Thermal damage and thermal fracture of rocks are two important indicators in geothermal mining projects.This paper investigates the effects of heating and water-cooling on granite specimens at various temperatures.The...Thermal damage and thermal fracture of rocks are two important indicators in geothermal mining projects.This paper investigates the effects of heating and water-cooling on granite specimens at various temperatures.The laboratory uniaxial compression experiments were also conducted.Then,a coupled thermo-mechanical ordinary state-based peridynamic(OSB-PD)model and corresponding numerical scheme were developed to simulate the damage of rocks after the heating and cooling processes,and the change of crack evolution process was predicted.The results demonstrate that elevated heating temperatures exacerbate the thermal damage to the specimens,resulting in a decrease in peak strength and an increase in ductility of granite.The escalating occurrence of thermal-induced cracks significantly affects the crack evolution process during the loading phase.The numerical results accurately reproduce the damage and fracture characteristics of the granite under different final heating temperatures(FHTs),which are consistent with the test results in terms of strength,crack evolution process,and failure mode.展开更多
Temperature-swing adsorption(TSA)is an effective technique for CO_(2) capture,but the temperature swing procedure is energy-intensive.Herein,we report a low-energy-consumption system by combining passive radiative coo...Temperature-swing adsorption(TSA)is an effective technique for CO_(2) capture,but the temperature swing procedure is energy-intensive.Herein,we report a low-energy-consumption system by combining passive radiative cooling and solar heating for the uptake of CO_(2) on commercial activated carbons(CACs).During adsorption,the adsorbents are coated with a layer of hierarchically porous poly(vinylidene fluoride-co-hexafluoropropene)[P(VdF-HFP)HP],which cools the adsorbents to a low temperature under sunlight through radiative cooling.For desorption,CACs with broad absorption of the solar spectrum are exposed to light irradiation for heating.The heating and cooling processes are completely driven by solar energy.Adsorption tests under mimicked sunlight using the CACs show that the performance of this system is comparable to that of the traditional ones.Furthermore,under real sunlight irradiation,the adsorption capacity of the CACs can be well maintained after multiple cycles.The present work may inspire the development of new temperature swing procedures with little energy consumption.展开更多
Maintaining thermal comfort within the human body is crucial for optimal health and overall well-being.By merely broadening the setpoint of indoor temperatures,we could significantly slash energy usage in building hea...Maintaining thermal comfort within the human body is crucial for optimal health and overall well-being.By merely broadening the setpoint of indoor temperatures,we could significantly slash energy usage in building heating,ventilation,and air-conditioning systems.In recent years,there has been a surge in advancements in personal thermal management(PTM),aiming to regulate heat and moisture transfer within our immediate surroundings,clothing,and skin.The advent of PTM is driven by the rapid development in nano/micro-materials and energy science and engineering.An emerging research area in PTM is personal radiative thermal management(PRTM),which demonstrates immense potential with its high radiative heat transfer efficiency and ease of regulation.However,it is less taken into account in traditional textiles,and there currently lies a gap in our knowledge and understanding of PRTM.In this review,we aim to present a thorough analysis of advanced textile materials and technologies for PRTM.Specifically,we will introduce and discuss the underlying radiation heat transfer mechanisms,fabrication methods of textiles,and various indoor/outdoor applications in light of their different regulation functionalities,including radiative cooling,radiative heating,and dual-mode thermoregulation.Furthermore,we will shine a light on the current hurdles,propose potential strategies,and delve into future technology trends for PRTM with an emphasis on functionalities and applications.展开更多
Passive daytime radiative cooling(PDRC) is environment-friendly without energy input by enhancing the coating's solar reflectance(R_(solar)) and thermal emittance(ε_(LWIR)) in the atmosphere's long-wave infra...Passive daytime radiative cooling(PDRC) is environment-friendly without energy input by enhancing the coating's solar reflectance(R_(solar)) and thermal emittance(ε_(LWIR)) in the atmosphere's long-wave infrared transmission window.However,high R_(solar) is usually achieved by increasing the coating's thickness,which not only increases materials' cost but also impairs heat transfer.Additionally,the desired high R_(solar) is vulnerable to dust pollution in the outdoors.In this work,a thin paint was designed by mixing hBN plates,PFOTS,and IPA. R_(solar)=0.963 and ε_(LWIR)=0.927 was achieved at a thickness of 150 μm due to the high backscattering ability of scatters.A high through-plane thermal conductivity(~1.82 W m^(-1) K^(-1)) also can be obtained.In addition,the porous structure coupled with the binder PFOTS resulted in a contact angle of 154°,demonstrating excellent durability under dust contamination.Outdoor experiments showed that the thin paint can obtain a 2.3℃ lower temperature for sub-ambient cooling than the reference PDRC coating in the daytime.Furtherly,the above-ambient heat dissipation performance can be enhanced by spraying the thin paint on a 3D heat sink,which was 15.7℃ lower than the reference 1D structure,demonstrating excellent performance for durable and scalable PDRC applications.展开更多
The Solar Close Observations and Proximity Experiments(SCOPE)mission,which has been proposed by the Yunnan Observatories,Chinese Academy of Sciences,aiming to operate at a distance of 5 to 10 solar radii from the Sun,...The Solar Close Observations and Proximity Experiments(SCOPE)mission,which has been proposed by the Yunnan Observatories,Chinese Academy of Sciences,aiming to operate at a distance of 5 to 10 solar radii from the Sun,plans to complete the in situ detection of the solar eruption process and observation of the magnetic field structure response.The solar flux received by the satellite ranges from 10^(3) to 10^(6) Wm^(-2),which poses challenges for thermal management of the solar arrays.In this work,the solar array cooling system of the Parker Solar Probe is discussed,the developments of the fluid loop technique are reviewed,and a research plan for a next-generation solar array cooling system is proposed.This paper provides a valuable reference for novel thermal control systems in spacecraft for solar observation.展开更多
This paper proposed an initiative optimization operation strategy and multi-objective energy management method for combined cooling heating and power(CCHP) with storage systems.Initially,the initiative optimization op...This paper proposed an initiative optimization operation strategy and multi-objective energy management method for combined cooling heating and power(CCHP) with storage systems.Initially,the initiative optimization operation strategy of CCHP system in the cooling season,the heating season and the transition season was formulated.The energy management of CCHP system was optimized by the multi-objective optimization model with maximum daily energy efficiency,minimum daily carbon emissions and minimum daily operation cost based on the proposed initiative optimization operation strategy.Furthermore,the pareto optimal solution set was solved by using the niche particle swarm multi-objective optimization algorithm.Ultimately,the most satisfactory energy management scheme was obtained by using the technique for order preference by similarity to ideal solution(TOPSIS) method.A case study of CCHP system used in a hospital in the north of China validated the effectiveness of this method.The results showed that the satisfactory energy management scheme of CCHP system was obtained based on this initiative optimization operation strategy and multi-objective energy management method.The CCHP system has achieved better energy efficiency,environmental protection and economic benefits.展开更多
Future changes of heating degree days (HDD) and cooling degree days (CDD) in the 21st century with and without considering populationfactor are investigated based on four sets of climate change simulations over Ea...Future changes of heating degree days (HDD) and cooling degree days (CDD) in the 21st century with and without considering populationfactor are investigated based on four sets of climate change simulations over East Asia using the regional climate model version 4.4 (RegCM4.4)driven by the global models of CSIRO-Mk3-6-0, EC-EARTH, HadGEM2-ES, and MPI-ESM-MR. Under global warming of 1.5℃, 2℃, 3℃,and 4℃, significant decrease of HDD can be found over China without considering population factor, with greater decrease over high elevationand high latitude regions, including the Tibetan Plateau, the northern part of Northeast China, and Northwest China; while population-weightedHDD increased in areas where population will increase in the future, such as Beijing, Tianjin, parts of southern Hebei, northern Shandong andHenan provinces. Similarly, the CDD projections with and without considering population factor are largely different. Specifically, withoutconsidering population, increase of CDD were observed over most parts of China except the Tibetan Plateau where the CDD remained zerobecause of the cold climate even under global warming; while considering population factor, the future CDD decreases in South China andincreases in North China, the Sichuan Basin, and the southeastern coastal areas, which is directly related to the population changes. The differentfuture changes of HDD and CDD when considering and disregarding the effects of population show that population distribution plays animportant role in energy consumption, which should be considered in future research.展开更多
It is well known that one unit of electrical energy saved is equal to more than two units produced. One way of economizing the power is utilization of energy efficient systems at all locations. In the present study, t...It is well known that one unit of electrical energy saved is equal to more than two units produced. One way of economizing the power is utilization of energy efficient systems at all locations. In the present study, the air conditioning system is analysed and an innovative way is suggested. We use natural low temperature of shallow sub surface (1 - 3 m) of the earth—geothermal cooling system. It is known that majority of the households and the apartment complexes in India have two tanks for water storage. One is the underground water sump and the other is the overhead water tank. In our study, we use these two water storage systems for space cooling during summer and also for heating during winter. The main aim of our paper is air-conditioning of the space in an economic way to save electricity. It is based on a simple idea of transferring the low temperature from underground water sump to the room in the house using water as a mode of transport. Since India is a tropical country located at low latitude, most of the year, the air temperature is high and demands space cooling. However, for a couple of months during severe winter months (Dec.-Jan.) at Ahmedabad, heating of the space is required. For heating the space, we suggest to use the well-known solar water heater. Effective use of heat exchanger is shown through computation, modelling schemes and lab experiment. We recommend geothermal cooling for 10 months in a year and solar hot water system during 2 months of winter. It is observed that the ambient air temperature of 35°C - 40°C in the room can be brought down to 26°C without much consumption of electricity. In a similar manner, the room temperature at night (13°C) during winter in Ahmedabad can be increased to 27°C through circulation of water from solar water heater in the heat exchanger.展开更多
The possible application of the film-cooling technique against aero-thermal heating for surfaces of high-speed flying vehicles is discussed. The technique has been widely used in the heat protection of gas turbine bla...The possible application of the film-cooling technique against aero-thermal heating for surfaces of high-speed flying vehicles is discussed. The technique has been widely used in the heat protection of gas turbine blades. It is shown in this paper that, by applying this technique to high-speed flying vehicles, the working principle is fundamentally different. Numerical simulations for two model problems axe performed to support the argument. Besides the heat protection, the appreciable drag reduction is found to be another favorable effect. For the second model problem, i.e., the gas cooling for an optical window on a sphere cone, the hydrodynamic instability of the film is studied by the linear stability analysis to observe possible occurrence of laminar-turbulent transition.展开更多
This paper describes possibilities to utilize sea water for district heating and cooling purposes in Tallinn costal area. The sea water temperature profiles and suitability of heating and cooling generation are studie...This paper describes possibilities to utilize sea water for district heating and cooling purposes in Tallinn costal area. The sea water temperature profiles and suitability of heating and cooling generation are studied for continental climatic conditions. The district network study bases on 21 buildings located near to the Gulf of Finland. Industrial reversible heat pump technology is selected to cover heating and cooling loads for the new buildings. Combination of existing district heating and heat pump technology is considered for existing buildings. The results show possibilities, threats and need for further research of the sea water based heat pump district network implementation.展开更多
An analysis of atmospheric SW-radiative forcing and local heating/cooling rate is made using a one year temporal and vertical profiles of aerosol and cloud over Yaoundé (11.51°E, 3.83°N). It appears tha...An analysis of atmospheric SW-radiative forcing and local heating/cooling rate is made using a one year temporal and vertical profiles of aerosol and cloud over Yaoundé (11.51°E, 3.83°N). It appears that the direct influence of aerosols on the surface compared to the TOA can be 3 times larger. Annual mean value obtained at 559 mb altitude is +27.74 W/m2 with range from 0 to +43 W/m2. At 904 mb, we obtained an annual mean of ﹣46.22 W/m2 with range from ﹣65 to ﹣9 W/m2. Frequency distribution indicates that more than 95% of ARF are between +10 and +70 W/m2 at 559 mb (upper limit of UL), and more than 85% of ARF are between ﹣70 and ﹣10 W/m2 at 904 mb (upper limit of PBL). This sign change is explained by the fact that the backscattering peaks at the upper limit of the aerosol PBL layer. The maximum CRF is noted at TOA where it reaches ﹣600 W/m2 based on the time interval and the structure of clouds. The highest values occur between 11.50 and 13.50 LST. Clouds lead to a general heating of the entire atmospheric column with a much greater effect near the surface. Aerosols effect on the heating rate profile show strong cooling during the day for the lower atmosphere, with slight heating at the upper atmosphere. This cooling contribution generally increases from the surface and peacks at the upper boundary of aerosol layer where reflectivity is the most important. Depending on the moment of the day, average heating effect of clouds peacks at surface or within the middle troposphere due to the absorption by clouds particles. Vertical profiles deeply evolve exhibiting differences that exceed ﹣3 K/day according to altitude from one hour to another during a given mean solar day.展开更多
基金funded by the Postgraduate Research&Practice Innovation Program of Jiangsu Province(Grant No.KYCX22_0613)the National Natural Science Foundation of China(Grant Nos.41831278 and 51878249).
文摘Thermal damage and thermal fracture of rocks are two important indicators in geothermal mining projects.This paper investigates the effects of heating and water-cooling on granite specimens at various temperatures.The laboratory uniaxial compression experiments were also conducted.Then,a coupled thermo-mechanical ordinary state-based peridynamic(OSB-PD)model and corresponding numerical scheme were developed to simulate the damage of rocks after the heating and cooling processes,and the change of crack evolution process was predicted.The results demonstrate that elevated heating temperatures exacerbate the thermal damage to the specimens,resulting in a decrease in peak strength and an increase in ductility of granite.The escalating occurrence of thermal-induced cracks significantly affects the crack evolution process during the loading phase.The numerical results accurately reproduce the damage and fracture characteristics of the granite under different final heating temperatures(FHTs),which are consistent with the test results in terms of strength,crack evolution process,and failure mode.
基金supported by the National Science Fund for Distinguished Young Scholars(22125804)the National Natural Science Foundation of China(21808110,22078155,and 21878149).
文摘Temperature-swing adsorption(TSA)is an effective technique for CO_(2) capture,but the temperature swing procedure is energy-intensive.Herein,we report a low-energy-consumption system by combining passive radiative cooling and solar heating for the uptake of CO_(2) on commercial activated carbons(CACs).During adsorption,the adsorbents are coated with a layer of hierarchically porous poly(vinylidene fluoride-co-hexafluoropropene)[P(VdF-HFP)HP],which cools the adsorbents to a low temperature under sunlight through radiative cooling.For desorption,CACs with broad absorption of the solar spectrum are exposed to light irradiation for heating.The heating and cooling processes are completely driven by solar energy.Adsorption tests under mimicked sunlight using the CACs show that the performance of this system is comparable to that of the traditional ones.Furthermore,under real sunlight irradiation,the adsorption capacity of the CACs can be well maintained after multiple cycles.The present work may inspire the development of new temperature swing procedures with little energy consumption.
基金support from the Research Grants Council of the Hong Kong Special Administrative Region,China(PolyU152052/21E)Green Tech Fund of Hong Kong(Project No.:GTF202220106)+1 种基金Innovation and Technology Fund of the Hong Kong Special Administrative Region,China(ITP/018/21TP)PolyU Endowed Young Scholars Scheme(Project No.:84CC).
文摘Maintaining thermal comfort within the human body is crucial for optimal health and overall well-being.By merely broadening the setpoint of indoor temperatures,we could significantly slash energy usage in building heating,ventilation,and air-conditioning systems.In recent years,there has been a surge in advancements in personal thermal management(PTM),aiming to regulate heat and moisture transfer within our immediate surroundings,clothing,and skin.The advent of PTM is driven by the rapid development in nano/micro-materials and energy science and engineering.An emerging research area in PTM is personal radiative thermal management(PRTM),which demonstrates immense potential with its high radiative heat transfer efficiency and ease of regulation.However,it is less taken into account in traditional textiles,and there currently lies a gap in our knowledge and understanding of PRTM.In this review,we aim to present a thorough analysis of advanced textile materials and technologies for PRTM.Specifically,we will introduce and discuss the underlying radiation heat transfer mechanisms,fabrication methods of textiles,and various indoor/outdoor applications in light of their different regulation functionalities,including radiative cooling,radiative heating,and dual-mode thermoregulation.Furthermore,we will shine a light on the current hurdles,propose potential strategies,and delve into future technology trends for PRTM with an emphasis on functionalities and applications.
基金financially supported by the Natural Science Foundation of Hunan Province(Grant No.2021JJ40732)the Central South University Innovation-Driven Research Programme(Grant No.2023CXQD012)。
文摘Passive daytime radiative cooling(PDRC) is environment-friendly without energy input by enhancing the coating's solar reflectance(R_(solar)) and thermal emittance(ε_(LWIR)) in the atmosphere's long-wave infrared transmission window.However,high R_(solar) is usually achieved by increasing the coating's thickness,which not only increases materials' cost but also impairs heat transfer.Additionally,the desired high R_(solar) is vulnerable to dust pollution in the outdoors.In this work,a thin paint was designed by mixing hBN plates,PFOTS,and IPA. R_(solar)=0.963 and ε_(LWIR)=0.927 was achieved at a thickness of 150 μm due to the high backscattering ability of scatters.A high through-plane thermal conductivity(~1.82 W m^(-1) K^(-1)) also can be obtained.In addition,the porous structure coupled with the binder PFOTS resulted in a contact angle of 154°,demonstrating excellent durability under dust contamination.Outdoor experiments showed that the thin paint can obtain a 2.3℃ lower temperature for sub-ambient cooling than the reference PDRC coating in the daytime.Furtherly,the above-ambient heat dissipation performance can be enhanced by spraying the thin paint on a 3D heat sink,which was 15.7℃ lower than the reference 1D structure,demonstrating excellent performance for durable and scalable PDRC applications.
基金This work has been supported by National Key R&D Program of China No.2022YFF0503804.
文摘The Solar Close Observations and Proximity Experiments(SCOPE)mission,which has been proposed by the Yunnan Observatories,Chinese Academy of Sciences,aiming to operate at a distance of 5 to 10 solar radii from the Sun,plans to complete the in situ detection of the solar eruption process and observation of the magnetic field structure response.The solar flux received by the satellite ranges from 10^(3) to 10^(6) Wm^(-2),which poses challenges for thermal management of the solar arrays.In this work,the solar array cooling system of the Parker Solar Probe is discussed,the developments of the fluid loop technique are reviewed,and a research plan for a next-generation solar array cooling system is proposed.This paper provides a valuable reference for novel thermal control systems in spacecraft for solar observation.
基金supported by Major International(Regional)Joint Research Project of the National Natural Science Foundation of China(61320106011)National High Technology Research and Development Program of China(863 Program)(2014AA052802)National Natural Science Foundation of China(61573224)
文摘This paper proposed an initiative optimization operation strategy and multi-objective energy management method for combined cooling heating and power(CCHP) with storage systems.Initially,the initiative optimization operation strategy of CCHP system in the cooling season,the heating season and the transition season was formulated.The energy management of CCHP system was optimized by the multi-objective optimization model with maximum daily energy efficiency,minimum daily carbon emissions and minimum daily operation cost based on the proposed initiative optimization operation strategy.Furthermore,the pareto optimal solution set was solved by using the niche particle swarm multi-objective optimization algorithm.Ultimately,the most satisfactory energy management scheme was obtained by using the technique for order preference by similarity to ideal solution(TOPSIS) method.A case study of CCHP system used in a hospital in the north of China validated the effectiveness of this method.The results showed that the satisfactory energy management scheme of CCHP system was obtained based on this initiative optimization operation strategy and multi-objective energy management method.The CCHP system has achieved better energy efficiency,environmental protection and economic benefits.
文摘Future changes of heating degree days (HDD) and cooling degree days (CDD) in the 21st century with and without considering populationfactor are investigated based on four sets of climate change simulations over East Asia using the regional climate model version 4.4 (RegCM4.4)driven by the global models of CSIRO-Mk3-6-0, EC-EARTH, HadGEM2-ES, and MPI-ESM-MR. Under global warming of 1.5℃, 2℃, 3℃,and 4℃, significant decrease of HDD can be found over China without considering population factor, with greater decrease over high elevationand high latitude regions, including the Tibetan Plateau, the northern part of Northeast China, and Northwest China; while population-weightedHDD increased in areas where population will increase in the future, such as Beijing, Tianjin, parts of southern Hebei, northern Shandong andHenan provinces. Similarly, the CDD projections with and without considering population factor are largely different. Specifically, withoutconsidering population, increase of CDD were observed over most parts of China except the Tibetan Plateau where the CDD remained zerobecause of the cold climate even under global warming; while considering population factor, the future CDD decreases in South China andincreases in North China, the Sichuan Basin, and the southeastern coastal areas, which is directly related to the population changes. The differentfuture changes of HDD and CDD when considering and disregarding the effects of population show that population distribution plays animportant role in energy consumption, which should be considered in future research.
文摘It is well known that one unit of electrical energy saved is equal to more than two units produced. One way of economizing the power is utilization of energy efficient systems at all locations. In the present study, the air conditioning system is analysed and an innovative way is suggested. We use natural low temperature of shallow sub surface (1 - 3 m) of the earth—geothermal cooling system. It is known that majority of the households and the apartment complexes in India have two tanks for water storage. One is the underground water sump and the other is the overhead water tank. In our study, we use these two water storage systems for space cooling during summer and also for heating during winter. The main aim of our paper is air-conditioning of the space in an economic way to save electricity. It is based on a simple idea of transferring the low temperature from underground water sump to the room in the house using water as a mode of transport. Since India is a tropical country located at low latitude, most of the year, the air temperature is high and demands space cooling. However, for a couple of months during severe winter months (Dec.-Jan.) at Ahmedabad, heating of the space is required. For heating the space, we suggest to use the well-known solar water heater. Effective use of heat exchanger is shown through computation, modelling schemes and lab experiment. We recommend geothermal cooling for 10 months in a year and solar hot water system during 2 months of winter. It is observed that the ambient air temperature of 35°C - 40°C in the room can be brought down to 26°C without much consumption of electricity. In a similar manner, the room temperature at night (13°C) during winter in Ahmedabad can be increased to 27°C through circulation of water from solar water heater in the heat exchanger.
基金Project supported by the National Natural Science Foundation of China(Nos.11472189 and11332007)
文摘The possible application of the film-cooling technique against aero-thermal heating for surfaces of high-speed flying vehicles is discussed. The technique has been widely used in the heat protection of gas turbine blades. It is shown in this paper that, by applying this technique to high-speed flying vehicles, the working principle is fundamentally different. Numerical simulations for two model problems axe performed to support the argument. Besides the heat protection, the appreciable drag reduction is found to be another favorable effect. For the second model problem, i.e., the gas cooling for an optical window on a sphere cone, the hydrodynamic instability of the film is studied by the linear stability analysis to observe possible occurrence of laminar-turbulent transition.
文摘This paper describes possibilities to utilize sea water for district heating and cooling purposes in Tallinn costal area. The sea water temperature profiles and suitability of heating and cooling generation are studied for continental climatic conditions. The district network study bases on 21 buildings located near to the Gulf of Finland. Industrial reversible heat pump technology is selected to cover heating and cooling loads for the new buildings. Combination of existing district heating and heat pump technology is considered for existing buildings. The results show possibilities, threats and need for further research of the sea water based heat pump district network implementation.
文摘An analysis of atmospheric SW-radiative forcing and local heating/cooling rate is made using a one year temporal and vertical profiles of aerosol and cloud over Yaoundé (11.51°E, 3.83°N). It appears that the direct influence of aerosols on the surface compared to the TOA can be 3 times larger. Annual mean value obtained at 559 mb altitude is +27.74 W/m2 with range from 0 to +43 W/m2. At 904 mb, we obtained an annual mean of ﹣46.22 W/m2 with range from ﹣65 to ﹣9 W/m2. Frequency distribution indicates that more than 95% of ARF are between +10 and +70 W/m2 at 559 mb (upper limit of UL), and more than 85% of ARF are between ﹣70 and ﹣10 W/m2 at 904 mb (upper limit of PBL). This sign change is explained by the fact that the backscattering peaks at the upper limit of the aerosol PBL layer. The maximum CRF is noted at TOA where it reaches ﹣600 W/m2 based on the time interval and the structure of clouds. The highest values occur between 11.50 and 13.50 LST. Clouds lead to a general heating of the entire atmospheric column with a much greater effect near the surface. Aerosols effect on the heating rate profile show strong cooling during the day for the lower atmosphere, with slight heating at the upper atmosphere. This cooling contribution generally increases from the surface and peacks at the upper boundary of aerosol layer where reflectivity is the most important. Depending on the moment of the day, average heating effect of clouds peacks at surface or within the middle troposphere due to the absorption by clouds particles. Vertical profiles deeply evolve exhibiting differences that exceed ﹣3 K/day according to altitude from one hour to another during a given mean solar day.
基金This work was partially supported by the Brook Byers Institute for Sustainable Systems, the Hightower Chair, Georgia Research Alliance, and grants (083604, 1441208) from the US National Science Foundation Program for Emerging Frontiers in Research and Innovation (EFRI).