The structures and catalytic performances of V_2O_5, Mg_3V_2O_8 and V/MgO catalysts have been correlated by means of XRD, FTIR, TPR and flow micro-reactor tests. The postulation about active site has been made. Based ...The structures and catalytic performances of V_2O_5, Mg_3V_2O_8 and V/MgO catalysts have been correlated by means of XRD, FTIR, TPR and flow micro-reactor tests. The postulation about active site has been made. Based on it, better catalysts have been first prepared via grafting and modification with Sb which are better than that via impregnation.展开更多
An iron（Ⅲ）-catalyzed selective oxidation of 5-HMF to 2,5-DFF in air at room temperature was developed.This approach gives 2,5-DFF with good selectivity and yields. Additionally, a two-step process was developed for...An iron（Ⅲ）-catalyzed selective oxidation of 5-HMF to 2,5-DFF in air at room temperature was developed.This approach gives 2,5-DFF with good selectivity and yields. Additionally, a two-step process was developed for the oxidation of 2,5-DFF to 2,5-FDCA at remarkably high substrate concentrations. This work demonstrates unequivocally the great potential of iron as a cheap and earth-abundant catalyst for the development of new protocols for the conversion of biomass to value-added chemicals.展开更多
文摘The structures and catalytic performances of V_2O_5, Mg_3V_2O_8 and V/MgO catalysts have been correlated by means of XRD, FTIR, TPR and flow micro-reactor tests. The postulation about active site has been made. Based on it, better catalysts have been first prepared via grafting and modification with Sb which are better than that via impregnation.
基金the National Basic Research Program of China (Nos. 2013CB228103, 2012CB215306)NNSFC (Nos. 21472033, 21325208, 21172209)+3 种基金FRFCU (No. WK2060190025)SRFDP (No. 20123402130008)CAS (No. KJCX2-EW-J02)Fok Ying Tung Education Foundation for the financial support
文摘An iron（Ⅲ）-catalyzed selective oxidation of 5-HMF to 2,5-DFF in air at room temperature was developed.This approach gives 2,5-DFF with good selectivity and yields. Additionally, a two-step process was developed for the oxidation of 2,5-DFF to 2,5-FDCA at remarkably high substrate concentrations. This work demonstrates unequivocally the great potential of iron as a cheap and earth-abundant catalyst for the development of new protocols for the conversion of biomass to value-added chemicals.
