In this paper, the discussion is concentrated on the properties of the polluted sediments and the combination of clean-up and disposal process for the upper layer heavily polluted sediments with good flowability. Base...In this paper, the discussion is concentrated on the properties of the polluted sediments and the combination of clean-up and disposal process for the upper layer heavily polluted sediments with good flowability. Based on the systematic analyses of various clean-up processes, a suitable engineering process has been evaluated and recommended. The process has been applied to the river reclamation in Yangpu District of Shanghai City, China. An improved centrifuge is used for dewatering the dredged sludge, which plays an important role in the combination of clean-up and disposal process. The assessment of the engineering process shows its environmental and technical economy feasibility, which is much better than that of traditional dredging-disposal processes.展开更多
Advanced integrated gasification combined cycle (IGCC) power generation systems require the development of high-temperature, regenerable desulfurization sorbents, which are capable of removing hydrogen sulfide from ...Advanced integrated gasification combined cycle (IGCC) power generation systems require the development of high-temperature, regenerable desulfurization sorbents, which are capable of removing hydrogen sulfide from coal gasifier gas to very low levels. In this paper, zinc ferrites prepared by co-precipitation were identified as a novel coal gas desulfurization sorbent at high temperature. Preparation of zinc ferrite and effects of binders on pore volume, strength and desulfurization efficiency of zinc ferrite desulfurizer were studied. Moreover, the behavior of zinc ferrite sorbent during desulfurization and regeneration under the temperature range of 350-400 ℃ are investigated. Effects of binders on the pore volume, mechanical strength and desulfurization efficiency of zinc ferrite sorbents indicated that the addition of kaolinite to zinc ferrite desulfurizer seems to be superior to other binders under the experimental conditions.展开更多
A rapid, cost effective and reliable analytical method was developed and validated for the simultaneous determination of four estrogens (17 β-estradiol, 17 α-ethinylestradiol, estrone, and estriol) in compost sample...A rapid, cost effective and reliable analytical method was developed and validated for the simultaneous determination of four estrogens (17 β-estradiol, 17 α-ethinylestradiol, estrone, and estriol) in compost samples from the biodegradation of biological infectious hazardous wastes. Ultrasonic solvent extraction, using methanol as extraction solvent, coupled with SPE clean-up, using cartridges HLB 60 mg - 6 ml Supelco®<sup></sup> and acetonitrile for reconstitution of eluents, was used for the simultaneous extraction of the four estrogens. Mean recoveries in the range of 98% - 107% were obtained. All compounds were separated in a single gradient run by UHPLC Kinetex<sup>TM</sup> 2.6 μm XB-C18 100 ÅLC (50 × 4.6 mm) column. Analytes were detected via multiple reaction monitoring (MRM) using an AB SCIEX API-5000TM triple quadrupole (Applied Biosystems/MDS SCIEX) with electrospray ionization in negative mode. Isocratic mobile phase of Water:ACN (50:50) resulted to be the optimum. Limits of detection and quantification were on the order of 0.66 ng·g<sup>-1</sup> and 2 ng·g<sup>-1</sup> for all the estrogens. These limits were lower than most of the values reported in the literature for similar matrices. Suitable level of linearity, good repeatability and reproducibility with coefficients of variation is lower than 11.7%, 6.8% and 8.3%, respectively.展开更多
Sharp corners usually are used on glass contours to meet the highly increasing demand for personalized products,but they result in a broken wheel center toolpath in edge grinding.To ensure that the whole wheel center ...Sharp corners usually are used on glass contours to meet the highly increasing demand for personalized products,but they result in a broken wheel center toolpath in edge grinding.To ensure that the whole wheel center toolpath is of G1 continuity and that the grinding depth is controllable at the corners,a transition toolpath generation method based on a velocity-blending algorithm is proposed.Taking the grinding depth into consideration,the sharp-corner grinding process is planned,and a velocity-blending algorithm is introduced.With the constraints,such as traverse displacement and grinding depth,the sharp-corner transition toolpath is generated with a three-phase motion arrangement and with confirmations of the acceleration/deceleration positions.A piece of glass with three sharp corners is ground on a three-axis numerical-control glass grinding equipment.The experimental results demonstrate that the proposed algorithm can protect the sharp corners from breakage efficiently and achieve satisfactory shape accuracy.This research proposed a toolpath generation method based on a velocity-blending algorithm for the manufacturing of personalized glass products,which generates the transition toolpath as needed around a sharp corner in real time.展开更多
Tool path generated by space-filling curve always turns frequently causing trembling to machine,reducing toollife and affecting workpiece quality. Length and generation time of tool paths are both relatively long. In ...Tool path generated by space-filling curve always turns frequently causing trembling to machine,reducing toollife and affecting workpiece quality. Length and generation time of tool paths are both relatively long. In order to solve these problems,a toolpath generation method of NC milling based on space-filling curve is proposed. First,T-spline surface is regarded as the modeling surface,the grid,which is based on the limited scallop-height,can be got in the parameter space,and the influence value of grid node is determined. Second,a box is defined and planned,and the tool paths are got preliminarily,which is based on minimal spanning tree; Finally,based on an improved chamfering algorithm,the whole tool paths are got. A simulation system is developed for computer simulation,and an experiment is carried out to verify the method. The results of simulation and experiment show that the method is effective and feasible,and length and time of the tool paths are reduced.展开更多
Based on differential game theory,the decision-making problem of two homogeneous countries facing transboundary marine litter governance is studied.On the basis of assuming that the input of marine litter is an exogen...Based on differential game theory,the decision-making problem of two homogeneous countries facing transboundary marine litter governance is studied.On the basis of assuming that the input of marine litter is an exogenous variable,the focus is on reducing the accumulation of marine litter through cleanup and transfer processing by both parties.Considering the constant and increasing input of marine litter,in the framework of international agreement constraints,the analysis of the game behavior of the players in the marine litter governance under the open-loop strategy(in the case of agreement constraints)and the Markov strategy(in the case of no agreement constraints)was compared and analyzed.The research results show that when the direct pollution cost of marine litter is high enough,both sides of the game adopt an open-loop strategy that complies with the constraints of the agreement,which can reduce the accumulation of marine litter and improve the environmental quality.However,when there is a high initial accumulation of marine litter,the Markov strategy without protocol constraints will be better than the open-loop strategy.In the case that marine litter does not need to be transferred,there will be no difference between the two sides of the game adopting the Markov strategy and adopting the open-loop strategy on the equilibrium growth path.展开更多
文摘In this paper, the discussion is concentrated on the properties of the polluted sediments and the combination of clean-up and disposal process for the upper layer heavily polluted sediments with good flowability. Based on the systematic analyses of various clean-up processes, a suitable engineering process has been evaluated and recommended. The process has been applied to the river reclamation in Yangpu District of Shanghai City, China. An improved centrifuge is used for dewatering the dredged sludge, which plays an important role in the combination of clean-up and disposal process. The assessment of the engineering process shows its environmental and technical economy feasibility, which is much better than that of traditional dredging-disposal processes.
基金the Ministry of Science and Technology of China under the Grant No. G2005CB221203the Natural Science Foundation of China under Contract No. 20576087.
文摘Advanced integrated gasification combined cycle (IGCC) power generation systems require the development of high-temperature, regenerable desulfurization sorbents, which are capable of removing hydrogen sulfide from coal gasifier gas to very low levels. In this paper, zinc ferrites prepared by co-precipitation were identified as a novel coal gas desulfurization sorbent at high temperature. Preparation of zinc ferrite and effects of binders on pore volume, strength and desulfurization efficiency of zinc ferrite desulfurizer were studied. Moreover, the behavior of zinc ferrite sorbent during desulfurization and regeneration under the temperature range of 350-400 ℃ are investigated. Effects of binders on the pore volume, mechanical strength and desulfurization efficiency of zinc ferrite sorbents indicated that the addition of kaolinite to zinc ferrite desulfurizer seems to be superior to other binders under the experimental conditions.
文摘A rapid, cost effective and reliable analytical method was developed and validated for the simultaneous determination of four estrogens (17 β-estradiol, 17 α-ethinylestradiol, estrone, and estriol) in compost samples from the biodegradation of biological infectious hazardous wastes. Ultrasonic solvent extraction, using methanol as extraction solvent, coupled with SPE clean-up, using cartridges HLB 60 mg - 6 ml Supelco®<sup></sup> and acetonitrile for reconstitution of eluents, was used for the simultaneous extraction of the four estrogens. Mean recoveries in the range of 98% - 107% were obtained. All compounds were separated in a single gradient run by UHPLC Kinetex<sup>TM</sup> 2.6 μm XB-C18 100 ÅLC (50 × 4.6 mm) column. Analytes were detected via multiple reaction monitoring (MRM) using an AB SCIEX API-5000TM triple quadrupole (Applied Biosystems/MDS SCIEX) with electrospray ionization in negative mode. Isocratic mobile phase of Water:ACN (50:50) resulted to be the optimum. Limits of detection and quantification were on the order of 0.66 ng·g<sup>-1</sup> and 2 ng·g<sup>-1</sup> for all the estrogens. These limits were lower than most of the values reported in the literature for similar matrices. Suitable level of linearity, good repeatability and reproducibility with coefficients of variation is lower than 11.7%, 6.8% and 8.3%, respectively.
基金Supported by National Key R&D Program of China(Grant No.2017YFB0309800)National Natural Science Foundation of China(Grant No.51405445)
文摘Sharp corners usually are used on glass contours to meet the highly increasing demand for personalized products,but they result in a broken wheel center toolpath in edge grinding.To ensure that the whole wheel center toolpath is of G1 continuity and that the grinding depth is controllable at the corners,a transition toolpath generation method based on a velocity-blending algorithm is proposed.Taking the grinding depth into consideration,the sharp-corner grinding process is planned,and a velocity-blending algorithm is introduced.With the constraints,such as traverse displacement and grinding depth,the sharp-corner transition toolpath is generated with a three-phase motion arrangement and with confirmations of the acceleration/deceleration positions.A piece of glass with three sharp corners is ground on a three-axis numerical-control glass grinding equipment.The experimental results demonstrate that the proposed algorithm can protect the sharp corners from breakage efficiently and achieve satisfactory shape accuracy.This research proposed a toolpath generation method based on a velocity-blending algorithm for the manufacturing of personalized glass products,which generates the transition toolpath as needed around a sharp corner in real time.
基金Supported by the National Natural Science Foundation of China(No.51575143)
文摘Tool path generated by space-filling curve always turns frequently causing trembling to machine,reducing toollife and affecting workpiece quality. Length and generation time of tool paths are both relatively long. In order to solve these problems,a toolpath generation method of NC milling based on space-filling curve is proposed. First,T-spline surface is regarded as the modeling surface,the grid,which is based on the limited scallop-height,can be got in the parameter space,and the influence value of grid node is determined. Second,a box is defined and planned,and the tool paths are got preliminarily,which is based on minimal spanning tree; Finally,based on an improved chamfering algorithm,the whole tool paths are got. A simulation system is developed for computer simulation,and an experiment is carried out to verify the method. The results of simulation and experiment show that the method is effective and feasible,and length and time of the tool paths are reduced.
基金supported by the Qihang Project of Zhejiang University(Grant No.202016)。
文摘Based on differential game theory,the decision-making problem of two homogeneous countries facing transboundary marine litter governance is studied.On the basis of assuming that the input of marine litter is an exogenous variable,the focus is on reducing the accumulation of marine litter through cleanup and transfer processing by both parties.Considering the constant and increasing input of marine litter,in the framework of international agreement constraints,the analysis of the game behavior of the players in the marine litter governance under the open-loop strategy(in the case of agreement constraints)and the Markov strategy(in the case of no agreement constraints)was compared and analyzed.The research results show that when the direct pollution cost of marine litter is high enough,both sides of the game adopt an open-loop strategy that complies with the constraints of the agreement,which can reduce the accumulation of marine litter and improve the environmental quality.However,when there is a high initial accumulation of marine litter,the Markov strategy without protocol constraints will be better than the open-loop strategy.In the case that marine litter does not need to be transferred,there will be no difference between the two sides of the game adopting the Markov strategy and adopting the open-loop strategy on the equilibrium growth path.