Coal fires have a very long history in China; the oldest coal fires have being burning for many million years. Up to now more than 56 coal fires spots were distin-guished. They mainly locate in West-North of China, No...Coal fires have a very long history in China; the oldest coal fires have being burning for many million years. Up to now more than 56 coal fires spots were distin-guished. They mainly locate in West-North of China, North of China and East-North of China. About millions of tons of coal have been burned in fires every year. Xinjiang Autonomy is the most serious region in coal fires as it has 38 coal fires spots and about 6.85 million tons of coal was burned every year. Coal fires in China ignited by wildfires, spontaneous combustion and human being during mining activities. These fires have re-leased about 0.9 million tons of gasses (including CO, CO2, SO2, NO2 CH4, CO2, H2S etc.) into the atmosphere every year, most of which are brought to the east by wind and result-ing more heavier air pollution in northern China.展开更多
Since the combustion system of coal-fired boiler in thermal power plant is characterized as time varying, strongly coupled, and nonlinear, it is hard to achieve a satisfactory performance by the conventional proportio...Since the combustion system of coal-fired boiler in thermal power plant is characterized as time varying, strongly coupled, and nonlinear, it is hard to achieve a satisfactory performance by the conventional proportional integral derivative (PID) control scheme. For the characteristics of the main steam pressure in coal-fired power plant boiler, the sliding mode control system with Smith predictive structure is proposed to look for performance and robustness improvement. First, internal model control (IMC) and Smith predictor (SP) is used to deal with the time delay, and sliding mode controller (SMCr) is designed to overcome the model mismatch. Simulation results show the effectiveness of the proposed controller compared with conventional ones.展开更多
Coal seam pyrolysis occurs during coal seam fires and during underground coal gasification. This is an important source of polycyclic aromatic hydrocarbon (PAH) emission in China. Pyrolysis in a coal seam was simula...Coal seam pyrolysis occurs during coal seam fires and during underground coal gasification. This is an important source of polycyclic aromatic hydrocarbon (PAH) emission in China. Pyrolysis in a coal seam was simulated in a tubular furnace. The 16 US Environmental Protection Agency priority controlled PAHs were analyzed by HPLC. The effects of temperature, heating rate, pyrolysis atmosphere, and coal size were investigated. The results indicate that the 3-ring PAHs AcP and AcPy are the main species in the pyrolysis gas. The 2-ring NaP and the 4-ring Pyr are also of concern. Increasing temperature caused the total PAH yield to go through a minimum. The lowest value was obtained at the temperature of 600℃. Higher heating rates promote PAH formation, especially formation of the lower molecular weight PAHs. The typical heating rate in a coal seam, 5 ℃/min, results in intermediate yields of PAHs. The total PAHs yield in an atmosphere of N2 is about 1.81 times that seen without added N2, which indicates that an air flow through the coal seam accelerates the formation of PAHs. An increase in coal particle size reduces the total PAHs emission but promotes the formation of 5- and f-ring PAHs.展开更多
According to statistics, the average dust collection efficiency of flue gas emission in the large and medium- sized power plants in Zhejiang Province at present has attained higher than 97% which surpasses the 95% sta...According to statistics, the average dust collection efficiency of flue gas emission in the large and medium- sized power plants in Zhejiang Province at present has attained higher than 97% which surpasses the 95% standard as stipulated by the Ministry of Electric Power. The dust collection efficiency of the Beilungang Power Plant has already attained 99.92%. In recent years, Zhejiang Electric Power Corporation has stipulated that all the newly constructed generating units shall be equipped with high efficiency electrostatic precipitator (ESP) while the existing power plants shall speed up their renovation work for their dust collectors. In combination with the fourth stage project of the Taizhou Power Plant, the improvement work of the dust展开更多
The physical,chemical and mineral facies properties of the flyash from Xiezhuang Coal Refuse Fired Power Plant have been studied by means of naked eyes,microscope,chemical composition analysis and XRD analysis,and com...The physical,chemical and mineral facies properties of the flyash from Xiezhuang Coal Refuse Fired Power Plant have been studied by means of naked eyes,microscope,chemical composition analysis and XRD analysis,and compared with that of the flyash from Taian Coal Fired Power Plant.The result shows that the flyash from coal refuse fired power plant is of better quality in making construction items,for being brighter in color,fine and high activity.Some ways of comprehensive utilization of the ash have been suggested in this paper.展开更多
The in-situ instrumentation technique for measuring mercury and itsspeciation downstream a utility 100 MW pulverized coal (PC) fired boiler system was developed andconducted by the use of the Ontario hydro method (OHM...The in-situ instrumentation technique for measuring mercury and itsspeciation downstream a utility 100 MW pulverized coal (PC) fired boiler system was developed andconducted by the use of the Ontario hydro method (OHM) consistent with American standard test methodtogether with the semi-continuous emissions monitoring (SCEM) system as well as a mobile laboratoryfor mercury monitoring. The mercury and its speciation concentrations including participate mercuryat three locations of before air preheater, before electrostatic precipitator (ESP) and after ESPwere measured using the OHM and SCEM methods under normal operation conditions of the boiler systemas a result of firing a bituminous coal. The vapor-phase total mercury Hg(VT) concentration declinedwith the decrease of flue gas temperature because of mercury species transformation from oxidizedmercury to particulate mercury as the flue gas moved downstream from the air preheater to the ESPand after the ESP. A good agreement for Hg°, Hg^(2+) and Hg( VT) was obtained between the twomethods in the ash-free area. But in the dense particle-laden flue gas area, there appeared to be abig bias for mercury speciation owing to dust cake formed in the filter of OHM sampling probe. Theparticulateaffinity to the flue gas mercury and the impacts of sampling condition to accuracy ofmeasure were discussed.展开更多
基金Supported by National Natural Science Foundation of China (40272124)
文摘Coal fires have a very long history in China; the oldest coal fires have being burning for many million years. Up to now more than 56 coal fires spots were distin-guished. They mainly locate in West-North of China, North of China and East-North of China. About millions of tons of coal have been burned in fires every year. Xinjiang Autonomy is the most serious region in coal fires as it has 38 coal fires spots and about 6.85 million tons of coal was burned every year. Coal fires in China ignited by wildfires, spontaneous combustion and human being during mining activities. These fires have re-leased about 0.9 million tons of gasses (including CO, CO2, SO2, NO2 CH4, CO2, H2S etc.) into the atmosphere every year, most of which are brought to the east by wind and result-ing more heavier air pollution in northern China.
基金Supported by the National Natural Science Foundation of China (61174059, 60934007, 61233004)the National Basic Research Program of China (2013CB035406)Shanghai Rising-Star Tracking Program (11QH1401300)
文摘Since the combustion system of coal-fired boiler in thermal power plant is characterized as time varying, strongly coupled, and nonlinear, it is hard to achieve a satisfactory performance by the conventional proportional integral derivative (PID) control scheme. For the characteristics of the main steam pressure in coal-fired power plant boiler, the sliding mode control system with Smith predictive structure is proposed to look for performance and robustness improvement. First, internal model control (IMC) and Smith predictor (SP) is used to deal with the time delay, and sliding mode controller (SMCr) is designed to overcome the model mismatch. Simulation results show the effectiveness of the proposed controller compared with conventional ones.
基金provided by the National Natural Science Foundation of China (No. 50876112)the Fundamental Research Funds for the Central Universities (No. 2009QH13)the International Scientific and Technological Cooperation Project(No. 2010DFR60610)
文摘Coal seam pyrolysis occurs during coal seam fires and during underground coal gasification. This is an important source of polycyclic aromatic hydrocarbon (PAH) emission in China. Pyrolysis in a coal seam was simulated in a tubular furnace. The 16 US Environmental Protection Agency priority controlled PAHs were analyzed by HPLC. The effects of temperature, heating rate, pyrolysis atmosphere, and coal size were investigated. The results indicate that the 3-ring PAHs AcP and AcPy are the main species in the pyrolysis gas. The 2-ring NaP and the 4-ring Pyr are also of concern. Increasing temperature caused the total PAH yield to go through a minimum. The lowest value was obtained at the temperature of 600℃. Higher heating rates promote PAH formation, especially formation of the lower molecular weight PAHs. The typical heating rate in a coal seam, 5 ℃/min, results in intermediate yields of PAHs. The total PAHs yield in an atmosphere of N2 is about 1.81 times that seen without added N2, which indicates that an air flow through the coal seam accelerates the formation of PAHs. An increase in coal particle size reduces the total PAHs emission but promotes the formation of 5- and f-ring PAHs.
文摘According to statistics, the average dust collection efficiency of flue gas emission in the large and medium- sized power plants in Zhejiang Province at present has attained higher than 97% which surpasses the 95% standard as stipulated by the Ministry of Electric Power. The dust collection efficiency of the Beilungang Power Plant has already attained 99.92%. In recent years, Zhejiang Electric Power Corporation has stipulated that all the newly constructed generating units shall be equipped with high efficiency electrostatic precipitator (ESP) while the existing power plants shall speed up their renovation work for their dust collectors. In combination with the fourth stage project of the Taizhou Power Plant, the improvement work of the dust
文摘The physical,chemical and mineral facies properties of the flyash from Xiezhuang Coal Refuse Fired Power Plant have been studied by means of naked eyes,microscope,chemical composition analysis and XRD analysis,and compared with that of the flyash from Taian Coal Fired Power Plant.The result shows that the flyash from coal refuse fired power plant is of better quality in making construction items,for being brighter in color,fine and high activity.Some ways of comprehensive utilization of the ash have been suggested in this paper.
文摘The in-situ instrumentation technique for measuring mercury and itsspeciation downstream a utility 100 MW pulverized coal (PC) fired boiler system was developed andconducted by the use of the Ontario hydro method (OHM) consistent with American standard test methodtogether with the semi-continuous emissions monitoring (SCEM) system as well as a mobile laboratoryfor mercury monitoring. The mercury and its speciation concentrations including participate mercuryat three locations of before air preheater, before electrostatic precipitator (ESP) and after ESPwere measured using the OHM and SCEM methods under normal operation conditions of the boiler systemas a result of firing a bituminous coal. The vapor-phase total mercury Hg(VT) concentration declinedwith the decrease of flue gas temperature because of mercury species transformation from oxidizedmercury to particulate mercury as the flue gas moved downstream from the air preheater to the ESPand after the ESP. A good agreement for Hg°, Hg^(2+) and Hg( VT) was obtained between the twomethods in the ash-free area. But in the dense particle-laden flue gas area, there appeared to be abig bias for mercury speciation owing to dust cake formed in the filter of OHM sampling probe. Theparticulateaffinity to the flue gas mercury and the impacts of sampling condition to accuracy ofmeasure were discussed.