Laser-induced breakdown spectroscopy was employed to determine the inorganic elements in coal. To improve the measurement＇s accuracy and precision, a new internal standardization scheme, which we named changed intern...Laser-induced breakdown spectroscopy was employed to determine the inorganic elements in coal. To improve the measurement＇s accuracy and precision, a new internal standardization scheme, which we named changed internal standardization, was compared with the traditional internal standardization and no internal standardization for the analysis of inorganic elements. The new internal standardization scheme used the atomic line of carbon at 247.86 nm and the molecular band of CN at 388.34 nm and C2 at 516.32 nm to normalize the lines of inorganic elements that were distributed in the same spectral channel. The performance of the utilization of the new internal standardization scheme was evaluated using a set of coal samples, including twenty calibration samples and five validation samples. The results show that the coefficients of determination R2 and the slope of calibration models coupled with changed internal standard- ization are better than that of the calibration models coupled with fixed internal standardization and no internal standardization. Moreover, the measurement accuracy and reproducibility of changed internal standardization for the analysis of five validation samples also yielded further improvement. The results that we obtained suggest that changed internal standardization could compensate for the matrix effects, as well as the influence of the difference in the spectral response of the light collection system.展开更多
The size distribution of the broken top coal blocks is an important factor,affecting the recovery ratio and the efficiency of drawing top coal in longwall top coal caving(LTCC)mining panel.The standard deviation of to...The size distribution of the broken top coal blocks is an important factor,affecting the recovery ratio and the efficiency of drawing top coal in longwall top coal caving(LTCC)mining panel.The standard deviation of top coal block size(dt)is one of the main parameters to reflect the size distribution of top coal.To find the effect of dt on the caving mechanism,this study simulates experiments with 9 different dt by using discrete element software PFC.The dt is divided into two stages:uniform distribution stage(UDS)whose dt is less than 0.1(Schemes 1–5),and nonuniform distribution stage(NDS)whose dt is more than 0.1(Schemes 6–9).This research mainly investigates the variation of recovery ratio,drawing body shape,boundary of top coal,and contact force between particles in the two stages,respectively.The results showed that with the increasing dt,the recovery ratio of the panel increases first and then decreases in UDS.It is the largest in Scheme 3,which mainly increases the drawing volume at the side of starting drawing end.However,the recovery ratio decreases first and then increases quickly in NDS,and it is the largest in Scheme 9,where the drawing volume at the side of finishing drawing end are relatively higher.In UDS,the major size of top coal is basically medium,while in NDS,the size varies from medium to small,and then to large,with a distinct difference in shape and volume of the drawing body.When the major size of top coal is medium and small,the cross-section width of the initial boundary of top coal at each height is relatively small.Conversely,when the top coal size is large,the initial boundary of top coal has a larger opening range,the rotating angle of lower boundary is relatively small in the normal drawing stage,which is conducive to the development of drawing body and reduces the residual top coal,and the maximum particle velocity and the particles movement angle are both larger.This study lays a foundation for the prediction of recovery ratio,and suggests that the uniform top coal is more manageable and has a larger recovery ratio.展开更多
基金supported by Open Research Fund of State Key Laboratory of Pulsed Power Laser Technology of China(No.SKL2013KF03)National Natural Science Foundation of China(Nos.51206055,51476061)+3 种基金the Fundamental Research Funds for the Central Universities of China(No.2014ZZ0014)the New Star of Pearl River on Science and Technology of Guangzhou,China(No.2014J2200054)the Key Laboratory of Efficient and Clean Energy Utilization of Guangdong Higher Education Institutes of China(No.KLB10004)Guangdong Province Key Laboratory of Efficient and Clean Energy Utilization,China(No.2013A061401005)
文摘Laser-induced breakdown spectroscopy was employed to determine the inorganic elements in coal. To improve the measurement＇s accuracy and precision, a new internal standardization scheme, which we named changed internal standardization, was compared with the traditional internal standardization and no internal standardization for the analysis of inorganic elements. The new internal standardization scheme used the atomic line of carbon at 247.86 nm and the molecular band of CN at 388.34 nm and C2 at 516.32 nm to normalize the lines of inorganic elements that were distributed in the same spectral channel. The performance of the utilization of the new internal standardization scheme was evaluated using a set of coal samples, including twenty calibration samples and five validation samples. The results show that the coefficients of determination R2 and the slope of calibration models coupled with changed internal standard- ization are better than that of the calibration models coupled with fixed internal standardization and no internal standardization. Moreover, the measurement accuracy and reproducibility of changed internal standardization for the analysis of five validation samples also yielded further improvement. The results that we obtained suggest that changed internal standardization could compensate for the matrix effects, as well as the influence of the difference in the spectral response of the light collection system.
基金supported by the National Key R&D Plan of China,China(Grant No.2018YFC0604501)the Natural Science Foundation of China,China(Grant Nos.51934008,51674264,51904305)the Research Fund of the State Key Laboratory of Coal Resources and Safe Mining,CUMT,China(Grant No.SKLCRSM19KF023).
文摘The size distribution of the broken top coal blocks is an important factor,affecting the recovery ratio and the efficiency of drawing top coal in longwall top coal caving(LTCC)mining panel.The standard deviation of top coal block size(dt)is one of the main parameters to reflect the size distribution of top coal.To find the effect of dt on the caving mechanism,this study simulates experiments with 9 different dt by using discrete element software PFC.The dt is divided into two stages:uniform distribution stage(UDS)whose dt is less than 0.1(Schemes 1–5),and nonuniform distribution stage(NDS)whose dt is more than 0.1(Schemes 6–9).This research mainly investigates the variation of recovery ratio,drawing body shape,boundary of top coal,and contact force between particles in the two stages,respectively.The results showed that with the increasing dt,the recovery ratio of the panel increases first and then decreases in UDS.It is the largest in Scheme 3,which mainly increases the drawing volume at the side of starting drawing end.However,the recovery ratio decreases first and then increases quickly in NDS,and it is the largest in Scheme 9,where the drawing volume at the side of finishing drawing end are relatively higher.In UDS,the major size of top coal is basically medium,while in NDS,the size varies from medium to small,and then to large,with a distinct difference in shape and volume of the drawing body.When the major size of top coal is medium and small,the cross-section width of the initial boundary of top coal at each height is relatively small.Conversely,when the top coal size is large,the initial boundary of top coal has a larger opening range,the rotating angle of lower boundary is relatively small in the normal drawing stage,which is conducive to the development of drawing body and reduces the residual top coal,and the maximum particle velocity and the particles movement angle are both larger.This study lays a foundation for the prediction of recovery ratio,and suggests that the uniform top coal is more manageable and has a larger recovery ratio.
