Effects of Fe solid solute on grain boundaries of bi-crystal Cu: A molecular dynamics simulation

Grain boundaries(GBs)play a crucial role on the structural stability and mechanical properties of Cu and its alloys.In this work,molecular dynamics(MD)simulations are employed to study the effects of Fe solutes on the formation energy,excess volume,dislocations and melting behaviors of GBs in CuFe alloys.It is illustrated that Fe solute affects the structural stability of Cu GBs substantially,the formation energy of GBs is reduced,but the thickness and melting point of GBs are increased,that is,the structural stability of Cu GBs is significantly improved owing to the Fe solutes.A strong scaling law exists between the formation energy,excess volume,thickness and melting point of GBs.Therefore,Fe solid solute plays an important role in the characteristics of GBs in bi-crystal Cu.

Modeling the Interaction between Vacancies and Grain Boundaries during Ductile Fracture

The experimental results in previous studies have indicated that during the ductile fracture of pure metals,vacancies aggregate and form voids at grain boundaries.However,the physical mechanism underlying this phenomenon remains not fully understood.This study derives the equilibrium distribution of vacancies analytically by following thermodynamics and the micromechanics of crystal defects.This derivation suggests that vacancies cluster in regions under hydrostatic compression to minimize the elastic strain energy.Subsequently,a finite element model is developed for examining more general scenarios of interaction between vacancies and grain boundaries.This model is first verified and validated through comparison with some available analytical solutions,demonstrating consistency between finite element simulation results and analytical solutions within a specified numerical accuracy.A systematic numerical study is then conducted to investigate the mechanism that might govern the micromechanical interaction between grain boundaries and the profuse vacancies typically generated during plastic deformation.The simulation results indicate that the reduction in total elastic strain energy can indeed drive vacancies toward grain boundaries,potentially facilitating void nucleation in ductile fracture.

Extensive identification of landslide boundaries using remote sensing images and deep learning method

The frequent occurrence of extreme weather events has rendered numerous landslides to a global natural disaster issue.It is crucial to rapidly and accurately determine the boundaries of landslides for geohazards evaluation and emergency response.Therefore,the Skip Connection DeepLab neural network(SCDnn),a deep learning model based on 770 optical remote sensing images of landslide,is proposed to improve the accuracy of landslide boundary detection.The SCDnn model is optimized for the over-segmentation issue which occurs in conventional deep learning models when there is a significant degree of similarity between topographical geomorphic features.SCDnn exhibits notable improvements in landslide feature extraction and semantic segmentation by combining an enhanced Atrous Spatial Pyramid Convolutional Block(ASPC)with a coding structure that reduces model complexity.The experimental results demonstrate that SCDnn can identify landslide boundaries in 119 images with MIoU values between 0.8and 0.9;while 52 images with MIoU values exceeding 0.9,which exceeds the identification accuracy of existing techniques.This work can offer a novel technique for the automatic extensive identification of landslide boundaries in remote sensing images in addition to establishing the groundwork for future inve stigations and applications in related domains.

Cenozoic giant coal-bearing basin belt discovered in China's sea and its adjacent areas

Sea area is an important area of oil and gas exploration in China.It has been found that China's sea area mainly consists of coal type oil and gas,and the exploration of coal-bearing series source rocks has become an important part of oil and gas exploration there.Through years of comprehensive geological research in China's sea area,it has been revealed that it has undergone multiple occurrences of tectonic opening and closing movements in varying degrees in the Paleogene,forming 26 Cenozoic sedimentary basins of various types,such as active continental margin,passive continental margin,transitional continental margin and drift rift basins.In the present study,it is observed for the first time that coal type source rocks are mainly developed in 14 continental margin basins in China's sea area,revealing that a very large C-shaped coal-bearing basin group developed there in the Cenozoic.Next,based on the coupling analysis of paleoclimate,paleobotany,paleogeography and paleostructure,it is observed that there are five coal-forming periods in China's sea area,namely the Paleocene,Eocene,early Oligocene,late Oligocene and Miocene-Pliocene,and the coal-forming age is gradually new from north to south.It is also found that the coal seams in the sea area are mainly developed in three coal-forming environments in Cenozoic,namely delta,fan delta and tidal flat-lagoon.The coal seams developed in different environments are characterized by thin thickness,many layers and poor stability.However,the coal-bearing series source rocks in China's sea area have a wide distribution range,very high thickness and large amount,thus forming a material basis for the formation of rich coal type oil and gas.

Sedimentology and Paleoenvironmental Characteristics of Fine-grained Sediments in Coal-bearing Strata in the Eastern Ordos Basin:A Case Study of the Exploratory Well in the Zizhou Area

The continuously collected cores from the Permo-Carboniferous coal-bearing strata of the eastern Ordos Basin are essential for studying the hydrocarbon potential in this region.This study adopted sedimentological and geochemical methods to analyze the sedimentary environment,material composition,and geochemical characteristics of the coal-bearing strata.The differences in depositional and paleoclimatic conditions were compared;and the factors influencing the organic matter content of fine-grained sediments were explored.The depositional environment of the Benxi and Jinci formations was lagoon to tidal flat with weakly reduced waters with low salinity and dry-hot paleoclimatic conditions;while that of the Taiyuan Formation was a carbonate platform and shallow water delta front,where the water was highly reductive.The xerothermic climate alternated with the warm and humid climate.The period of maximum transgression in the Permo-Carboniferous has the highest water salinity.The Shanxi Formation was deposited in a shallow water delta front with a brackish and fresh water environment and alternative weak reductiveness.And the paleoclimate condition is dry-hot.The TOC content in fine-grained samples was averaging 1.52%.The main controlling mechanism of organic matter in this area was the input conditions according to the analysis on input and preservation of organic matter.

Formation mechanism of co-axial grain boundaries in a Mg alloy

Due to the insufficient slip systems in hexagonal close-packed structure,twinning is frequently activated to support stable plastic deformation of Mg alloy.In this work,we found four typical twin-like interfaces with misorientations of 102°,109°,142°and 149°,respectively,which had not only a shared[1120]zone axis of neighboring grains,but also overlapped diffraction spots similar to twins.However,highresolution transmission electron microscope(HRTEM)analysis revealed that the interfaces in real space deviated from the supposed twinning planes in reciprocal space,i.e.their overlapped diffraction spots.We clarified that the incoherent interfaces were co-axial grain boundaries(CGBs).Additionally,a special angle ofθ,close to 90°,between the interface and one side of basal plane,was frequently formed in CGBs.We proposed that interaction of multiple twinning contributes to the formation of CGBs,and theθis formed due to alternative tensile and compression twinning under a uniaxial loading.

Nano-capillary induced assemble of quantum dots on perovskite grain boundaries for efficient and stable perovskite solar cells

In recent years, perovskite solar cells(PSCs) have propelled into the limelight owing to rapid development of efficiency;however, the abundant defects at the perovskite grain boundaries result in unwanted energy loss and structural degradation. Here, the grain boundaries of perovskite polycrystalline films have been found to act as nanocapillaries for capturing perovskite quantum dots(PQDs), which enable the conformal assemble of PQDs at the top interspace between perovskite grains. The existence of PQDs passivated the surface defects, optimized the interfacial band alignments, and ultimately improved the power conversion efficiency from 19.27% to 22.47% in inverted PSCs. Our findings open up the possibility of selective assembly and structural modulation of the perovskite nanostructures towards efficient and stable PSCs.

CONSTANT DISTANCE BOUNDARIES OF THE t-QUASICIRCLE AND THE KOCH SNOWFLAKE CURVE

LetΓbe a Jordan curve in the complex plane and let Γ_(λ) be the constant distance boundary ofΓ.Vellis and Wu[10]introduced the notion of a(ζ,r_(0))-chordal property which guarantees that,whenλis not too large, Γ_(λ) is a Jordan curve whenζ=1/2 and Γ_(λ) is a quasicircle when 0<ζ<1/2.We introduce the(ζ,r_(0),t)-chordal property,which generalizes the(ζ,r_(0))-chordal property,and we show that under the condition thatΓis(ζ,r_(0),√t)-chordal with 0<ζ<r_(0)^(1−√t)/2,there existsε>0 such that Γ_(λ) is a t-quasicircle once Γ_(λ) is a Jordan curve when 0<λ<ε.In the last part of this paper,we provide an example:Γis a kind of Koch snowflake curve which does not have the(ζ,r_(0))-chordal property for any 0<ζ<1/2,however Γ_(λ) is a Jordan curve whenλis small enough.Meanwhile,Γhas the(ζ,r_(0),√t)-chordal property with 0<ζ<r_(0)^(1−√t)/2 for any t∈(0,1/4).As a corollary of our main theorem, Γ_(λ) is a t-quasicircle for all 0<t<1/4 whenλis small enough.This means that our(ζ,r_(0),t)-chordal property is more general and applicable to more complicated curves.

跨界向未来——Crossboundaries事务所对“未来学校”的思考与探索

文章通过对Crossboundaries事务所的访谈,结合其设计理念与项目实践,就以下话题展开探讨:学校设计的基本观念,横跨多个设计领域的校园整体环境设计,支撑多样化学习方式的空间要素,校园空间环境中的色彩设计,校园户外空间的潜在教育价值挖掘与设计策略,装配式建造方式与校园多样化空间营造及对中国未来学校建设的愿景。

百脉根类LATERAL ORGAN BOUNDARIES基因的分离及表达方式(英文)

植物顶端分生组织可分为中央区,周缘区和肋区。在植物胚后发育中,侧生器官产生于顶端分生组织的周缘区。顶端分生组织和侧生器官之间的边界的建立和维持是一个非常重要的发育过程,许多调节子参与控制这个过程。拟南芥的 LATERALORGANBOUNDARIES(LOB)基因具有独特的表达模式,其表达的范围与上述的边界区域重合。LOB基因隶属于一个大的基因家族——L O B 结构域基因家族。该家族编码的蛋白在 N 端具有一个保守的LOB结构域,该家族 LOB 基因以外的成员也参与拟南芥不同的发育过程。为了探讨在与拟南芥亲缘关系较远的豆科中 LOB 同源基因的功能,我们在豆科模式植物百脉根中分离了3 个 LOB 同源基因,命名为 LjLOB 基因,并用 RNA 原位杂交方法研究了这3个基因的表达模式。研究结果显示,L j L O B 1 和LjLOB3都强烈地在小叶原基的基部表达,这种表达模式可能与小叶原基和复叶原基之间的边界相关。而LjLOB4则在发育中的花芽不同轮之间的边界上表达。百脉根中这3 个基因具有不同的表达模式,强烈地提示它们的功能发生了分歧:L j L O B 1 和L j L O B 3 可能在复叶发育中具有重要功能;而LjLOB4 则可能参与了花的发育。

EFFECT OF NANOCRYSTALLINE AND TWIN BOUNDARIES ON CORROSION BEHAVIOR OF 316L STAINLESS STEEL USING SMAT

By means of surface mechanical attrition treatment （ SMAT）, the groin size with a diameter of aboat 60hm formed at about 20μm depth and numerous mechanical twins at about 50μm depth from the treated surface were synthesized in 316L stainless steel because of the different distributions of strain and strain rate along depth orientation. For instance the maximum strain rate reached 10^3-10^4s^-1 on the top surface. The relationship between the microsturcture and the corrosion property was studied in 0.05M H2SO4＋ 0.25M Na2SO4 aqueous solution, and the results show an extreme improvement of corrosion resistance owing to the appearance of twin boundaries and the obvious reduction in corrosion resistance attributed to the presence of nanocrystaline boundaries.

Types and Characteristics of Volcanostratigraphic Boundaries and Their Oil-Gas Reservoir Significance

Just like in sedimentary stratigraphy, the factor for constructing volcanostratigraphic volcanostratigraphic boundary is an important framework. The fundamental factor of volcanostratigraphic boundaries is to classify the types and define their characteristics. Based on field investigation and cross-wells section analysis of Mesozoic volcanostratigraphy in NE China, 5 types of volcanostratigraphic boundaries have been recognized, namely eruptive conformity boundary （ECB）, eruptive unconformity boundary （EUB）, eruptive interval unconformity boundary （EIUB）, tectonic unconformity boundary （TUB） and intrusive contacts boundary （ICB）. Except ICB, the unconformity boundaries can be divided into angular unconformity and paraconformity. The time spans and signs of these boundaries are analyzed by using age data of some volcanic fields that have been published. The time spans of ECB and EUB are from several minutes to years. In lava flows, cooling crust is distributed above and below ECB and EUB; in pyroclastic flows, airfalls and lahars, a fine layer below these boundaries has no discernable erosion at every part of the boundary. EUB may be curved or cross curved and jagged. The scale of ECB/EUB is dependent on the scale of lava flow or pyroclastic flows. The time span of EIUB is from decades to thousands of years. There is also weathered crust under EIUB and sedimentary rock beds overlie EIUB. In most instances, weathered crust and thin sedimentary beds are associated with each other laterally. The boundary is a smooth curved plane. The scale of EIUB is dependent on the scale of the volcano or volcano groups. The characteristics of TUB are similar to EIUB＇s. The time interval of TUB is from tens of thousands to millions of years. The scale of TUB depends on the scale of the basin or volcanic field. Both the lab data and logging data of wells in the Songliao Basin reveal that the porosity is greatly related to the boundaries in the lava flows. There is a high-porosity belt below ECB, EUB or EIUB, and the porosity decreases when it is apart from the boundary. The high-porosity belt below ECB and EUB is mainly contributed by primary porosity, such as vesicles. The high-porosity belt below EIUB is mainly contributed by primary and secondary porosity, such as association of vesicles and spongy pores, so the area near the boundary in lava flows is a very important target for reservoirs.

Behaviors of Lanthanum and Cerium on Grain Boundaries in Carbon Manganese Clean Steel

The behaviors of La and Ce on gram boundaries in carbon manganese clean steel were investigated by high-reso- lution transmission elecetron microscope （HRTEM）, scanning elecetron microscopy（SEM ）, energy dispersive spectrometer （EDS） and X-ray diffraction（XRD） analysis. The existing forms of rare earths （RE） in clean steel were as follows： dissolved in sohd solution, forming inclusion or second phase containing RE （RE-Fe-P, La-P, Fe-La eutectic and Fe-Ce phase）. The dissolved La or Ce segregated at grain boundaries. The segregation of both S and P at gram boundaries was reduced with suitable RE content. The impact toughness of the steel was improved obviously. La and Ce had effecets on purifying molten steel and modifying inclusions in clean steel, whereas with excessive La or Ce, La-Fe-P, La-P and Fe-La eutecetic phase or Ce-Fe-P and Fe-Ce intermetallic compound would form along grain boundaries, causing the impact energy to decrease significantly.

Formation Mechanism of "Drag Depressions" and Irregular Boundaries in Intraplate Deformation

Almost all intraplate caprocks experienced strong deformation during the convergence of microplates, and then disintegrated into many secondary geologic units with the special characters, such as irregular boundaries and particular structural assemblages. In order to understand the formation mechanism of these special phenomena, a rheological experiment on the structural scenery of the Tongling area is carried out. The result shows that the primary regular and uniform boundaries of the Tongling area becomes irregular because of the enclosing and confinement of surrounding geological units in the process of 'compression-shearing-rotation-drag'; simultaneously, two specific 'drag depressions' developed at two opposite corners of the block. The former and the later phenomena can be regarded as a typical regional-scale rheological effect and necessary outcome of intraplate deformation respectively.

Seismic wave input method for three-dimensional soil-structure dynamic interaction analysis based on the substructure of artificial boundaries

The method of inputting the seismic wave determines the accuracy of the simulation of soil-structure dynamic interaction. The wave method is a commonly used approach for seismic wave input, which converts the incident wave into equivalent loads on the cutoff boundaries. The wave method has high precision, but the implementation is complicated, especially for three-dimensional models. By deducing another form of equivalent input seismic loads in the fi nite element model, a new seismic wave input method is proposed. In the new method, by imposing the displacements of the free wave fi eld on the nodes of the substructure composed of elements that contain artifi cial boundaries, the equivalent input seismic loads are obtained through dynamic analysis of the substructure. Subsequently, the equivalent input seismic loads are imposed on the artifi cial boundary nodes to complete the seismic wave input and perform seismic analysis of the soil-structure dynamic interaction model. Compared with the wave method, the new method is simplifi ed by avoiding the complex processes of calculating the equivalent input seismic loads. The validity of the new method is verifi ed by the dynamic analysis numerical examples of the homogeneous and layered half space under vertical and oblique incident seismic waves.

GENERATION AND APPLICATION OF UNSTRUCTURED ADAPTIVE MESHES WITH MOVING BOUNDARIES

This paper presents a method to generate unstructured adaptive meshes with moving boundaries and its application to CFD. Delaunay triangulation criterion in conjunction with the automatic point creation is used to generate 2 D and 3 D unstructured grids. A local grid regeneration method is proposed to cope with moving boundaries. Numerical examples include the interactions of shock waves with movable bodies and the movement of a projectile within a ram accelerator, illustrating an efficient and robust mesh generation method developed.

Interdecadal fluctuation of dry and wet climate boundaries in China in the past 50 years

Based on the mean yearly precipitation and the total yearly evaporation data of 295 meteorological stations in China in 1951-1999, the aridity index is calculated in this paper. According to the aridity index, the climatic regions in China are classified into three types, namely, arid region, semi-arid region and humid region. Dry and wet climate boundaries in China fluctuate markedly and differentiate greatly in each region in the past 50 years. The fluctuation amplitudes are 20-400 km in Northeast China, 40-400 km in North China, 30-350 km in the eastern part of Northwest China and 40-370 km in Southwest China. Before the 1980s (including 1980), the climate tended to be dry in Northeast China and North China, to be wet in the eastern part of Northwest China and very wet in Southwest China. Since the 1990s there have been dry signs in Southwest China, the eastern part of Northwest China and North China. The climate becomes wetter in Northeast China. Semi-arid region is the transitional zone between humid and arid regions, the monsoon edge belt in China, and the susceptible region of environmental evolution. At the end of the 1960s dry and wet climate in China witnessed abrupt changes, changing wetness into dryness. Dry and wet climate boundaries show the fluctuation characteristics of the whole shifts and the opposite fluctuations of eastward, westward, southward and northward directions. The fluctuations of climatic boundaries and the dry and wet variations of climate have distinctive interdecadal features.

THE NAVIER-STOKES EQUATIONS WITH THE KINEMATIC AND VORTICITY BOUNDARY CONDITIONS ON NON-FLAT BOUNDARIES

We study the initial-boundary value problem of the Navier-Stokes equations for incompressible fluids in a general domain in R^n with compact and smooth boundary, subject to the kinematic and vorticity boundary conditions on the non-flat boundary. We observe that, under the nonhomogeneous boundary conditions, the pressure p can be still recovered by solving the Neumann problem for the Poisson equation. Then we establish the well-posedness of the unsteady Stokes equations and employ the solution to reduce our initial-boundary value problem into an initial-boundary value problem with absolute boundary conditions. Based on this, we first establish the well-posedness for an appropriate local linearized problem with the absolute boundary conditions and the initial condition （without the incompressibility condition）, which establishes a velocity mapping. Then we develop apriori estimates for the velocity mapping, especially involving the Sobolev norm for the time-derivative of the mapping to deal with the complicated boundary conditions, which leads to the existence of the fixed point of the mapping and the existence of solutions to our initial-boundary value problem. Finally, we establish that, when the viscosity coefficient tends zero, the strong solutions of the initial-boundary value problem in R^n（n ≥ 3） with nonhomogeneous vorticity boundary condition converge in L^2 to the corresponding Euler equations satisfying the kinematic condition.

Effect of the frequency of high-angle grain boundaries on the corrosion performance of 5wt%Cr steel in a CO2 aqueous environment

The corrosion behavior of 5 wt%Cr steel tempered at different temperatures was investigated by immersion testing and electrochemical testing in a CO_2 aqueous environment. When the tempering temperature exceeded 500℃, the corrosion rate increased. The corrosion layers consisted of Cr-rich compounds, which affected the corrosion behaviors of the steels immersed in the corrosive solution. The results of electrochemical experiments demonstrated that 5 wt%Cr steels with different microstructures exhibited pre-passivation characteristics that decreased their corrosion rate. Analysis by electron back-scattered diffraction showed that the frequency of high-angle grain boundaries(HAGBs) and the corrosion rate were well-correlated in specimens tempered at different temperatures. The corrosion rate increased with increasing HAGB frequency.

Extraction of auroral oval boundaries from UVI images: A new FLICM clustering-based method and its evaluation

Based on the fuzzy local information c-means （FLICM） clustering algorithm, a new method is developed for extracting the equatorward and poleward boundaries of the auroral oval from images acquired by the Ultraviolet Imager （UVI） aboard the POLAR satellite. First, the method iteratively segments the UVI image with the FLICM clustering algorithm, according to an integrity criterion for the segmented auroral oval. Then, possible gaps in the extracted auroral oval are filled, based on prior knowledge of its shape. To evaluate the method objectively, the extracted boundaries are compared with the precipitating electron boundaries determined from DMSP satellite precipitation particle data. The evaluation results demonstrate that the proposed method generates more accurate auroral boundaries than traditional methods.