Reaction of chiral 2,2'-biamino-1,1'-binaphthalene (R or S) with monosubstituted porphyrin Ib and 2b-c afforded novel chiral diporphyrins 3a-c and 4a-c. Their dimetal complexes [(M)(2)DiPor] have also been pre...Reaction of chiral 2,2'-biamino-1,1'-binaphthalene (R or S) with monosubstituted porphyrin Ib and 2b-c afforded novel chiral diporphyrins 3a-c and 4a-c. Their dimetal complexes [(M)(2)DiPor] have also been prepared. Both structures have been identified by MS, IR, W-visible, H-1 NMR spectra and elemental analysis. These novel chiral compounds show very high optical activities.展开更多
基金Project supported by the Natural Science Foundation of Hubei Province (No. 98J043) and the National Natural Science Foundation of China (No. 29972035).
文摘Reaction of chiral 2,2'-biamino-1,1'-binaphthalene (R or S) with monosubstituted porphyrin Ib and 2b-c afforded novel chiral diporphyrins 3a-c and 4a-c. Their dimetal complexes [(M)(2)DiPor] have also been prepared. Both structures have been identified by MS, IR, W-visible, H-1 NMR spectra and elemental analysis. These novel chiral compounds show very high optical activities.
