Pyrite is separated from other minerals mainly by fotation.However,the hydrophilicity of pyrite is afected by many factors,causing it to easily enter the concentrate and consequently reduce the quality of concentrate....Pyrite is separated from other minerals mainly by fotation.However,the hydrophilicity of pyrite is afected by many factors,causing it to easily enter the concentrate and consequently reduce the quality of concentrate.Highly efcient pyrite depressants can be selectively adsorbed on the surface of pyrite to improve its hydrophilicity,thereby increasing the fotation separation efciency.Understanding the fundamental inhibition mechanism of depressants on pyrite is a prerequisite to improve the fotation desulfurization efciency.The inhibition ability and mechanism of diferent types of pyrite depressants are reviewed in this manuscript.In recent years,molecular simulation has increasingly become a powerful tool to study the interaction between reagents and minerals,shedding new light on the adsorption mechanisms of reagents on mineral surfaces at the atomic and electronic levels.The properties of sulfde mineral and fotation reagents as well as the microscopic adsorption mechanistic studies of reagents on mineral surfaces based on quantum chemistry and molecular simulation are also reviewed.展开更多
基金supported by the following:“Foundation for University Key Teacher by Henan Province”(No.2020GGJS051)“Key Project of Science and Technology Research of Education Department of Henan Province”(No.20A440004)+2 种基金“The Henan Polytechnic University Science Fund for Distinguished Young Scholars”(No.J2021-1)“Foundation for University Key Teacher by Henan Polytechnic University”(No.2017XQG-12)“Henan Key Laboratory of Coal Green Conversion”(No.CGCF202009).
文摘Pyrite is separated from other minerals mainly by fotation.However,the hydrophilicity of pyrite is afected by many factors,causing it to easily enter the concentrate and consequently reduce the quality of concentrate.Highly efcient pyrite depressants can be selectively adsorbed on the surface of pyrite to improve its hydrophilicity,thereby increasing the fotation separation efciency.Understanding the fundamental inhibition mechanism of depressants on pyrite is a prerequisite to improve the fotation desulfurization efciency.The inhibition ability and mechanism of diferent types of pyrite depressants are reviewed in this manuscript.In recent years,molecular simulation has increasingly become a powerful tool to study the interaction between reagents and minerals,shedding new light on the adsorption mechanisms of reagents on mineral surfaces at the atomic and electronic levels.The properties of sulfde mineral and fotation reagents as well as the microscopic adsorption mechanistic studies of reagents on mineral surfaces based on quantum chemistry and molecular simulation are also reviewed.