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Improving performance of direct coal liquefaction through swelling with solvent under the radiation of ultrasonic wave
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作者 倪献智 李克健 王力 《Journal of Coal Science & Engineering(China)》 2004年第2期85-88,共4页
Three kinds of lower rank bituminous coals from Yanzhou mine and Tengxian mine from Shandong Province were treated and hydrogenated in the study. The test re- sults show that the performance of hydrogenation liquefact... Three kinds of lower rank bituminous coals from Yanzhou mine and Tengxian mine from Shandong Province were treated and hydrogenated in the study. The test re- sults show that the performance of hydrogenation liquefaction of the pretreated coals is improved markedly. Under the test condition of H2 initial pressure 8.2 MPa, addition of FeSO4·7H2O and S as catalyst, final reacting temperature 400 ℃ and reacting time 1.5 h, the oil yield of pretreated YZ1 coal is 69.76% compared with 62.53% of oil yield of un- treated YZ1. Seminally the oil yield of pretreated YZ2 coal is 55.43% compared with 20.88% of untreated YZ2 coal. The results of tests also prove that the improving degree of hydrogenation liquefaction of the pretreated coals is related with radiation duration when the radiation frequency and radiation power of ultrasonic wave are fixed. 展开更多
关键词 coal solvent swell ultrasonic wave hydrogenation liquefaction
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超声波辐射下溶胀改善煤液化性能的研究 被引量:7
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作者 倪献智 王力 +1 位作者 陈丽慧 马小隆 《煤炭转化》 CAS CSCD 北大核心 2003年第4期37-41,共5页
以山东兖州局的北宿煤 ( BS)、兴隆庄煤 ( XLZ)、枣庄局的柴里煤 ( CL)等为研究用煤 ,首先在自然条件下使用吡啶溶剂进行原煤样的溶胀 ,然后利用超声波仪 ,在 40 k Hz和 5 0 0 W辐射功率和室温的条件下 ,进行超声波辐射作用下的吡啶溶... 以山东兖州局的北宿煤 ( BS)、兴隆庄煤 ( XLZ)、枣庄局的柴里煤 ( CL)等为研究用煤 ,首先在自然条件下使用吡啶溶剂进行原煤样的溶胀 ,然后利用超声波仪 ,在 40 k Hz和 5 0 0 W辐射功率和室温的条件下 ,进行超声波辐射作用下的吡啶溶剂溶胀 .经过对脱除溶剂后溶胀煤的加氢液化实验、低温干馏焦油产率测定、挥发分产率测定及体积溶胀率的测定 ,结果表明该三种原煤具有良好的可溶胀性能 ,溶胀煤均具有良好的加氢液化性能 .在 H2 冷态压力 8.2 MPa,40 0℃ ,Fe SO4·7H2 O和升华 S作催化剂、反应 1 .5 h的液化实验条件下 ,自然溶胀煤的液化油产率比原煤增加 1 2%~ 2 5 % ,北宿溶胀煤的液化油产率达到 69.76% .辐射溶胀后的溶胀煤与自然溶胀煤比较 ,在如上所述同样的液化条件下 ,兴隆庄煤的液化油产率增加了 2 2 % ,并且煤的总转化率也增加了 .实验数据表明 ,对于以提高煤加氢液化反应活性为目的的研究 ,当超声波辐射的频率和功率一定时 ,辐射时间对于改善煤样加氢液化的性能存在着最适宜值 ,这一最适宜值与煤的变质程度有直接关系 . 展开更多
关键词 超声波辐射 溶剂溶胀 液化性能 加氢液化 焦油产率
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