An in-process technology approach is proposed to identify the source of acid mine drainage(AMD)generation and prevent its formation in a porphyry copper waste rock(WR).Adopting actions before stockpiling the WR enable...An in-process technology approach is proposed to identify the source of acid mine drainage(AMD)generation and prevent its formation in a porphyry copper waste rock(WR).Adopting actions before stockpiling the WR enables the establishment of potential contaminants and predicts the more convenient method for AMD prevention.A WR sample was separated into size fractions,and the WR’s net acidgenerating potential was quantified using chemical and mineralogical characterization.The diameter of physical locking of sulfides(DPLS)was determined,and the fractions below the DPLS were desulfurized using flotation.Finally,the WR fractions and tailing from the flotation test were submitted to acid-base accounting and weathering tests to evaluate their acid-generating potential.Results show that the WR’s main sulfide mineral is pyrite,and the DPLS was defined as 850μm.A sulfide recovery of 91%was achieved using a combination of HydroFloat^(®)and Denver cells for a size fraction lower than DPLS.No grinding was conducted.The results show that size fractions greater than DPLS and the desulfurized WR are unlikely to produce AMD.The outcomes show that in-processing technology can be a more proactive approach and an effective tool for avoiding AMD in a porphyry copper WR.展开更多
Eco-industry, circular economy, cleaner production, industrial ecology or industrial ecosystem and other subjects are all categories related to sustainable developinent. This paper studies the relations and difference...Eco-industry, circular economy, cleaner production, industrial ecology or industrial ecosystem and other subjects are all categories related to sustainable developinent. This paper studies the relations and differences between the four categories and sustainable development as well as ecological economics. Circular economy, eco-industry, industrial ecosystem and cleaner production were put forward during the revolution in “end treatment pattern” of traditional industrial society. Industrial ecology, eco-industry and circular economy theory are three content expansions of cleaner production. Ecological economics is of instructive function theoretically and methodologically for circular economy, eco-industrial, cleaner production and industrial ecology. Circular economy theory is easier to be accepted, compared with ecological economics theory. And circular economy in nature is the complete application of ecological economics theory.展开更多
A pulping method using NH4OH with less amount of KOH as cooking liquor on wheat straw was developed. KOH could reduce consumption of NH3 and cooking time for its strong alkalinity. The effects of various pulping condi...A pulping method using NH4OH with less amount of KOH as cooking liquor on wheat straw was developed. KOH could reduce consumption of NH3 and cooking time for its strong alkalinity. The effects of various pulping conditions such as composition of cooking liquor, liquid-to-solid ratio, maximum temperature, cooking time to the maximum temperature and cooking time at the maximum temperature were studied. Experimental results indicated that the rate of delignification was 85.12% and the pulp yield was 49.65% under suitable pulping conditions. It looks promising to use black liquor containing nitrogen, phosphorus, potassium and organic substance as fertilizer resources for agricultural production. A new pattern of ecological cycling may be set up between paper industry and farming.展开更多
Based on systematical research on the conception evolution of ecological enterprise, theoretical and practical development of constructing ecological enterprise, the paper makes conclusion that ecological enter- prise...Based on systematical research on the conception evolution of ecological enterprise, theoretical and practical development of constructing ecological enterprise, the paper makes conclusion that ecological enter- prises are developing into a new stage in which governments are launching some pilot projects about construct- ing ecological enterprises. And after that, governments should make policies to spread construction of ecological enterprises, to construct ecological enterprises in legal system and conforming to the standard as soon as possibly. So that, the basic units of ecological economy that fit to the conditions of China will be set up.展开更多
In order to promote cleaner production in China, a package of policy options was presented based on the identification of the barriers encountered in the CP demonstration project and the effectiveness and feasibility ...In order to promote cleaner production in China, a package of policy options was presented based on the identification of the barriers encountered in the CP demonstration project and the effectiveness and feasibility of policy options for the CP implementation were analyzed. Furthermore, the policy mechanism framework was given, which composes of compulsory, economic incentive, social pressure and supportive function. Finally, the implementation strategy of the policy mechanism, in which the emphasis will be changed from compulsory policy options towards economic and social pressure policy options, was proposed.展开更多
Pulping production process produces a large amount of wastewater and pollutant emitted, which has become one of the main pollution sources in pulp and paper industry. To solve this problem, it is necessary to implemen...Pulping production process produces a large amount of wastewater and pollutant emitted, which has become one of the main pollution sources in pulp and paper industry. To solve this problem, it is necessary to implement cleaner production by using modeling and optimization technology. This paper studies the modeling and multi\|objective genetic algorithms for continuous digester process. First, model is established, in which environmental pollution and saving energy factors are considered. Then hybrid genetic algorithm based on Pareto stratum\|niche count is designed for finding near\|Pareto or Pareto optimal solutions in the problem and a new genetic evaluation and selection mechanism is proposed. Finally using the real data from a pulp mill shows the results of computer simulation. Through comparing with the practical curve of digester,this method can reduce the pollutant effectively and increase the profit while keeping the pulp quality unchanged.展开更多
Rapid urbanization and growing size of cities will have an increasing impact on the global environment in the 21st century. As an engine of urban development to drive economic growth and technological innovations, ind...Rapid urbanization and growing size of cities will have an increasing impact on the global environment in the 21st century. As an engine of urban development to drive economic growth and technological innovations, industry has moved its focus from controlling environmental hazards to stimulating sustainable industrial development throughout the entire product lifecycle. These process- and technology-driven innovations for industrial production are prerequisites for enhancement of urban environment and sustainable development of cities. In this review, problems of environment and resources scarcity associated with rapid urbanization are demonstrated. And, on the basis of expatiations on the concepts and policies of the cleaner production(CP) and other similar initiatives with the goal of preventing pollution at the source and of managing the raw material more efficiently, two different ways to link the practice of cleaner production in industrial sector with performance of urban environment are discussed in detail. Then, the introduction, practice and legislation of CP strategies in China are outlined, and possibility for China to develop CPC (Cleaner Practices for Cities) approaches in the demonstration cities is discussed. Finally, some suggestions on implementation of CPC strategies are put forward.展开更多
It is necessary for the sintering process to carry out cleaner production, which is also of great significance to the iron and steel enterprises of a long-flow process. According to the cleaner production standard rec...It is necessary for the sintering process to carry out cleaner production, which is also of great significance to the iron and steel enterprises of a long-flow process. According to the cleaner production standard recently issued by China' s Ministry of Environmental Protection, the research detailed in this study has analyzed and estimated the level of cleaner production at Baosteel in the aspects of technical equipment, resource and energy utilization, product quality, emissions, recycling and environmental management, etc. The research also expatiated some effective measures with which cleaner production can be carried out in Baosteel's sintering process, and discovered some potential opportunities of cleaner production.展开更多
It is important to establish the evaluation system of the cleaner production of the mining enterprise, which canprovide the technical support and guidance for the cleaner production evaluation and facilitating the pro...It is important to establish the evaluation system of the cleaner production of the mining enterprise, which canprovide the technical support and guidance for the cleaner production evaluation and facilitating the promotion ofcleaner productive techniques so as to realize the integration of economic development and environmental protection.This paper, according to the characteristic of mining and Analytic Hierarchy Process (AHP), establishes the evaluationindex system, puts forward the overall quantitative evaluation method based on Fuzzy Mathematics and the experts’experience, and establishes the evaluation system of cleaner production. The main problems in cleaner production of themine are analyzed by calculation, and some countermeasures and suggestions are proposed.展开更多
In the study,the connotation and objectives of agricultural cleaner production were introduced firstly,and then the development status of agricultural cleaner production in China was analyzed,and the problems existing...In the study,the connotation and objectives of agricultural cleaner production were introduced firstly,and then the development status of agricultural cleaner production in China was analyzed,and the problems existing in the development of agricultural cleaner production were pointed out.From the strategy of agricultural sustainable development,the necessity and feasibility of implementing agricultural cleaner production in China were discussed.Finally,some related countermeasures were put forward according to the problems existing in the development of agricultural cleaner production,so as to provide theoretical references for the realization of agricultural sustainable development in China.展开更多
Cleaner Production focuses on environmental improvement with economic benefits. Based on the benefit assessment home and abroad, the assessment method and process in textile industry is discussed, including maneuverab...Cleaner Production focuses on environmental improvement with economic benefits. Based on the benefit assessment home and abroad, the assessment method and process in textile industry is discussed, including maneuverable indicator system, mathematics model. According to corresponding principles of Cleaner Production, representative problems are mentioned. With Analytic Hierarchy Process and Fuzzy Mathematics, some enterprise is collected to attain the economic, environmental and social benefit of Cleaner Production. The results show that Cleaner Production improves utilization efficiency of resources, energy sources even waste, and creates conditions of Sustainable Development in textile industry.展开更多
Numerous studies evaluated the effects of end-of-pipe control environmental regulations(EER).However,few scholars discussed the effects of process management environmental regulations(PER),such as the China Cleaner Pr...Numerous studies evaluated the effects of end-of-pipe control environmental regulations(EER).However,few scholars discussed the effects of process management environmental regulations(PER),such as the China Cleaner Production Standards(CCPS)implemented by the country's Ministry of Ecology and Environment.Using data on China's manufacturing enterprises,this paper adopts the CCPS policies as quasi-natural experiments and uses differences-in-differences(DID)methods to analyze their effects on enterprise profitability and profit quality,respectively.The results show that:first,the CCPS significantly improve both profitability and profit quality;that is,the implementation of the environmental regulation policy plays a significant role in improving enterprise profit rates and cash flows.Second,for the profitability mediator effects,the short-term Porter effect of CCPS is not significant but shows the opposite during the lag period and significantly reduces the management cost and wage levels,comprehensively promoting enterprise profitability.Third,for the profit quality meditator effects,environmental regulations improve the enterprises'cash flow by reducing management costs and increasing government subsidies;however,its effect on bank credit subsidies is not significant.Fourth,for the moderator effects,the environmental regulations'effect on enterprises profitability and profit quality depends on the strategic interaction among local governments,the scale and ownership of the enterprise,and regional differences.That is,the strategic interaction weakens the effect of environmental regulations on enterprise performance.Environmental regulations have a stronger influence on profitability and profit quality for large-scale,state-owned,and coastal enterprises.展开更多
The draft Integrated Pollution Prevention and Control(IPPC)regulation mandates compliance with best available techniques(BATs)for textile manufacturers.A study in Turkish textile facilities,covering 56 units across fo...The draft Integrated Pollution Prevention and Control(IPPC)regulation mandates compliance with best available techniques(BATs)for textile manufacturers.A study in Turkish textile facilities,covering 56 units across four sub-sectors,assessed the status of 488 BATs through on-site visits and surveys.The aim was to gauge the sector’s adherence to BATs.The findings revealed that 37% of surveyed BATs were fully implemented,rising to 88% when considering potential future implementations.This suggests a strong industry inclination toward adopting BATs for cleaner production and competitiveness.The study highlighted significant BAT-related investments in the textile sector,driven by environmental concerns,regulations,customer demands,resource efficiency,competition,and cost-benefit considerations.However,the study results also indicated that there is still much work to do for the implementation of some BATs.It was found that 60 BATs had lower implementation ratios(IR:0%-43%).Lower IR values for these BATs are mainly due to factors like specificity,high costs,long payback periods,operational difficulties,limited expertise,space constraints,customer requirements,quality concerns,operational issues,and sector-specific challenges.The study recommends similar assessments in other European industrial sectors to evaluate compliance with mandatory BATs outlined in the Industrial Emissions Directive.The insights from this study on the Turkish textile sector can serve as a valuable guide for future evaluations.展开更多
An environmentally friendly and resource-conserving route to the clean production of electrolytic manganese was developed,in which the electrolytic manganese residue(EMR)was initially calcined for cement buffering;the...An environmentally friendly and resource-conserving route to the clean production of electrolytic manganese was developed,in which the electrolytic manganese residue(EMR)was initially calcined for cement buffering;then the generated SO2-containing flue gas was managed using manganese oxide ore and anolyte(MOOA)desulfurization;at last,the desulfurized slurry was introduced to the electrolytic manganese production(EMP).Results showed that 4.0 wt%coke addition reduced the sulfur of calcined EMR to 0.9%,thereby satisfying the cement-buffer requirement.Pilot-scale desulfurization showed that about 7.5 vol%of high SO2 containing flue gas can be cleaned to less than 0.1 vol%through a five-stage countercurrent MOOA desulfurization.The desulfurized slurry had 42.44 g·L-Mn2+and 1.92 g·L-1 S2 O62-,which was suitable for electrowinning after purification,and the purity of manganese product was 99.93%,satisfy the National Standard of China YB/T051-2015.This new integrated technology fulfilled 99.7%of sulfur reutilization from the EMR and 94.1%was effectively used to the EMP.The MOOA desulfurization linked the EMP a closed cycle without any pollutant discharge,which promoted the cleaner production of EMP industry.展开更多
This paper presents a process development and design of chlorine dioxide production based on hydrogen peroxide. The process is characterized by cleaner production, high efficiency, and waste minimization. Optimization...This paper presents a process development and design of chlorine dioxide production based on hydrogen peroxide. The process is characterized by cleaner production, high efficiency, and waste minimization. Optimization of process conditions, selection of equipment, and experiment of recycle of waste acid are carried out. The process design is realized in consideration of several aspects such as operation, material, equipment design and safety. An industrialized process flowsheet is developed according to experiment. A pilot testing is carried out to confirm the lab results. Process design of chlorine dioxide production based on hydrogen peroxide is realized.展开更多
In this article, a kind of new method for production planning was put forward on the basis of traditional planning method by analyzing the characteristics of similar single-piece make to order(abbreviated as SSMO). Th...In this article, a kind of new method for production planning was put forward on the basis of traditional planning method by analyzing the characteristics of similar single-piece make to order(abbreviated as SSMO). Three points are important here: weakening the master production scheduling(MPS), stressing the rough scheduling(RS) and approving the components and parts scheduling(CPS).展开更多
基金supported by Agencia Nacional de Investigación y Desarrollo de Chile(ANID)Anillo-Grant ANID/ACT210027,Fondecyt 1211498,and ANID/AFB230001+1 种基金the ANID scholarship Grant 21210801partially performed by Luis Cisternas during the visit to the Universitédu Québec,supported by MINEDUC-UA project,code ANT1999.
文摘An in-process technology approach is proposed to identify the source of acid mine drainage(AMD)generation and prevent its formation in a porphyry copper waste rock(WR).Adopting actions before stockpiling the WR enables the establishment of potential contaminants and predicts the more convenient method for AMD prevention.A WR sample was separated into size fractions,and the WR’s net acidgenerating potential was quantified using chemical and mineralogical characterization.The diameter of physical locking of sulfides(DPLS)was determined,and the fractions below the DPLS were desulfurized using flotation.Finally,the WR fractions and tailing from the flotation test were submitted to acid-base accounting and weathering tests to evaluate their acid-generating potential.Results show that the WR’s main sulfide mineral is pyrite,and the DPLS was defined as 850μm.A sulfide recovery of 91%was achieved using a combination of HydroFloat^(®)and Denver cells for a size fraction lower than DPLS.No grinding was conducted.The results show that size fractions greater than DPLS and the desulfurized WR are unlikely to produce AMD.The outcomes show that in-processing technology can be a more proactive approach and an effective tool for avoiding AMD in a porphyry copper WR.
文摘Eco-industry, circular economy, cleaner production, industrial ecology or industrial ecosystem and other subjects are all categories related to sustainable developinent. This paper studies the relations and differences between the four categories and sustainable development as well as ecological economics. Circular economy, eco-industry, industrial ecosystem and cleaner production were put forward during the revolution in “end treatment pattern” of traditional industrial society. Industrial ecology, eco-industry and circular economy theory are three content expansions of cleaner production. Ecological economics is of instructive function theoretically and methodologically for circular economy, eco-industrial, cleaner production and industrial ecology. Circular economy theory is easier to be accepted, compared with ecological economics theory. And circular economy in nature is the complete application of ecological economics theory.
文摘A pulping method using NH4OH with less amount of KOH as cooking liquor on wheat straw was developed. KOH could reduce consumption of NH3 and cooking time for its strong alkalinity. The effects of various pulping conditions such as composition of cooking liquor, liquid-to-solid ratio, maximum temperature, cooking time to the maximum temperature and cooking time at the maximum temperature were studied. Experimental results indicated that the rate of delignification was 85.12% and the pulp yield was 49.65% under suitable pulping conditions. It looks promising to use black liquor containing nitrogen, phosphorus, potassium and organic substance as fertilizer resources for agricultural production. A new pattern of ecological cycling may be set up between paper industry and farming.
文摘Based on systematical research on the conception evolution of ecological enterprise, theoretical and practical development of constructing ecological enterprise, the paper makes conclusion that ecological enter- prises are developing into a new stage in which governments are launching some pilot projects about construct- ing ecological enterprises. And after that, governments should make policies to spread construction of ecological enterprises, to construct ecological enterprises in legal system and conforming to the standard as soon as possibly. So that, the basic units of ecological economy that fit to the conditions of China will be set up.
文摘In order to promote cleaner production in China, a package of policy options was presented based on the identification of the barriers encountered in the CP demonstration project and the effectiveness and feasibility of policy options for the CP implementation were analyzed. Furthermore, the policy mechanism framework was given, which composes of compulsory, economic incentive, social pressure and supportive function. Finally, the implementation strategy of the policy mechanism, in which the emphasis will be changed from compulsory policy options towards economic and social pressure policy options, was proposed.
基金TheNationNaturalScienceFoundationofChina (No .6 9974 0 34)
文摘Pulping production process produces a large amount of wastewater and pollutant emitted, which has become one of the main pollution sources in pulp and paper industry. To solve this problem, it is necessary to implement cleaner production by using modeling and optimization technology. This paper studies the modeling and multi\|objective genetic algorithms for continuous digester process. First, model is established, in which environmental pollution and saving energy factors are considered. Then hybrid genetic algorithm based on Pareto stratum\|niche count is designed for finding near\|Pareto or Pareto optimal solutions in the problem and a new genetic evaluation and selection mechanism is proposed. Finally using the real data from a pulp mill shows the results of computer simulation. Through comparing with the practical curve of digester,this method can reduce the pollutant effectively and increase the profit while keeping the pulp quality unchanged.
基金Under the auspices of Knowledge Innovation Project of Chinese Academy of Sciences (No. KZCX3-SW-427) Ma-jor State Basic Research Program of China (No. G1999045707)
文摘Rapid urbanization and growing size of cities will have an increasing impact on the global environment in the 21st century. As an engine of urban development to drive economic growth and technological innovations, industry has moved its focus from controlling environmental hazards to stimulating sustainable industrial development throughout the entire product lifecycle. These process- and technology-driven innovations for industrial production are prerequisites for enhancement of urban environment and sustainable development of cities. In this review, problems of environment and resources scarcity associated with rapid urbanization are demonstrated. And, on the basis of expatiations on the concepts and policies of the cleaner production(CP) and other similar initiatives with the goal of preventing pollution at the source and of managing the raw material more efficiently, two different ways to link the practice of cleaner production in industrial sector with performance of urban environment are discussed in detail. Then, the introduction, practice and legislation of CP strategies in China are outlined, and possibility for China to develop CPC (Cleaner Practices for Cities) approaches in the demonstration cities is discussed. Finally, some suggestions on implementation of CPC strategies are put forward.
文摘It is necessary for the sintering process to carry out cleaner production, which is also of great significance to the iron and steel enterprises of a long-flow process. According to the cleaner production standard recently issued by China' s Ministry of Environmental Protection, the research detailed in this study has analyzed and estimated the level of cleaner production at Baosteel in the aspects of technical equipment, resource and energy utilization, product quality, emissions, recycling and environmental management, etc. The research also expatiated some effective measures with which cleaner production can be carried out in Baosteel's sintering process, and discovered some potential opportunities of cleaner production.
文摘It is important to establish the evaluation system of the cleaner production of the mining enterprise, which canprovide the technical support and guidance for the cleaner production evaluation and facilitating the promotion ofcleaner productive techniques so as to realize the integration of economic development and environmental protection.This paper, according to the characteristic of mining and Analytic Hierarchy Process (AHP), establishes the evaluationindex system, puts forward the overall quantitative evaluation method based on Fuzzy Mathematics and the experts’experience, and establishes the evaluation system of cleaner production. The main problems in cleaner production of themine are analyzed by calculation, and some countermeasures and suggestions are proposed.
基金Supported by Natural Science Foundation of Hainan Province (40879)Key Subject "Cartography and Geographic Information System"and "Natural Geography" of Hainan Normal University
文摘In the study,the connotation and objectives of agricultural cleaner production were introduced firstly,and then the development status of agricultural cleaner production in China was analyzed,and the problems existing in the development of agricultural cleaner production were pointed out.From the strategy of agricultural sustainable development,the necessity and feasibility of implementing agricultural cleaner production in China were discussed.Finally,some related countermeasures were put forward according to the problems existing in the development of agricultural cleaner production,so as to provide theoretical references for the realization of agricultural sustainable development in China.
文摘Cleaner Production focuses on environmental improvement with economic benefits. Based on the benefit assessment home and abroad, the assessment method and process in textile industry is discussed, including maneuverable indicator system, mathematics model. According to corresponding principles of Cleaner Production, representative problems are mentioned. With Analytic Hierarchy Process and Fuzzy Mathematics, some enterprise is collected to attain the economic, environmental and social benefit of Cleaner Production. The results show that Cleaner Production improves utilization efficiency of resources, energy sources even waste, and creates conditions of Sustainable Development in textile industry.
基金This study is supported by the Dengfeng Strategy of the key discipline construction project,“Environmental Technology Economics”,at the Chinese Academy of Social Sciences[Grant number.2017-ZXKHJ]the National Social Science Fund Youth Fund Project:“Research on the effect Mechanism and Heterogeneity of Environmental Regulation on the Formation of Zombie Enterprises”[Grant number.19CJY028]+1 种基金General Project funded by the National Social Science Foundation:Economic Mechanism Analysis and Management Innovation System Study in Rural Water Environment Issues[Grant Number.10BJY064]the project funded by the Basic Business Fund of High Learning Institutions of the Central Government:Obstacles and Countermeasures to Spatial Integration of Economic Growth:with Yangtze River Economic Belt as an example[Grant number.20156322020201].
文摘Numerous studies evaluated the effects of end-of-pipe control environmental regulations(EER).However,few scholars discussed the effects of process management environmental regulations(PER),such as the China Cleaner Production Standards(CCPS)implemented by the country's Ministry of Ecology and Environment.Using data on China's manufacturing enterprises,this paper adopts the CCPS policies as quasi-natural experiments and uses differences-in-differences(DID)methods to analyze their effects on enterprise profitability and profit quality,respectively.The results show that:first,the CCPS significantly improve both profitability and profit quality;that is,the implementation of the environmental regulation policy plays a significant role in improving enterprise profit rates and cash flows.Second,for the profitability mediator effects,the short-term Porter effect of CCPS is not significant but shows the opposite during the lag period and significantly reduces the management cost and wage levels,comprehensively promoting enterprise profitability.Third,for the profit quality meditator effects,environmental regulations improve the enterprises'cash flow by reducing management costs and increasing government subsidies;however,its effect on bank credit subsidies is not significant.Fourth,for the moderator effects,the environmental regulations'effect on enterprises profitability and profit quality depends on the strategic interaction among local governments,the scale and ownership of the enterprise,and regional differences.That is,the strategic interaction weakens the effect of environmental regulations on enterprise performance.Environmental regulations have a stronger influence on profitability and profit quality for large-scale,state-owned,and coastal enterprises.
文摘The draft Integrated Pollution Prevention and Control(IPPC)regulation mandates compliance with best available techniques(BATs)for textile manufacturers.A study in Turkish textile facilities,covering 56 units across four sub-sectors,assessed the status of 488 BATs through on-site visits and surveys.The aim was to gauge the sector’s adherence to BATs.The findings revealed that 37% of surveyed BATs were fully implemented,rising to 88% when considering potential future implementations.This suggests a strong industry inclination toward adopting BATs for cleaner production and competitiveness.The study highlighted significant BAT-related investments in the textile sector,driven by environmental concerns,regulations,customer demands,resource efficiency,competition,and cost-benefit considerations.However,the study results also indicated that there is still much work to do for the implementation of some BATs.It was found that 60 BATs had lower implementation ratios(IR:0%-43%).Lower IR values for these BATs are mainly due to factors like specificity,high costs,long payback periods,operational difficulties,limited expertise,space constraints,customer requirements,quality concerns,operational issues,and sector-specific challenges.The study recommends similar assessments in other European industrial sectors to evaluate compliance with mandatory BATs outlined in the Industrial Emissions Directive.The insights from this study on the Turkish textile sector can serve as a valuable guide for future evaluations.
基金supported by the National Key R&D Program of China(No.2018YFC0213405)。
文摘An environmentally friendly and resource-conserving route to the clean production of electrolytic manganese was developed,in which the electrolytic manganese residue(EMR)was initially calcined for cement buffering;then the generated SO2-containing flue gas was managed using manganese oxide ore and anolyte(MOOA)desulfurization;at last,the desulfurized slurry was introduced to the electrolytic manganese production(EMP).Results showed that 4.0 wt%coke addition reduced the sulfur of calcined EMR to 0.9%,thereby satisfying the cement-buffer requirement.Pilot-scale desulfurization showed that about 7.5 vol%of high SO2 containing flue gas can be cleaned to less than 0.1 vol%through a five-stage countercurrent MOOA desulfurization.The desulfurized slurry had 42.44 g·L-Mn2+and 1.92 g·L-1 S2 O62-,which was suitable for electrowinning after purification,and the purity of manganese product was 99.93%,satisfy the National Standard of China YB/T051-2015.This new integrated technology fulfilled 99.7%of sulfur reutilization from the EMR and 94.1%was effectively used to the EMP.The MOOA desulfurization linked the EMP a closed cycle without any pollutant discharge,which promoted the cleaner production of EMP industry.
基金Supported by the Excellent Young Scientist Award of NSFC (20225620) the National Natural Science Foundation of China (No. 20376025) the Ministry of Education of China, the Bureau of Education of Guangdong Province.
文摘This paper presents a process development and design of chlorine dioxide production based on hydrogen peroxide. The process is characterized by cleaner production, high efficiency, and waste minimization. Optimization of process conditions, selection of equipment, and experiment of recycle of waste acid are carried out. The process design is realized in consideration of several aspects such as operation, material, equipment design and safety. An industrialized process flowsheet is developed according to experiment. A pilot testing is carried out to confirm the lab results. Process design of chlorine dioxide production based on hydrogen peroxide is realized.
文摘In this article, a kind of new method for production planning was put forward on the basis of traditional planning method by analyzing the characteristics of similar single-piece make to order(abbreviated as SSMO). Three points are important here: weakening the master production scheduling(MPS), stressing the rough scheduling(RS) and approving the components and parts scheduling(CPS).