Ring-opening Polymerization of Chloromethyl Thiirane with Catalytic Systems Composed of Lanthanide Compound and Ethyl Aluminum Sesquichloride

The Ziegler-Natta type catalytic systems composed of lanthanide compound and ethyl aluminum sesquichloride are effective to convert chloromethyl thiirane to polymer of molecular weight ca. 10,000. The effects of rare earth element and ligand were studied.

Studies on Ring-Opening Polymerization of Chloromethyl Thiirane with Rare Earth Catalysts and Functional Resins Synthesized therewith

Studies on ring-opening polymerization of chloromethyl thiirane with rareearth catalysts and functional resins synthesized therewith were reviewed.