A review of the synthesis and application of zeolites from coal-based solid wastes

Zeolite derived from coal-based solid wastes(coal gangue and coal fly ash)can overcome the environmental problems caused by coal-based solid wastes and achieve valuable utilization.In this paper,the physicochemical properties of coal gangue and coal fly ash are introduced.The mechanism and application characteristics of the pretreatment processes for zeolite synthesis from coal-based solid wastes are also introduced.The synthesis processes of coal-based solid waste zeolite and their advantages and disadvantages are summarized.Furthermore,the application characteristics of various coal-based solid waste zeolites and their common application fields are illustrated.Finally,we propose an alkaline fusion-assisted supercritical hydrothermal crystallization as an efficient method for synthesizing coal-based solid waste zeolites.In addition,more attention should be given to the recycling of alkaline waste liquid and the application of coal-based solid waste zeolites in the field of volatile organic compound adsorption removal.

Co-combustion of municipal solid waste and coal gangue in a circulating fluidized bed combustor

Mixed incineration of municipal solid waste (MSW) in existing coal gangue power plant is a potentially highefficiency and low-cost MSW disposal way. In this paper, the co-combustion and pollutants emission characteristic of MSW and coal gangue was investigated in a circulating fluidized bed (CFB) combustor. The effect of MSW blend ratio, bed temperature and excess air ratio was detailedly studied. The results show the NOX and HC1 emission increases with the increasing MSW blend ratio and the SO2 emission decreases. With the increase of bed temperature, the CO emission decreases while the NOX and SO2 emission increases. The HC1 emission is nearly stable in the temperature range of 850-950℃. The increase of excess air ratio gradually increases the NOX emission but has no significant effect on the SO2 emission. The HC1 emission firstly increases and then decreases with the increase of excess air ratio. For a typical CFB operating condition with excess air ratio of 1.4, bed temperature of 900℃ and MSW blend ratio of 10%, the original CO, NOX, SO2 and HC1 emissions are 52, 181, 3373 and 58 mg/Nm^3 respectively.

Response of arbuscular mycorrhizal fungi and phosphorus solubilizing bacteria to remediation abandoned solid waste of coal mine

Coal is the vital resource of energy in China,but abandoned coal ash and gangue lead to the degradation of vegetation cover and reduce soil quality.Both arbuscular mycorrhizal fungi (AMF) and phosphate solubilizing bacteria (PSB) play a key role in biogeochemical cycle such as soil organic matter decomposition,nutrition release,and energy flow.To improve and reclamation the soil quality and ecological efficiency of the coal mining waste,we investigated the effects of an AMF strain (Glomus mosseae) and a PSB strain (Pantoesstewarti) on phytate mineralization and subsequent transfer to the host plant (Medicago sativa L.) using a two-compartment microcosm with a central 30 mm nylon mesh barrier.The results showed that significantly higher available P (AP),above ground biomass (AGB) and underground biomass (UGB) were in combined inoculation of AMF-PSB than other treatments in root and hyphae compartment.The microbial inoculum of the AMF or PSB had a significant influence on soil acid phosphatase activities (ACP).AMF-PSB enhanced phytate mineralization,improved plant biomass.AP and ACP positively influenced the AGB and UGB.AMF-PSB could be used as bioinoculant to enhance sustainable production of the plant in abandoned solid waste of coal mine.

Modeling and motion control simulation of tendon based parallel manipulator translation mechanism for sensor based high value waste processing

A novel sorting system based on one degree of freedom (DOF) tendon based parallel manipulator (TBPM) for high value waste processing was presented and designed. In order to control the motion of loads, nonlinear state feed forward control algorithm in the tendon length coordinate was used. Considering the system redundancy and actuation behavior, algorithms of optimal tension distribution and forward kinematics were designed. Then, the simulation experiments of motion control were implemented. The results demonstrate that the proposed TBPM translation system performs robust capacities. It can transfer the loads 1 m away within 1.5 s. With further optimization, the translation duration can be further reduced to be about 1 s and the optimized translation is followed with 43.59 m/s2 maximum acceleration. The translation errors at the aim position remain below 0.4 mm.

Research on municipal solid waste composting with coal ash

Considering the fact that there is much coal ash in the municipal solid waste (MSW) in some cities of China, the feasibility of composting in this situation was studied and the effect of content of the coal ash on the composting process and some basic relative technological parameters were investigated. The values of the moisture, the total organic matter, the content of coal ash, the C/N ratio and the ventilation were suggested to be 50%60%, 40%60%, 40%60%, (25∶1)(35∶1) and 0.050.20 m 3/(min·m 3), respectively.

Techno-economic analysis on oxy-fuel based steam turbine power system using municipal solid waste and coals with ultrasonicator sulfur removal

Municipal solid waste(MSW)is a carbon–neutral energy source and possesses a moderate heating value;hence,it can be used as an alternative fuel for coal.To use high ash and high sulfur Indian coals efficiently,a techno economic analysis is performed for electricity generation using supercritical and subcritical based steam turbines operating in the oxy-fuel co-combustion mode of MSW with Indian coals.The impact of the capture of direct and indirect greenhouse gasses such as CO_(2),NO_(x)and SO_(x)on the net thermal efficiency of the power plants is assessed.The supercritical based steam turbine achieved a higher net thermal efficiency by 8.8%using MSW based feedstock compared to sub-critical conditions.The co-combustion mode reduced the levelized cost of electricity(LCOE)by 48–73$/MWh.Techno-economic analysis for sulfur removal in coal using ultrasonication technology has not yet been reported in the literature.The incorporation of an ultrasonicator(a pre-combustion sulfur remover)and a duct sorbent injector(a post-combustion SO_(x)absorber)increased the LCOE by 1.39–2.75$/MWh.In high sulfur coals,the SO_(x)emissions decreased from 224.79 mg/m^(3)to 9.2 mg/m^(3).

Combustion and NO_(x)Emission Characteristics of Coal Slime Solid Waste at Different Feeding Positions

The NO_(x)emission of coal slime burned in circulating fluidized bed(CFB)boilers could hardly meet the increasingly strict standards in China.Feeding coal slime from the top of furnace led to uneven combustion in furnace and cyclones,short residence time and overheated tail heating surface.The effects of feeding positions on the combustion uniformity and pollutant emission characteristics of coal slime were studied.The experimental results showed that the coal slime combustion was more uniform when feeding from the front wall and longer residence time was conducive to the control of NO_(x)emission.When the boiler temperature and excess air ratio were almost identical,the initial NO_(x)emissions were 45.0 mg·m^(−3)and 70.7 mg·m^(−3)when feeding from the front wall and the top of furnace,respectively;the NO_(x)emission was cut down 36.35%when feeding from the front wall,successfully meeting the ultra-low NO_(x)emission standard of China.The adoption of feeding from the front wall greatly reduced the original emission of NO_(x);the operation costs in the practical applications were saved to a large extent.

Experimental Study on Ratio and Performance of Coal Gangue/Bottom Ash Geopolymer Double-Liquid Grouting Material

Mine grouting reinforcement and water plugging projects often require large amounts of grouting materials.To reduce the carbon emission of grouting material production,improve the utilization of solid waste from mining enterprises,and meet the needs of mine reinforcement and seepage control,a double-liquid grouting material containing a high admixture of coal gangue powder/bottom ash geopolymer was studied.The setting time,fluidity,bleeding rate,and mechanical properties of grouting materials were studied through laboratory tests,and SEM analyzed the microstructure of the materials.The results show that the total mixture of calcined gangue does not exceed 60%.And the proportion of bottom ash replacing cement should be within 30%.At the same time,the volume mixture of sodium silicate is 20%.And the water-solid ratio does not exceed 0.6.The stability of the slurry prepared under this ratio is good.The microstructure of the stone body is dense,and its strength can meet the requirements of rock reinforcement and seepage control.Its economic and environmental benefits are more significant than the traditional cement-silicate double-liquid grouting material.

煤电化基地大宗固废“三化”协同利用基础与技术

我国14个大型煤炭基地及89个大宗固体废弃物综合利用示范基地建设,标志着矿区大宗固废利用已被纳入全国战略发展布局。长期以来煤炭资源高强度的开发与利用,造成矿区浅埋煤层资源临近枯竭,煤电化基地大规模固废堆积及地表沉陷,已成为制约矿区绿色低碳、高质量发展的难题。大宗煤基固废协同利用与绿色充填是解放“三下一上”压煤,延长矿井服务年限,实现固废无害化、资源化、规模化“三化”利用的有效途径。基于产煤大省山西省、“华东能源粮仓”安徽两淮基地及宁东能源化工基地的煤基固废种类和产量,详细阐述了以煤矸石、粉煤灰、炉底渣、气化渣和脱硫石膏等为主要材料的煤基固废通过重金属吸附解吸和络合钝化技术实现无害化处置,列举煤基固废分类应用于低热值煤基固废发电、制备建筑材料如水泥、砖瓦等资源化利用途径,对比分析煤基固废采煤沉陷区复垦回填及井下充填规模化利用途径,突出煤基固废井下充填的优越性。基于煤电化基地深部煤炭资源,提出绿色充填开采理论与关键技术,包括深部煤矸石源头减量与采选充协同技术、充填材料高效制备与深部井下输送技术及煤基固废充填材料深部多场耦合机理,探究多源煤基固废从源头、过程到终端的深部充填开采全过程的技术原理与方法,以解决矿区深部井下充填的技术难题。根据宁东基地任家庄煤矿、山西省霍尔辛赫煤矿及淮北矿区地质条件和充填目的,分别提出超前钻孔注充低位充填方案、关键层非典型特征条件下多离层梯级注浆方案和煤基固废协同利用关键技术,综合矿山固废处置与利用、深部煤炭资源开发利用、地表沉陷控制、生态环境保护等优势,形成煤电化基地大宗固废协同利用与绿色开采模式,为煤炭开采高质量化和环境低损伤化提供参考。

玻璃纤维改性煤基固废胶结充填材料性能研究

基于煤矸石、粉煤灰等煤基固废再生资源利用和胶结充填材料性能优化问题,研究了玻璃纤维掺量、长度和养护龄期对煤基固废胶结材料输送性能和力学性能的影响规律,探讨了玻璃纤维增强机理。实验结果表明:玻璃纤维改性煤基固废胶结材料坍落度随纤维长度和掺量的增大而减小,但均大于200 mm,满足输送性能要求;抗压强度和抗拉强度随纤维长度的增大呈先增高后降低,随纤维掺量的增加而增高的变化规律;当玻璃纤维长度为6 mm、掺量为0.3%时,质量分数为79%的煤基固废胶结材料的综合性能最佳;玻璃纤维改性煤基固废胶结材料水化反应后,生成的针状和团状产物填充了材料细小裂隙且附着于纤维表面,能够有效提高材料的力学性能。

建筑物下特厚煤层镁渣基全固废连采连充开采技术与实践

我国建筑物下压煤量巨大,同时煤矸石、粉煤灰等煤基工业固体废弃物排放量日益增加,严重制约地方经济社会发展。以榆林麻黄梁煤矿为试验矿井,针对其特厚煤层、建筑物下压煤、充填成本高等问题,提出了特厚煤层全固废连采连充开采技术。采用四阶段工序并将特厚煤层分为上、下2部分二次回采压覆煤炭,最大程度控制地面沉降。为降低充填原材料成本,采用化学优化剂对镁渣进行源头改性,抑制镁渣冷却粉化,稳定水化活性,协同粉煤灰、脱硫石膏等煤基固废,研发了改性镁−煤渣基胶凝材料。采用改性镁−煤渣基胶凝材料胶结煤矸石、粉煤灰制备了全固废充填材料。针对麻黄梁煤矿四阶段强、弱充填强度要求,设计不同配比的改性镁渣基充填材料试验,优选配比并应用于井下充填。论述了膏体充填系统与充填接顶方法。麻黄梁煤矿全固废胶结充填工艺试验显示,井下28 d龄期充填体钻芯平均单轴抗压强度超设计强度27%,钻芯浸出毒性满足相关国家标准要求,成功回收了建筑物下压覆煤炭资源,社会经济效益显著。麻黄梁煤矿特厚煤层全固废胶结充填开采实践为国内类似矿井提供了有益借鉴,同时为我国大型煤炭基地的“煤−电−化−冶”固废大规模资源化利用提供了新的思路。

大宗煤基固废膏体充填材料少水化配比优化研究

为解决西部采煤区固废多、处理难的问题,以宁东矿区的脱硫石膏、粉煤灰、水泥为主要原料,对原料的微观形态及少水配比的煤基固废膏体充填材料的成分进行分析,以初期流动性、脱模后7 d和28 d的抗压强度为指标进行充填材料配比优化。设计了3因素3水平17组配比方案,建立响应面回归模型,分析单因素及多因素交互作用对少水充填材料强度和流动性的影响。研究结果表明,粉煤灰与水泥质量比是影响少水充填材料强度的重要因素,料浆质量分数是影响少水充填材料流动性的重要因素。少水配比的煤基固废膏体充填材料的最优配合比:脱硫石膏质量分数53%,粉煤灰与水泥质量比2∶1,料浆质量分数74%。波速与强度的响应关系表明,可以利用充填体的波速来预测其强度。

煤矿固体废弃物理化特征及生态环境影响研究

煤矿固体废弃物是煤炭开采、洗选和利用过程中产生的一种工业固体废弃物。我国煤矿固体废弃物虽然利用率逐年上升,但现阶段的堆存量仍然很大,它不仅侵占土地资源,还会造成严重的环境污染。本文通过系统检索知网、Web of Science和Google Scholar数据库,收集了2014—2024年间关于煤矿固体废弃物理化特征及生态环境影响方面的研究文献,综合分析发现,煤矿固体废弃物对环境的影响主要表现在:①煤矿固体废弃物在堆存过程中产生的多环芳烃、SO_(2)等气体和细颗粒物,会对大气产生污染;②煤矿固体废弃物中的重金属在淋滤过程中会污染周围地下水;③煤矿固体废弃物中的Cd、Cr、Hg等重金属元素会通过风化、浸出等过程向周围土壤迁移释放,造成严重的重金属污染。基于安全、环保、监测等相关规定,结合目前综合利用和处理现状,提出了今后煤矿固体废弃物的研究重点。

多源煤基固废胶结充填体力学及变形破坏特征试验研究

【目的】为研究多源煤基固废胶结充填体的力学特性及变形破坏规律,选择5种典型煤基固废,开展了煤基固废胶结充填体(Coal-Based Solid Waste Cemented Backfill,CBSWCB)的单轴压缩、声发射响应及微观结构测试试验。【方法】分析了CBSWCB单轴抗压强度的影响因素和交互作用,建立了基于交互作用的抗压强度影响因素四维空间可视化模型,结合CBSWCB的声发射及微观结构特征,阐明了单轴压缩条件下的力学演化特征及宏观变形破坏规律,从微观角度进一步论证了CBSWCB承载过程中水化反应机理及宏细观联系。【结果和结论】试验结果表明:(1)单轴抗压强度的主要影响因素是质量分数,而炉底渣掺量的影响程度最小。(2)单轴压缩下CBSWCB的宏观变形破坏由塑性、弱劈裂破坏逐渐向脆性、剪切破坏转化。(3) CBSWCB试件声发射参数演化可以分为上升期、平静期、活跃期、稳定期,声发射累计振铃计数曲线呈现明显的“阶梯状”增长,累计振铃计数在上升期和平稳期内缓慢增加,在活跃期急剧增加,在稳定期逐渐趋于平缓。(4)水泥掺量偏低以及多源煤基固废充填材料属性差异导致水化反应程度有限,水化产物数量较少是CBSWCB单轴抗压强度普遍偏低的主要原因。研究结果可为多源煤基固废用于充填开采提供一定参考依据。

煤矸石-建筑固废砖填充材料正交试验及性能研究

利用正交试验设计(4因素4水平)对煤矸石-建筑固废砖填充材料(以下称膏体填充材料)的流动性与强度进行了测试。研究了粉煤灰掺量、废砖骨料取代率、质量浓度、减水剂掺量对膏体填充材料的坍落度、扩展度和早、中、后期抗压强度以及劈裂抗拉性能的影响,确定膏体填充材料的最优配合比,并对试验结果进行系统性分析。结果表明:各个因素对膏体填充材料流动性的影响显著,可总结为流动性随粉煤灰掺量、废砖骨料取代率、质量浓度的增加而下降,随减水剂掺量的增加而上升;各个因素对膏体填充材料早期抗压强度无明显影响;废砖取代率与减水剂掺量对膏体填充材料中、后期强度有一定的影响,当废砖骨料替代率为50%~75%、减水剂掺量为0.6%时,膏体填充材料抗压强度更高;粉煤灰掺量17%、废砖骨料取代率75%、质量浓度81%、减水剂掺量0.6%为最优组合。对选定方案的填充材料进行了微观形貌测试,说明该组合下配制出来的煤矸石膏体填充材料能保证强度,综合性能最佳。

以煤矸石为原料制备P型沸石微粉的研究

基于煤矸石利用率较低的现状和煤矸石富含硅铝成分的特征,提出了将煤矸石废弃物制备成沸石分子筛矿物微粉的思路。以七台河市煤矸石为原材料,采用碱融-水热法合成P型沸石分子筛微粉末,探讨了陈化温度、液固比、碱固比等反应条件对P型分子筛形貌的影响,获得最佳工艺条件为:硅铝比为1∶1,陈化温度为50℃,液固比为7∶1,碱固比为0.8∶1。SEM测试结果显示,合成产物的微观形貌为粒径6μm左右的球形沸石分子筛。XRD测试结果表明,产物特征峰与NaP型分子筛标准特征峰相吻合。

面间煤柱与顺槽“掘-充-留”一体化科学问题与技术

我国将煤炭作为兜底保障能源的局面短期内无法改变,仍将长时间面临煤炭资源保护与煤基固废利用率低的难题。通过创新采掘方法,同时实现提高煤炭资源回采率、规模化处置煤基固废,为煤炭行业绿色可持续发展提供了新途径。在深入调研煤炭资源开采技术发展现状的基础上,提出了煤矿“掘-充-留”掘进新工法。从大断面巷道快速掘进、连续高效充填和巷道安全留设3个方面,通过理论分析、数值模拟等手段,系统论述了“掘-充-留”工法的科学问题和关键技术,研究结果表明:①针对大断面巷道快速掘进、掘进工作面围岩稳定性控制等工程难题,凝练了煤岩特性与掘进机截割参数匹配机制、覆岩载荷空间传递机制与围岩变形机理、锚杆/索-顶板相互作用关系及支护机制3个科学难题,构建了以掘进区地质环境超前实时感知、落-装-运煤多工序智能协同作业、钻锚支架随掘随支围岩时效控制和大断面巷道防漏风及通风优化为核心的技术体系;②从大断面巷道承载体系及时构建及其承载性能调控两个方面凝练了连续高效充填的科学问题,包括充填体-煤层-锚杆/索协同承载机制、多元固废基充填材料水化固结机制,明晰充填体物理力学特性时空演化规律,建立了充填空间安全高效搭建、充填材料工作性能调控、充填材料流动-固结感知为核心的连续高效充填关键技术体系,相关理论与技术的突破可以为充填材料的原材料优选及配比设计、添加剂开发/选型及工作性能调控、掘进速率及充填步距优化设计、充填体固结监测等提供基础理论依据;③基于巷道安全留设及全生命周期内围岩易断裂、易片帮和易损伤等关键难题,阐述了巷道围岩应力场时空分布特征、巷道变形与损伤演化机制、巷道围岩工程质量监测与稳定性调控理论3个科学问题,形成了以巷道围岩稳定性智能预警、巷道围岩变形控制为核心的关键技术体系。开展煤矿“掘-充-留”工法的科学研究与工程示范,实现固废规模化处置-面间煤柱高效回收-顺槽快速掘进的协同,可以推动煤炭行业绿色低碳转型发展。

基于“以废治废”模式的强化煤化工废水生物处理研究进展

在“以废治废”的模式下,煤化工各环节副产品及废弃物可为强化煤化工废水生物处理提供直接或间接的外源材料,实现在地化、资源化、高值化利用。针对这些原材料,从共代谢物质、吸附材料、导电材料、无机膜生物反应器四个角度总结了国内外最新研究进展,同时结合企业实际进行应用展望。

铁碳材料促进有机固体废弃物厌氧消化作用的研究进展

有机固体废弃物的厌氧消化在实现废物资源化利用中有重要意义。近年来,通过使用不同类型的添加剂提高厌氧消化的效率成为研究热点,其中铁基和碳基材料因为具有良好的导电性被广泛使用。着重归纳了铁基和碳基材料促进有机固体废弃物厌氧消化的研究进展,总结了两种添加剂在厌氧消化中的作用机制。铁基材料主要通过降低氧化还原电位为微生物创造生存条件、加强直接种间电子转移(DIET)、通过刺激关键酶促进水解和酸化过程的作用。碳基材料除可加强DIET外,还通过吸附抑制性化合物和富集功能性微生物及支持微生物定殖来发挥作用。同时,铁碳材料可协同促进厌氧消化。最后,深入分析了这两种材料在有机固体废弃物的厌氧消化过程中存在问题,并展望了其发展前景。

选煤固废资源化利用研究进展

煤炭洗选是实现煤炭清洁高效利用的前提和基础,洗选过程产生的固体废弃物(矸石和尾煤等)产量逐年增加,其综合治理及利用已经成为亟待解决的重要问题。论文介绍了选煤固废的理化特性,系统总结了选煤固废资源化利用研究进展,就选煤固废综合利用技术的现存问题和发展方向进行了展望。煤矸石和尾煤含有大量的硅铝化物及锂、镓、钛等微量元素,在燃烧发电、充填、建筑材料制备、土壤改良、高值化利用等方面具有广阔的应用前景。相对而言,目前煤矸石的综合利用途径更为全面,尤其是以超高水充填技术、采选充+X技术等技术为代表的矸石充填开采,具有煤矸石大宗处理的巨大潜力。尾煤的资源化利用是近年来的热点,在环境治理、土壤改良等方面取得了突破,可以用来制备吸附剂、土壤改良剂等材料。选煤固废资源化利用未来应着眼于适应市场需求以及可持续发展理念,通过完善技术、引入智能化等进一步实现选煤固废高效、安全、环保、分级梯级利用。