A general solution for one dimensional chemo-mechanical coupled hydrogel rod

Smart hydrogels are environmentally sensitive hydrogels, which can produce a sensitive response to external stimuli, and often exhibit the characteristics of multi filed coupling. In this paper, a hydrogel rod under chemomechanical coupling was analytically studied based on a poroelastical model. The already known constitutive and governing equations were simplified into the one dimensional case, then two different boundary conditions were considered. The expressions of concentration, displacement,chemical potential and stress related to time were obtained in a series form. Examples illustrate the interaction mechanism of chemical and mechanical effect. It was found that there was a balance state in the diffusion of concentration and the diffusion process could lead to the expansion or the stress change of the hydrogel rod.

The Influence of Entanglements of Net Chains on Phase Transition Temperature of Sensitive Hydrogels in Chemo-Mechanical Coupled Fields

Phase transition of hydrogel,which is polymerized by polymer network,can be regarded as the transition of polymer network stability.The stability of the polymer network might be changed when the external environment changed.This change will lead to the transformation of sensitive hydrogels stability,thus phase transition of hydrogel take place.Here,we present a new free density energy function,which considers the non-gaussianity of the polymer network,chains entanglement and functionality of junctions through adding Gent hyplastic model and Edwards-Vilgis slip-link model to Flory-Huggins theory.A program to calculate the phase transition temperature was written based on new free energy function.Taking PNIPAM hydrogel as an example,the effects of network entanglement on the phase transition temperature of hydrogel were studied by analyzing the microstructure parameters of the hydrogel networks.Analytical results suggest a significant relationship between phase transition temperature and entanglement network.

A Finite Element Procedure for Analysis of Chemo-Mechanical Coupling Behavior of Hydrogels

Chemo-mechanical coupling behavior of materials is a transformation process between mechanical and chemical energy.In this paper,based on the coupled chemo-mechanical constitutive equations and governing equations during isothermal process,the equivalent integral forms of chemo-mechanical coupling governing equations and corresponding finite element procedure are obtained by using Hamilton’s principle.An isoparametric plane element for chemo-mechanical coupling is associated into ABAQUS finite element package through user element subroutine UEL.The numerical examples exhibit that the ionic concentration variation can cause mechanical deformation and mechanical action can produce redistribution of ionic concentration for hydrogels.It is proved that the present developed chemo-mechanical coupling finite element procedure can be utilized to model the coupling behavior of hydrogels effectively.

Influence of Coupled Chemo-Mechanical Process on Corrosion Characteristics in Reinforcing Bars

We studied the corrosion characteristics of reinforcing bars in concrete under different corrosion conditions. The area-box （AB） value was used to classify the shape of pitting corrosion morphology in meso-scale, and fractographs of reinforcing bars with different corrosion morphology were discussed in micro- and macro-scales. The results show that the existence of the tensile stress affects the corrosion characteristics of reinforcing bars. The pitting morphology and fractograph of reinforcing bars exhibit a statistical fractal feature. The linear regression model fits the relationship between fractal dimensions of corrosion morphology and fractal dimension of fractograph fairly well. Using fractal dimension as the characterization parameter can not only reflect the characteristics of pitting corrosion morphology in reinforcing bars, but also reveal the fracture feature of corroded reinforcing bars.

Theory and Calculation of the J-Integral for Coupled Chemo-Mechanical Fracture Mechanics

In this paper,by introducing a chemical field,the J-integral formulation is presented for the chemo-mechanical coupled medium based on the laws of thermodynamics.A finite element implementation of the J-integral was performed to study the mode I chemo-mechanical coupled fracture problem.For derivation of the coupled J-integral,the equivalent domain integral(EDI)method was applied to obtain the mode I J-integral,with expression of the area integrals based on constitutive relationships of a linear elastic small deformation for chemo-mechanical coupling,instead of the finite deformation problem.A finite element procedure is developed to compute the mode I J-integral,and numerical simulation of the y-direction stress field is studied by a subroutine UEL(User defined element)developed in ABAQUS software.Accuracy of the numerical results obtained using the mode I J-integral was verified by comparing them to a well-established model based on linear elastic fracture mechanics(LEFM).Furthermore,a numerical example was presented to illustrate path-independence of the formulated J-integral for a chemo-mechanical coupled specimen under different boundary conditions,showing a high accuracy and reliability of the present method.The variation laws of J-integral and the y-direction stress field with external chemical,mechanical loading and time are revealed.The J-integral value increases with larger external concentration loading in the same integral domain.The extent of diffusion is much greater with larger concentration,which leads to a stronger coupling effect due to the chemical field.This work provides new insights into the fracture mechanics for the chemo-mechanical coupled medium.

Comparison of the interface reaction behaviors of CaO–V_(2)O_(5) and MnO_(2)–V_(2)O_(5) solid-state systems based on the diffusion couple method

The formation mechanism of calcium vanadate and manganese vanadate and the difference between calcium and manganese in the reaction with vanadium are basic issues in the calcification roasting and manganese roasting process with vanadium slag.In this work,CaO–V_(2)O_(5) and MnO_(2)–V_(2)O_(5) diffusion couples were prepared and roasted for different time periods to illustrate and compare the diffusion reaction mechanisms.Then,the changes in the diffusion product and diffusion coefficient were investigated and calculated based on scanning electron microscopy (SEM) with energy dispersive X-ray spectroscopy (EDS) analysis.Results show that with the extension of the roasting time,the diffusion reaction gradually proceeds among the CaO–V_(2)O_(5) and MnO_(2)–V_(2)O_(5) diffusion couples.The regional boundaries of calcium and vanadium are easily identifiable for the CaO–V_(2)O_(5) diffusion couple.Meanwhile,for the MnO_(2)–V_(2)O_(5) diffusion couple,MnO_(2) gradually decomposes to form Mn_(2)O_(3),and vanadium diffuses into the interior of Mn_(2)O_(3).Only a part of vanadium combines with manganese to form the diffusion production layer.CaV_(2)O_(6) and MnV_(2)O_(6) are the interfacial reaction products of the CaO–V_(2)O_(5) and MnO_(2)–V_(2)O_(5) diffusion couples,respectively,whose thicknesses are 39.85 and 32.13μm when roasted for 16 h.After 16 h,both diffusion couples reach the reaction equilibrium due to the limitation of diffusion.The diffusion coefficient of the CaO–V_(2)O_(5) diffusion couple is higher than that of the MnO_(2)–V_(2)O_(5) diffusion couple for the same roasting time,and the diffusion reaction between vanadium and calcium is easier than that between vanadium and manganese.

Modeling and Simulation of a Transmission Line Response to a 400 kV/400V Capacitor Coupled Substation

The access to electricity in rural areas is extremely limited, but it is crucial for all citizens. The population in rural areas of sub-Saharan African (SSA) countries is generally low, making it economically unfeasible to implement traditional rural electrification (CRE) projects due to the high cost of establishing the necessary distribution infrastructure. To address this cost issue, one alternative technology for rural electrification (URE) that can be explored is the Capacitor Coupled Substation (CCS) technology. CCS is a cost-effective solution for supplying electricity to rural areas. The research is necessitated by the need to offer a cost-effective technology for supplying electricity to sparsely populated communities. This paper examines the impact on the transmission network when a 400 kV/400V CCS is connected to it. The system response when a CCS is connected to the network was modeled using MATLAB/Si-mulink. The results, based on the fixed load of 80 kW, showed negligible interference on the transmission line voltage. However, there was minor impact on the parameters downstream of the tapping point. These findings were further supported by introducing a fault condition to the CCS, which showed that interferences with the CCS could affect the overall stability of the transmission network downstream of the tapping node, similar to the behavior of an unstable load.

Analytical evaluation of steady-state solute distribution in through- diffusion and membrane behavior test under non-perfectly flushing boundary conditions

The through-diffusion and membrane behavior testing procedure using a closed-system apparatus has been widely used for concurrent measurement of diffusion and membrane efficiency coefficients of low-permeability clay-based barrier materials.However,the common assumption of perfectly flushing conditions at the specimen boundaries could induce errors in analyses of the diffusion coefficients and membrane efficiencies.In this study,an innovative pseudo three-dimensional(3D)analytical method was proposed to evaluate solute distribution along the boundary surfaces of the soil-porous disks system,considering the non-perfectly flushing conditions.The results were consistent with numerical models under two scenarios considering different inflow/outflow positions.The proposed model has been demonstrated to be an accurate and reliable method to estimate solute distributions along the bound-aries.The calculated membrane efficiency coefficient and diffusion coefficient based on the proposed analytical method are more accurate,resulting in up to 50%less relative error than the traditional approach that adopts the arithmetic mean value of the influent and effluent concentrations.The retar-dation factor of the clay specimen also can be calculated with a revised cumulative mass approach.Finally,the simulated transient solute transport matched with experimental data from a multi-stage through-diffusion and membrane behavior test,validating the accuracy of the proposed method.

Evaluation of Large Amplitude Free Vibration Behavior of Moderately Thick Square Plates Using Coupled Displacememt Field Method

A simple and efficient coupled displacement field method is developed to study the large amplitude free vibration behavior of the moderately thick square plates.A single term trigonometric admissible displacement field is assumed for one of the variables,say,the total rotations(in both X,Y directions).Making use of the coupling equation,the spatial variation for the lateral displacement field is derived in terms of the total rotations.The coupled displacement field method makes the energy formulation to contain half the number of unknown independent coefficients,in the case of a square plate,contrary to the conventional RayleighRitz method.The lesser number of undetermined coefficients significantly simplifies the vibration problem.The expressions for the linear and nonlinear fundamental frequency parameters for the all edges simply supported moderately thick square plates are derived.The numerical results obtained from the present formulation are in very good agreement with those obtained from the existing literature.

Experimental and numerical study on dynamic mechanical behaviors of shale under true triaxial compression at high strain rate

High-energy gas fracturing of shale is a novel,high efficacy and eco-friendly mining technique,which is a typical dynamic perturbing behavior.To effectively extract shale gas,it is important to understand the dynamic mechanical properties of shale.Dynamic experiments on shale subjected to true triaxial compression at different strain rates are first conducted in this research.The dynamic stress-strain curves,peak strain,peak stress and failure modes of shale are investigated.The results of the study indicate that the intermediate principal stress and the minor principal stress have the significant influence on the dynamic mechanical behaviors,although this effect decreases as the strain rate increases.The characteristics of compression-shear failure primarily occur in shale subjected to triaxial compression at high strain rates,which distinguishes it from the fragmentation characteristics observed in shale under dynamic uniaxial compression.Additionally,a numerical three-dimensional Split Hopkinson Pressure Bar(3D-SHPB),which is established by coupling PFC3D and FLAC3D methods,is validated to replicate the laboratory characteristics of shale.The dynamic mechanical characteristics of shale subjected to different confining stresses are systematically investigated by the coupling PFC3D and FLAC3D method.The numerical results are in good agreement with the experimental data.

Experimental study and numerical simulation of the impact of under-sleeper pads on the dynamic and static mechanical behavior of heavy-haul railway ballast track

Laying the under-sleeper pad(USP)is one of the effective measures commonly used to delay ballast degradation and reduce maintenance workload.To explore the impact of application of the USP on the dynamic and static mechanical behavior of the ballast track in the heavy-haul railway system,numerical simulation models of the ballast bed with USP and without USP are presented in this paper by using the discrete element method(DEM)-multi-flexible body dynamic(MFBD)coupling analysis method.The ballast bed support stiffness test and dynamic displacement tests were carried out on the actual operation of a heavy-haul railway line to verify the validity of the models.The results show that using the USP results in a 43.01%reduction in the ballast bed support stiffness and achieves a more uniform distribution of track loads on the sleepers.It effectively reduces the load borne by the sleeper directly under the wheel load,with a 7.89%reduction in the pressure on the sleeper.Furthermore,the laying of the USP changes the lateral resistance sharing ratio of the ballast bed,significantly reducing the stress level of the ballast bed under train loads,with an average stress reduction of 42.19 kPa.It also reduces the plastic displacement of ballast particles and lowers the peak value of rotational angular velocity by about 50%to 70%,which is conducive to slowing down ballast bed settlement deformation and reducing maintenance costs.In summary,laying the USP has a potential value in enhancing the stability and extending the lifespan of the ballast bed in heavy-haul railway systems.

Chemo-mechanical couplings in compacted argillite submitted to high-pH environment

In the French concept of deep nuclear wastes repository, the galleries should be backfilled with excavated argillite after the site exploitation period. After several thousands of years, the degradation of the concrete lining of the galleries will generate alkaline fluid (pH 】 12) that will diffuse through the backfill. The objective of the paper is to describe the influence of such solute diffusion on the microstructure and the mechanical behavior of compacted argillite. Saturated-portlandite water was circulated through compacted samples for 3, 6 and 12 months at 20 °C or 60 °C, respectively. The microstructures before and after fluid circulation were determined with mercury intrusion porosimetry. Since it was planned to introduce additives (bentonite or lime) in the remoulded argillite to backfill the deep galleries, such mixtures were also studied. The results show that the influence of the alkaline fluid on the properties of the argillite is a function of the nature of the additive. The pure argillite undergoes slight modifications that can be related to a limited dissolution of its clayey particles. Conversely, intense alteration of the bentonite-argillite mixture was observed. Lime addition improves the mechanical characteristics of the argillite through the precipitation of cementitious compounds.

A MULTI-COUPLED FINITE ELEMENT ANALYSIS OF RESISTANCE SPOT WELDING PROCESS

A two-dimensional axisymmetric finite element model is developed to analyze the transient thermal and mechanical behaviors of the Resistance Spot Welding （RSW） process using commercial software ANSYS. Firstly a direct-coupled electrical-thermal Finite Element Analysis （FEA） is performed to analyze the transient thermal characteristics of the RSW process. Then based on the thermal results a sequential coupled thermo-elastic-plastic analysis is conducted to determine the mechanical features of the RSW process. The thermal history of the whole process and the temperature distribution of the weldment are obtained through the analysis. The mechanical features, including the distributions of the contact pressure at both the faying surface and the electrode-workpiece interface, the stress and strain distributions in the weldment and their changes during the RSW process, the deformation of the weldment and the electrode displacement are also calculated.

The Bifurcation Behavior of CO Coupling Reactor

The bifurcation behavior of the CO coupling reactor was examined based on the one-dimensional pseudo homogeneous axial dispersion dynamic model. The method of finite difference was used for solving the boundary value problem; the continuation technique and the direct method were applied to determine the bifurcation diagram. The effects of dimensionless adiabatic temperature rise, Damkohler number, activation energy, heat transfer coefficient and feed ratio on the bifurcation behavior were investigated. It was shown that there existed static bifurcation and the oscillations did not occur in the reactor. The result also revealed that the reactor exhibited at most 1-3-1 multiplicity patterns within the range of practical possible parameters and the measures, such as weakening the axial dispersion of reactor, enhancing heat transfer, decreasing the concentration of ethyl nitrite, were efficient for avoiding the possible risk of multiple steady states.

Quartic coupling and its effect on wetting behaviors in nematic liquid crystals

Based on the fact that rubbed groove patterns also affect the anchoring of liquid crystals at substrates,a quartic coupling is included in constructing the surface energy for a liquid crystal cell.The phase diagram and the wetting behaviors of the liquid crystal cell,bounded by surfactant-laden interfaces in a magnetic field perpendicular to the substrate are discussed by taking the quartic coupling into account.The nematic order increases at the surface while it decreases in the bulk as a result of the introduction of quartic substrate-liquid crystal coupling,indicating that the groove anchoring makes the liquid crystal molecules align more orderly near the substrate than away from it.This causes a different wetting behavior：complete wetting.

ELECTROMECHANICAL COUPLING MODEL AND ANALYSIS OF TRANSIENT BEHAVIOR FOR INERTIAL RECIPROCATION MACHINES

The dynamical equations for a inertial reciprocating machine excited by two rotating eccentric weights were built by the matrix methodology for establishing dynamical equations of discrete systems. A mathematical model of electromechanical coupling system for the machine was formed by combining the dynamical equations with the state equations of the two motors. The computer simulation to the model was performed for several values of the damping coefficient or the motor power, respectively. The substance of transient behavior of the machine is unveiled by analyzing the results of the computer simulation, and new methods are presented for diminishing the transient amplitude of the vibrating machine and improving the transient behavior. The reliable mathematical model is provided for intelligent control of the transient behavior and engineering design of the equipment.

INFLUENCE OF COMPRESSION-BENDING COUPLING ON THE STABILITY BEHAVIOR OF ANISOTROPIC LAMINATED PANELS

Dynamic-Relaxation Method (DRM) is applied to studying the influence of compression-bending coupling on nonlinear behavior of cylindrically slightly curved panels of unsymmetric laminated composite materials subjected to uniform uniaxial Compression during loading and unloading. Numerical results are given for cross-ply plates and panels under S4S4 and S4S2 boundary conditions. The results show that the effects of absolute value and the sign of the coupling coefficient on the stability behavior of the panles are significant.

Electromechanical coupling model and analysis of transient behavior for inertial vibrating machines

A mathematical model of electromechanical coupling system for a planar inertial vibrating machine is built by setting up dynamical equations of discrete systems with a matrix methodology proposed. The substance of the transient behavior of the machine is unveiled by analyzing the results of the computer simulation to the model, and new methods are presented for diminishing the transient amplitude of the vibrating machine and improving the transient behavior. The reliable mathematical model is provided for intelligent control of the transient behavior of the equipment.

Two-dimensional Numerical Simulation of an Elastic Wedge Water Entry by a Coupled FDM-FEM Method

Hydroelastic behavior of an elastic wedge impacting on calm water surface was investigated. A partitioned approach by coupling finite difference method （FDM） and finite element method （FEM） was developed to analyze the fluid structure interaction （FSI） problem. The FDM, in which the Constraint Interpolation Profile （CIP） method was applied, was used for solving the flow field in a fixed regular Cartesian grid system. Free surface was captured by the Tangent of Hyperbola for Interface Capturing with Slope Weighting （THINC/SW） scheme. The FEM was applied for calculating the structural deformation. A volume weighted method, which was based on the immersed boundary （IB） method, was adopted for coupling the FDM and the FEM together. An elastic wedge water entry problem was calculated by the coupled FDM-FEM method. Also a comparison between the current numerical results and the published results indicate that the coupled FDM-FEM method has reasonably good accuracy in predicting the impact force.

Internal Vibration and Synchronization of Four Coupled Self-Excited Elastic Beams

The vibration behavior and the synchronization between some internal points of four coupled self-excited beams are numerically studied. Coupling through the root of the beams is considered. The transverse displacements of the internal points and the beam tips are monitored, and the power spectra of the resulting time series are employed to determine the oscillation frequencies. The synchronization between beams is analyzed using phase portraits and correlation coefficients. Numerical results show multiple frequencies in the vibration pattern, and complex patterns of synchronization between pairs of beams.