岩的风化程度反应敏感。研究可为超基性岩和基性玄武岩岩质区的工程地质调查与勘察、潜在地质灾害评价、地质灾害隐患防治等提供新思路、新方法,对相似岩质区的岩体风化程度评价研究提供参考。展开更多
The Niutitang Formation in the South China Block might be a source of hydrocarbon as it contains an enormous quantity of organic matter.Black rock of the Early Cambrian Niutitang Formation is widely distributed in the...The Niutitang Formation in the South China Block might be a source of hydrocarbon as it contains an enormous quantity of organic matter.Black rock of the Early Cambrian Niutitang Formation is widely distributed in the Yangtze region,but detailed geochemical understanding of it is still emerging.This research discusses the detailed geochemical characteristics of the Niutitang Formation to reconstruct the paleoenvironmental conditions,employing total organic carbon(TOC)content,major,trace,and rare earth element data.For this purpose,black rock specimens of the Niutitang Formation from two outcrop sections were utilized for geochemical characterization,and the results compared with another eight sections from the South China Block.The average total organic carbon in these sediments is significantly higher(5.80 wt.%).In the platform region,lower quantities of TOC indicate a poor potential to produce hydrocarbons.At the same time,significantly higher TOC is observed in the deep shelf and slope sediments,indicating a significant potential to produce hydrocarbons.The average Ce,Eu and Y anomalies from both Longbizui and Sancha sections studied are 0.74,0.86,1.77,1.07,and 1.19,1.30,respectively.The chemical index of alteration(CAI)throughout the Yangtze block is higher(averaging 71.32)than that of Post Archean Australian Shale(PAAS 69),indicating a moderately weathered source of the Niutitang Formation relative to PAAS.As the sediments are moderately weathered,this suggests these rocks might have been derived from felsic rocks,mainly granite-granodiorite.The normalization of REEs in the black rocks reveals a reduction of light REEs with increase in heavy REEs enrichment.Similarly,a positive Eu anomaly,negative Ce anomaly,and a moderate Y/Ho(34.61)are clues to a hybrid depositional mechanism associated with hydrothermal action and terrigenous input.These anomalies are also evidence of upwelling in the paleo-ocean and mixing of organic matter,which created anoxic bottom water during the deposition of the Niutitang Formation in the basin and upper oxic water conditions before deposition.The main controlling factors for the distribution of rare earth elements in these black rocks of the Niutitang Formation are pH,terrigenous input,source rock composition,tectonism,an upwelling mechanism,and hydrothermal activity.展开更多
化学蚀变指数（chemical index of alteration）（CIA）最早作为判别源岩化学风化程度而提出，随后又应用于对沉积物沉积环境的判定。化学蚀变指数的表达式为CIA={n（Al2O3）／[n（Al2O3）＋n（CaO^＊）＋n（Na2O）＋n（K2O）]}×10...化学蚀变指数（chemical index of alteration）（CIA）最早作为判别源岩化学风化程度而提出，随后又应用于对沉积物沉积环境的判定。化学蚀变指数的表达式为CIA={n（Al2O3）／[n（Al2O3）＋n（CaO^＊）＋n（Na2O）＋n（K2O）]}×100。CaO^＊代表硅酸盐中的CaO，n（CaO^＊）=n（CaO）-n（CO2方解石）-n0．5×n（CO2白云石）-10／3xn（P2O5）。化学蚀变指数样品的选取极为重要，最佳岩性为细碎屑岩，并需清除成岩过程中钾交代作用的影响，以及采用成分变异指数（ICV）来判别沉积再循环作用和沉积物成分被改造的程度。使用A—CN—K三角图解判别物源区的源岩性质和样品钾交代的程度及其风化趋势。黔南-桂北地区南华系的CIA研究表明：该地区南华系下部的长安组其下部CIA值为60～65之间，中部为70～5，上部回落到65—70之间。南华系中部富禄组CIA值高，在85-95之间。南华系上部的南沱组CIA值再次回落到60—65的范围。上述CIA值的变化表明本区南华纪时期自老至新经历多次由干燥寒冷-温暖潮湿气候期的变化。本文据此提出扬子地块南华系新的划分、对比方案。展开更多
基金the National Natural Science Foundation of China(No.41561001,42271007).
文摘The major,trace,and rare earth elements of the Duanjiapo(DJP)section in the south of the Loess Plateau,the Jiaxian(JX)section in the north,and the Jiuzhoutai(JZT)section in the west are studied.The results show that the main elemental characteristics of loess in three profiles are consistent with the upper continental crust(UCC).In terms of trace elements,Th,Nb,Zr,Hf,Y,Cs,W,Cr,V,Li,and Pb show relative enrichment compared with UCC;Rb,Ba,Sr and Be exhibit relative depletion.The average ofΣREE is 171.91ppm with a negative anomaly forδEu and essentially no anomaly forδCe.The results of K_(2)O/Na_(2)O,Rb/Sr ratios,as well as the leaching co-efficient from three profiles,indicate DJP>JX>JZT,suggesting that DJP experiences the strongest weathering leaching effect.The chemical index of alteration(CIA)reveals that all three profiles of loess are in the primary stage of Ca and Na depletion.DJP is generally in the early to moderate stage of chemical weathering,while JX and JZT are both in the early stage.
文摘随着光伏产业和新能源汽车产业的蓬勃发展,国内外锂资源需求持续增加,黏土型锂矿逐渐成为矿产勘查的重点。经地质调查,南漳县西部梁山组黏土岩存在锂的超常富集现象,具备形成独立锂矿床的潜力,而梁山组富锂黏土岩物源特征、沉积环境和成矿规律的研究仍为空白。因此,有必要研究南漳县西部梁山组富锂黏土岩物源特征,以进一步揭示其源区地质特征,为后续找矿工作提供有效指导。经测定,南漳县西部梁山组富锂黏土岩样品Al_(2)O_(3)/TiO_(2)比值为14.45~37.69,平均值为27.68;K_(2)O/Al_(2)O_(3)比值为0.0017~0.0206,平均值为0.0098;Cr/Zr比值为0.1449~0.3519,平均值为0.2775。结果表明,黏土岩物源区主要为长英质岩石。La/Sc-Th/Co图解、Zr-TiO_(2)图解中,所有样品点均落在长英质物源区,显示物源的单一性。大多数样品的化学蚀变指数(Chemical Index of Alteration,CIA)、化学风化指数(Chemical Index of Weathering,CIW)均在90以上,说明源岩经历强烈化学风化作用。
文摘对岩石风化强度反应敏感的化学风化指标是定量评价岩石风化程度的重要参数。评述了包括帕克风化指数(weathering index of Parker,WIP)、风化势能指数(weathering potential index,WPI)、化学蚀变指数(chemical index of alteration,CIA)等12种在以往研究中被认为适合用于岩浆岩风化程度判定的化学风化指标的优点及其局限性。引入了岩石氧化因数X_(o)(X_(o)=Fe_(2)O_(3)/(FeO+Fe_(2)O_(3)))评价火山岩的风化程度,并使用该指标评价了12种化学风化指标在评价超基性岩和基性岩风化中的适用性。在黔西晚二叠世超基性岩和基性玄武岩的实际应用中,将X_(o)≤0.44和X_(o)≤0.55作为超基性岩和基性玄武岩未遭受风化的下限,结合定性分析结果,按风化程度将两种岩石分为新鲜岩石、微风化岩石、中风化岩石、强风化岩石和全风化岩石。X_(o)与12种化学风化指标散点交会的结果显示:BWI、A-FM、LOI这3种指标既适合于风化初期超基性岩和基性玄武岩风化程度的评价,也适合风化中后期超基性岩和基性玄武岩风化程度的评价,其余9种指标仅对风化中后期超基性岩和基性玄武岩的风化程度反应敏感。研究可为超基性岩和基性玄武岩岩质区的工程地质调查与勘察、潜在地质灾害评价、地质灾害隐患防治等提供新思路、新方法,对相似岩质区的岩体风化程度评价研究提供参考。
基金supported by the National Natural Science Foundation of China(Nos.41572099 and 41872127).
文摘The Niutitang Formation in the South China Block might be a source of hydrocarbon as it contains an enormous quantity of organic matter.Black rock of the Early Cambrian Niutitang Formation is widely distributed in the Yangtze region,but detailed geochemical understanding of it is still emerging.This research discusses the detailed geochemical characteristics of the Niutitang Formation to reconstruct the paleoenvironmental conditions,employing total organic carbon(TOC)content,major,trace,and rare earth element data.For this purpose,black rock specimens of the Niutitang Formation from two outcrop sections were utilized for geochemical characterization,and the results compared with another eight sections from the South China Block.The average total organic carbon in these sediments is significantly higher(5.80 wt.%).In the platform region,lower quantities of TOC indicate a poor potential to produce hydrocarbons.At the same time,significantly higher TOC is observed in the deep shelf and slope sediments,indicating a significant potential to produce hydrocarbons.The average Ce,Eu and Y anomalies from both Longbizui and Sancha sections studied are 0.74,0.86,1.77,1.07,and 1.19,1.30,respectively.The chemical index of alteration(CAI)throughout the Yangtze block is higher(averaging 71.32)than that of Post Archean Australian Shale(PAAS 69),indicating a moderately weathered source of the Niutitang Formation relative to PAAS.As the sediments are moderately weathered,this suggests these rocks might have been derived from felsic rocks,mainly granite-granodiorite.The normalization of REEs in the black rocks reveals a reduction of light REEs with increase in heavy REEs enrichment.Similarly,a positive Eu anomaly,negative Ce anomaly,and a moderate Y/Ho(34.61)are clues to a hybrid depositional mechanism associated with hydrothermal action and terrigenous input.These anomalies are also evidence of upwelling in the paleo-ocean and mixing of organic matter,which created anoxic bottom water during the deposition of the Niutitang Formation in the basin and upper oxic water conditions before deposition.The main controlling factors for the distribution of rare earth elements in these black rocks of the Niutitang Formation are pH,terrigenous input,source rock composition,tectonism,an upwelling mechanism,and hydrothermal activity.
文摘化学蚀变指数（chemical index of alteration）（CIA）最早作为判别源岩化学风化程度而提出，随后又应用于对沉积物沉积环境的判定。化学蚀变指数的表达式为CIA={n（Al2O3）／[n（Al2O3）＋n（CaO^＊）＋n（Na2O）＋n（K2O）]}×100。CaO^＊代表硅酸盐中的CaO，n（CaO^＊）=n（CaO）-n（CO2方解石）-n0．5×n（CO2白云石）-10／3xn（P2O5）。化学蚀变指数样品的选取极为重要，最佳岩性为细碎屑岩，并需清除成岩过程中钾交代作用的影响，以及采用成分变异指数（ICV）来判别沉积再循环作用和沉积物成分被改造的程度。使用A—CN—K三角图解判别物源区的源岩性质和样品钾交代的程度及其风化趋势。黔南-桂北地区南华系的CIA研究表明：该地区南华系下部的长安组其下部CIA值为60～65之间，中部为70～5，上部回落到65—70之间。南华系中部富禄组CIA值高，在85-95之间。南华系上部的南沱组CIA值再次回落到60—65的范围。上述CIA值的变化表明本区南华纪时期自老至新经历多次由干燥寒冷-温暖潮湿气候期的变化。本文据此提出扬子地块南华系新的划分、对比方案。
