Recently, owing to high costs and increasing demands for better catalysts, it is worthwhile to improve its activity and selectivity, and reduce its costs. Adding secondary promoters such as phosphorus, boron, magnesiu...Recently, owing to high costs and increasing demands for better catalysts, it is worthwhile to improve its activity and selectivity, and reduce its costs. Adding secondary promoters such as phosphorus, boron, magnesium, titanium, zinc and ruthenium to Co-Mo/Al;O;catalyst has been proved to be one of the ways to attain this result. The addition of those metals or metal oxides changes the surface states of molybdenumstructure.展开更多
A physical model based on similarity principles was built to simulate RH desulfurization process. In order to quantitatively analyze RH desulfurization process, a mathematical model was proposed. By analyzing experime...A physical model based on similarity principles was built to simulate RH desulfurization process. In order to quantitatively analyze RH desulfurization process, a mathematical model was proposed. By analyzing experimental results with the mathematical model, an empirical formula whose determination coefficient was 0.98 was given to express the relationship between transient desulfurization efficiency and time. All the determination coefficients of four fitted curves based on four repeated experiments with different gas flow rates were more than 0.94, which was the exact evidence of the rationality of the empirical formula. Meanwhile, it was found that transient desulfurization ability increased firstly and then decreased with increasing gas flow rate and reached the maximum value when the gas flow rate was 1.8 m^3/h. A plenty of repeated trials showed the same rule, which validated the mathematical model and the conclusions obtained from physical experiments.展开更多
文摘Recently, owing to high costs and increasing demands for better catalysts, it is worthwhile to improve its activity and selectivity, and reduce its costs. Adding secondary promoters such as phosphorus, boron, magnesium, titanium, zinc and ruthenium to Co-Mo/Al;O;catalyst has been proved to be one of the ways to attain this result. The addition of those metals or metal oxides changes the surface states of molybdenumstructure.
基金Item Sponsored by National Natural Science Foundation of China(51304016,51374021)
文摘A physical model based on similarity principles was built to simulate RH desulfurization process. In order to quantitatively analyze RH desulfurization process, a mathematical model was proposed. By analyzing experimental results with the mathematical model, an empirical formula whose determination coefficient was 0.98 was given to express the relationship between transient desulfurization efficiency and time. All the determination coefficients of four fitted curves based on four repeated experiments with different gas flow rates were more than 0.94, which was the exact evidence of the rationality of the empirical formula. Meanwhile, it was found that transient desulfurization ability increased firstly and then decreased with increasing gas flow rate and reached the maximum value when the gas flow rate was 1.8 m^3/h. A plenty of repeated trials showed the same rule, which validated the mathematical model and the conclusions obtained from physical experiments.
