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Investigation on the performance and detoxification of modified low temperature coal tar pitch 被引量:1
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作者 Fengyan SUN Yu LIU 《Frontiers of Structural and Civil Engineering》 SCIE EI CSCD 2017年第3期315-321,共7页
In this paper, studies on the modification on the low temperature coal tar pitch extracted from coal tar residue in Inner Mongolia are conducted. First, the low temperature coal tar pitch in liquid state is solidified... In this paper, studies on the modification on the low temperature coal tar pitch extracted from coal tar residue in Inner Mongolia are conducted. First, the low temperature coal tar pitch in liquid state is solidified with a higher softening point by chemical crosslinking modification. The modified coal tar pitch can achieve the standard pavement performance requirements. Then, the effects of chemical crosslinking agent and physical modification additives on the mechanical performance and toxic properties of coal tar pitch are investigated. The detoxification mechanism is also studied, which further promote the applicability of modified low temperature coal tar pitch in the pavement constructions. 展开更多
关键词 coal tar pitch low ternpemture modification detoxification
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对苯二甲醇改性煤沥青降低毒性多环芳烃含量 被引量:7
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作者 冯永辉 张蔺峰 +7 位作者 刘刚 牛艳霞 王玉高 申峻 李瑞丰 杜建奎 杨志峰 徐青柏 《太原理工大学学报》 CAS 北大核心 2018年第1期48-54,共7页
采用交联剂对苯二甲醇在对甲苯磺酸催化及环己烷溶剂作用下,对煤沥青进行化学改性以降低其毒性多环芳烃含量。探讨了改性剂用量、催化剂用量、反应温度、反应时间对美国环保局(EPA)优先监控的16种毒性多环芳烃含量降低率的影响,筛选出... 采用交联剂对苯二甲醇在对甲苯磺酸催化及环己烷溶剂作用下,对煤沥青进行化学改性以降低其毒性多环芳烃含量。探讨了改性剂用量、催化剂用量、反应温度、反应时间对美国环保局(EPA)优先监控的16种毒性多环芳烃含量降低率的影响,筛选出最佳工艺条件:改性剂用量占煤沥青6%,催化剂用量占煤沥青12%,反应温度50℃,反应时间2h.在此条件下,煤沥青中16种毒性多环芳烃总含量降低率达到74.14%,其中强致癌物苯并[a]芘含量降低率为78.38%.通过模型化合物芘与改性剂的反应,对产物进行热重及红外分析推测脱毒机理,结果证明多环芳烃与对苯二甲醇之间极可能发生亲电取代交联作用。 展开更多
关键词 煤沥青 多环芳烃 改性脱毒 对苯二甲醇 亲电取代交联
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