In this work, a metal-organic framework with free standing basic groups（e, g., amino and acylamide groups） decorated in the pore wall was utilized to catalyze the CO2 cycloaddition reaction and its basic properties ...In this work, a metal-organic framework with free standing basic groups（e, g., amino and acylamide groups） decorated in the pore wall was utilized to catalyze the CO2 cycloaddition reaction and its basic properties were tested in Knoevenagel condensation reactions. The results reveal that the metal-organic frarnework（MOF） material has excellent catalytic activity and high repeatability for the synthesis of chloropropene carbonate from CO2 and epichlorohydrin with no co-catalyst under mild reaction conditions, suggesting that it is a promising heteroge- neous catalyst for CO2 cycloaddition reaction.展开更多
基金Supported by the National Natural Science Foundation of China（Nos.21261017, 21561020） and the Union of Industry Study Fund of Dongguan City, China（No.2014509112210）.
文摘In this work, a metal-organic framework with free standing basic groups（e, g., amino and acylamide groups） decorated in the pore wall was utilized to catalyze the CO2 cycloaddition reaction and its basic properties were tested in Knoevenagel condensation reactions. The results reveal that the metal-organic frarnework（MOF） material has excellent catalytic activity and high repeatability for the synthesis of chloropropene carbonate from CO2 and epichlorohydrin with no co-catalyst under mild reaction conditions, suggesting that it is a promising heteroge- neous catalyst for CO2 cycloaddition reaction.
