本文针对平面内弯矩作用下的T形圆管相贯节点焊缝处热点应力分布开展研究.利用径向拉伸法建立了T形圆管相贯节点的有限元网格模型,对热点应力分析结果的可靠性进行了网格密度分析和试验对比分析,提出了满足计算精度要求的基本密度网格....本文针对平面内弯矩作用下的T形圆管相贯节点焊缝处热点应力分布开展研究.利用径向拉伸法建立了T形圆管相贯节点的有限元网格模型,对热点应力分析结果的可靠性进行了网格密度分析和试验对比分析,提出了满足计算精度要求的基本密度网格.通过无量纲几何参数分析归纳了热点应力沿相贯线的环向分布规律及几何参数影响规律,发现了冠点波峰分裂现象及分裂过程中波峰曲线的三种变化形态,在此基础上提出了采用以π为周期的系数来修正冠点曲线形状的波形修正方法及分布曲线参数公式.与伦敦大学学院(University College London,UCL)两位学者的公式和试验数据进行对比分析,结果表明本文公式具有更简洁的表达形式和更高的精度.展开更多
A full-dimensional analytical potential energy surface （APES） for the F ＋ CH4 →HF ＋ CH3 reaction is developed based on 7127 ab initio energy points at the unrestricted coupled-cluster with single, double, and per...A full-dimensional analytical potential energy surface （APES） for the F ＋ CH4 →HF ＋ CH3 reaction is developed based on 7127 ab initio energy points at the unrestricted coupled-cluster with single, double, and perturbative triple excitations. The correlation-consistent polarized triple-split valence basis set is used. The APES is represented with a many-body expansion containing 239 parameters determined by the least square fitting method. The two-body terms of the APES are fitted by potential energy curves with multi-reference configuration interaction, which can describe the diatomic molecules （CH, H2, HF, and CF） accurately. It is found that the APES can reproduce the geometry and vibrational frequencies of the saddle point better than those available in the literature. The rate constants based on the present APES support the experimental results of Moore et al. [Int. J. Chem. Kin. 26, 813 （1994）]. The analytical first-order derivation of energy is also provided, making the present APES convenient and efficient for investigating the title reaction with quasiclassical trajectory calculations.展开更多
In the present investigation, series of Bis (heterocycle)s bearing pyrazoline in combination of the imidazole derivatives have been synthesized via 1,3-dipolar cycloaddition reactions of N-(nitrobenzyl)-imidazole nitr...In the present investigation, series of Bis (heterocycle)s bearing pyrazoline in combination of the imidazole derivatives have been synthesized via 1,3-dipolar cycloaddition reactions of N-(nitrobenzyl)-imidazole nitrile imines with different dipolarophiles. All the newly synthesized compounds were characterized and screened for analgesic-anti-inflammatory activities and were compared with the standard drugs. The compounds exhibited excellent anti-inflammatory and analgesic activities. Out of the compounds studied 4b, 4d and 4g compounds shown statistically significant activity comparable to the standard drugs Ibuprofen and Aspirin at the same dose.展开更多
The 1947 edition of T‘ai-Chi Ch‘üan:Its Effects and Practical Applications,an English translation of the original Chinese work,is by far the first discovered English publication systematically introducing the k...The 1947 edition of T‘ai-Chi Ch‘üan:Its Effects and Practical Applications,an English translation of the original Chinese work,is by far the first discovered English publication systematically introducing the knowledge and skills of taijiquan(previously known as T‘ai-Chi Ch‘üan).The 1947 edition had long remained in oblivion in Chinese academic circles,although it paved the way for the extensive popularization of taijiquan and has exerted a far-reaching impact on the English-speaking world.This paper applies the four dimensions of canonicity(rich content,substantial creativity,time-and-space transcendency,infinite readability)to examine the aesthetic value of the English text.The purpose is to reveal the understanding and reception of taijiquan among English readers,shed light on the English translation of the taijiquan culture,and promote the canonization of taijiquan as a representative of fine traditional Chinese culture and its integration into global cultures.展开更多
文摘本文针对平面内弯矩作用下的T形圆管相贯节点焊缝处热点应力分布开展研究.利用径向拉伸法建立了T形圆管相贯节点的有限元网格模型,对热点应力分析结果的可靠性进行了网格密度分析和试验对比分析,提出了满足计算精度要求的基本密度网格.通过无量纲几何参数分析归纳了热点应力沿相贯线的环向分布规律及几何参数影响规律,发现了冠点波峰分裂现象及分裂过程中波峰曲线的三种变化形态,在此基础上提出了采用以π为周期的系数来修正冠点曲线形状的波形修正方法及分布曲线参数公式.与伦敦大学学院(University College London,UCL)两位学者的公式和试验数据进行对比分析,结果表明本文公式具有更简洁的表达形式和更高的精度.
基金supported by the National Natural Science Foundation of China (Grant Nos. 11174117 and 10974078)
文摘A full-dimensional analytical potential energy surface （APES） for the F ＋ CH4 →HF ＋ CH3 reaction is developed based on 7127 ab initio energy points at the unrestricted coupled-cluster with single, double, and perturbative triple excitations. The correlation-consistent polarized triple-split valence basis set is used. The APES is represented with a many-body expansion containing 239 parameters determined by the least square fitting method. The two-body terms of the APES are fitted by potential energy curves with multi-reference configuration interaction, which can describe the diatomic molecules （CH, H2, HF, and CF） accurately. It is found that the APES can reproduce the geometry and vibrational frequencies of the saddle point better than those available in the literature. The rate constants based on the present APES support the experimental results of Moore et al. [Int. J. Chem. Kin. 26, 813 （1994）]. The analytical first-order derivation of energy is also provided, making the present APES convenient and efficient for investigating the title reaction with quasiclassical trajectory calculations.
文摘In the present investigation, series of Bis (heterocycle)s bearing pyrazoline in combination of the imidazole derivatives have been synthesized via 1,3-dipolar cycloaddition reactions of N-(nitrobenzyl)-imidazole nitrile imines with different dipolarophiles. All the newly synthesized compounds were characterized and screened for analgesic-anti-inflammatory activities and were compared with the standard drugs. The compounds exhibited excellent anti-inflammatory and analgesic activities. Out of the compounds studied 4b, 4d and 4g compounds shown statistically significant activity comparable to the standard drugs Ibuprofen and Aspirin at the same dose.
基金a staged research result of the“Translation of the Library of Chinese Martial Arts from the Perspective of the Belt and Road Initiative”(17BTY034),a program funded by the National Social Science Fund of China.
文摘The 1947 edition of T‘ai-Chi Ch‘üan:Its Effects and Practical Applications,an English translation of the original Chinese work,is by far the first discovered English publication systematically introducing the knowledge and skills of taijiquan(previously known as T‘ai-Chi Ch‘üan).The 1947 edition had long remained in oblivion in Chinese academic circles,although it paved the way for the extensive popularization of taijiquan and has exerted a far-reaching impact on the English-speaking world.This paper applies the four dimensions of canonicity(rich content,substantial creativity,time-and-space transcendency,infinite readability)to examine the aesthetic value of the English text.The purpose is to reveal the understanding and reception of taijiquan among English readers,shed light on the English translation of the taijiquan culture,and promote the canonization of taijiquan as a representative of fine traditional Chinese culture and its integration into global cultures.
