Advanced field methods of carbon (C) analysis should now be capable of providing repetitive, sequential measurements for the evaluation of spatial and temporal variation at a scale that was previously unfeasible. Some...Advanced field methods of carbon (C) analysis should now be capable of providing repetitive, sequential measurements for the evaluation of spatial and temporal variation at a scale that was previously unfeasible. Some spectroscopy techniques, such as laser-induced breakdown spectroscopy (LIBS), have portable features that may potentially lead to clean and rapid alternative approaches for this purpose. The goal of this study was to quantify the C content of soils with different textures and with high iron and aluminum concentrations using LIBS. LIBS emission spectra from soil pellets were captured, and the C content was estimated (emission line of C (I) at 193.03 nm) after spectral offset and aluminum spectral interference correction. This technique is highly portable and could be ideal for providing the soil C content in a heterogeneous experiment. Dry combustion was used as a reference method, and for calibration a conventional linear model was evaluated based on soil textural classes. The correlation between reference and LIBS values showed r = 0.86 for medium-textured soils and r = 0.93 for fine-textured soils. The data showed that better correlation and lower error (14%) values were found for the fine-textured LIBS model. The limit of detection (LOD) was found to be 0.32% for medium-textured soils and 0.13% for fine-textured soils. The results indicated that LIBS quantification can be affected by the texture and chemical composition of soil. Signal treatment was shown to be very important for mitigation of these interferences and to improve quantification.展开更多
This study is carried out to appreciate the coarse elements influence of the gravel lateritic soils on the pavement behavior. The material involves not only the 0/20 mm granular particles considered in the specificati...This study is carried out to appreciate the coarse elements influence of the gravel lateritic soils on the pavement behavior. The material involves not only the 0/20 mm granular particles considered in the specifications and on the laboratory tests, but also all of the material that is actually used in the construction sites. Geotechnical characterization was leaned on five differentiated granular classes of 0/20;0/25;0/31.5;0/40 and 0/63 mm diameters. The sample of 0/40 mm gets the best compaction aptitude, while that of 0/31.5 mm reaches the greatest bearing strength and a good Optimum Moisture Content. According to the requirements and its bearing strengths, the material is usable up to subbase layer and its behavior depends on the grain size.展开更多
基金The authors express their gratitude for the grant from FAPESP(2010/09211-6),CNPq(560292/2010-4)CAPES,Embrapa and Pecus Research Network.
文摘Advanced field methods of carbon (C) analysis should now be capable of providing repetitive, sequential measurements for the evaluation of spatial and temporal variation at a scale that was previously unfeasible. Some spectroscopy techniques, such as laser-induced breakdown spectroscopy (LIBS), have portable features that may potentially lead to clean and rapid alternative approaches for this purpose. The goal of this study was to quantify the C content of soils with different textures and with high iron and aluminum concentrations using LIBS. LIBS emission spectra from soil pellets were captured, and the C content was estimated (emission line of C (I) at 193.03 nm) after spectral offset and aluminum spectral interference correction. This technique is highly portable and could be ideal for providing the soil C content in a heterogeneous experiment. Dry combustion was used as a reference method, and for calibration a conventional linear model was evaluated based on soil textural classes. The correlation between reference and LIBS values showed r = 0.86 for medium-textured soils and r = 0.93 for fine-textured soils. The data showed that better correlation and lower error (14%) values were found for the fine-textured LIBS model. The limit of detection (LOD) was found to be 0.32% for medium-textured soils and 0.13% for fine-textured soils. The results indicated that LIBS quantification can be affected by the texture and chemical composition of soil. Signal treatment was shown to be very important for mitigation of these interferences and to improve quantification.
文摘This study is carried out to appreciate the coarse elements influence of the gravel lateritic soils on the pavement behavior. The material involves not only the 0/20 mm granular particles considered in the specifications and on the laboratory tests, but also all of the material that is actually used in the construction sites. Geotechnical characterization was leaned on five differentiated granular classes of 0/20;0/25;0/31.5;0/40 and 0/63 mm diameters. The sample of 0/40 mm gets the best compaction aptitude, while that of 0/31.5 mm reaches the greatest bearing strength and a good Optimum Moisture Content. According to the requirements and its bearing strengths, the material is usable up to subbase layer and its behavior depends on the grain size.
