Coal gasification fine slag(FS)is a typical solid waste generated in coal gasification.Its current disposal methods of stockpil-ing and landfilling have caused serious soil and ecological hazards.Separation recovery a...Coal gasification fine slag(FS)is a typical solid waste generated in coal gasification.Its current disposal methods of stockpil-ing and landfilling have caused serious soil and ecological hazards.Separation recovery and the high-value utilization of residual carbon(RC)in FS are the keys to realizing the win-win situation of the coal chemical industry in terms of economic and environmental benefits.The structural properties,such as pore,surface functional group,and microcrystalline structures,of RC in FS(FS-RC)not only affect the flotation recovery efficiency of FS-RC but also form the basis for the high-value utilization of FS-RC.In this paper,the characteristics of FS-RC in terms of pore structure,surface functional groups,and microcrystalline structure are sorted out in accordance with gasification type and FS particle size.The reasons for the formation of the special structural properties of FS-RC are analyzed,and their influence on the flotation separation and high-value utilization of FS-RC is summarized.Separation methods based on the pore structural characterist-ics of FS-RC,such as ultrasonic pretreatment-pore-blocking flotation and pore breaking-flocculation flotation,are proposed to be the key development technologies for improving FS-RC recovery in the future.The design of low-cost,low-dose collectors containing polar bonds based on the surface and microcrystalline structures of FS-RC is proposed to be an important breakthrough point for strengthening the flotation efficiency of FS-RC in the future.The high-value utilization of FS should be based on the physicochemical structural proper-ties of FS-RC and should focus on the environmental impact of hazardous elements and the recyclability of chemical waste liquid to es-tablish an environmentally friendly utilization method.This review is of great theoretical importance for the comprehensive understand-ing of the unique structural properties of FS-RC,the breakthrough of the technological bottleneck in the efficient flotation separation of FS,and the expansion of the field of the high value-added utilization of FS-RC.展开更多
Under the background of a transformation of the global energy structure,coal gasification technology has a wide application prospect,but its by-product,the coal gasification residue(CGR),is still not being efficiently...Under the background of a transformation of the global energy structure,coal gasification technology has a wide application prospect,but its by-product,the coal gasification residue(CGR),is still not being efficiently utilized for recycling.The CGR contains abundant carbon components,which could be applied to the microwave absorption field as the carbon matrix.In this study,Fe/CGR composites are fabricated via a two-step method,including the impregnation of Fe^(3+)and the reduction process.The influence of the different loading capacities of the Fe component on the morphology and electromagnetic properties is studied.Moreover,the loading content of Fe and the surface morphology of the Fe/CGR can be reasonably controlled by adjusting the concentration of the ferric nitrate solution.Meanwhile,Fe particles are evenly inserted on the CGR framework,which expands the Fe/CGR interfaces to enhance interfacial polarization,thus further improving the microwave-absorbing(MA)properties of composites.Particularly,as the Fe^(3+)concentration is 1.0 mol/L,the Fe/CGR composite exhibits outstanding performance.The reflection loss reaches-39.3 dB at 2.5 mm,and the absorption bandwidth covers 4.1 GHz at 1.5 mm.In this study,facile processability,resource recycling,appropriately matched impedance,and excellent MA performance are achieved.Finally,the Fe/CGR composites not only enhance the recycling of the CGR but also pioneer a new path for the synthesis of excellent absorbents.展开更多
Coal is an essential fossil fuel in China; however, coal mining and its utilization are being under the increasing pressure from ecological and environmental protection. Therefore, the consulting project "Technic...Coal is an essential fossil fuel in China; however, coal mining and its utilization are being under the increasing pressure from ecological and environmental protection. Therefore, the consulting project "Technical Revolution in Ecological and Efficient Coal Mining and Utilization & Intelligence and Diverse Coordination of Coal-based Energy System," initiated by Chinese Academy of Engineering, puts forward three stages(3.0, 4.0 and 5.0) of China's coal industry development strategy. Aimed at "reduced staff,ultra-low ecological damage, and emission level near to natural gas," breakthroughs should be achieved in the following three key technologies during the China Coal Industry 3.0 stage(2016–2025): including intelligent coal mining, ecological mining, ultra-low emission and environmental protection. This paper focuses on the development trends of the China Coal Industry 3.0 and its support for China Coal Industry 4.0 and 5.0 is analyzed and prospected as well, which may offer technical assistance and strategy orientation for realizing the transformation from traditional coal energy to clean energy.展开更多
The dominant status of coal on the energy production and consumption structure of China will not be changed in the middle period of this century. To realize highly efficient utilization of coal,low pollution and low c...The dominant status of coal on the energy production and consumption structure of China will not be changed in the middle period of this century. To realize highly efficient utilization of coal,low pollution and low cost are great and impendent tasks. These difficult problems can be almost resolved through establishing large-scale pithead power stations using two-stage highly efficient dry coal-cleaning system before coal burning,which is a highly efficient,clean and economical strategy considering the current energy and environmental status of China. All these will be discussed in detail in this paper.展开更多
Four different groups of components were separated from coal under mild conditions of extraction and stripping process. Within these groups, and with pre-separation, individual utilization of all coal components can b...Four different groups of components were separated from coal under mild conditions of extraction and stripping process. Within these groups, and with pre-separation, individual utilization of all coal components can be realized, similar to petroleum components and enhance the inherent value and utilization value of coal, as well as increase environmental benefits. The characteristics of each component were analyzed with measurements by FTIR, GC/MS, TEM and the establishment of caking properties. The results show that coal can be separated into residues, ultra-pure coal, asphaltene components and light components by adding solvents for stripping into the CS2/NMP mixed extraction solution. Those four groups of components present great differences in the presence of carbon and hydrogen elements, in the structure of functional groups, in their macroscopic structure and micro-morphology and caking properties. Every component possesses its own inherent values and approaches. A new idea of coal processes and utilization, similar to the use of petroleum is proposed.展开更多
Phase change materials (PCMs) can be incorporated with low-cost minerals to synthesize composites for thermal energy storage in building applications.Stone coal (SC) after vanadium extraction treatment shows potential...Phase change materials (PCMs) can be incorporated with low-cost minerals to synthesize composites for thermal energy storage in building applications.Stone coal (SC) after vanadium extraction treatment shows potential for secondary utilization in composite preparation.We prepared SC-based composite PCMs with SC as a matrix,stearic acid (SA) as a PCM,and expanded graphite (EG) as an additive.The combined roasting and acid leaching treatment of raw SC was conducted to understand the effect of vanadium extraction on promoting loading capacity.Results showed that the combined treatment of roasting at 900℃ and leaching increased the SC loading of the composite by 6.2%by improving the specific surface area.The loading capacity and thermal conductivity of the composite obviously increased by 127%and 48.19%,respectively,due to the contribution of 3wt% EG.These data were supported by the high load of 66.69%and thermal conductivity of 0.59 W·m^(-1)·K-1of the designed composite.The obtained composite exhibited a phase change temperature of 52.17℃,melting latent heat of 121.5 J·g^(-1),and good chemical compatibility.The SC-based composite has prospects in building applications exploiting the secondary utilization of minerals.展开更多
Shortages in water resources and the fragile ecosystem by coal-mine water affect the Yulin coal-mine base in northwest China, so taking coal-mine water into account is an important issue for the sustainable management...Shortages in water resources and the fragile ecosystem by coal-mine water affect the Yulin coal-mine base in northwest China, so taking coal-mine water into account is an important issue for the sustainable management of water resources. This paper aims to explore how the Yulin coal-mine base can improve its conjunctive utilization of water resources. Integrated utilization is proposed by establishing a multi-objective, multi-water-source, optimal-allocation model;setting up an integrated information platform;and giving very useful measures and policy suggestions to the local government. Finally, this research can also serve as an example of integrated water utilization for other energy bases.展开更多
About 10% of total electricity (386 MkW) was generated by nuclear power plants in the world (2014) and about 58,400 tons of uranium has been mined in uranium mines annually. A plenty of radioactive waste material is p...About 10% of total electricity (386 MkW) was generated by nuclear power plants in the world (2014) and about 58,400 tons of uranium has been mined in uranium mines annually. A plenty of radioactive waste material is produced from uranium mines and nuclear power plants. The wastes must be disposed or stored safely for a long term. Because if they leak and/or move from disposal or storage sites due to air/groundwater flow, then a serious environmental pollution can occur. Hence, multi-layer system has been proposed and employed in order to seal off these radioactive waste materials from biosphere. Basically, bentonite is now used for establishing one of absorbing and sealing layers in this system. However, the amount of high quality bentonite is very limited and in some cases it is hard to be obtained. On the other hand, a great deal of refuse from coal burning plants is produced every year and the amount of it is expected to be higher each year especially in developing countries. More than half of coal ash is utilized and the remaining is disposed at the disposal sites. However, the life of the disposal site is limited and it is difficult to find a new disposal site. It is requested that the percentage of the utilization of the coal ash be increased in every field. From the above two points of view, a fly ash-based barrier system is considered in this research and this paper discusses the applicability of fly ash as a content of barrier material. Based on the results of a series of laboratory tests, it can be concluded that fly ash has a potential for use in the buffer material as the bentonite is substituted.展开更多
The utilization of coal derived pyrite by electrolysis was studied. It is obvious that the sulfur and Fe in pyrite can be electrolyzed into Fe 3+ and SO 2- 4, and the no pollutant is drained off. In this paper, the in...The utilization of coal derived pyrite by electrolysis was studied. It is obvious that the sulfur and Fe in pyrite can be electrolyzed into Fe 3+ and SO 2- 4, and the no pollutant is drained off. In this paper, the influence of conditions, including electrolysis potential, time, temperature, the acidity of electrolysis solutions, the concentration of adding agent, the concentration of pyrite, and the rate of conversion of pyrite (Cr) was investigated. Cr increases with the rise of potential, time, temperature, acidity and the concentration of additive agent, but decreases with the rise of concentration of pyrite. At the certain conditions (at the potential of 3 0 V, temperature of 298 K, time of 12 h, the concentration of MnSO 4 of 6%, concentration of pyrite of 4%, and concentration of acid of 10%), Cr is high to 93%. In the same time, the mechanism of electrolysis of pyrite was provided. The electrolysis of pyrite is actually the recycle of Mn ion between anodic surface and pyrite. At last, the production of FeSO 4·7H 2O through electrolysis of pyrite was introduced.展开更多
Coals are carbon-rich materials with excellent aromatic nature and macro- molecular structure. They pose great potential as the source of organic chemical feed- stock and high value-added carbonaceous materials in the...Coals are carbon-rich materials with excellent aromatic nature and macro- molecular structure. They pose great potential as the source of organic chemical feed- stock and high value-added carbonaceous materials in the 21st century. As some of the most important analytical methods, thermal analysis (TA) techniques with strong com- petence in materials characterization and reaction mechanism research, have been ex- tensively employed to accumulate the knowledge about coal conversion and utilization in a most effective, efficient and responsible way. Unfortunately, some efforts did not promote the sound growth of a systematic discipline, which might arise from the intrinsic drawback of conventional TA. Proposals on acquiring much more reliable understanding of the mechanism and kinetics of reactions were made in this review.展开更多
The co-combustion of low-rank coals through fluidized bed boiler(CFB)is an effective approach to enhance the level of resource utilization.To date,there has been a lack of investigation concerning the co-combustion ki...The co-combustion of low-rank coals through fluidized bed boiler(CFB)is an effective approach to enhance the level of resource utilization.To date,there has been a lack of investigation concerning the co-combustion kinetics and self-desulfurization characteristics of coal slime,coal gangue,and raw coal.In this study,we adopted multiple model-free and model-fitting methods to comparatively analyze co-combustion kinetics of blended coals on the basis of thermogravimetric data.Then,the sulfur balance and self-desulfurization of blended coals in the co-combustion were intensively investigated using a tube furnace set-up.The results reveal that in the presence of coal gangue in blended coals,the average activation energy(E_(a))falls within the range of 65.7 kJ/mol to 100.4 kJ/mol,as determined by four model-free methods.Conversely,in the absence of coal gangue,only the Flynn-Wall-Ozawa(FWO)and Friedman(FM)methods are deemed appropriate for calculating the average E_(a),yielding a value of 77.3 kJ/mol.The first order reaction model is confirmed to be reliable for analyzing the co-combustion kinetics of low-rank blended coals.Irrespective of the specific composition of the blended coal,a significant linear correlation exists between the Ea and the natural logarithm of the pre-exponential factor(lnA)within an extensive range of parameters.Moreover,the addition of coal gangue to the blended coal substantially enhances the self-desulfurization level,resulting in an increase from 25.7%to60.7%at 1073 K.The self-desulfurization efficiency exhibits a good linear relationship with both the mass ratio of coal gangue to coal slime and the molar ratio of calcium to sulfur.In a practical implementation,the optimal addition ratio of coal gangue is a trade-off between the self-desulfurization efficiency and the ignition capacity.展开更多
面向“30·60”双碳目标,矿区能源利用方式的绿色、经济、高效转型成为我国能源革命的迫切需求。西部矿区拥有丰富的可再生能源资源禀赋,但仍面临着可再生能源就地消纳困难,电力设备投资成本高、利用率低以及外送输电通道有限的困...面向“30·60”双碳目标,矿区能源利用方式的绿色、经济、高效转型成为我国能源革命的迫切需求。西部矿区拥有丰富的可再生能源资源禀赋,但仍面临着可再生能源就地消纳困难,电力设备投资成本高、利用率低以及外送输电通道有限的困难。为提升矿区用能清洁化程度,提升矿区能源供给的稳定性与可靠性,增强矿区对外部电网的支撑能力,提出全清洁能源下的高品质矿区能源系统(High-quality Coal Mine Energy System,HCMES)及其配置优化方法。首先,考虑西部矿山综合能源系统的负荷特点与伴生能源利用,结合可再生能源发电与废弃矿井抽水蓄能,构建全清洁能源下的HCMES架构。其次,考虑到矿区生产全流程负荷的需求响应能力,考虑系统的能量平衡约束,提出全清洁能源下的高品质矿区能源系统优化配置模型。最后,以系统年平均综合成本最小化为目标,将原问题转化为混合整数线性规划模型,求解生成高品质矿区能源系统优化配置方案。以我国西部某年产煤量1200万t的矿区实际数据为实例,验证所提模型与方法的有效性,并分析可再生能源出力与生产负荷需求不确定性对系统优化配置结果的影响。算例仿真设置了4种矿区能源系统配置方式:不配置储能、配置抽水蓄能、配置电化学储能、配置抽水蓄能(不外购电能)。结果表明,所提出的HCMES相较于其他配置方式可减少电气一次设备投资11.11%,相较于方式3可降低年平均综合成本7.91%,且最多可减少矿区生产用能总二氧化碳排放量91.17%。展开更多
基金the National Natural Science Foundation of China(No.52374279)the Natural Science Foundation of Shaanxi Province(No.2023-YBGY-055).
文摘Coal gasification fine slag(FS)is a typical solid waste generated in coal gasification.Its current disposal methods of stockpil-ing and landfilling have caused serious soil and ecological hazards.Separation recovery and the high-value utilization of residual carbon(RC)in FS are the keys to realizing the win-win situation of the coal chemical industry in terms of economic and environmental benefits.The structural properties,such as pore,surface functional group,and microcrystalline structures,of RC in FS(FS-RC)not only affect the flotation recovery efficiency of FS-RC but also form the basis for the high-value utilization of FS-RC.In this paper,the characteristics of FS-RC in terms of pore structure,surface functional groups,and microcrystalline structure are sorted out in accordance with gasification type and FS particle size.The reasons for the formation of the special structural properties of FS-RC are analyzed,and their influence on the flotation separation and high-value utilization of FS-RC is summarized.Separation methods based on the pore structural characterist-ics of FS-RC,such as ultrasonic pretreatment-pore-blocking flotation and pore breaking-flocculation flotation,are proposed to be the key development technologies for improving FS-RC recovery in the future.The design of low-cost,low-dose collectors containing polar bonds based on the surface and microcrystalline structures of FS-RC is proposed to be an important breakthrough point for strengthening the flotation efficiency of FS-RC in the future.The high-value utilization of FS should be based on the physicochemical structural proper-ties of FS-RC and should focus on the environmental impact of hazardous elements and the recyclability of chemical waste liquid to es-tablish an environmentally friendly utilization method.This review is of great theoretical importance for the comprehensive understand-ing of the unique structural properties of FS-RC,the breakthrough of the technological bottleneck in the efficient flotation separation of FS,and the expansion of the field of the high value-added utilization of FS-RC.
基金supported by the National Nature Science Foundation of China(No.51802212)the National College Students’Innovation and Entrepreneurship Training Program(No.2021465)+2 种基金the Natural Science Foundation of Shanxi Province,China(No.201801D221119)the Open Foundation of China-Belarus Belt and Road Joint Laboratory on Electromagnetic Environment Effect(Nos.ZBKF2022030802 and ZBKF2022030702)the Graduate Education Innovation Programs of Taiyuan University of Science and Technology(No.XCX212003)。
文摘Under the background of a transformation of the global energy structure,coal gasification technology has a wide application prospect,but its by-product,the coal gasification residue(CGR),is still not being efficiently utilized for recycling.The CGR contains abundant carbon components,which could be applied to the microwave absorption field as the carbon matrix.In this study,Fe/CGR composites are fabricated via a two-step method,including the impregnation of Fe^(3+)and the reduction process.The influence of the different loading capacities of the Fe component on the morphology and electromagnetic properties is studied.Moreover,the loading content of Fe and the surface morphology of the Fe/CGR can be reasonably controlled by adjusting the concentration of the ferric nitrate solution.Meanwhile,Fe particles are evenly inserted on the CGR framework,which expands the Fe/CGR interfaces to enhance interfacial polarization,thus further improving the microwave-absorbing(MA)properties of composites.Particularly,as the Fe^(3+)concentration is 1.0 mol/L,the Fe/CGR composite exhibits outstanding performance.The reflection loss reaches-39.3 dB at 2.5 mm,and the absorption bandwidth covers 4.1 GHz at 1.5 mm.In this study,facile processability,resource recycling,appropriately matched impedance,and excellent MA performance are achieved.Finally,the Fe/CGR composites not only enhance the recycling of the CGR but also pioneer a new path for the synthesis of excellent absorbents.
基金supported by the Major State Basic Research Development Program of China (No. 2014CB046302)
文摘Coal is an essential fossil fuel in China; however, coal mining and its utilization are being under the increasing pressure from ecological and environmental protection. Therefore, the consulting project "Technical Revolution in Ecological and Efficient Coal Mining and Utilization & Intelligence and Diverse Coordination of Coal-based Energy System," initiated by Chinese Academy of Engineering, puts forward three stages(3.0, 4.0 and 5.0) of China's coal industry development strategy. Aimed at "reduced staff,ultra-low ecological damage, and emission level near to natural gas," breakthroughs should be achieved in the following three key technologies during the China Coal Industry 3.0 stage(2016–2025): including intelligent coal mining, ecological mining, ultra-low emission and environmental protection. This paper focuses on the development trends of the China Coal Industry 3.0 and its support for China Coal Industry 4.0 and 5.0 is analyzed and prospected as well, which may offer technical assistance and strategy orientation for realizing the transformation from traditional coal energy to clean energy.
文摘The dominant status of coal on the energy production and consumption structure of China will not be changed in the middle period of this century. To realize highly efficient utilization of coal,low pollution and low cost are great and impendent tasks. These difficult problems can be almost resolved through establishing large-scale pithead power stations using two-stage highly efficient dry coal-cleaning system before coal burning,which is a highly efficient,clean and economical strategy considering the current energy and environmental status of China. All these will be discussed in detail in this paper.
基金Projects 50474066 and 50874108 supported by the National Natural Science Foundation of Chinathe Scientific Research Key Project Fund of the Ministry of Education (107055)+1 种基金the Jiangsu Natural Science Foundation (BK2007038)the Open Fund of Key Laboratory of the Education Ministry of Coal Process and Clean Utilization (CPEUKF06-03, CPEUKF08-06) for their financial support
文摘Four different groups of components were separated from coal under mild conditions of extraction and stripping process. Within these groups, and with pre-separation, individual utilization of all coal components can be realized, similar to petroleum components and enhance the inherent value and utilization value of coal, as well as increase environmental benefits. The characteristics of each component were analyzed with measurements by FTIR, GC/MS, TEM and the establishment of caking properties. The results show that coal can be separated into residues, ultra-pure coal, asphaltene components and light components by adding solvents for stripping into the CS2/NMP mixed extraction solution. Those four groups of components present great differences in the presence of carbon and hydrogen elements, in the structure of functional groups, in their macroscopic structure and micro-morphology and caking properties. Every component possesses its own inherent values and approaches. A new idea of coal processes and utilization, similar to the use of petroleum is proposed.
基金financially supported by the National Natural Science Foundation of China, China (Nos. 52274252 and 51874047)the Special Fund for the Construction of Innovative Provinces in Hunan Province, China (No. 2020RC3038)the Changsha City Fund for Distinguished and Innovative Young Scholars, China (No. kq1802007)。
文摘Phase change materials (PCMs) can be incorporated with low-cost minerals to synthesize composites for thermal energy storage in building applications.Stone coal (SC) after vanadium extraction treatment shows potential for secondary utilization in composite preparation.We prepared SC-based composite PCMs with SC as a matrix,stearic acid (SA) as a PCM,and expanded graphite (EG) as an additive.The combined roasting and acid leaching treatment of raw SC was conducted to understand the effect of vanadium extraction on promoting loading capacity.Results showed that the combined treatment of roasting at 900℃ and leaching increased the SC loading of the composite by 6.2%by improving the specific surface area.The loading capacity and thermal conductivity of the composite obviously increased by 127%and 48.19%,respectively,due to the contribution of 3wt% EG.These data were supported by the high load of 66.69%and thermal conductivity of 0.59 W·m^(-1)·K-1of the designed composite.The obtained composite exhibited a phase change temperature of 52.17℃,melting latent heat of 121.5 J·g^(-1),and good chemical compatibility.The SC-based composite has prospects in building applications exploiting the secondary utilization of minerals.
文摘Shortages in water resources and the fragile ecosystem by coal-mine water affect the Yulin coal-mine base in northwest China, so taking coal-mine water into account is an important issue for the sustainable management of water resources. This paper aims to explore how the Yulin coal-mine base can improve its conjunctive utilization of water resources. Integrated utilization is proposed by establishing a multi-objective, multi-water-source, optimal-allocation model;setting up an integrated information platform;and giving very useful measures and policy suggestions to the local government. Finally, this research can also serve as an example of integrated water utilization for other energy bases.
文摘About 10% of total electricity (386 MkW) was generated by nuclear power plants in the world (2014) and about 58,400 tons of uranium has been mined in uranium mines annually. A plenty of radioactive waste material is produced from uranium mines and nuclear power plants. The wastes must be disposed or stored safely for a long term. Because if they leak and/or move from disposal or storage sites due to air/groundwater flow, then a serious environmental pollution can occur. Hence, multi-layer system has been proposed and employed in order to seal off these radioactive waste materials from biosphere. Basically, bentonite is now used for establishing one of absorbing and sealing layers in this system. However, the amount of high quality bentonite is very limited and in some cases it is hard to be obtained. On the other hand, a great deal of refuse from coal burning plants is produced every year and the amount of it is expected to be higher each year especially in developing countries. More than half of coal ash is utilized and the remaining is disposed at the disposal sites. However, the life of the disposal site is limited and it is difficult to find a new disposal site. It is requested that the percentage of the utilization of the coal ash be increased in every field. From the above two points of view, a fly ash-based barrier system is considered in this research and this paper discusses the applicability of fly ash as a content of barrier material. Based on the results of a series of laboratory tests, it can be concluded that fly ash has a potential for use in the buffer material as the bentonite is substituted.
文摘The utilization of coal derived pyrite by electrolysis was studied. It is obvious that the sulfur and Fe in pyrite can be electrolyzed into Fe 3+ and SO 2- 4, and the no pollutant is drained off. In this paper, the influence of conditions, including electrolysis potential, time, temperature, the acidity of electrolysis solutions, the concentration of adding agent, the concentration of pyrite, and the rate of conversion of pyrite (Cr) was investigated. Cr increases with the rise of potential, time, temperature, acidity and the concentration of additive agent, but decreases with the rise of concentration of pyrite. At the certain conditions (at the potential of 3 0 V, temperature of 298 K, time of 12 h, the concentration of MnSO 4 of 6%, concentration of pyrite of 4%, and concentration of acid of 10%), Cr is high to 93%. In the same time, the mechanism of electrolysis of pyrite was provided. The electrolysis of pyrite is actually the recycle of Mn ion between anodic surface and pyrite. At last, the production of FeSO 4·7H 2O through electrolysis of pyrite was introduced.
文摘Coals are carbon-rich materials with excellent aromatic nature and macro- molecular structure. They pose great potential as the source of organic chemical feed- stock and high value-added carbonaceous materials in the 21st century. As some of the most important analytical methods, thermal analysis (TA) techniques with strong com- petence in materials characterization and reaction mechanism research, have been ex- tensively employed to accumulate the knowledge about coal conversion and utilization in a most effective, efficient and responsible way. Unfortunately, some efforts did not promote the sound growth of a systematic discipline, which might arise from the intrinsic drawback of conventional TA. Proposals on acquiring much more reliable understanding of the mechanism and kinetics of reactions were made in this review.
基金supported by the National Natural Science Foundation of China(52276110)。
文摘The co-combustion of low-rank coals through fluidized bed boiler(CFB)is an effective approach to enhance the level of resource utilization.To date,there has been a lack of investigation concerning the co-combustion kinetics and self-desulfurization characteristics of coal slime,coal gangue,and raw coal.In this study,we adopted multiple model-free and model-fitting methods to comparatively analyze co-combustion kinetics of blended coals on the basis of thermogravimetric data.Then,the sulfur balance and self-desulfurization of blended coals in the co-combustion were intensively investigated using a tube furnace set-up.The results reveal that in the presence of coal gangue in blended coals,the average activation energy(E_(a))falls within the range of 65.7 kJ/mol to 100.4 kJ/mol,as determined by four model-free methods.Conversely,in the absence of coal gangue,only the Flynn-Wall-Ozawa(FWO)and Friedman(FM)methods are deemed appropriate for calculating the average E_(a),yielding a value of 77.3 kJ/mol.The first order reaction model is confirmed to be reliable for analyzing the co-combustion kinetics of low-rank blended coals.Irrespective of the specific composition of the blended coal,a significant linear correlation exists between the Ea and the natural logarithm of the pre-exponential factor(lnA)within an extensive range of parameters.Moreover,the addition of coal gangue to the blended coal substantially enhances the self-desulfurization level,resulting in an increase from 25.7%to60.7%at 1073 K.The self-desulfurization efficiency exhibits a good linear relationship with both the mass ratio of coal gangue to coal slime and the molar ratio of calcium to sulfur.In a practical implementation,the optimal addition ratio of coal gangue is a trade-off between the self-desulfurization efficiency and the ignition capacity.
文摘面向“30·60”双碳目标,矿区能源利用方式的绿色、经济、高效转型成为我国能源革命的迫切需求。西部矿区拥有丰富的可再生能源资源禀赋,但仍面临着可再生能源就地消纳困难,电力设备投资成本高、利用率低以及外送输电通道有限的困难。为提升矿区用能清洁化程度,提升矿区能源供给的稳定性与可靠性,增强矿区对外部电网的支撑能力,提出全清洁能源下的高品质矿区能源系统(High-quality Coal Mine Energy System,HCMES)及其配置优化方法。首先,考虑西部矿山综合能源系统的负荷特点与伴生能源利用,结合可再生能源发电与废弃矿井抽水蓄能,构建全清洁能源下的HCMES架构。其次,考虑到矿区生产全流程负荷的需求响应能力,考虑系统的能量平衡约束,提出全清洁能源下的高品质矿区能源系统优化配置模型。最后,以系统年平均综合成本最小化为目标,将原问题转化为混合整数线性规划模型,求解生成高品质矿区能源系统优化配置方案。以我国西部某年产煤量1200万t的矿区实际数据为实例,验证所提模型与方法的有效性,并分析可再生能源出力与生产负荷需求不确定性对系统优化配置结果的影响。算例仿真设置了4种矿区能源系统配置方式:不配置储能、配置抽水蓄能、配置电化学储能、配置抽水蓄能(不外购电能)。结果表明,所提出的HCMES相较于其他配置方式可减少电气一次设备投资11.11%,相较于方式3可降低年平均综合成本7.91%,且最多可减少矿区生产用能总二氧化碳排放量91.17%。