We investigated the photocatalytic degradation of dye wastewater by using titanium dioxide (TiO2) coated on a coal cinder. The coal cinder was used as the carrier, with a thin film of TiO2 coated on it by using the so...We investigated the photocatalytic degradation of dye wastewater by using titanium dioxide (TiO2) coated on a coal cinder. The coal cinder was used as the carrier, with a thin film of TiO2 coated on it by using the sol-gel method. Using the Congo red as the model pollutant for dye wastewater, we studied the decolorization efficiency, and effects of TiO2 film thickness and roasting temperature on the efficiency. We also evaluated the recycling and regeneration of the immobilized TiO2 (TiO2/cinder). Results show that the decolorization rate of Congo red solution was more than 98% after 2 h treatment when we used TiO2/cinder calcined at 500 °C for 2 h and coated four times as the photocatalyst. At the same time, the TiO2/cinder remained high catalytic activity after being reused and regenerated for many times.展开更多
[Objective]The research was designed to explore the effect of long-term stacking of solid waste produced in the coal-burning process of central heating enterprises on physical and chemical properties of soil.[Method]T...[Objective]The research was designed to explore the effect of long-term stacking of solid waste produced in the coal-burning process of central heating enterprises on physical and chemical properties of soil.[Method]This study took the heating enterprises in Shenyang City as the research object.The morphological structure and element composition of coal cinder were determined by continuously collecting coal and cinder samples in different periods.At the same time,the original soil and cinder soil of the stacking site were collected to determine the changes of soil morphological structure,element composition and physical and chemical properties,so as to provide reference for the resource utilization of local cinder waste and the potential pollution risk of the stacking site.[Result]The contents of C,H,O,N,and S non-metallic elements in coal cinder decreased by 69.5%,71.2%,76.0%,74.5%,and 34.6%,respectively when compared with raw coal;while the content of Si increased significantly by 95.7%.The contents of Al,K,and Fe in cinder decreased by 4.3%,60.2%,and 33.3%,respectively,while the contents of Mg and Na increased by 36.1%and 130.9%,respectively.Compared with the original soil,the contents of C,H,and O in shallow cinder soil and deep cinder soil increased by 126.5%,67.9%,80.93%,and 21.3%,25.0%and 42.3%,respectively.The residual carbon existed in the form of activated carbon.The contents of Mg,Al,K,Na,Ca,and Fe in shallow cinder soil and deep cinder soil increased by 61.6%,5.4%,46.1%,35.8%,32.5%,6.3%and 22.3%,12.3%,12.2%,15.6%,5.8%and 2.8%,respectively compared with the original soil.The content of heavy metal elements in coal cinder did not reach the detection limit.Under the scanning electron microscope,the raw coal is mainly block structure,while the cinder is honeycombed and porous and dust.[Conclusion]Cinder stacking can significantly improve the content of organic matter and available K in shallow cinder soil,and improve the porosity and permeability of soil.In addition,cinder waste has high pH and pore structure,which can be used as acid soil conditioner,seedling flower matrix and compound fertilizer filler to take full advantage of cinder waste,improve soil structure and supply nutrients.展开更多
This paper reports methods and results of the investigation of natural radionuclides levels in multiple me-dia in the bone-coal mine areas in Hubei, Hunan, Jiangxi, Zhejiang, and Anhui Provinces. In the studied bone-c...This paper reports methods and results of the investigation of natural radionuclides levels in multiple me-dia in the bone-coal mine areas in Hubei, Hunan, Jiangxi, Zhejiang, and Anhui Provinces. In the studied bone-coal mine areas, the specific activities of 238U and 226Ra in the soil samples were 0.37 and 0.24 Bq/g, respectively; the spe-cific activities of 226Ra in the samples of bone-coal, bone-coal cinder and bone-coal cinder brick (BCCB) were 1.3, 1.4 and 0.9 Bq/g, respectively. In the water samples collected from the bone-coal mine areas, the average concentra-tions of natural uranium and 226Ra were 33μg/L and 58 mBq/L, respectively, while in the water samples collected from outside the bone-coal mine areas, they were 3.4μg/L and 45 mBq/L, respectively. In addition, the specific activi-ties of 238U and 226Ra in air aerosol samples from the bone-coal mine areas were 0.6 and 0.5 mBq/m3, respectively.展开更多
During 1991-1993,the activity levels of the bone-coal mines were investigated in Zhejiang,Hubei,Hunan,Jiangxi and Anhui Province,respectively,where the reserve of bone-coal is about 90% of our country’s total reserve...During 1991-1993,the activity levels of the bone-coal mines were investigated in Zhejiang,Hubei,Hunan,Jiangxi and Anhui Province,respectively,where the reserve of bone-coal is about 90% of our country’s total reserve.The average of γ radiation doserate level measured for bone-coal,bone-coal cinder(BCC) and bone-coal cinder brick(BCCB) in these provinces is about 500 nGy/h,400 nGy/h and 700 nGy/h respectively,while that for fields,roads and houses made of BCCB in corresponding regions of these provinces is about 200 nGy/h,260 nGy/h and 300 nGy/h respectively.It is shown that the environmental activity level of bone-coal mining area is about 3 times higher than the reference spots.展开更多
It was investigated that the radon concentrations in bone-coal mining areas,in outside and inside BCCB houses and ordinary red-brick (ORB) houses of the reference points in Hubei,Hunan,Jiangxi,Zhejiang and Anhui Provi...It was investigated that the radon concentrations in bone-coal mining areas,in outside and inside BCCB houses and ordinary red-brick (ORB) houses of the reference points in Hubei,Hunan,Jiangxi,Zhejiang and Anhui Provinces. It was shown that the average annual radon concentration inside BCCB houses in the bone-coal mining areas in the five provinces ranges from 85.7 to 303 Bq/m3,with an average of 151 Bq/m3,which is 3 times that inside ORB houses at the reference points. The average annual radon concentration outside BCCB houses in the bone-coal mining areas in the five provinces ranges from 12.0 to 73.8 Bq/m3,with an average of 34.9 Bq/m3,which is 1.5 times that outside ordinary ORB at the reference points. And the radon concentration in shafts of Hubei and Zhejiang Prov- ince is 9.51×103 Bq/m3 and 965 Bq/m3,respectively. This report also shows the changing patterns of radon concen- trations with day,season,height,etc.展开更多
基金Funded by the Youth Fund Project of Yibin University (No. QJ05-28)
文摘We investigated the photocatalytic degradation of dye wastewater by using titanium dioxide (TiO2) coated on a coal cinder. The coal cinder was used as the carrier, with a thin film of TiO2 coated on it by using the sol-gel method. Using the Congo red as the model pollutant for dye wastewater, we studied the decolorization efficiency, and effects of TiO2 film thickness and roasting temperature on the efficiency. We also evaluated the recycling and regeneration of the immobilized TiO2 (TiO2/cinder). Results show that the decolorization rate of Congo red solution was more than 98% after 2 h treatment when we used TiO2/cinder calcined at 500 °C for 2 h and coated four times as the photocatalyst. At the same time, the TiO2/cinder remained high catalytic activity after being reused and regenerated for many times.
基金Supported by Open Fund Project of the Key Laboratory of Waste Fertilizer Utilization of the Ministry of Agriculture and Rural Areas (KLFAW201901)
文摘[Objective]The research was designed to explore the effect of long-term stacking of solid waste produced in the coal-burning process of central heating enterprises on physical and chemical properties of soil.[Method]This study took the heating enterprises in Shenyang City as the research object.The morphological structure and element composition of coal cinder were determined by continuously collecting coal and cinder samples in different periods.At the same time,the original soil and cinder soil of the stacking site were collected to determine the changes of soil morphological structure,element composition and physical and chemical properties,so as to provide reference for the resource utilization of local cinder waste and the potential pollution risk of the stacking site.[Result]The contents of C,H,O,N,and S non-metallic elements in coal cinder decreased by 69.5%,71.2%,76.0%,74.5%,and 34.6%,respectively when compared with raw coal;while the content of Si increased significantly by 95.7%.The contents of Al,K,and Fe in cinder decreased by 4.3%,60.2%,and 33.3%,respectively,while the contents of Mg and Na increased by 36.1%and 130.9%,respectively.Compared with the original soil,the contents of C,H,and O in shallow cinder soil and deep cinder soil increased by 126.5%,67.9%,80.93%,and 21.3%,25.0%and 42.3%,respectively.The residual carbon existed in the form of activated carbon.The contents of Mg,Al,K,Na,Ca,and Fe in shallow cinder soil and deep cinder soil increased by 61.6%,5.4%,46.1%,35.8%,32.5%,6.3%and 22.3%,12.3%,12.2%,15.6%,5.8%and 2.8%,respectively compared with the original soil.The content of heavy metal elements in coal cinder did not reach the detection limit.Under the scanning electron microscope,the raw coal is mainly block structure,while the cinder is honeycombed and porous and dust.[Conclusion]Cinder stacking can significantly improve the content of organic matter and available K in shallow cinder soil,and improve the porosity and permeability of soil.In addition,cinder waste has high pH and pore structure,which can be used as acid soil conditioner,seedling flower matrix and compound fertilizer filler to take full advantage of cinder waste,improve soil structure and supply nutrients.
基金Supported by State Environment Protection Bureau and Chinese Nuclear Indnstry Corporation (Project No.90201001)
文摘This paper reports methods and results of the investigation of natural radionuclides levels in multiple me-dia in the bone-coal mine areas in Hubei, Hunan, Jiangxi, Zhejiang, and Anhui Provinces. In the studied bone-coal mine areas, the specific activities of 238U and 226Ra in the soil samples were 0.37 and 0.24 Bq/g, respectively; the spe-cific activities of 226Ra in the samples of bone-coal, bone-coal cinder and bone-coal cinder brick (BCCB) were 1.3, 1.4 and 0.9 Bq/g, respectively. In the water samples collected from the bone-coal mine areas, the average concentra-tions of natural uranium and 226Ra were 33μg/L and 58 mBq/L, respectively, while in the water samples collected from outside the bone-coal mine areas, they were 3.4μg/L and 45 mBq/L, respectively. In addition, the specific activi-ties of 238U and 226Ra in air aerosol samples from the bone-coal mine areas were 0.6 and 0.5 mBq/m3, respectively.
基金Supported by State Environment Protection Bureau and Chinese Nuclear Industry Corporation (Project No.90201001)
文摘During 1991-1993,the activity levels of the bone-coal mines were investigated in Zhejiang,Hubei,Hunan,Jiangxi and Anhui Province,respectively,where the reserve of bone-coal is about 90% of our country’s total reserve.The average of γ radiation doserate level measured for bone-coal,bone-coal cinder(BCC) and bone-coal cinder brick(BCCB) in these provinces is about 500 nGy/h,400 nGy/h and 700 nGy/h respectively,while that for fields,roads and houses made of BCCB in corresponding regions of these provinces is about 200 nGy/h,260 nGy/h and 300 nGy/h respectively.It is shown that the environmental activity level of bone-coal mining area is about 3 times higher than the reference spots.
基金Supported by State Environment Protection Bureau and Chinese Nuclear Industry Corporation (Project No.90201001)
文摘It was investigated that the radon concentrations in bone-coal mining areas,in outside and inside BCCB houses and ordinary red-brick (ORB) houses of the reference points in Hubei,Hunan,Jiangxi,Zhejiang and Anhui Provinces. It was shown that the average annual radon concentration inside BCCB houses in the bone-coal mining areas in the five provinces ranges from 85.7 to 303 Bq/m3,with an average of 151 Bq/m3,which is 3 times that inside ORB houses at the reference points. The average annual radon concentration outside BCCB houses in the bone-coal mining areas in the five provinces ranges from 12.0 to 73.8 Bq/m3,with an average of 34.9 Bq/m3,which is 1.5 times that outside ordinary ORB at the reference points. And the radon concentration in shafts of Hubei and Zhejiang Prov- ince is 9.51×103 Bq/m3 and 965 Bq/m3,respectively. This report also shows the changing patterns of radon concen- trations with day,season,height,etc.
