The thermal degradation of two synthetic lubricants base oils, poly-a-olefins （PAO） and di-esters （DE）, was investigated under oxidative pyrolysis condition and their properties were characterized in simulated ＂a...The thermal degradation of two synthetic lubricants base oils, poly-a-olefins （PAO） and di-esters （DE）, was investigated under oxidative pyrolysis condition and their properties were characterized in simulated ＂areo-engine＂ by comparing the thermal stability and identifying the products of thermal decomposition as a function of exposure temperature. The characterization of the products were performed by means of Fourier transform infrared spectrometry （FTIR）, gas chromatography/mass spectrometry （GC/MS） and viscosity experiments. The results show that PAO has the lower thermal stability, being degraded at 200℃ different from 300 ℃ for DE. Several by-products are identified during the thermal degradation of two lubricant base oils. The majority of PAO products consist of alkenes and olefins, while more oxygen-contained organic compounds are detected in DE samples based on GC/MS analysis. The related reaction mechanisms are discussed based on the experimental results.展开更多
Compared with single-polarized synthetic aperture radar （SAR） images, full polarimetric SAIl images contain not only geometrical and backward scattering characteristics, but also the polarization features of the sca...Compared with single-polarized synthetic aperture radar （SAR） images, full polarimetric SAIl images contain not only geometrical and backward scattering characteristics, but also the polarization features of the scattering targets. Therefore, the polarimetric SAR has more advantages for oil spill detection on the sea surface. As a crucial step in the oil spill detection, a feature extraction directly influences the accuracy of oil spill discrimination. The polarimetric features of sea oil spills, such as polarimetric entropy, average scatter angle, in the full polarimetric SAR images are analyzed firstly. And a new polarimetric parameter P which reflects the proportion between Bragg and specular scattering signals is proposed. In order to investigate the capability of the polarimetric features for observing an oil spill, systematic comparisons and analyses of the multipolarization features are provided on the basis of the full polarimetric SAR images acquired by SIR-C/X-SAR and Radarsat-2. The experiment results show that in C-band SAR images the oil spills can be detected more easily than in L-band SAR images under low to moderate wind speed conditions. Moreover, it also finds that the new polarimetric parameter is sensitive to the sea surface scattering mechanisms. And the experiment results demonstrate that the new polarimetric parameter and pedestal height perform better than other polarimetric parameters for the oil spill detection in the C-band SAR images.展开更多
Oil spills pose a major threat to ocean ecosystems and their health. Synthetic aperture radar（SAR） sensors can detect oil spills on the sea surface. These oil spills appear as dark spots in SAR images. However, dark...Oil spills pose a major threat to ocean ecosystems and their health. Synthetic aperture radar（SAR） sensors can detect oil spills on the sea surface. These oil spills appear as dark spots in SAR images. However, dark formations can be caused by a number of phenomena. It is aimed to distinguishing oil spills or look-alike objects. A novel method based on a bidimensional empirical mode decomposition is proposed. The selected dark formations are first decomposed into several bidimensional intrinsic mode functions and the residue. Subsequently, 64 dimension feature sets are calculated using the Hilbert spectral analysis and five new features are extracted with a relief algorithm. Mahalanobis distances are then used for classification. Three data sets containing oil spills or look-alikes are used to test the accuracy rate of the method. The accuracy rate is more than 90%. The experimental results demonstrate that the novel method can detect oil spills validly and accurately.展开更多
The oxygen-containing compounds in Fischer Tropsch synthetic oil greatly affect the downstream deep processing of hydrocarbons,and effective removal is required.Com-pared to traditional removal technologies such as hy...The oxygen-containing compounds in Fischer Tropsch synthetic oil greatly affect the downstream deep processing of hydrocarbons,and effective removal is required.Com-pared to traditional removal technologies such as hydrogenation deoxygenation,solvent extraction,and extraction distillation,adsorption deoxygenation technology has the advantages of low cost,mild operating conditions,easy removal and recovery,and mini-mal impact on oil quality.Therefore,adsorption deoxygenation technology has devel-oped rapidly in various removal processes and has become a research hotspot in the cur-rent Fischer Tropsch oil deoxygenation.Adsorbents are the core of adsorption deoxygen-ation technology.Therefore,this article briefly introduces the adsorption mechanism and summarizes the research progress of adsorbents widely used in recent years,such as silica gel,alumina,molecular sieves,and metal organic frameworks,in adsorbing oxygen-containing compounds in Fischer Tropsch synthetic oils.And provide reference sugges-tions for further adsorption and deoxygenation directions in the future.展开更多
The maritime administrative department employs synthetic aperture radar (SAR) satellite remote sensing technology to obtain evidence of illegal discharge of ships. If the ship is discharged during navigation, it forms...The maritime administrative department employs synthetic aperture radar (SAR) satellite remote sensing technology to obtain evidence of illegal discharge of ships. If the ship is discharged during navigation, it forms a long dark wake on the SAR image due to the suppression of the Bragg wave by the oil fi lm. This study investigates key techniques for rapid detection of long ship wakes, thereby providing law enforcement agencies with candidate ships for possible discharge. This paper presents a rapid long ship wake detection method that uses satellite imaging parameters and the axial direction of the ship in images to determine the potential detection area of the wake. Then, the threshold of long ship wake detection is determined using statistical analysis, the area is binarized, and isolated points are removed using a morphological filter operator. The method was tested with ENVISAT Synthetic Aperture Radar and GF-3 SAR data, and results showed that the method was eff ective, and the overall accuracy of the decision reaches 71%. We present two innovations;one is a method that draws a Doppler shift curve, and uses the SAR imaging parameters to determine the detection area of the long wake to achieve rapid detection and reduce the image detection area. The other is where a classical linear fitting method is used to quickly and accurately determine whether the detected dark area is a long ship wake and realizes the twisted long ship wake detection caused by the sea surface flow field, which is otherwise diffi cult to detect by the traditional Radon and Hough transform methods. This method has good suppression performance for the dark spot false alarm formed by low speed wind region or upward flow. The method is developed for maritime ship monitoring system and will promote the operational application of maritime ship monitoring system.展开更多
The changes in content of fatty acids were studied every three months along the storage’s period, after adding an equal concentration (200 mg/Kg) of the natural antioxidant Tocotrienols (α-, β-, γ- and δ-T3) and ...The changes in content of fatty acids were studied every three months along the storage’s period, after adding an equal concentration (200 mg/Kg) of the natural antioxidant Tocotrienols (α-, β-, γ- and δ-T3) and of the synthetic one (BHT, BHA, AP) to four samples of different vegetable oils (sunflower oil, soybean oil, corn oil and olive oil). Then the oxidized and non-oxidized FAMEs were calculated to determine the antioxidant activity (AOA). The results showed that there was difference in AOA depending on the antioxidant of used. Tocotrienols were relatively weak compared with the synthetic antioxidant in all different types of oil. The AOA for each antioxidant was differed in different oil types. It was the most in the sunflower oil compared with the rest different oil types, while it was the lower for corn oil for all antioxidant. The AOA for BHA was the highest for different oil types compared with other antioxidants, and the δ-T3 had the lowest, while the rest anti-oxidants were in the following order: (BHA, BHT, AP, α-T3, β-T3, γ-T3, δ-T3).展开更多
基金Supported by the Fund from the Air Force Armament Department of China for Innovative Research Group(Grant KJ2012283)
文摘The thermal degradation of two synthetic lubricants base oils, poly-a-olefins （PAO） and di-esters （DE）, was investigated under oxidative pyrolysis condition and their properties were characterized in simulated ＂areo-engine＂ by comparing the thermal stability and identifying the products of thermal decomposition as a function of exposure temperature. The characterization of the products were performed by means of Fourier transform infrared spectrometry （FTIR）, gas chromatography/mass spectrometry （GC/MS） and viscosity experiments. The results show that PAO has the lower thermal stability, being degraded at 200℃ different from 300 ℃ for DE. Several by-products are identified during the thermal degradation of two lubricant base oils. The majority of PAO products consist of alkenes and olefins, while more oxygen-contained organic compounds are detected in DE samples based on GC/MS analysis. The related reaction mechanisms are discussed based on the experimental results.
基金The National Natural Science Foundation of China under contract Nos 41576170 and 41376179the Public Science and Technology Research Funds Projects of Ocean(Ocean University of China) under contract No.2013418025-2
文摘Compared with single-polarized synthetic aperture radar （SAR） images, full polarimetric SAIl images contain not only geometrical and backward scattering characteristics, but also the polarization features of the scattering targets. Therefore, the polarimetric SAR has more advantages for oil spill detection on the sea surface. As a crucial step in the oil spill detection, a feature extraction directly influences the accuracy of oil spill discrimination. The polarimetric features of sea oil spills, such as polarimetric entropy, average scatter angle, in the full polarimetric SAR images are analyzed firstly. And a new polarimetric parameter P which reflects the proportion between Bragg and specular scattering signals is proposed. In order to investigate the capability of the polarimetric features for observing an oil spill, systematic comparisons and analyses of the multipolarization features are provided on the basis of the full polarimetric SAR images acquired by SIR-C/X-SAR and Radarsat-2. The experiment results show that in C-band SAR images the oil spills can be detected more easily than in L-band SAR images under low to moderate wind speed conditions. Moreover, it also finds that the new polarimetric parameter is sensitive to the sea surface scattering mechanisms. And the experiment results demonstrate that the new polarimetric parameter and pedestal height perform better than other polarimetric parameters for the oil spill detection in the C-band SAR images.
基金The National Science and Technology Support Project under contract No.2014BAB12B02the Natural Science Foundation of Liaoning Province under contract No.201602042
文摘Oil spills pose a major threat to ocean ecosystems and their health. Synthetic aperture radar（SAR） sensors can detect oil spills on the sea surface. These oil spills appear as dark spots in SAR images. However, dark formations can be caused by a number of phenomena. It is aimed to distinguishing oil spills or look-alike objects. A novel method based on a bidimensional empirical mode decomposition is proposed. The selected dark formations are first decomposed into several bidimensional intrinsic mode functions and the residue. Subsequently, 64 dimension feature sets are calculated using the Hilbert spectral analysis and five new features are extracted with a relief algorithm. Mahalanobis distances are then used for classification. Three data sets containing oil spills or look-alikes are used to test the accuracy rate of the method. The accuracy rate is more than 90%. The experimental results demonstrate that the novel method can detect oil spills validly and accurately.
文摘The oxygen-containing compounds in Fischer Tropsch synthetic oil greatly affect the downstream deep processing of hydrocarbons,and effective removal is required.Com-pared to traditional removal technologies such as hydrogenation deoxygenation,solvent extraction,and extraction distillation,adsorption deoxygenation technology has the advantages of low cost,mild operating conditions,easy removal and recovery,and mini-mal impact on oil quality.Therefore,adsorption deoxygenation technology has devel-oped rapidly in various removal processes and has become a research hotspot in the cur-rent Fischer Tropsch oil deoxygenation.Adsorbents are the core of adsorption deoxygen-ation technology.Therefore,this article briefly introduces the adsorption mechanism and summarizes the research progress of adsorbents widely used in recent years,such as silica gel,alumina,molecular sieves,and metal organic frameworks,in adsorbing oxygen-containing compounds in Fischer Tropsch synthetic oils.And provide reference sugges-tions for further adsorption and deoxygenation directions in the future.
基金Supported by the National Natural Science Foundation of China(No.41476088)the National High Resolution Project of China(No.41Y30B12-9001-14/16)+1 种基金the 2016 Key Projects for Marine Environmental Security(No.2016YFC14032)the research grants of the Second Institute of Oceanography,MNR(No.JT1307)
文摘The maritime administrative department employs synthetic aperture radar (SAR) satellite remote sensing technology to obtain evidence of illegal discharge of ships. If the ship is discharged during navigation, it forms a long dark wake on the SAR image due to the suppression of the Bragg wave by the oil fi lm. This study investigates key techniques for rapid detection of long ship wakes, thereby providing law enforcement agencies with candidate ships for possible discharge. This paper presents a rapid long ship wake detection method that uses satellite imaging parameters and the axial direction of the ship in images to determine the potential detection area of the wake. Then, the threshold of long ship wake detection is determined using statistical analysis, the area is binarized, and isolated points are removed using a morphological filter operator. The method was tested with ENVISAT Synthetic Aperture Radar and GF-3 SAR data, and results showed that the method was eff ective, and the overall accuracy of the decision reaches 71%. We present two innovations;one is a method that draws a Doppler shift curve, and uses the SAR imaging parameters to determine the detection area of the long wake to achieve rapid detection and reduce the image detection area. The other is where a classical linear fitting method is used to quickly and accurately determine whether the detected dark area is a long ship wake and realizes the twisted long ship wake detection caused by the sea surface flow field, which is otherwise diffi cult to detect by the traditional Radon and Hough transform methods. This method has good suppression performance for the dark spot false alarm formed by low speed wind region or upward flow. The method is developed for maritime ship monitoring system and will promote the operational application of maritime ship monitoring system.
文摘The changes in content of fatty acids were studied every three months along the storage’s period, after adding an equal concentration (200 mg/Kg) of the natural antioxidant Tocotrienols (α-, β-, γ- and δ-T3) and of the synthetic one (BHT, BHA, AP) to four samples of different vegetable oils (sunflower oil, soybean oil, corn oil and olive oil). Then the oxidized and non-oxidized FAMEs were calculated to determine the antioxidant activity (AOA). The results showed that there was difference in AOA depending on the antioxidant of used. Tocotrienols were relatively weak compared with the synthetic antioxidant in all different types of oil. The AOA for each antioxidant was differed in different oil types. It was the most in the sunflower oil compared with the rest different oil types, while it was the lower for corn oil for all antioxidant. The AOA for BHA was the highest for different oil types compared with other antioxidants, and the δ-T3 had the lowest, while the rest anti-oxidants were in the following order: (BHA, BHT, AP, α-T3, β-T3, γ-T3, δ-T3).
