Asymmetric reductive amination of carbonyl compounds was carried out using a novel class of aliphatic quarternary ammonium based chiral ionic liquid. S-(+)-2,3-dihydroxy-N,N,N-tributylpropanaminum bromide chiral ionic...Asymmetric reductive amination of carbonyl compounds was carried out using a novel class of aliphatic quarternary ammonium based chiral ionic liquid. S-(+)-2,3-dihydroxy-N,N,N-tributylpropanaminum bromide chiral ionic liquid has been synthesized, characterized and used for asymmetric reductive amination of carbonyl compounds in the presence of sodium borohydride. These preliminary results are encouraging and advocate dual role of novel ionic liquid as a medium and reducing agent for proficient conversion of ketones to amines, however, reductive amination reaction needs to be established for other substituents.展开更多
Mesogen-Jacketed liquid crystalline polymers were synthesized in various chiral conditions using 1) (\|)\|menthol as a reaction solvent (additive),2) (\|)\|dimenthyl peroxydicarbonate as a chiral free radical initiato...Mesogen-Jacketed liquid crystalline polymers were synthesized in various chiral conditions using 1) (\|)\|menthol as a reaction solvent (additive),2) (\|)\|dimenthyl peroxydicarbonate as a chiral free radical initiator,3) menthyl methacrylate as a comonomer for copolymerization,4) (-)-sparteine-fluorenyllithium as a chiral anionic initiator and 5) a chiral monomer.In the polymerization using a chiral initiator or a chiral solvent,the helix-sense-selection was not found.In the case of the copolymerization,the chiral monomeric unit incorporated into the polymer chain was found to induce liquid crystallinity.Chiral mesogen-Jacketed polymer was also synthesized from chiral monomer 5.However,this polymer did not form a liquid crystal phase although it met the model of Mesogen-Jacketed liquid crystalline polymers.展开更多
文摘Asymmetric reductive amination of carbonyl compounds was carried out using a novel class of aliphatic quarternary ammonium based chiral ionic liquid. S-(+)-2,3-dihydroxy-N,N,N-tributylpropanaminum bromide chiral ionic liquid has been synthesized, characterized and used for asymmetric reductive amination of carbonyl compounds in the presence of sodium borohydride. These preliminary results are encouraging and advocate dual role of novel ionic liquid as a medium and reducing agent for proficient conversion of ketones to amines, however, reductive amination reaction needs to be established for other substituents.
文摘Mesogen-Jacketed liquid crystalline polymers were synthesized in various chiral conditions using 1) (\|)\|menthol as a reaction solvent (additive),2) (\|)\|dimenthyl peroxydicarbonate as a chiral free radical initiator,3) menthyl methacrylate as a comonomer for copolymerization,4) (-)-sparteine-fluorenyllithium as a chiral anionic initiator and 5) a chiral monomer.In the polymerization using a chiral initiator or a chiral solvent,the helix-sense-selection was not found.In the case of the copolymerization,the chiral monomeric unit incorporated into the polymer chain was found to induce liquid crystallinity.Chiral mesogen-Jacketed polymer was also synthesized from chiral monomer 5.However,this polymer did not form a liquid crystal phase although it met the model of Mesogen-Jacketed liquid crystalline polymers.
