Feasibility Investigation of Bitumen Properties by Blending of Coal Tar Pitch

There are numerous methods and additives available to improve the durability and quality of road bitumen. A coal tar obtained by coal coking was distilled in a laboratory into fractions of initial boiling point IBP-180℃ (gasoline-like fuel), 180℃ - 360℃ (diesel-like fuel), and >360℃ (residue or coal tar pitch). The coal tar pitch was added into road bitumen by up to 1 - 5 wt% and investigated the alteration of physical and chemical properties. The physico-mechanical properties of coal tar pitch and bitumen blends, as well as the chemical group composition, were determined using standard techniques (MNS) and the SARA method, respectively. Results of 3% coal tar pitch addition into bitumen enhanced ductility by 12.4% and softening point by 1.6℃. We found that blending with bitumen coal tar pitch as a modifier could improve bitumen properties.

Speciation and thermal transformation of sulfur forms in high-sulfur coal and its utilization in coal-blending coking process:A review

The utilization of high-sulfur coal is becoming more urgent due to the excessive utilization of low-sulfur,high-quality coal resources,and sulfur removal from high-sulfur coal is the most important issue.This paper reviews the speciation,forms and distribution of sulfur in coal,the sulfur removal from raw coal,the thermal transformation of sulfur during coal pyrolysis,and the sulfur regulation during coal-blending coking of high organic-sulfur coals.It was suggested that the proper characterization of sulfur in coal cannot be obtained only by either chemical method or instrumental characterization,which raises the need of a combination of current or newly adopted characterization methods.Different from the removal of inorganic sulfur from coal,the organic sulfur can only be partly removed by chemical technologies;and the coal structure and property,particularly high-sulfur coking coals which have caking ability,may be altered and affected by the pretreatment processes.Based on the interactions among the sulfur radicals,sulfur-containing and hydrogen-containing fragments during coal pyrolysis and the reactions with minerals or nascent char,regulating the sulfur transformation behavior in the process of thermal conversion is the most effective way to utilize high organic-sulfur coals in the coke-making industry.An in-situ regulation approach of sulfur transformation during coal-blending coking has been suggested.That is,the high volatile coals with an appropriate releasing temperature range of CH4 overlapping well with that of H2 S from high organic-sulfur coals is blended with high organic-sulfur coals,and the C–S/C–C bonds in some sulfur forms are catalytically broken and immediately hydrogenated by the hydrogencontaining radicals generated from high volatile coals.Wherein,the effect of mass transfer on sulfur regulation during the coking process should be considered for the larger-scale coking tests through optimizing the ratios of different coals in the coal blend.

Influence of coal blending on mineral transformation at high temperatures

Transformation of mineral matter is important for coal utilization at high temperatures.This is especially true for blended coal.XRD and FTIR were employed together to study the transformation of mineral matter at high temperature in blended coals.It was found that the concentration of catalytic minerals, namely iron oxides, increases with an increasing ratio of Shenfu coal, which could improve coal gasification.The transformation characteristics of the minerals in blended coals are not exactly predictable from the blend ratio.This was proved by comparing the iron oxide content to the blending ratio.The results from FTIR are comparable with those from XRD.FTIR is an effective method for examining variation in mineral matter.

Quality of Some Nigerian Coals as Blending Stock in Metallurgical Coke Production

Two Nigerian coals, Lafia-Obi and Chikila were blended in the mass ratio of 70:30 with imported American and Polish coking coals. Proximate analysis, free swelling index, Ruhr dilatometer and Gieseler plastometer were used in assessing the coking qualities of both the single coals and the blends. The results show that the blends are lower in moisture and ash contents;higher in volatile matter and fixed carbon than the single Nigerian coals. The rheological parameters revealed superiority in thermo-plastic properties of the blends over the unblended local coals. Lafia-Obi/Foreign coals blends possess lower ash and better rheological properties compared to Chikila/Foreign coal composites which have high ash and poor rheological properties. These together suggest that amongst the two Nigerian coals, Lafia-Obi is superior for blending with the foreign ones in metallurgical coke production.

Guidance method to use mixed coal in blending for coking

Based on the principle that the adaptation can be reflected by the overlap of reflectance distribution peaks,the effect of various types mixed coal for coking is analyzed.Based on the action of the vitrinite of different reflectance range and the adaptation,a new method for guidance blending coal is established.Through simulation,blending coal using the software of HD automatic microscope photometer,makes the synthetic blending coal reflectance distribution map to nothing notch wide single peak flat-shaped symmetrical distribution,blending coal random reflectance meets 1.1 - 1.2,the standard deviation meets 0.35 - 0.4.It is based on the conditions that active component in the blending is excessive.Using this method,the mixed coal can be used as much as possible and play a positive role.The problem about implementation process is discussed.

A New Distinguish Method of Blending Coals Slagging Characteristic

The slagging characteristic of coal effects the safe operation of boiler unit directly, the study on coal slagging is paid more and more attention by scholars of the world. Because of the complexity of coal characteristic, the blending coals slagging characteristic is more complex than single coal. The study method of blending coals characteristic is the same as the single coal method, but the simple method can’t distinguish the blending coals slagging characteristic well and truly. This paper gives the new distinguish method of blending coals slagging characteristic based on experimentation condition, it is the rate of slag and furnace refuse. The rate of slagging on furnace wall and the refuse on furnace bottom has utilized to distinguish the slagging characteristic of coal. The result shows that the rate of slag and furnace refuse method has better veracity.

COMPARING STUDY OF BLENDING PREHEATING MODIFIED COAL COKING AND STAMPING COKING FOR DONGSHEN COAL

The compaison of the properties of coke of three coking methods is introduced. The mechanical properties and high temperature reactivity of coke bleding preheating modified Dongshen coal are improved obviously than those of normal coke, and achieve or exceed that of stamping coke. This method shows more ability of expending coking coal resources.

Study on mathematical model of steam coal blending

It is necessary to set up a new mathematical model of steam coal blending instead of the old model. Indexes such as moisture content, ash content, volatile matter, sulfur content and heating value in the new mathematical model have linear relation. The new mathematical model can also predict ash-fusion temperature precisely by considering coal ash ratio in steam coal blending, therefore it is possible to obtain linear relation of ash-fusion temperature between single coal and steam coal blending. The new mathematical model can improve precision of steam coal blending and perfect the old mathematical model of steam coal blending.

Effect of Coal Gangue with Different Kaolin Contents on Compressive Strength and Pore Size of Blended Cement Paste

The effects of activated coal gangue on compressive strength, porosity and pore size distribution of hardened cement pastes were investigated. Activated coal gangue with two different kaolin contents, one higher and one lower, were used to partially replace Portland cement at 0%, 10%, and 30% by weight. The water to binder ratio（w/b） of 0.5 was used for all the blended cement paste mixes. Experimental results indicate that the blended cement of activated coal gangue mortar with higher kaolin mineral content has a higher compressive strength than that with lower kaolin mineral content. The porosity and pore size of blended cement mortar were significantly affected by the replacement of activated coal gangue.

Blended coals for improved coal water slurries

Three coal samples of different ranks were used to study the effect of coal blending on the preparation of Coal Water Slurry (CWS). The results show that by taking advantage of two kinds of coal, the coal concentration in slurry made from hard-to-pulp coal can be effectively improved and increased by 3%–5% generally. DLT coal (DaLiuTa coal mine) is very poor in slurryability and the stability and rheology of the resulting slurry are not very good. When the amount of easily slurried coal is more than 30%, all properties of the CWS improve and the CWS meets the requirements for use as fuel. Coalification, porosity, surface oxygenic functional groups, zeta potential and grindability have a great effect on the performance of blended coal CWS. This leads to some differences in performance between the slurry made from a single coal and slurry made from blended coal.

Additivity of pore structural parameters of granular activated carbons derived from different coals and their blends

A series of granular activated carbons （GACs） were prepared by briquetting method from Chinese coals of different ranks and their blends, with coal pitch as the binder. Pore structural parameters including BET specific surface area （SBEr）, total pore volume （Vr） and average pore diameter （da） were measured and cal- culated as well as process parameters such as yield of char （CY） and burn-off （B）. The relationship between the pore structural parameters of the GAC from coal blend （BC-GAC） and the ones of the GACs from corresponding single coals （SC-GACs） was analyzed, in which an index, the relative error （δ）, was presented to define the bias between fitted values and experimental values of these parameters of the BC-GACs. The results show that the BC-GAC keeps qualitatively the pore structural features of the SC-GACs; as concerned as the quantitative relationship, the pore structural parameters of the BC-GAC from coal blend consisting of non-caking coals can be obtained by adding proportionally the pore structural parameters of the SC-GACs with a less than 10%. Meanwhile, for the BC-GAC from coal blend containing weak caking bituminous coal, the δ increases up to 25% and the experimental pore size distribution differs greatly from the fitted one.

Characterization of bio-coal briquettes blended from low quality coal and biomass waste treated by Garant■bio-activator and its application for fuel combustion

Experimental research was carried out on the manufacturing of bio-coal briquettes from a blend of two different types of low-quality coal and biomass waste in the absence of coal carbonization,where the third blend of the material was fermented by adding a bio-activator solution before pressurizing the components into briquettes.The coal samples from Caringin-Garut Regency(BB-Garut)had a low calorific value and a high sulfur content(6.57 wt%),whereas the coal samples from Bayah-Lebak Regency(BB-Bayah)had a higher calorific value and a lower sulfur content(0.51 wt%).The biomass added to the coal blend is in the form of fermented cow dung(Bio-Kohe),and it had a calorific value of 4192 kcal/kg and a total sulfur content of 1.56 wt%.The main objective of this study is to determine the total decrease in the sulfur content in a blend of coal and biomass in which a fennentation process was carried out using a bio-activator for 24 h.The used bio-activator was made from Garant■(1:40)+molasses 1 wt%/vol,and its used amount was 0.2 L/kg.Also,the total sulfur content in the blend was 1.00 wt%-1.14 wt%,which fulfills the necessary quality requirements for non-carbonized bio-coal briquettes.The pyritic and sulfate content in the raw coal was dominant,and the organic sulfur,when fermented with Garant■,was found to be less in the produced bio-coal briquettes by 38%-58%.

Experimental Research on Spontaneous Combustion Tendency of High Volatile Blended Coals

Experiment of oxidation characteristics with slow velocity of high volatile blended coals was investigated in the surroundings of low oxygen conditions, which gives three kinetic factors in the step of low temperature through the methods of thermo gravimetric analysis, the Coats-Redfern integration and Achar-Brindley-Sharp-Wendworth. The results of calculation show that activation energy and pre-exponential factor increase with the reaction process, and tendency of spontaneous combustion of the blended coal have changed. The experimental results show that the type of absorbing oxygen is mainly physical adsorption and calorific value is very small during increasing weight. Volatile of blended coal releases before single coal and combustion temperature of blended coal is between one and other single coals. If the oxygen content is below 16% in the milling system, explosion-proof effect on high volatile blended coal can be obtained.

Coal washing improvement by determination of optimal mixture of feed blends

Coals from different mines are feed in the Zirab plant without any control on weight percentage blending of them. Three major coal types of different ranks (Kiasar, Lavidj and Karmozd) were blended in various proportions to find an optimum condition in flotation circuit in Alborz Markazi coal washing plant. Flotation tests were conducted for prepared blended coal samples to assess floatability of various coal samples. In this paper, mixture design as a statistical method was used to optimize coal blend to increase recovery and grade in Zirab coal washing plant. The statistical analysis showed that the weight percent blending of different coals and interaction between Lavidj and Karmozd regions coal had significant effects on the coal recovery. The optimum condition of 95% recovery and 12% ash content could be reached with 10%, 20%, and 70% blending portion of Kiasar, Lavidj and Karmozd regions coal, respectively.

Blended coal’s property prediction model based on PCA and SVM

In order to predict blended coal's property accurately, a new kind of hybrid prediction model based on principal component analysis (PCA) and support vector machine (SVM) was established. PCA was used to transform the high-dimensional and correlative influencing factors data to low-dimensional principal component subspace. Well-trained SVM was used to extract influencing factors as input to predict blended coal's property. Then experiments were made by using the real data, and the results were compared with weighted averaging method (WAM) and BP neural network. The results show that PCA-SVM has higher prediction accuracy in the condition of few data, thus the hybrid model is of great use in the domain of power coal blending.

Combustion characteristics of high ash Indian thermal,heat affected coal and their blends

Onsite mine fire generates large volumes of heat-affected coal in Jharia coalfields,India.Direct utilization of such heat-affected coal in thermal utilities is not feasible as such coal does not have the desirable volatile matter required for combustion.In the present work,experimental studies have been carried out to investigate the possible utilization of such heat-affected coal in thermal utilities by blending with other coal.Heat-affected coal(31%ash and 5300 kcal/kg GCV)collected from Jharia coalfield were blended with thermal coal(28%ash and 5650 kcal/kg GCV)in different ratios of 90:10,80:20,70:30 and 60:40 to identify the desirable blend ratio for burning of blended coal in thermal utilities.Burning characteristics of all the coals were carried out using TGA.Various combustion parameters such as ignition temperature,peak temperature,burnout temperature,ignition index,burnout index,combustion performance index,rate and heat intensity index of the combustion process and activation energy were evaluated to analyse the combustion process.Experimental and theoretical analysis shows the blend ratio of 90:10 can be used in place of only thermal coal in utilities to reduce the fuel cost.

Thermal Behavior of Coal and Biomass Blends in Inert and Oxidizing Gaseous Environments

Oxy-fuel combustion and gasification (pre-combustion) may have potential for capturing carbon dioxide at lower costs for power generation. Oxy-co-firing and co-gasifying coal with biomass could further reduce effective CO2 emissions and utilize renewable energy resources. A key feature of these two approaches is that they process fuel in concentrated CO2 or O2/CO2 instead of N2 or O2/N2. Accurate predictive models of these processes using blends of coal and biomass can be used in process simulation and could aid in the development and implementation of these technologies. To develop these accurate predictive models, it is important to understand the conversion routes and thermal behavior of these fuels in appropriate gas environments. The objectives of this study are to investigate the impact of inert and oxidative gaseous environments on thermal behavior and reactivity of coal and biomass blends and to study the effect of biomass percentage on coal/biomass blend co-utilization. Fuel samples included a Powder River Basin (PRB) sub-bituminous coal, yellow pine wood sawdust pellets, and mixtures of 10 and 20 weight percent wood in coal. The samples were tested under N2, CO2, and 10% O2 in CO2 by volume using a non-isothermal thermogravimetric method for temperatures up to 1000℃. Fuel weight losses of both coal and wood are essentially the same in CO2 as in N2 in the low temperature range, but higher in 10% O2 in CO2 compared to N2 and CO2. However, total weight losses at 1000℃ under CO2 and 10% O2 in CO2 are similar and higher than in N2 due to char gasification by the CO2 and combustion by O2. The char combustion in 10% O2 in CO2 takes place at lower temperature than char gasification in CO2. Coal and wood blends have higher reactivity compared to coal alone in the lower temperature range due to the high volatile matter content of wood. Interactions of wood and coal in these gas environments and blend percentage are discussed.

The Effects of Blends of Enugu Coal and Anthracite on Tin Smelting Using Nigerian Dogo Na Hauwa Cassiterite

The effects of blending Enugu coal and anthracite on tin smelting using Nigerian Dogo Na Hauwa cassiterite have been studied. The work utilized various blends ranging from 100% to 0% anthracite. The content of the Enugu coal in the blend varied from 5% to 100%. The various tin metal recovery percentage for each batch of smelting using various blends was noted. Anthracite alone had the highest recovery of 71.90% followed by 5% blend of Enugu with anthracite. The result, however, showed that as the Enugu Coal was increased in the blend, the recovery was also decreasing. This equally affected the quality of tin metal recovered by increasing the grade. The work recommended that since the cost of production is the critical issue, 5% - 15% range of Enugu Coal should be used in preparing blends to bring down the cost of imported anthracite which is put at $906.69 per ton. The use of 15% Enugu coal will result in lowering the cost of imported anthracite by $136.0.

Study on combustion kinetics of the blend melt with coal and waste plastic

The combustiondynamic experiments of blend-melt samples of blending pulverized coal and waste plastic are carried out in different proportions at different combustion temperatures.The experiment shows that all of correlation coefficients for fitting straight lines of curve F(a)-1/T of the blend-melt samples are above 0.95,which indicates that the combustion of samples conforms to the rules of first order reaction.The experiment also shows that the activation energy is the lowest and the combustion becomes easier with the mix proportion of 20%-25% at 200 ℃.

Thermal decomposition analysis of coal-waste sludge and coal-sunflower seed husk blends

The thermal decomposition analysis of coal-pharmaceutical waste sludge,coal-sewage waste sludge blends and coal-sunflower seed husk blends are studied by TG dynamic runs at the heating rate of 20 ℃/min within the temperature range of 25 ℃-900 ℃.The effect of different kinetic models on the determination of kinetic parameters of thermal decomposition has been investigated.Results show that for coal-pharmaceutical sludge blend,coal-sewage sludge blend and coal-sunflower seed husk blend the optimal model functions are the three-dimensional diffusion reaction,2-dimensional and 3-diemensional nucleation and growth reactions,respectively.The Arrhenius kinetic parameters of the pre-exponential factor and activation energy of blends,as well waste sludge and sunflower seed husk only are proposed.