Solid wastes derived from metallurgical industries pose a significant threat to environment. The utilization and disposal of these solid wastes are the major concern in the world. Semi-coke generated in coal-based dir...Solid wastes derived from metallurgical industries pose a significant threat to environment. The utilization and disposal of these solid wastes are the major concern in the world. Semi-coke generated in coal-based direct reduction process of iron ore is a by-product and its suitable utilization is not available so far. In order to handle it properly, the characteristics of this by-product were comprehensively investigated. A series of analysis methods were used to demonstrate its mineral compositions, petrography and physico-chemical properties. The results reveal that the semi-coke has poor washability. The fixed carbon content of semi-coke reaches 76.11% and the gross calorific value is 28.10 MJ/kg, both of which are similar to those of traditional sinter coke breeze. Also, semi-coke ash possesses lower content of SiO2, Al2O3, S and higher content of CaO and MgO, which could improve the strength of sinter ore when partially substituting for coke breeze in sintering. Semi-coke features well-development porous structure and higher reaction activity, which predicts that the sintering speed could be elevated to some extent when employing it as a partial replacement of coke breeze, so the studies further suggest that the potential adverse effect of the high reactivity on sintering process could be weakened by adequately coarsening the semi-coke's particle size.展开更多
Coal has been the main energy source in China for a long period.Therefore,the energy industry must improve coal power generation efficiency and achieve near-zero CO_(2) emissions.Integrated gasification fuel cell(IGFC...Coal has been the main energy source in China for a long period.Therefore,the energy industry must improve coal power generation efficiency and achieve near-zero CO_(2) emissions.Integrated gasification fuel cell(IGFC)systems that combine coal gasification and high-temperature fuel cells,such as solid oxide fuel cells or molten carbonate fuel cells(MCFCs),are proving to be promising for efficient and clean power generation,compared with traditional coal-fired power plants.In 2017,with the support of National Key R&D Program of China,a consortium led by the China Energy Group and including 12 institutions was formed to develop the advanced IGFC technology with near-zero CO_(2) emissions.The objectives of this project include understanding the performance of an IGFC power generation system under different operating conditions,designing master system principles for engineering optimization,developing key technologies and intellectual property portfolios,setting up supply chains for key materials and equipment,and operating the first megawatt IGFC demonstration system with near-zero CO_(2) emission,in early 2022.In this paper,the main developments and projections pertaining to the IGFC project are highlighted.展开更多
Vehicle exhaust and transported biomass burning emissions are important air pollution sources in many urban areas,and domestic cooking with biomass fuels causes indoor air pollution in many rural areas.Using agricultu...Vehicle exhaust and transported biomass burning emissions are important air pollution sources in many urban areas,and domestic cooking with biomass fuels causes indoor air pollution in many rural areas.Using agricultural waste-generated synthetic fuels can reduce emissions both from vehicles and biomass burning.To estimate the potential benefits of synthetic diesel in Beijing,the emission factor model for the Beijing vehicle fleet was applied to estimate exhaust emissions for the 2015-2030 period.Compared with 100%petroleum diesel,a 20%synthetic diesel blend reduced diesel fleet emissions by 24%for carbon monoxide,30%for total hydrocarbons,5.5%for nitrogen oxides,and 19%for fine particulate matter with an aerodynamic diameter of≤2.5μm(PM2.5)while using 100%synthetic diesel decreased emissions by 36%for carbon monoxide,48%for total hydrocarbons,10%for nitrogen oxides,and 34%for PM2.5.The use of biomass for producing synthetic fuels rather than burning in the field also reduces air pollution.Over 60g of PM2.5 agricultural open-field burning emissions are avoided per liter of synthetic fuel produced.Replacing solid crop residues with synthetic liquid fuels in household cooking would reduce PM2.5 emissions by more than 90%.展开更多
Thermochemical recuperation heat recovery is an advanced waste heat utilization technology that can effectively recover exhaust waste heat from oxy-fuel Stirling engines.The novel combustor of a Stirling engine with t...Thermochemical recuperation heat recovery is an advanced waste heat utilization technology that can effectively recover exhaust waste heat from oxy-fuel Stirling engines.The novel combustor of a Stirling engine with thermochemical recuperation heat recovery system is expected to utilize both reformed gas and diesel fuels as sources of combustion.In this research,the effects of various factors,including the H_(2)O addition,fuel distribution ratio(FDR),excess oxygen coefficient,and cyclone structure on the temperature distribution in the combustor,combustion emissions,and external combustion system efficiency of the Stirling engine were experimentally investigated.With the increase of steam-to-carbon ratio(S/C),the temperature difference between the upper and lower heating tubes reduces and the circumferential temperature fluctuation decreases,and the combustion of diesel and reformed gas remains close to complete combustion.At S/C=2,the external combustion efficiency is 80.6%,indicating a 1.6%decrease compared to conventional combustion.With the increase of FDR,the temperature uniformity of the heater tube is improved,and the CO and HC emissions decrease.However,the impact of the FDR on the maximum temperature difference and temperature fluctuation across the heater is insignificant.When the FDR rises from 21%to 38%,the external combustion efficiency increases from 87.4%to92.3%.The excess oxygen coefficient plays a secondary role in influencing temperature uniformity and temperature difference,and the reformed gas and diesel fuel can be burned efficiently at a low excess oxygen coefficient of 1.04.With an increase in the cyclone angle,the heater tube temperature increases,while the maximum temperature difference at the lower part decreases,and the temperature fluctuation increases.Simultaneously,the CO and HC emissions increase,and the external combustion efficiency experiences a decrease.A cyclone angle of 30°is found to be an appropriate value for achieving optimal mixing between reformed gas and diesel fuel.The research findings present valuable new insights that can be utilized to enhance the performance optimization of Stirling engines.展开更多
Green hydrogen is anticipated to play a major role in the decarbonization of the mobility sector.Its chemical storage in CO_(2)-neutral synthetic liquid fuels is advantageous in terms of safety and reliability compare...Green hydrogen is anticipated to play a major role in the decarbonization of the mobility sector.Its chemical storage in CO_(2)-neutral synthetic liquid fuels is advantageous in terms of safety and reliability compared to other hydrogen storage developments,and thus represents a complementary building block to developments in electric and hydrogen mobility for the low-carbon transition in the mobility sector.Its development is especially relevant for transport sectors which will have no alternatives to liquid fuels in the foreseeable future.In this paper,three alternative technological routes for the chemical storage of hydrogen in CO_(2)-neutral synthetic liquid fuels are identified and comparatively evaluated in terms of feedstock potential,product potential,demand for renewable electricity and associated costs,efficiency as well as expected market relevance.While all three routes exhibited similar levels of overall efficiencies,electricity-based liquid fuels in Germany are currently limited by the high cost and limited supply of renewable electricity.In contrast,liquid fuels generated from biogenic waste have a constant supply of biogenic feedstock and are largely independent from the supply and cost of renewable electricity.展开更多
With life cycle assessment(LCA) methodology,a life cycle model of coal-based vehicle fuels(CBVFs) including coal-based dimethyl ether(CBDME) and coal-based diesel(CBD) is established.Their primary energy consumption(P...With life cycle assessment(LCA) methodology,a life cycle model of coal-based vehicle fuels(CBVFs) including coal-based dimethyl ether(CBDME) and coal-based diesel(CBD) is established.Their primary energy consumption(PEC) and global warming potential(GWP) from well to wheel including feedstock extraction,fuel production,fuel consumption in vehicle and energy transportation are calculated and compared.Results show that the life cycle PEC and GWP of CBD pathway are 1.17 and 1.34 times as CBDME pathway.Based on the above results,CBDME will become a choice with great potential to replace conventional petroleum-based diesel (CPBD) in China.展开更多
基金Project(2011GH561685)supported by the China Torch Program
文摘Solid wastes derived from metallurgical industries pose a significant threat to environment. The utilization and disposal of these solid wastes are the major concern in the world. Semi-coke generated in coal-based direct reduction process of iron ore is a by-product and its suitable utilization is not available so far. In order to handle it properly, the characteristics of this by-product were comprehensively investigated. A series of analysis methods were used to demonstrate its mineral compositions, petrography and physico-chemical properties. The results reveal that the semi-coke has poor washability. The fixed carbon content of semi-coke reaches 76.11% and the gross calorific value is 28.10 MJ/kg, both of which are similar to those of traditional sinter coke breeze. Also, semi-coke ash possesses lower content of SiO2, Al2O3, S and higher content of CaO and MgO, which could improve the strength of sinter ore when partially substituting for coke breeze in sintering. Semi-coke features well-development porous structure and higher reaction activity, which predicts that the sintering speed could be elevated to some extent when employing it as a partial replacement of coke breeze, so the studies further suggest that the potential adverse effect of the high reactivity on sintering process could be weakened by adequately coarsening the semi-coke's particle size.
基金This work was financially supported by the National Key R&D Program of China(2017YFB0601900).
文摘Coal has been the main energy source in China for a long period.Therefore,the energy industry must improve coal power generation efficiency and achieve near-zero CO_(2) emissions.Integrated gasification fuel cell(IGFC)systems that combine coal gasification and high-temperature fuel cells,such as solid oxide fuel cells or molten carbonate fuel cells(MCFCs),are proving to be promising for efficient and clean power generation,compared with traditional coal-fired power plants.In 2017,with the support of National Key R&D Program of China,a consortium led by the China Energy Group and including 12 institutions was formed to develop the advanced IGFC technology with near-zero CO_(2) emissions.The objectives of this project include understanding the performance of an IGFC power generation system under different operating conditions,designing master system principles for engineering optimization,developing key technologies and intellectual property portfolios,setting up supply chains for key materials and equipment,and operating the first megawatt IGFC demonstration system with near-zero CO_(2) emission,in early 2022.In this paper,the main developments and projections pertaining to the IGFC project are highlighted.
文摘Vehicle exhaust and transported biomass burning emissions are important air pollution sources in many urban areas,and domestic cooking with biomass fuels causes indoor air pollution in many rural areas.Using agricultural waste-generated synthetic fuels can reduce emissions both from vehicles and biomass burning.To estimate the potential benefits of synthetic diesel in Beijing,the emission factor model for the Beijing vehicle fleet was applied to estimate exhaust emissions for the 2015-2030 period.Compared with 100%petroleum diesel,a 20%synthetic diesel blend reduced diesel fleet emissions by 24%for carbon monoxide,30%for total hydrocarbons,5.5%for nitrogen oxides,and 19%for fine particulate matter with an aerodynamic diameter of≤2.5μm(PM2.5)while using 100%synthetic diesel decreased emissions by 36%for carbon monoxide,48%for total hydrocarbons,10%for nitrogen oxides,and 34%for PM2.5.The use of biomass for producing synthetic fuels rather than burning in the field also reduces air pollution.Over 60g of PM2.5 agricultural open-field burning emissions are avoided per liter of synthetic fuel produced.Replacing solid crop residues with synthetic liquid fuels in household cooking would reduce PM2.5 emissions by more than 90%.
基金supported by the Ministry of Science and Technology of China(Grant No.2022YFE0209000)the Shanghai Rising-Star Program(Grant No.21QB1403900)Shanghai Municipal Commission of Science and Technology(Grant No.22170712600)。
文摘Thermochemical recuperation heat recovery is an advanced waste heat utilization technology that can effectively recover exhaust waste heat from oxy-fuel Stirling engines.The novel combustor of a Stirling engine with thermochemical recuperation heat recovery system is expected to utilize both reformed gas and diesel fuels as sources of combustion.In this research,the effects of various factors,including the H_(2)O addition,fuel distribution ratio(FDR),excess oxygen coefficient,and cyclone structure on the temperature distribution in the combustor,combustion emissions,and external combustion system efficiency of the Stirling engine were experimentally investigated.With the increase of steam-to-carbon ratio(S/C),the temperature difference between the upper and lower heating tubes reduces and the circumferential temperature fluctuation decreases,and the combustion of diesel and reformed gas remains close to complete combustion.At S/C=2,the external combustion efficiency is 80.6%,indicating a 1.6%decrease compared to conventional combustion.With the increase of FDR,the temperature uniformity of the heater tube is improved,and the CO and HC emissions decrease.However,the impact of the FDR on the maximum temperature difference and temperature fluctuation across the heater is insignificant.When the FDR rises from 21%to 38%,the external combustion efficiency increases from 87.4%to92.3%.The excess oxygen coefficient plays a secondary role in influencing temperature uniformity and temperature difference,and the reformed gas and diesel fuel can be burned efficiently at a low excess oxygen coefficient of 1.04.With an increase in the cyclone angle,the heater tube temperature increases,while the maximum temperature difference at the lower part decreases,and the temperature fluctuation increases.Simultaneously,the CO and HC emissions increase,and the external combustion efficiency experiences a decrease.A cyclone angle of 30°is found to be an appropriate value for achieving optimal mixing between reformed gas and diesel fuel.The research findings present valuable new insights that can be utilized to enhance the performance optimization of Stirling engines.
基金funded by the German Federal Ministry of Education and Research(BMBF)through the research project grant no.01LN1713A.All opinions,results and conclusions in the text are those of the authors and do not necessarily reflect the opinion of the BMBF.
文摘Green hydrogen is anticipated to play a major role in the decarbonization of the mobility sector.Its chemical storage in CO_(2)-neutral synthetic liquid fuels is advantageous in terms of safety and reliability compared to other hydrogen storage developments,and thus represents a complementary building block to developments in electric and hydrogen mobility for the low-carbon transition in the mobility sector.Its development is especially relevant for transport sectors which will have no alternatives to liquid fuels in the foreseeable future.In this paper,three alternative technological routes for the chemical storage of hydrogen in CO_(2)-neutral synthetic liquid fuels are identified and comparatively evaluated in terms of feedstock potential,product potential,demand for renewable electricity and associated costs,efficiency as well as expected market relevance.While all three routes exhibited similar levels of overall efficiencies,electricity-based liquid fuels in Germany are currently limited by the high cost and limited supply of renewable electricity.In contrast,liquid fuels generated from biogenic waste have a constant supply of biogenic feedstock and are largely independent from the supply and cost of renewable electricity.
文摘With life cycle assessment(LCA) methodology,a life cycle model of coal-based vehicle fuels(CBVFs) including coal-based dimethyl ether(CBDME) and coal-based diesel(CBD) is established.Their primary energy consumption(PEC) and global warming potential(GWP) from well to wheel including feedstock extraction,fuel production,fuel consumption in vehicle and energy transportation are calculated and compared.Results show that the life cycle PEC and GWP of CBD pathway are 1.17 and 1.34 times as CBDME pathway.Based on the above results,CBDME will become a choice with great potential to replace conventional petroleum-based diesel (CPBD) in China.
