High-alkali species in coal are notorious for causing ash slagging and fouling incidents.In this paper,four high-alkali coals were individually subject to hydrothermal pretreatment(HTP),within a batch-type autoclave a...High-alkali species in coal are notorious for causing ash slagging and fouling incidents.In this paper,four high-alkali coals were individually subject to hydrothermal pretreatment(HTP),within a batch-type autoclave at 300 -C for 1 h,and the treated coals were analyzed,along with the oxygen-containing functional groups determined by Fourier transform infrared spectrometer(FT-IR).Then the alkali species and other components in the coal ash were quantified by X-ray fluorescence(XRF)for evaluating the ash slagging and fouling tendency.Apart from this,FactSage was adopted to simulate the occurrence and transformation of alkali species during coal thermal conversion ending at various temperatures.The findings indicate that the treated coals are superior to the parent ones in terms of certain remarkable changes via HTP.The moisture,oxygen and sulfur of the hydrothermally treated coals decline obviously,while the calorific value rises sharply.HTP could reduce the alkali species to less than 2%(%,by weight,equivalent to Na2O in dry ash),with a maximum removal ratio of 88.9%,lowering the ash slagging and fouling tendency.The proposed mechanism of HTP was that the alkali species in coal matrix became released due to the breakage of the coal functional groups and micropores during HTP.展开更多
[Objective] The study aimed to discuss the effects of coal mining subsided water area on temperature change in Huaibei coal mine. [Method] Based on the data of monthly temperature from 1957 to 2007 recorded by Suixi ...[Objective] The study aimed to discuss the effects of coal mining subsided water area on temperature change in Huaibei coal mine. [Method] Based on the data of monthly temperature from 1957 to 2007 recorded by Suixi （coal mining subsided water area） and Fuyang stations （control）, the effects of coal mining subsided water area on temperature change in Huaibei coal mine were discussed using linear trend estimation and comparative analysis methods. [Result] Spring, autumn, winter and annual average temperatures of coal mining subsided water area （Suixi） were increased in the last 51 years, and the increase of winter temperature was mostly significant with a tendency rate of 0.49 ℃/10 a. Meanwhile, annual temperature range of coal mining subsided water area was decreased from 1957 to 2007. Temperatures of Suixi in four seasons were lower than those of Fuyang from the 1960s to 1990s, and temperatures of coal mining subsided water area （Suixi） were higher than those of Fuyang in spring, autumn and winter but lower than those of Fuyang in summer from 2000 to 2007. [ Result] Coal mining subsided water area had certain effects on temperature change of Huaibei coal mine.展开更多
基金the National Key Basic Research Program of China (No. 2014CB238905)
文摘High-alkali species in coal are notorious for causing ash slagging and fouling incidents.In this paper,four high-alkali coals were individually subject to hydrothermal pretreatment(HTP),within a batch-type autoclave at 300 -C for 1 h,and the treated coals were analyzed,along with the oxygen-containing functional groups determined by Fourier transform infrared spectrometer(FT-IR).Then the alkali species and other components in the coal ash were quantified by X-ray fluorescence(XRF)for evaluating the ash slagging and fouling tendency.Apart from this,FactSage was adopted to simulate the occurrence and transformation of alkali species during coal thermal conversion ending at various temperatures.The findings indicate that the treated coals are superior to the parent ones in terms of certain remarkable changes via HTP.The moisture,oxygen and sulfur of the hydrothermally treated coals decline obviously,while the calorific value rises sharply.HTP could reduce the alkali species to less than 2%(%,by weight,equivalent to Na2O in dry ash),with a maximum removal ratio of 88.9%,lowering the ash slagging and fouling tendency.The proposed mechanism of HTP was that the alkali species in coal matrix became released due to the breakage of the coal functional groups and micropores during HTP.
基金Supported by the Key Project of Provincial Natural Science Research for Colleges and Universities in Anhui Province, China ( KJ2013A244)
文摘[Objective] The study aimed to discuss the effects of coal mining subsided water area on temperature change in Huaibei coal mine. [Method] Based on the data of monthly temperature from 1957 to 2007 recorded by Suixi （coal mining subsided water area） and Fuyang stations （control）, the effects of coal mining subsided water area on temperature change in Huaibei coal mine were discussed using linear trend estimation and comparative analysis methods. [Result] Spring, autumn, winter and annual average temperatures of coal mining subsided water area （Suixi） were increased in the last 51 years, and the increase of winter temperature was mostly significant with a tendency rate of 0.49 ℃/10 a. Meanwhile, annual temperature range of coal mining subsided water area was decreased from 1957 to 2007. Temperatures of Suixi in four seasons were lower than those of Fuyang from the 1960s to 1990s, and temperatures of coal mining subsided water area （Suixi） were higher than those of Fuyang in spring, autumn and winter but lower than those of Fuyang in summer from 2000 to 2007. [ Result] Coal mining subsided water area had certain effects on temperature change of Huaibei coal mine.
