Coal mining-induced surface subsidence poses significant ecological and infrastructural challenges, necessitating a comprehensive study to ensure safe mining practices, particularly in underwater conditions. This proj...Coal mining-induced surface subsidence poses significant ecological and infrastructural challenges, necessitating a comprehensive study to ensure safe mining practices, particularly in underwater conditions. This project aims to address the extensive impact of coal mining on the environment, infrastructure, and overall safety, focusing on the Shigong River area above the working face. The study employs qualitative and quantitative analyses, along with on-site engineering measurements, to gather data on crucial parameters such as coal seam characteristics, roof rock lithology, thickness, water resistance, and structural damage degree. The research encompasses a multidisciplinary approach, involving mining, geology, hydrogeology, geophysical exploration, rock mechanics, mine surveying, and computational mathematics. The importance of effective safety measures and prevention techniques is emphasized, laying the foundation for research focused on the Xingyun coal mine. The brief concludes by highlighting the potential economic and social benefits of this project and its contribution to valuable experience for future subsea coal mining.展开更多
Safety is paramount in coal mining as it affects efficiency.Thus,it is essential to enhance the management of coal mine safety.With the ongoing advancement of modern technologies,more innovative solutions are being in...Safety is paramount in coal mining as it affects efficiency.Thus,it is essential to enhance the management of coal mine safety.With the ongoing advancement of modern technologies,more innovative solutions are being integrated into the safety management of coal mining,including virtual simulation technology.This paper focuses on analyzing and researching the application of virtual simulation technology in the safety management of coal mining,providing insights for reference.展开更多
The crowd sensing technology can realize the sensing and computing of people,machines,and environment in smart industrial IoT-based coal mine,which provides a solution for safety monitoring through distributed intelli...The crowd sensing technology can realize the sensing and computing of people,machines,and environment in smart industrial IoT-based coal mine,which provides a solution for safety monitoring through distributed intelligence optimization.However,due to the difficulty of neural network training to achieve global optimality and the fact that traditional LSTM methods do not consider the relationship between adjacent machines,the accuracy of human body position prediction and pressure value prediction is not high.To solve these problems,this paper proposes a smart industrial IoT empowered crowd sensing for safety monitoring in coal mine.First,we propose a Particle Swarm Optimization-Elman Neural Network(PE)algorithm for the mobile human position prediction.Second,we propose an ADI-LSTM neural network prediction algorithm for pressure values of machines supports in underground mines.Among them,our proposed PE algorithm has the lowest average cumulative prediction error,and the trajectory fit rate is improved by 24.1%,13.9%and 8.7%compared with Kalman filtering,Elman and Kalman plus Elman algorithms,respectively.Meanwhile,compared with single-input ARIMA,RNN,LSTM,and GRU,the RMSE values of our proposed ADI-LSTM are reduced by 36.6%,52%,32%,and 13.7%,respectively;and the MAPE values are reduced by 0.0003%,0.9482%,1.1844%,and 0.3620%,respectively.展开更多
The internal mechanism of the high hydrophobicity of the coal samples from the Pingdingshan mining area was studied through industrial,element,and surface functional group analysis.Laboratory testing and molecular dyn...The internal mechanism of the high hydrophobicity of the coal samples from the Pingdingshan mining area was studied through industrial,element,and surface functional group analysis.Laboratory testing and molecular dynamics simulations were employed to study the impact of three types of surfactants on the surface adsorption properties and wettability of highly hydrophobic bituminous coal.The results show that the surface of highly hydrophobic bituminous coal is compact,rich in inorganic minerals,and poorly wettable and that coal molecules are dominated by hydrophobic functional groups of aromatic rings and aliphatic structures.The wetting performance of surfactants as the intermediate carrier to connect coal and water molecules is largely determined by the interaction force between surfactants and coal(Fs-c)and the interaction force between surfactants and water(Fs-w),which effectively improve the wettability of modified coal dust via modifying its surface electrical properties and surface energy.A new type of wetting agent with a dust removal rate of 89%has been developed through discovery of a compound wetting agent solution with optimal wetting and settling performance.This paper provides theoretical and technical support for removing highly hydrophobic bituminous coal dust in underground mining.展开更多
In the process of green and smart mine construction under the context of carbon neutrality,China's coal safety situation has been continuously improved in recent years.In order to recognize the development of coal...In the process of green and smart mine construction under the context of carbon neutrality,China's coal safety situation has been continuously improved in recent years.In order to recognize the development of coal production in China and prepare for future monitoring and prevention of safety incidents,this study mainly elaborated on the basic situation of coal resources and national mining accidents over the past five years(2017-2021),from four dimensions(accident level,type,region,and time),and then proposed the preventive measures based on accident statistical laws.The results show that the storage of coal resources has obvious geographic characteristics,mainly concentrated in the Midwest,with coal resources in Shanxi and Shaanxi accounting for about 49.4%.The proportion of coal consumption has dropped from 70.2%to 56%between 2011 and 2021,but still accounts for more than half of the all.Meanwhile,the accident-prone areas are positively correlated with the amount of coal production.Among different levels of coal mine accidents,general accidents had the highest number of accidents and deaths,with 692 accidents and 783 deaths,accounting for 87.6%and 54.64%respectively.The frequency of roof,gas,and transportation accidents is relatively high,and the number of single fatalities caused by gas accidents is the largest,about 4.18.In terms of geographical distribution of accidents,the safety situation in Shanxi Province is the most severe.From the time distribution of coal mine accidents,the accidents mainly occurred in July and August,and rarely occurred in February and December.Finally,the"4+4"safety management model is proposed,combining the statistical results with coal production in China.Based on the existing health and safety management systems,the manage-ments are divided into four sub-categories,and more specific measures are suggested.展开更多
Coal mine safety is a complex system, which is controlled by a number of interrelated factors and is difficult to estimate. This paper proposes an index system of safety assessment based on correlated factors involved...Coal mine safety is a complex system, which is controlled by a number of interrelated factors and is difficult to estimate. This paper proposes an index system of safety assessment based on correlated factors involved in coal mining and a comprehensive evaluation model that combines the advantages of the AHP and a grey clustering method to guarantee the accuracy and objectivity of weight coefficients. First, we confirmed the weight of every index using the AHP, then did a general safety assessment by means of a grey clustering method. This model analyses the status of mining safety both qualitatively and quantitatively. It keeps management and technical groups informed of the situation of the coal production line in real time, which aids in making correct decisions based on practical safety issues. A case study in the application of the model is presented. The results show that the method is applicable and realistic with regard to the core of a coal mine's safety management. Consequently, the safe production of a mine and the awareness of advanced safe production management is accelerated.展开更多
Four types of meager and meager-lean coal and one type of high-quality anthracite were selected based on the safety requirements for blast furnace coal injection and domestic coal quality to conduct microstructure and...Four types of meager and meager-lean coal and one type of high-quality anthracite were selected based on the safety requirements for blast furnace coal injection and domestic coal quality to conduct microstructure and component analyses.The analyses of the organic and inorganic macerals and the chemical compositions of the selected coal samples indicate that the four types of meager and meager-lean coal have low volatilization,low ash content,and low sulfur content;these qualities are suitable for blast furnace injection.Grindability test was conducted on the four types of meager and meager-lean coal and the anthracite mixed coal samples.Results indicate that the mixture of meager and meager-lean coal and anthracite is beneficial to improve the grindability of pulverized coal.The explosive tests reveal that the selected coal samples are non-explosive or weakly explosive.When the proportion of meager and meager-lean coal is less than 40wt%,the mixed coal powder would not explode during the blowing process.The minimum ignition temperature test determines that the minimum ignition temperatures of the four types of meager and meager-lean coal and anthracite are 326,313,310,315,and 393°C,respectively.This study provides a guiding research idea for the safety of meager and meager-lean coal used in blast furnace injection.展开更多
In order to accurately and quickly identify the safety status pattern of coalmines,a new safety status pattern recognition method based on the extension neural network (ENN) was proposed,and the design of structure of...In order to accurately and quickly identify the safety status pattern of coalmines,a new safety status pattern recognition method based on the extension neural network (ENN) was proposed,and the design of structure of network,the rationale of recognition algorithm and the performance of proposed method were discussed in detail.The safety status pattern recognition problem of coalmines can be regard as a classification problem whose features are defined in a range,so using the ENN is most appropriate for this problem.The ENN-based recognition method can use a novel extension distance to measure the similarity between the object to be recognized and the class centers.To demonstrate the effectiveness of the proposed method,a real-world application on the geological safety status pattern recognition of coalmines was tested.Comparative experiments with existing method and other traditional ANN-based methods were conducted.The experimental results show that the proposed ENN-based recognition method can identify the safety status pattern of coalmines accurately with shorter learning time and simpler structure.The experimental results also confirm that the proposed method has a better performance in recognition accuracy,generalization ability and fault-tolerant ability,which are very useful in recognizing the safety status pattern in the process of coal production.展开更多
In recent years improper allocation of safety input has prevailed in coal mines in China, which resulted in the frequent accidents in coal mining operation. A comprehensive assessment of the input efficiency of coal m...In recent years improper allocation of safety input has prevailed in coal mines in China, which resulted in the frequent accidents in coal mining operation. A comprehensive assessment of the input efficiency of coal mine safety should lead to improved efficiency in the use of funds and management resources. This helps government and enterprise managers better understand how safety inputs are used and to optimize allocation of resources. Study on coal mine's efficiency assessment of safety input was con- ducted in this paper. A C^2R model with non-Archimedean infinitesimal vector based on output is established after consideration of the input characteristics and the model properties. An assessment of an operating mine was done using a specific set of input and output criteria. It is found that the safety input was efficient in 2002 and 2005 and was weakly efficient in 2003. However, the efficiency was relatively low in both 2001 and 2004. The safety input resources can be optimized and adjusted by means of projection theory. Such analysis shows that, on average in 2001 and 2004, 45% of the expended funds could have been saved. Likewise, 10% of the safety management and technical staff could have been eliminated and working hours devoted to safety could have been reduced by 12%. These conditions could have Riven the same results.展开更多
Coal mine safety supervision system plays an important role in the coal mine safety management in China.However,the current supervision system is established on the basis of learning the advanced experience from other...Coal mine safety supervision system plays an important role in the coal mine safety management in China.However,the current supervision system is established on the basis of learning the advanced experience from other developed countries.It needs to be further improved according to national conditions.Therefore,the effectiveness of coal mine safety supervision system reform on three types of collieries are assessed by using time series analysis method based on comparative analysis of the supervision system before and after the reform in this paper.The regression results show that the structural reform is not conductive to the improvement of coal mine safety situation in the short term,but conductive significantly in the long term.Specifically,the effects in township coal mines are more significant than stateowned key coal mines in the long run,but negative effects also exist in the short term.The negative effects in state-owned key coal mines are non-significant compared with township coal mines.Moreover,the regression results are analyzed from the aspects of the closure policy of illegal small township coal mines at the end of 1998 and shortage of the new supervision system.Finally,the suggestions on improving the new supervision system are put forward based on the above analysis.展开更多
According to the randomness and uncertainty of information in the safety diagnosis of coal mine production system (CMPS), a novel safety diagnosis method was proposed by applying fuzzy logic inference method, which co...According to the randomness and uncertainty of information in the safety diagnosis of coal mine production system (CMPS), a novel safety diagnosis method was proposed by applying fuzzy logic inference method, which consists of safety diagnosis fuzzifier, defuzzifier, fuzzy rules base and inference engine. Through the safety diagnosis on coal mine roadway rail transportation system, the result shows that the unsafe probability is about 0.5 influenced by no speed reduction and over quick turnout on roadway, which is the most possible reason leading to the accident of roadway rail transportation system.展开更多
Firstly, the early warning index system of coal mine safety production was given from four aspects as per- sonnel, environment, equipment and management. Then, improvement measures which are additional momentum method...Firstly, the early warning index system of coal mine safety production was given from four aspects as per- sonnel, environment, equipment and management. Then, improvement measures which are additional momentum method, adaptive learning rate, particle swarm optimization algorithm, variable weight method and asynchronous learning factor, are used to optimize BP neural network models. Further, the models are applied to a comparative study on coal mine safety warning instance. Results show that the identification precision of MPSO-BP network model is higher than GBP and PSO-BP model, and MPSO- BP model can not only effectively reduce the possibility of the network falling into a local minimum point, but also has fast convergence and high precision, which will provide the scientific basis for the forewarnin~ management of coal mine safetv production.展开更多
硬炭因资源丰富、结构稳定及安全性高等优势,已成为钠离子电池常用阳极材料。其中,煤基衍生硬炭受到了广泛的关注。本工作以长焰煤为碳源,硫脲为氮硫源,NaCl为模板,通过两步炭化工艺和杂原子掺杂相结合的方法合成了N和S共掺杂的煤基硬炭...硬炭因资源丰富、结构稳定及安全性高等优势,已成为钠离子电池常用阳极材料。其中,煤基衍生硬炭受到了广泛的关注。本工作以长焰煤为碳源,硫脲为氮硫源,NaCl为模板,通过两步炭化工艺和杂原子掺杂相结合的方法合成了N和S共掺杂的煤基硬炭(NSPC1200)。两步炭化过程在调节碳微晶结构和扩大层间距方面发挥了重要的作用。N和S的共掺杂调节了炭材料的电子结构,赋予其更多的活性位点;此外,引入NaCl作为模板有助于孔结构的构建,有利于电极和电解质之间的接触,从而实现Na+和电子的有效传输。在协同作用下,样品NSPC1200表现出优异的储钠能力,在20 mA g^(−1)电流密度下呈现314.2 mAh g^(−1)的可逆容量。即使在100 mA g^(−1)下循环200次,仍保持224.4 mAh g^(−1)的比容量。这项工作成功实现了策略性调整煤基炭材料微观结构的目标,最终获得了具有优异的电化学性能的硬炭阳极。展开更多
文摘Coal mining-induced surface subsidence poses significant ecological and infrastructural challenges, necessitating a comprehensive study to ensure safe mining practices, particularly in underwater conditions. This project aims to address the extensive impact of coal mining on the environment, infrastructure, and overall safety, focusing on the Shigong River area above the working face. The study employs qualitative and quantitative analyses, along with on-site engineering measurements, to gather data on crucial parameters such as coal seam characteristics, roof rock lithology, thickness, water resistance, and structural damage degree. The research encompasses a multidisciplinary approach, involving mining, geology, hydrogeology, geophysical exploration, rock mechanics, mine surveying, and computational mathematics. The importance of effective safety measures and prevention techniques is emphasized, laying the foundation for research focused on the Xingyun coal mine. The brief concludes by highlighting the potential economic and social benefits of this project and its contribution to valuable experience for future subsea coal mining.
文摘Safety is paramount in coal mining as it affects efficiency.Thus,it is essential to enhance the management of coal mine safety.With the ongoing advancement of modern technologies,more innovative solutions are being integrated into the safety management of coal mining,including virtual simulation technology.This paper focuses on analyzing and researching the application of virtual simulation technology in the safety management of coal mining,providing insights for reference.
基金supported in part by the National Natural Science Foundation of China(Grant No.61902311),in part by the Postdoctoral Research Foundation of China(Grant No.2019M663801)in part by the Scientific Research Project of Shaanxi Provincial Education Department(Grant No.22JK0459)+1 种基金Key R&D Foundation of Shaanxi Province(Grant No.2021SF-479)in part by the Japan Society for the Promotion of Science(JSPS)Grants-in-Aid for Scientific Research(KAKENHI)under Grant JP18K18044 and JP21K17736.
文摘The crowd sensing technology can realize the sensing and computing of people,machines,and environment in smart industrial IoT-based coal mine,which provides a solution for safety monitoring through distributed intelligence optimization.However,due to the difficulty of neural network training to achieve global optimality and the fact that traditional LSTM methods do not consider the relationship between adjacent machines,the accuracy of human body position prediction and pressure value prediction is not high.To solve these problems,this paper proposes a smart industrial IoT empowered crowd sensing for safety monitoring in coal mine.First,we propose a Particle Swarm Optimization-Elman Neural Network(PE)algorithm for the mobile human position prediction.Second,we propose an ADI-LSTM neural network prediction algorithm for pressure values of machines supports in underground mines.Among them,our proposed PE algorithm has the lowest average cumulative prediction error,and the trajectory fit rate is improved by 24.1%,13.9%and 8.7%compared with Kalman filtering,Elman and Kalman plus Elman algorithms,respectively.Meanwhile,compared with single-input ARIMA,RNN,LSTM,and GRU,the RMSE values of our proposed ADI-LSTM are reduced by 36.6%,52%,32%,and 13.7%,respectively;and the MAPE values are reduced by 0.0003%,0.9482%,1.1844%,and 0.3620%,respectively.
文摘The internal mechanism of the high hydrophobicity of the coal samples from the Pingdingshan mining area was studied through industrial,element,and surface functional group analysis.Laboratory testing and molecular dynamics simulations were employed to study the impact of three types of surfactants on the surface adsorption properties and wettability of highly hydrophobic bituminous coal.The results show that the surface of highly hydrophobic bituminous coal is compact,rich in inorganic minerals,and poorly wettable and that coal molecules are dominated by hydrophobic functional groups of aromatic rings and aliphatic structures.The wetting performance of surfactants as the intermediate carrier to connect coal and water molecules is largely determined by the interaction force between surfactants and coal(Fs-c)and the interaction force between surfactants and water(Fs-w),which effectively improve the wettability of modified coal dust via modifying its surface electrical properties and surface energy.A new type of wetting agent with a dust removal rate of 89%has been developed through discovery of a compound wetting agent solution with optimal wetting and settling performance.This paper provides theoretical and technical support for removing highly hydrophobic bituminous coal dust in underground mining.
基金supported by the National Key R&D Program of China (2022YFC3004701)the National Natural Science Foundation of China (52274242,51904293)+1 种基金the Natural Science Foundation of Jiangsu Province (BK20190627)the China Postdoctoral Science Foundation (2019M661998).
文摘In the process of green and smart mine construction under the context of carbon neutrality,China's coal safety situation has been continuously improved in recent years.In order to recognize the development of coal production in China and prepare for future monitoring and prevention of safety incidents,this study mainly elaborated on the basic situation of coal resources and national mining accidents over the past five years(2017-2021),from four dimensions(accident level,type,region,and time),and then proposed the preventive measures based on accident statistical laws.The results show that the storage of coal resources has obvious geographic characteristics,mainly concentrated in the Midwest,with coal resources in Shanxi and Shaanxi accounting for about 49.4%.The proportion of coal consumption has dropped from 70.2%to 56%between 2011 and 2021,but still accounts for more than half of the all.Meanwhile,the accident-prone areas are positively correlated with the amount of coal production.Among different levels of coal mine accidents,general accidents had the highest number of accidents and deaths,with 692 accidents and 783 deaths,accounting for 87.6%and 54.64%respectively.The frequency of roof,gas,and transportation accidents is relatively high,and the number of single fatalities caused by gas accidents is the largest,about 4.18.In terms of geographical distribution of accidents,the safety situation in Shanxi Province is the most severe.From the time distribution of coal mine accidents,the accidents mainly occurred in July and August,and rarely occurred in February and December.Finally,the"4+4"safety management model is proposed,combining the statistical results with coal production in China.Based on the existing health and safety management systems,the manage-ments are divided into four sub-categories,and more specific measures are suggested.
文摘Coal mine safety is a complex system, which is controlled by a number of interrelated factors and is difficult to estimate. This paper proposes an index system of safety assessment based on correlated factors involved in coal mining and a comprehensive evaluation model that combines the advantages of the AHP and a grey clustering method to guarantee the accuracy and objectivity of weight coefficients. First, we confirmed the weight of every index using the AHP, then did a general safety assessment by means of a grey clustering method. This model analyses the status of mining safety both qualitatively and quantitatively. It keeps management and technical groups informed of the situation of the coal production line in real time, which aids in making correct decisions based on practical safety issues. A case study in the application of the model is presented. The results show that the method is applicable and realistic with regard to the core of a coal mine's safety management. Consequently, the safe production of a mine and the awareness of advanced safe production management is accelerated.
文摘Four types of meager and meager-lean coal and one type of high-quality anthracite were selected based on the safety requirements for blast furnace coal injection and domestic coal quality to conduct microstructure and component analyses.The analyses of the organic and inorganic macerals and the chemical compositions of the selected coal samples indicate that the four types of meager and meager-lean coal have low volatilization,low ash content,and low sulfur content;these qualities are suitable for blast furnace injection.Grindability test was conducted on the four types of meager and meager-lean coal and the anthracite mixed coal samples.Results indicate that the mixture of meager and meager-lean coal and anthracite is beneficial to improve the grindability of pulverized coal.The explosive tests reveal that the selected coal samples are non-explosive or weakly explosive.When the proportion of meager and meager-lean coal is less than 40wt%,the mixed coal powder would not explode during the blowing process.The minimum ignition temperature test determines that the minimum ignition temperatures of the four types of meager and meager-lean coal and anthracite are 326,313,310,315,and 393°C,respectively.This study provides a guiding research idea for the safety of meager and meager-lean coal used in blast furnace injection.
基金Project(107021) supported by the Key Foundation of Chinese Ministry of Education Project(2009643013) supported by China Scholarship Fund
文摘In order to accurately and quickly identify the safety status pattern of coalmines,a new safety status pattern recognition method based on the extension neural network (ENN) was proposed,and the design of structure of network,the rationale of recognition algorithm and the performance of proposed method were discussed in detail.The safety status pattern recognition problem of coalmines can be regard as a classification problem whose features are defined in a range,so using the ENN is most appropriate for this problem.The ENN-based recognition method can use a novel extension distance to measure the similarity between the object to be recognized and the class centers.To demonstrate the effectiveness of the proposed method,a real-world application on the geological safety status pattern recognition of coalmines was tested.Comparative experiments with existing method and other traditional ANN-based methods were conducted.The experimental results show that the proposed ENN-based recognition method can identify the safety status pattern of coalmines accurately with shorter learning time and simpler structure.The experimental results also confirm that the proposed method has a better performance in recognition accuracy,generalization ability and fault-tolerant ability,which are very useful in recognizing the safety status pattern in the process of coal production.
基金Project 70771105 supported by the National Natural Science Foundation of China
文摘In recent years improper allocation of safety input has prevailed in coal mines in China, which resulted in the frequent accidents in coal mining operation. A comprehensive assessment of the input efficiency of coal mine safety should lead to improved efficiency in the use of funds and management resources. This helps government and enterprise managers better understand how safety inputs are used and to optimize allocation of resources. Study on coal mine's efficiency assessment of safety input was con- ducted in this paper. A C^2R model with non-Archimedean infinitesimal vector based on output is established after consideration of the input characteristics and the model properties. An assessment of an operating mine was done using a specific set of input and output criteria. It is found that the safety input was efficient in 2002 and 2005 and was weakly efficient in 2003. However, the efficiency was relatively low in both 2001 and 2004. The safety input resources can be optimized and adjusted by means of projection theory. Such analysis shows that, on average in 2001 and 2004, 45% of the expended funds could have been saved. Likewise, 10% of the safety management and technical staff could have been eliminated and working hours devoted to safety could have been reduced by 12%. These conditions could have Riven the same results.
基金supported by the National Nat-ural Science Foundation Projects of China under Grant 71271206Innovation Project of Graduate Education for Jiangsu Province under Grant KYZZ_0377.
文摘Coal mine safety supervision system plays an important role in the coal mine safety management in China.However,the current supervision system is established on the basis of learning the advanced experience from other developed countries.It needs to be further improved according to national conditions.Therefore,the effectiveness of coal mine safety supervision system reform on three types of collieries are assessed by using time series analysis method based on comparative analysis of the supervision system before and after the reform in this paper.The regression results show that the structural reform is not conductive to the improvement of coal mine safety situation in the short term,but conductive significantly in the long term.Specifically,the effects in township coal mines are more significant than stateowned key coal mines in the long run,but negative effects also exist in the short term.The negative effects in state-owned key coal mines are non-significant compared with township coal mines.Moreover,the regression results are analyzed from the aspects of the closure policy of illegal small township coal mines at the end of 1998 and shortage of the new supervision system.Finally,the suggestions on improving the new supervision system are put forward based on the above analysis.
基金Project(2006BAK04B0302)supported by the National Science and Technology Pillar Program during the 11th Five-year Plan of China
文摘According to the randomness and uncertainty of information in the safety diagnosis of coal mine production system (CMPS), a novel safety diagnosis method was proposed by applying fuzzy logic inference method, which consists of safety diagnosis fuzzifier, defuzzifier, fuzzy rules base and inference engine. Through the safety diagnosis on coal mine roadway rail transportation system, the result shows that the unsafe probability is about 0.5 influenced by no speed reduction and over quick turnout on roadway, which is the most possible reason leading to the accident of roadway rail transportation system.
文摘Firstly, the early warning index system of coal mine safety production was given from four aspects as per- sonnel, environment, equipment and management. Then, improvement measures which are additional momentum method, adaptive learning rate, particle swarm optimization algorithm, variable weight method and asynchronous learning factor, are used to optimize BP neural network models. Further, the models are applied to a comparative study on coal mine safety warning instance. Results show that the identification precision of MPSO-BP network model is higher than GBP and PSO-BP model, and MPSO- BP model can not only effectively reduce the possibility of the network falling into a local minimum point, but also has fast convergence and high precision, which will provide the scientific basis for the forewarnin~ management of coal mine safetv production.
文摘硬炭因资源丰富、结构稳定及安全性高等优势,已成为钠离子电池常用阳极材料。其中,煤基衍生硬炭受到了广泛的关注。本工作以长焰煤为碳源,硫脲为氮硫源,NaCl为模板,通过两步炭化工艺和杂原子掺杂相结合的方法合成了N和S共掺杂的煤基硬炭(NSPC1200)。两步炭化过程在调节碳微晶结构和扩大层间距方面发挥了重要的作用。N和S的共掺杂调节了炭材料的电子结构,赋予其更多的活性位点;此外,引入NaCl作为模板有助于孔结构的构建,有利于电极和电解质之间的接触,从而实现Na+和电子的有效传输。在协同作用下,样品NSPC1200表现出优异的储钠能力,在20 mA g^(−1)电流密度下呈现314.2 mAh g^(−1)的可逆容量。即使在100 mA g^(−1)下循环200次,仍保持224.4 mAh g^(−1)的比容量。这项工作成功实现了策略性调整煤基炭材料微观结构的目标,最终获得了具有优异的电化学性能的硬炭阳极。