Cinchona alkaloids are utilized as chiral ligands to promote the enantioselective addition of dialkylzinc to N-diphenylphos-phinylimines affording enantiomerically enriched N-diphenyl-phosphinylamines in up to 91% ee.
基金Project supported by the National Natural Science Foundation of China(No.20102005).
文摘Cinchona alkaloids are utilized as chiral ligands to promote the enantioselective addition of dialkylzinc to N-diphenylphos-phinylimines affording enantiomerically enriched N-diphenyl-phosphinylamines in up to 91% ee.