Coal forming environments in the tectonically controlled intermontane Stephanian Cévennes coal basin (Massif central, France) show a complex interelationship between structural and sedimentological features. The ...Coal forming environments in the tectonically controlled intermontane Stephanian Cévennes coal basin (Massif central, France) show a complex interelationship between structural and sedimentological features. The study of the general structural features and the geometry of the coal beds developed during the different stages in the evolution of the basin, and the spatial relation of the lithofacial units to the early tectonic activities, lead the authors to suggest the following model. The synsedimentary faults that occurred as both intrabasinal and marginal faults controlled not only the spatial distribution, shape and thickness of the detrital rock units and coal seams, but also caused the inversion of the tectonic style. The marginal faults exercised important controls on the geometry of the basin and the distribution of lithofacial units. However due to the subsidence of the central part of the basin and the depocenter, and the to differences in the timing and intensity of the displacement the coal enrichment zones shifted both vertically and laterally. This eventually resulted in the inversion of the whole tectonic framework from semi graben through graben to a new semi graben. The style and rate of the tectonic movement and basin filling that occurred in the Stephanian Cévennes coal basin were in turn closely linked with the tectonic movement in the surrounding area. Therefore the authors propose that the environment and processes of coal formation in this basin are closely linked to its tectonic evolution.展开更多
Forming adsorbents FFA-R,FFA-A and FFA-B were prepared from different particle size coal fly ashes FA-R,FA-A and FA-B,their average particle sizes(d_(50)) were 15.75,3.61 and 1.73 μm respectively.The structure an...Forming adsorbents FFA-R,FFA-A and FFA-B were prepared from different particle size coal fly ashes FA-R,FA-A and FA-B,their average particle sizes(d_(50)) were 15.75,3.61 and 1.73 μm respectively.The structure and adsorption properties for Cr^(6+) of forming adsorbents from aqueous solution were studied.The results show that forming adsorbent prepared from the coal fly ash with smaller particle size exhibits higher specific surface area,higher pore volume and better adsorption properties for Cr^(6+).The adsorption kinetics of Cr^(6+) on FFA-R,FFA-A and FFA-B fitts the second order kinetic model and the second adsorption rate constants are 7.523,3.197 and 2.187 mg·g^(-1)·min^(-1/2),respectively.The adsorption of Cr^(6+) on FFA-R,FFA-A and FFA-B can be described in terms of Langmuir isotherms better,and the adsorption processes are spontaneous and exothermic.展开更多
The Paleogene coal accumulation basins of China are part of the global Tertiary coal-accumulated zone of the Pacific Rim located in the eastern coastal provinces and areas. Although the coal-bearing basins of the Chin...The Paleogene coal accumulation basins of China are part of the global Tertiary coal-accumulated zone of the Pacific Rim located in the eastern coastal provinces and areas. Although the coal-bearing basins of the China Sea area are faults and depressed basins, they come up in groups. The overall structures are suitable for the development of coal-bearing deposition. The continuity of basin groups are good, and the coal-bearing depositions are thick. For example, the coal-bearing deposi- tion is more than a kilometer thick at the Qiongdongnan Basin and Xihu Sag in the East China Sea, which the continental Pa- leogene coal basins cannot reach. Research shows that the coal accumulation basins in the sea area consist of many sags. There are two types of coal accumulation sags: half-graben sag and graben sag. In terms of water depth, coal accumulation sags can also be classified as deep-water half-graben sag and shallow-water half-graben sag; the graben sag is the deep-water sag. There are two distinct coal-accumulated zones in the basin: gentle slope and steep slope, with the gentle slope being the dominant one. The marshes of the supratidal zone and intertidal zone in a tidal flat system is favorable for the coal accumulation process widely taking place. There are two types of peat accumulation: autochthonous accumulation and allochthonous accumulation. Because of tectonic activities in the basins, allochthonous accumulations may be the more important form of coal-forming ac- tivities in the sea area. The very thick coal-bearing deposition in the sea area provides a rich material base for the assemblage of coal-related gas. Also, as a result of the deep burial depth, the degree of coal metamorphism is relatively high, so the coal-bearing strata become good hydrocarbon source rocks.展开更多
The changes in sulfur form in coal were analyzed by sulfur K-XANES(K-edge X-ray absorption near edge structures) spectra before and after the coal microwave desulfurization in a Na OH solution. After the desulfurizati...The changes in sulfur form in coal were analyzed by sulfur K-XANES(K-edge X-ray absorption near edge structures) spectra before and after the coal microwave desulfurization in a Na OH solution. After the desulfurization, the pyritic sulfur content of coal decreased significantly from 53.6% to 39.2%, while the sulfate sulfur content increased from 17.3% to 34.6%. Only a small amount of thiophene sulfur(20.1–16.1%) was removed. Some sulfur-containing components were oxidized to sulfate sulfur. Under the optimum conditions, the ash content decreased, while the volatile content increased. The calorific value of coal slightly decreased with a slight variation in the amplitudes. The overall structure of coal did not change significantly based on Fourier transform infrared(FTIR) spectral analyses. Thus, the desulfurization of coal with microwave irradiation in a Na OH solution did not significantly change the properties of coal.展开更多
This article set forth two types of destructive form of stopping tunnel coal wall: destructive form in coal and destructive form in interface of coal layer. In addition, the mechanism of destruction in stopping tunnel...This article set forth two types of destructive form of stopping tunnel coal wall: destructive form in coal and destructive form in interface of coal layer. In addition, the mechanism of destruction in stopping tunnel coal wall is analyzed.展开更多
文摘Coal forming environments in the tectonically controlled intermontane Stephanian Cévennes coal basin (Massif central, France) show a complex interelationship between structural and sedimentological features. The study of the general structural features and the geometry of the coal beds developed during the different stages in the evolution of the basin, and the spatial relation of the lithofacial units to the early tectonic activities, lead the authors to suggest the following model. The synsedimentary faults that occurred as both intrabasinal and marginal faults controlled not only the spatial distribution, shape and thickness of the detrital rock units and coal seams, but also caused the inversion of the tectonic style. The marginal faults exercised important controls on the geometry of the basin and the distribution of lithofacial units. However due to the subsidence of the central part of the basin and the depocenter, and the to differences in the timing and intensity of the displacement the coal enrichment zones shifted both vertically and laterally. This eventually resulted in the inversion of the whole tectonic framework from semi graben through graben to a new semi graben. The style and rate of the tectonic movement and basin filling that occurred in the Stephanian Cévennes coal basin were in turn closely linked with the tectonic movement in the surrounding area. Therefore the authors propose that the environment and processes of coal formation in this basin are closely linked to its tectonic evolution.
基金Funded by the National Natural Science Foundation of China(No.51278418)the Natural Science Basic Research Plan in Shaanxi Province of China(No.2013K11-10)the Key Laboratory of Environmental Protection&Pollution and Remediation of Water and Soil of Shaanxi Province(Chang’an University)
文摘Forming adsorbents FFA-R,FFA-A and FFA-B were prepared from different particle size coal fly ashes FA-R,FA-A and FA-B,their average particle sizes(d_(50)) were 15.75,3.61 and 1.73 μm respectively.The structure and adsorption properties for Cr^(6+) of forming adsorbents from aqueous solution were studied.The results show that forming adsorbent prepared from the coal fly ash with smaller particle size exhibits higher specific surface area,higher pore volume and better adsorption properties for Cr^(6+).The adsorption kinetics of Cr^(6+) on FFA-R,FFA-A and FFA-B fitts the second order kinetic model and the second adsorption rate constants are 7.523,3.197 and 2.187 mg·g^(-1)·min^(-1/2),respectively.The adsorption of Cr^(6+) on FFA-R,FFA-A and FFA-B can be described in terms of Langmuir isotherms better,and the adsorption processes are spontaneous and exothermic.
基金Supported by the Major Research Project of the National Natural Science Foundation (40872100)
文摘The Paleogene coal accumulation basins of China are part of the global Tertiary coal-accumulated zone of the Pacific Rim located in the eastern coastal provinces and areas. Although the coal-bearing basins of the China Sea area are faults and depressed basins, they come up in groups. The overall structures are suitable for the development of coal-bearing deposition. The continuity of basin groups are good, and the coal-bearing depositions are thick. For example, the coal-bearing deposi- tion is more than a kilometer thick at the Qiongdongnan Basin and Xihu Sag in the East China Sea, which the continental Pa- leogene coal basins cannot reach. Research shows that the coal accumulation basins in the sea area consist of many sags. There are two types of coal accumulation sags: half-graben sag and graben sag. In terms of water depth, coal accumulation sags can also be classified as deep-water half-graben sag and shallow-water half-graben sag; the graben sag is the deep-water sag. There are two distinct coal-accumulated zones in the basin: gentle slope and steep slope, with the gentle slope being the dominant one. The marshes of the supratidal zone and intertidal zone in a tidal flat system is favorable for the coal accumulation process widely taking place. There are two types of peat accumulation: autochthonous accumulation and allochthonous accumulation. Because of tectonic activities in the basins, allochthonous accumulations may be the more important form of coal-forming ac- tivities in the sea area. The very thick coal-bearing deposition in the sea area provides a rich material base for the assemblage of coal-related gas. Also, as a result of the deep burial depth, the degree of coal metamorphism is relatively high, so the coal-bearing strata become good hydrocarbon source rocks.
基金provided by the National Natural Science Foundation of China(No.51274199)the Specialized Research Fund for the Doctoral Program of Higher Education(No.20130095110008)
文摘The changes in sulfur form in coal were analyzed by sulfur K-XANES(K-edge X-ray absorption near edge structures) spectra before and after the coal microwave desulfurization in a Na OH solution. After the desulfurization, the pyritic sulfur content of coal decreased significantly from 53.6% to 39.2%, while the sulfate sulfur content increased from 17.3% to 34.6%. Only a small amount of thiophene sulfur(20.1–16.1%) was removed. Some sulfur-containing components were oxidized to sulfate sulfur. Under the optimum conditions, the ash content decreased, while the volatile content increased. The calorific value of coal slightly decreased with a slight variation in the amplitudes. The overall structure of coal did not change significantly based on Fourier transform infrared(FTIR) spectral analyses. Thus, the desulfurization of coal with microwave irradiation in a Na OH solution did not significantly change the properties of coal.
文摘This article set forth two types of destructive form of stopping tunnel coal wall: destructive form in coal and destructive form in interface of coal layer. In addition, the mechanism of destruction in stopping tunnel coal wall is analyzed.