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Assessment of electrostatic discharge sensitivity of nitrogen-rich heterocyclic energetic compounds and their salts as high energy-density dangerous compounds:A study of structural variables
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作者 Mohammad Hossein Keshavarz Sedigheh Heydari Bani +1 位作者 Reza Bakhtiari Seyyed Hesamodin Hosseini 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第9期15-22,共8页
Nitrogen-rich heterocyclic energetic compounds(NRHECs)and their salts have witnessed widespread synthesis in recent years.The substantial energy-density content within these compounds can lead to potentially dangerous... Nitrogen-rich heterocyclic energetic compounds(NRHECs)and their salts have witnessed widespread synthesis in recent years.The substantial energy-density content within these compounds can lead to potentially dangerous explosive reactions when subjected to external stimuli such as electrical discharge.Therefore,developing a reliable model for predicting their electrostatic discharge sensitivity(ESD)becomes imperative.This study proposes a novel and straightforward model based on the presence of specific groups(-NH_(2) or-NH-,-N=N^(+)-O^(-)and-NNO_(2),-ONO_(2) or-NO_(2))under certain conditions to assess the ESD of NRHECs and their salts,employing interpretable structural parameters.Utilizing a comprehensive dataset comprising 54 ESD measurements of NRHECs and their salts,divided into 49/5 training/test sets,the model achieves promising results.The Root Mean Square Error(RMSE),Mean Absolute Error(MAE),and Maximum Error for the training set are reported as 0.16 J,0.12 J,and 0.5 J,respectively.Notably,the ratios RMSE(training)/RMSE(test),MAE(training)/MAE(test),and Max Error(training)/Max Error(test)are all greater than 1.0,indicating the robust predictive capabilities of the model.The presented model demonstrates its efficacy in providing a reliable assessment of ESD for the targeted NRHECs and their salts,without the need for intricate computer codes or expert involvement. 展开更多
关键词 Electrostatic discharge sensitivity Heterocyclic energetic compounds containing azole compound Interpretable structural parameter Safety
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The Generation of a Reduced Mechanism for Flame Inhibition by Phosphorus Containing Compounds Based on Path Flux Analysis Method 被引量:1
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作者 李山岭 蒋勇 邱榕 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2013年第4期357-365,共9页
In order to analyze the complex chemical kinetic mechanism systematically and find out the redundant species and reactions, a numerical platform for mechanism analysis and simplification is established basing on Path ... In order to analyze the complex chemical kinetic mechanism systematically and find out the redundant species and reactions, a numerical platform for mechanism analysis and simplification is established basing on Path Flux Analysis (PFA). It is used to reduce a detailed mechanism for flame inhibited by phosphorus containing compounds, a reduced mechanism with 65 species and 335 reactions is obtained. The detailed and reduced mechanism are both used to calculate the freely-propagating premix C3H8/air flame with different dimethyl methylphosphonate doped over a wide range of equivalence ratios. The concentration distributions of free radicals and major species are compared, and the results under two different mechanisms agree well. The laminar flame speed obtained by the two mechanisms also matches well, with the maximum relative error introduces as a small value of 1.7%. On the basis of the reduced mechanism validation, the correlativity analysis is conducted between flame speed and flee radical concentrations, which can provide information for target species selection in the further mechanism reduction. By analyzing the species and reactions fluxes, the species and reaction paths which contribute the flame inhibition significantly are determined. 展开更多
关键词 mechanism reduction path flux analysis phosphorus containing compounds flame inhibition
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Simultaneous biodegradation of nitrogen-containing aromatic compounds in a sequencing batch bioreactor 被引量:11
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作者 LIU Xing-yu WANG Bao-jun +3 位作者 JIANG Cheng-ying ZHAO Ke-xin Harold L. Drake LIU Shuang-Jiang 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2007年第5期530-535,共6页
Many nitrogen-containing aromatic compounds (NACs), such as nitrobenzene (NB), 4-nitrophenol (4-NP), aniline (AN), and 2,4-dinitrophenol (2,4-DNP), are environmentally hazardous, and their removal from conta... Many nitrogen-containing aromatic compounds (NACs), such as nitrobenzene (NB), 4-nitrophenol (4-NP), aniline (AN), and 2,4-dinitrophenol (2,4-DNP), are environmentally hazardous, and their removal from contaminated water is one of the main challenges facing wastewater treatment plants. In this study, synthetic wastewater containing NB, 4-NP, 2,4-DNP, and AN at concentrations ranging from 50 to 180 mg/L was fed into a sequencing batch reactor (SBR). Analyses of the SBR system indicated that it simultaneously removed more than 99% of the NACs at loading rates of 0.36 kg NB/(m^3·d), 0.3 kg 4-NP/(m^3·d), 0.25 kg AN/(m^3·d), and 0.1 kg 2,4-DNP/(m^3·d). Bacterial groups of Bacteriodetes, Candidate division TM7, α-Proteobacteria, and β-Proteobacteria were dominant in the clone libraries of 16S rRNA genes retrieved from the microbial communities in the SBR system. "Cycle tests" designed to alter feeding and aeration parameters of the SBR system demonstrated that the resident microbial biome of the SBR system responded rapidly to changing conditions. Consumption of O2 was concomitant with the apparent mineralization of NACs. Aromatic ring-cleaving dioxygenase activities suggested that (1) AN and NB were degraded via catechol 2,3-dioxygenase; (2) 4-NP was degraded via 1,2,4-benzentriol 1,2-dioxygenase; and (3) 2,4-DNP was degraded via an unresolved pathway. 展开更多
关键词 nitrogen-containing aromatic compounds BIODEGRADATION sequencing batch reactor Candidate division TM7
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Production of aryl oxygen-containing compounds from catalytic pyrolysis of bagasse lignin over LaTixFe1xO3 被引量:4
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作者 Haiying Wang Hongjing Han +5 位作者 Enhao Sun Yanan Zhang Jinxin Li Yanguang Chen Hua Song Hongzhi Zhao 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2019年第8期1939-1944,共6页
A new approach,named production of aryl oxygen-containing compounds from the catalytic pyrolysis of bagasse lignin(BL) over perovskite oxide,was proposed,A series of LaTixFe1-xO3(LTF-x) samples were prepared by the so... A new approach,named production of aryl oxygen-containing compounds from the catalytic pyrolysis of bagasse lignin(BL) over perovskite oxide,was proposed,A series of LaTixFe1-xO3(LTF-x) samples were prepared by the solid state reaction method.The crystal phase and morphology of LTF-x were characterized by XRD and SEM respectively.Catalytic pyrolysis performance of LTF-x was performed by TG-DTG and the distribution patterns of gaseous,liquid and solid products from BL was investigated using a fixed-bed micro-reactor.The optimal reaction conditions were determined:the pyrolysis temperature was 600℃,the mass ratio of mBL:mLTF-0.2 was 3:1,the veloeity of earrier gas was 100 ml·min-1.The gaseous produets were mainly eomposed of CO2,CO,CH4 and CnHm(n=2-4,m=2 n+2 or m=2 n),The main aryl oxygen-containing compounds in liquid products were phenolics,guaiacols,syringols and phenylates,the rest were benzenes,furans,esters and carboxylic acid.The total contents of aryl oxygencontaining compounds were from 62% up to more than 72% under the action of the perovskite.Moreover,the LTF-0.2 sample had nice regenerability. 展开更多
关键词 BAGASSE LIGNIN Perovskite Catalytic pyrolysis ARYL oxygen-containing compounds
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Adsorptive removal of nitrogen-containing compounds from fuel by metal-organic frameworks 被引量:5
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作者 Zhaoyang Wang Zhiguo Sun +1 位作者 Linghao Kong Gang Li 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2013年第6期869-875,共7页
The adsorptive denitrogenation from fuels over three metal-organic frameworks(MIL-96(Al),MIL-53(Al)and MIL-101(Cr))was studied by batch adsorption experiments.Four nitrogen-containing compounds(NCCs)pyridine,pyrrole,q... The adsorptive denitrogenation from fuels over three metal-organic frameworks(MIL-96(Al),MIL-53(Al)and MIL-101(Cr))was studied by batch adsorption experiments.Four nitrogen-containing compounds(NCCs)pyridine,pyrrole,quinoline and indole were used as model NCCs in fuels to study the adsorption mechanism.The physicochemical properties of the adsorbents were characterized by XRD,N2physical adsorption,FT-IR spectrum and Hammett indicator method.The metal-organic frameworks(MOFs),especially the MIL-101(Cr)containing Lewis acid sites as well as high specific surface area,can adsorb large quantities of NCCs from fuels.In addition,the adsorptive capacity over MIL-101(Cr)will be different for NCCs with different basicity.The stronger basicity of the NCC is,the more it can be absorbed over MIL-101(Cr).Furthermore,pore size and shape also affect the adsorption capacity for a given adsorbate,which can be proved by the adsorption over MIL-53(Al)and MIL-96(Al).The pseudo-second-order kinetic model and Langmuir equation can be used to describe kinetics and thermodynamics of the adsorption process,respectively.Finally,the regeneration of the used adsorbent has been conducted successfully by just washing it with ethanol. 展开更多
关键词 metal-organic framework nitrogen-containing compound adsorptive denitrogenation denitrogenation kinetics denitrogenation thermodynamics
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Structural Characterization and Octanol/water Partition Coefficients(LogP) Prediction for Oxygen-containing Organic Compounds 被引量:8
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作者 廖立敏 黄茜 雷光东 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2017年第8期1243-1250,共8页
New descriptors were constructed and structures of some oxygen-containing organic compounds were parameterized. The multiple linear regression(MLR) and partial least squares regression(PLS) methods were employed t... New descriptors were constructed and structures of some oxygen-containing organic compounds were parameterized. The multiple linear regression(MLR) and partial least squares regression(PLS) methods were employed to build two relationship models between the structures and octanol/water partition coefficients(LogP) of the compounds. The modeling correlation coefficients(R) were 0.976 and 0.922, and the "leave one out" cross validation correlation coefficients(R(CV)) were 0.973 and 0.909, respectively. The results showed that the structural descriptors could well characterize the molecular structures of the compounds; the stability and predictive power of the models were good. 展开更多
关键词 oxygen-containing organic compounds octanol/water partition coefficients(LogP) structural descriptors relationship between structures and properties
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QSPR Study on the Boiling Points of Some Oxygenand Sulfur-containing Organic Compounds 被引量:1
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作者 陈建挺 刘红玲 +2 位作者 王甫洋 于红霞 李定龙 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2009年第12期1561-1568,共8页
Structural and thermodynamic parameters of 56 oxygen-containing and 56 sulfur- containing organic compounds were computed at the B3LPY/6-311G** level using density functional theory (DFT) method. Furthermore,the d... Structural and thermodynamic parameters of 56 oxygen-containing and 56 sulfur- containing organic compounds were computed at the B3LPY/6-311G** level using density functional theory (DFT) method. Furthermore,the dependent equations between the experimental data of boiling points (Tb) and theoretical parameters were proposed with SPSS12.0 for windows software,whose correlation coefficients R2 are 0.933 and 0.945. These dependent equations were validated by cross-validation method (q2 are 0.923 and 0.929,respectively). VIF (variance inflation factors) and t-value methods were also used to verify the significance and self-correlationship of each variable. Results indicate that our dependent equation exhibits good prediction ability,and molecular polarizability (α) is the main factor affecting the Tb of oxygen- and sulfur-containing organic compounds. To our interest,obvious dependence could also be found among the oxygen- and sulfur-containing organic compounds' experimental data of boiling points (Tb) with R^2 of 0.857. 展开更多
关键词 boiling points oxygen-containing organic compounds sulfur-containing organic compounds quantitative structure-property relationship (QSPR) DFT
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^(31)P NMR Study on Some Phosphorus-Containing Compounds 被引量:1
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作者 Zhen XU Ji Liang SHI +1 位作者 Xin CHEN Xi Kui JIANG 《Chinese Chemical Letters》 SCIE CAS CSCD 2000年第12期1057-1060,共4页
31P NMR has become a widely applied spectroscopic probe of the structure of phosphorus-containing compounds. Meanwhile, the application of 31P NMR has been rapidly expanded to biochemistry and medicinal chemistry of p... 31P NMR has become a widely applied spectroscopic probe of the structure of phosphorus-containing compounds. Meanwhile, the application of 31P NMR has been rapidly expanded to biochemistry and medicinal chemistry of phosphorus-containing compounds because the growing importance of the phosphorus compounds is now widely realized. We report here the results of 31P NMR study on some phosphorus-containing compounds, namely, O-alkyl O-4-nitrophenyl methyl phosphonates with different alkyl chain-length (MePO-n), 4-nitrophenyl alkylphenylphosphinates with different alkyl chain-length (PhP-n), diethyl phosphono- acetonitrile anion and diethyl phosphite anion . Our results indicate that 31P NMR can not only be applied to not only the study of the hydrolytic reactions of MePO-8 and PhP-8 but also be applied to the study of the presence of the anions of diethylphosphonoacetonitrile and diethyl phosphite in nucleophilic reactions. 展开更多
关键词 31P NMR phosphorus-containing compounds nucleophilic reaction.
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Reduction of Sulphur-containing Aromatic Nitro Compounds with Hydrazine Hydrate over Iron(III) Oxide-MgO Catalyst 被引量:2
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作者 Qi Xun SHI Rong Wen LU Zhu Xia ZHANG De Feng ZHAO 《Chinese Chemical Letters》 SCIE CAS CSCD 2006年第4期441-443,共3页
Sulphur-containing aromatic amines were prepared efficiently in good to excellent yields by reduction of the corresponding sulphur-containing aromatic nitro compounds with hydrazine hydrate in the presence of iron(Ⅲ... Sulphur-containing aromatic amines were prepared efficiently in good to excellent yields by reduction of the corresponding sulphur-containing aromatic nitro compounds with hydrazine hydrate in the presence of iron(Ⅲ) oxide-MgO catalyst. The catalyst exhibited high activity and stability for the reduction of sulphur-containing aromatic nitro compounds. The yields of sulphur-containing aromatic amines were up to 91-99 % at 355 K after reduction for 1-4 h over this catalyst. 展开更多
关键词 Iron(Ⅲ) oxide-MgO catalyst hydrazine hydrate sulphur-containing aromatic nitro compounds reduction.
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Physical and chemical effects of phosphorus-containing compounds on laminar premixed flame 被引量:1
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作者 Yongfeng Yin Yong Jiang +1 位作者 Rong Qiu and Caiyi Xiong 《Chinese Physics B》 SCIE EI CAS CSCD 2018年第9期360-373,共14页
Phosphorus-containing compounds are the promising halon alternatives for flame inhibitions. However, some literatures suggested that the phosphorus-related inhibitors may behave as the unfavorable ones that will incre... Phosphorus-containing compounds are the promising halon alternatives for flame inhibitions. However, some literatures suggested that the phosphorus-related inhibitors may behave as the unfavorable ones that will increase the burning velocity under lean-burn conditions, and this indeed posed potential threats to the fire prevention and fighting. To seek deeper insights into the reaction process, a numerical investigation was actualized to study the phosphorus-related effects on methane-air flames. By replacing a phosphorus-related inhibitor with the corresponding decomposed molecules, the detailed promoting and inhibiting effects of combustion were separated from the general chemical effect. A comparative study was carried out to identify the interaction between the two effects under different combustion conditions. It is observed that the promoting effect becomes the dominant factor during the reaction process when the equivalence ratio is smaller than 0.60. In this lean-burn condition, the exothermic reactions were faster than the others within the reaction chains due to the reduction of radical recombination in hydrocarbon oxidation. The results are believed to be useful for the further application and improvement of flame inhibitors. 展开更多
关键词 phosphorus-containing compounds flame inhibition chemical effect burning velocity
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Organic Electrofluorescent Materials Using Pyridine-Containing Macrocyclic Compounds 被引量:1
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作者 Tingxi LI Long FU Wenwen YU Renhe HUANG 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2008年第5期753-756,共4页
Novel pyridine-containing macrocyclic compounds, such as 6,12,19,25-tetramethyl-7,11,20,24-dinitrilo-dibenzo [b,m]1,4,12,15-tetra-azacyclodoc osine (TMCD), were synthesized and used as electron transport layer in or... Novel pyridine-containing macrocyclic compounds, such as 6,12,19,25-tetramethyl-7,11,20,24-dinitrilo-dibenzo [b,m]1,4,12,15-tetra-azacyclodoc osine (TMCD), were synthesized and used as electron transport layer in organic electroluminescent devices. Devices with a structure of glass/indium-tin oxide/arylamine derivative/ tris(quinolinolato)aluminum(Ⅲ) (Alq)/TMCD/LiF/Al exhibited green emission from the Alq layer with external quantum efficiency of 0.84% and luminous efficiency of 1.3 lm/W. The derivatives of TMCD were synthesized and characterized as well. These compounds were also found to be useful as the electron-transporting materials in organic electroluminescent devices. 展开更多
关键词 Pyridine-containing macrocyclic compound Organic electroluminescent Electron-transporting material
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Synthesis and Characterization of Compounds Containing 1,2,3-Triazole via Click Reaction and Ag(Ⅰ) Complex 被引量:1
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作者 LI Wen-Si FENG Sheng-Yu 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2018年第12期1932-1938,1845,共8页
In this work, 1,4-bis(4-phenyl-1,2,3-triazole)benzene, 1,3-bis(4-phenyl-1,2,3-triazole)propane, bis(1-phenyl-1,2,3-triazole)-methylphenylsilane, and 1-ally-4-phenyl-1,2,3-triazole have been designed and synthesized vi... In this work, 1,4-bis(4-phenyl-1,2,3-triazole)benzene, 1,3-bis(4-phenyl-1,2,3-triazole)propane, bis(1-phenyl-1,2,3-triazole)-methylphenylsilane, and 1-ally-4-phenyl-1,2,3-triazole have been designed and synthesized via Click reaction. Fourier transform infrared spectroscopy(FT-IR) and nuclear magnetic resonance spectroscopy(NMR) were used to confirm the compounds' structures. The effect of silicon atom on the optical properties has also been studied. The UV-vis absorption wavelength of silicon-containing compound is about ca. 10 nm red-shifted when compared with that of other three compounds. The fluorescence emission bands of the compounds in CHCl_3 solutions were observed around ca. 440 nm. And the luminescent coordination compound, namely [AgL1?NO_3?3H_2O]n, based on the ligand 1-allyl-4-phenyl-1,2,3-triazole has been prepared. In addition, this complex exhibits a 1 D chain structure. The crystal structure has been determined by single-crystal X-ray diffraction, and the optical properties have been investigated by fluorescence spectrum. In summary, our work may provide new materials with luminescent property which is potentially useful in material fields. 展开更多
关键词 Click reaction silicon-containing 1 2 3-triazole compounds crystal structure
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Preparation of Sulphur-containing Aromatic Amines by Reduction of the Corresponding Aromatic Nitro Compounds with Hydrazine Hydrate over Iron Oxide Hydroxide Catalyst 被引量:1
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作者 Qi Xun SHI Rong Wen LU Zhu Xia ZHANG De Feng ZHAO 《Chinese Chemical Letters》 SCIE CAS CSCD 2006年第8期1045-1047,共3页
Sulphur-containing aromatic nitro compounds were rapidly reduced to the corresponding amines in high yields by employing hydrazine hydrate as a hydrogen donor in the presence of iron oxide hydroxide catalyst. It was w... Sulphur-containing aromatic nitro compounds were rapidly reduced to the corresponding amines in high yields by employing hydrazine hydrate as a hydrogen donor in the presence of iron oxide hydroxide catalyst. It was worth noting that the catalyst exhibited extremely high activity. The reduction could be completed within 20-50 min and the yields were up to 97-99 %. 展开更多
关键词 Iron oxide hydroxide catalyst hydrazine hydrate sulphur-containing aromatic nitro compounds reduction.
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An Innovative Method for the Determination of Sulfur-containing Compounds by Vapor Molecular Absorption Spectrometry
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作者 Duan Yixiang, Zhang Hanqi, Liu Xinwei, Wang Lishuang and Jin Qinhan (Department of Chemistry, Jilin University, Changchun) 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 1991年第4期245-246,共2页
Since the most sensitive resonance lines of nonmetallic elements are situated in vacuum ultraviolet region (below 190 nm), they can not be directly determined with a common AAS instrument covering the spectral range... Since the most sensitive resonance lines of nonmetallic elements are situated in vacuum ultraviolet region (below 190 nm), they can not be directly determined with a common AAS instrument covering the spectral range from 190 to 700 nm. The molecular absorption spectrometry is often used for the determination of nonmetallic elements. Syty et al. used vapor molecular absorption spectrometry(VMAS) to determine the sulfur dioxide and sulfide, in which a hydrogen hollow cathode lamp was used as a continuum source to determine SO;at 210 nm and a deuterium arc 展开更多
关键词 Molecular absorption SPECTROMETRY sulfur-containing compound
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Scope of translational medicine in developing boroncontaining compounds for therapeutics
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作者 Ana Karen García-ávila Eunice Dalet Farfán-García +2 位作者 Juan Alberto Guevara-Salazar José Guadalupe Trujillo-Ferrara Marvin Antonio Soriano-Ursúa 《World Journal of Translational Medicine》 2017年第1期1-9,共9页
The ubiquitousness of naturally occurring boron-containing compounds(BCCs) has led to their constant contact with humankind.Recently,many synthetic BCCs have been elaborated for a broad spectrum of purposes,especially... The ubiquitousness of naturally occurring boron-containing compounds(BCCs) has led to their constant contact with humankind.Recently,many synthetic BCCs have been elaborated for a broad spectrum of purposes,especially boric,boronic and borinic acids.Although BCCs were once employed primarily as antiseptics and later as antibiotics,they have become an increasingly relevant therapeutic tool.Nevertheless,this potential of BCCs has been drastically limited due to some unfortunate intra-hospital accidents in the 1940 s and 1950 s.The increasing use of BCCs as insecticides,antimicrobials,and other agents is providing new insights into their role in the physiology of several living species and in the pathophysiology of humans.It is becoming clear that BCCs act through a wide range of mechanisms,as do their corresponding boron-free counterparts.When comparing BCCs and similar boron-free compounds,in many cases the former show advantages in the medical field.The current minireview focuses on how BCCs have been developed by means of translational medicine,a process connecting biomedical research with clinical applications.This process of discovery is currently in an exponential stage. 展开更多
关键词 Boron Boron-containing compounds Drug development Toxicity MEDICINAL chemistry PHARMACOLOGY
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Simple identification approach for trace heteroatom-containing compounds in petroleum fraction by Automated Mass Spectral Deconvolution and Identification System
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《色谱》 CAS CSCD 北大核心 2016年第9期925-932,共8页
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Synthesis and Cytotoxicity of the First Arene Ruthenium Compound Containing Two Thiosemicarbazone Ligands 被引量:1
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作者 SU Wei LUO Zhi-Jin +3 位作者 CUI Hao TANG Zhao-Feng LI Pei-Yuan PENG Bing-Hua 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2019年第9期1543-1548,共6页
A Ru-arene compound containing two thiosemicarbazone ligands [(η6-p-cymene)Ru(TSC)2 Cl]Cl(1, TSC = benzophenone 4-methylthiosemicarbazone) has been synthesized and characterized by 1 H NMR, elemental analysis and HR-... A Ru-arene compound containing two thiosemicarbazone ligands [(η6-p-cymene)Ru(TSC)2 Cl]Cl(1, TSC = benzophenone 4-methylthiosemicarbazone) has been synthesized and characterized by 1 H NMR, elemental analysis and HR-ESI mass spectrometry analysis. The molecular structure was determined by single-crystal X-ray diffraction analysis. The in vitro anticancer activities of the complex have been evaluated against two human cancer cell lines(SGC-7901, BEL-7404), and the IC50 values are 32.5 and 57 μM, respectively. 展开更多
关键词 RUTHENIUM ARENE THIOSEMICARBAZONES X-ray crystal diffraction CYTOTOXICITY running head ARENE RUTHENIUM compound containing TSC
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The Interaction of Cobalt (Ⅲ) Mixed-Ligand Coordination Compound Containing Dipyrido[3,2-a:2′,3′-c] phenazine With Calf Thymus DNA - 被引量:3
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作者 Lan JIN Pin YANG (State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093: Institute of Molecular Science, Shanxi University. Taiyuan 030006) 《Chinese Chemical Letters》 SCIE CAS CSCD 1997年第6期551-552,共2页
The binding of Co (phen)2dppz3+ to calf thymus DNA,as investigated using absorption spectroscopy. viscosity and electrophoresis measurements,here dppz is dipyrido[3, 2-a: 2'3'-c]phenazine. The compound shows a... The binding of Co (phen)2dppz3+ to calf thymus DNA,as investigated using absorption spectroscopy. viscosity and electrophoresis measurements,here dppz is dipyrido[3, 2-a: 2'3'-c]phenazine. The compound shows absorption hypochromicity and the specific viscosity increased upon binding to calf thymus DNA The complex is also shown to be more efficient photosensitisers for single strand breaks in plasmid DNA 展开更多
关键词 phenazine With Calf Thymus DNA Figure Mixed-Ligand Coordination compound containing Dipyrido[3 2-a The Interaction of Cobalt
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Catalytic depolymerization of calcium lignosulfonate by NiMgFeO_x derived from sub-micron sized NiMgFe hydrotalcite prepared by introducing hydroxyl compounds 被引量:3
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作者 Hongjing Han Jinxin Li +5 位作者 Haiying Wang Feng Xue Yanguang Chen Yanan Zhang Yizhen Wang Mei Zhang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2019年第8期1933-1938,共6页
A new method for regulating the synthesis of Ni Mg Fe hydrotalcites(NMF LDHs) with the addition of hydroxyl compounds was proposed. A series of NMF LDHs were prepared by the above method, and then were calcined to obt... A new method for regulating the synthesis of Ni Mg Fe hydrotalcites(NMF LDHs) with the addition of hydroxyl compounds was proposed. A series of NMF LDHs were prepared by the above method, and then were calcined to obtain the Ni Mg FeOx(NMFOx) samples. The NMFOxsamples were characterized by XRD,SEM, TG-DTG, XPS and CO2-TPD, respectively. The catalytic performance of NMFOxfor depolymerizing calcium lignosulfonate(CLS) was evaluated by hydrothermal reaction. The results showed that the addition of hydroxyl compounds favored reducing the particle sizes of NMF LDHs. For the depolymerization of CSL, the yield of liquid product increased from 45% to 75.8% with the addition of NMFOx-ethanol(NMFOxET). The liquid products were mainly phenolics, aromatics, ketones and esters. The total selectivity of oxy-containing compounds was over 90.6%, among them, the phenolics were approximately 35.2%. The valence of Ni and Fe, crystalline phase and basicity almost remained unchanged. The NMFOx-ET samples were recycled for the depolymerization of CLS, moreover, the NMFOx-ET samples had high activity and stability after 4 cycles. 展开更多
关键词 HYDROTALCITE CALCIUM LIGNOSULFONATE DEPOLYMERIZATION Oxy-containing compounds
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Characteristics and Problem of Chrome-containing Refractory 被引量:4
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作者 Akira YAMAGUCHI 《China's Refractories》 CAS 2007年第3期3-7,共5页
One of characteristics of Cr2O3-containing refractory is excellent corrosion resistance. However, there is a problem of hexavalent chromium, which is noxious to the human body, and easily formed by the reactions among... One of characteristics of Cr2O3-containing refractory is excellent corrosion resistance. However, there is a problem of hexavalent chromium, which is noxious to the human body, and easily formed by the reactions among the refractory and CaO, Na2O and/or K2O in slag. In this article, the reason why the Cr2O3-containing refractory has excellent corrosion resistance, the forming conditions of hexavalent compounds, and the methods for suppressing generation of the compound, are described as a base of further development of excellent refractories. 展开更多
关键词 Chrome-containing refractory Cr2O3 CaCr2O4 CaCrO4 Corrosion resistance Hexavalent chromium compound
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