High-efficiency Carbonation Modification Methods of Recycled Coarse Aggregates

To solve the problem of only surface carbonation and realize high-efficiency carbonation of recycled coarse aggregate,the method of carbonated recycled coarse aggregate with nano materials pre-soaking was first put forward.The carbonation effect of modified recycled coarse aggregate with three different carbonation methods was evaluated,and water absorption,apparent density and crush index of modified recycled coarse aggregate were measured.Combined with XRD,SEM,and MIP microscopic analysis,the high-efficiency carbonation strengthening mechanism of modified recycled coarse aggregate was revealed.The experimental results show that,compared with the non-carbonated recycled coarse aggregate,the physical and microscopic properties of carbonated recycled coarse aggregate are improved.The method of carbonation with nano-SiO_(2) pre-soaking can realize the high-efficiency carbonation of recycled coarse aggregate,for modified recycled coarse aggregate with the method,water absorption is reduced by 23.03%,porosity is reduced by 44.06%,and the average pore diameter is 21.82 nm.The high-efficiency carbonation strengthening mechanism show that the pre-socked nano-SiO_(2) is bound to the hydration product Ca(OH)_(2) of the old mortar with nano-scale C-S-H,which can improve the CO_(2) absorption rate,accelerate the carbonation reaction,generate more stable CaCO_(3) and nano-scale silica gel,and bond to the dense three-dimensional network structure to realize the bidirectional enhancement of nano-materials and pressurized carbonation.It is concluded that the method of carbonation with nano-SiO_(2) pre-soaking is a novel high-efficiency carbonation modification of recycled coarse aggregate.

Effect of variations in the polar and azimuthal angles of coarse particles on the structure of drainage channels in thickened beds

The 3D reconstruction and quantitative characterization of drainage channels and coarse tailings particles in a bed were conducted in this study.The influence of variations in the azimuthal angle(θ)and polar angle(φ)of coarse particles on drainage channel structure was analyzed,and the drainage mechanism of the bed was studied.Results showed that water discharge in the bed reduced the size of pores and throat channels,increasing slurry concentration.The throat channel structure was a key component of the drainage process.Theφandθof particles changed predominantly along the length direction.The changes inφhad a cumulative plugging effect on the drainage channel and increased the difficulty of water discharge.The rake and rod formed a shear ring in the tailings bed with shear,and theθdistribution of particles changed from disorderly to orderly during the rotation process.The drainage channel was squeezed during the shearing process with the change inθ,which broke the channel structure,encouraged water discharge in the bed,and facilitated a further increase in slurry concentration.The findings of this work are expected to offer theoretical guidance for preparing high-concentration underflow in the tailings thickening process.

Properties of coarse particles in suspended particulate matter of the North Yellow Sea during summer

Fine particles in seawater commonly form large porous aggregates. Aggregate density and settling velocity determine the behavior of this suspended particulate matter(SPM) within the water column.However, few studies of aggregate particles over a continental shelf have been undertaken. In our case study, properties of aggregate particles, including size and composition, over the continental shelf of the North Yellow Sea were investigated. During a scienti?c cruise in July 2016, in situ ef fective particle size distributions of SPM at 10 stations were measured, while temperature and turbidity measurements and samples of water were obtained from surface, middle, and bottom layers. Dispersed and inorganic particle size distributions were determined in the laboratory. The in situ SPM was divided into(1) small particles(<32 μm),(2) medium particles(32–256 μm) and(3) large particles(>256 μm). Large particles and medium particles dominated the total volume concentrations(VCs) of in situ SPM. After dispersion, the VCs of medium particles decreased to low values(<0.1 μL/L). The VCs of large particles in the surface and middle layers also decreased markedly, although they had higher peak values(0.1–1 μL/L). This suggests that almost all in situ medium particles and some large particles were aggregated, while other large particles were single particles. Correlation analysis showed that primary particles <32 μm in?uenced the formation of these aggregates. Microscopic examination revealed that these aggregates consisted of both organic and inorganic ?ne particles, while large particles were mucus-bound organic aggregates or individual plankton.The vertical distribution of coarser particles was clearly related to water strati?cation. Generally, medium aggregate particles were dominant in SPM of the bottom layer. A thermocline blocked resuspension of?ne material into upper layers, yielding low VCs of medium-sized aggregate particles in the surface layer.Abundant large biogenic particles were present in both surface and middle layers.

Anthracene Adsorption to Particles and Water-Stable Aggregates of Mangrove Sediment in Jiulong River Estuary, China

Polycyclic aromatic hydrocarbons (PAHs) pollution in mangroves has drawn much attention, but knowledge of the sorption of PAHs in mangrove sediment is limited. This study investigated the particles and water-stable aggregates (WSA) of mangrove sediment in Jiulong River Estuary, China, and the characteristics of anthracene adsorption to them. The adsorption of anthracene was strongly influenced by the physicochemical and structural properties of sediment particles and WSA. The main sorbents of mangrove sediment were carbonized particles and clays. The porous structure of carbonized particles made it easy to sequestrate sequester the anthracene, and the aging allowed anthracene to move into deeper sites of the carbonized particles. Clays had high anthracene-fixing capacities, and they included organic matters and formed aggregates. The sorption contents coefficient Kf of anthracene with WSA of different sizes increased in the order 0.063 - 0.25 mm > 0.063 mm > 0.25 - 1.0 mm > 1.0 mm. The order was correlated with which due to the contents and characteristics of organic matters in the aggregates.

Discrete element modeling of migration and evolution rules of coarse aggregates in the static compaction process

To investigate migration and evolution rules of coarse aggregates in the static compaction process, an algorithm of generating digital coarse aggregates that can reflect real morphology（ such as shape, size and fracture surface） of aggregate particles, is represented by polyhedral particles based on the discrete element method（ DEM）. A digital specimen comprised of aggregates and air voids is developed. In addition,a static compaction model consisting of a digital specimen and three plates is constructed and a series of evaluation indices such as mean contact force σMCF, wall stress in direction of zcoordinate σWSZZ, porosity and coordination numbers are presented to investigate the motion rules of coarse aggregates at different compaction displacements of 7. 5, 15 and 30 mm. The three-dimensional static compaction model is also verified with laboratory measurements. The results indicate that the compaction displacements are positively related to σMCF and σWSZZ, which increase gradually with the increase in iterative steps. When the compaction proceeds, the digital specimen porosity decreases, but the coordination number increases. The variation ranges of these four indices are different at different compaction displacements. This study provides a method to analyze the compaction mechanism of particle materials such as asphalt mixture and graded broken stone.

Shear behavior of coarse aggregates for dam construction under varied stress paths

Coarse aggregates are the major infrastructure materials of concrete-faced rock-fill dams and are consolidated to bear upper and lateral loads. With the increase of dam height, high confining pressure and complex stress states complicate the shear behavfor of coarse aggregates, and thus impede the high dam＇s proper construction, operation and maintenance. An experimental program was conducted to study the shear behavior of dam coarse aggregates using a large-scale triaxial shear apparatus. Through triaxial shear tests, the strain-stress behaviors of aggregates were observed under constant confining pressures： 300 kPa, 600 kPa 900 kPa and 1200 kPa. Shear strengths and aggregate breakage characteristics associated with high pressure shear processes are discussed. Stress path tests were conducted to observe and analyze coarse aggregate response under complex stress states. In triaxial shear tests, it was found that peak deviator stresses increase along with confining pressures, whereas the peak principal stress ratios decrease as confining pressures increase With increasing confining pressures, the dilation decreases and the contraction eventually prevails. Initial strength parameters （Poisson＇s ratio and tangent modulus） show a nonlinear relationship with confining pressures when the pressures are relatively low. Shear strength parameters decrease with increasing confining pressures. The failure envelope lines are convex curves, with clear curvature under low confining pressures. Under moderate confining pressures, dilation is offset by particle breakage. Under high confining pressures, dilation disappears.

Gas-Solid Flow Behavior in a Pneumatic Conveying System for Drying Applications: Coarse Particles Feeding with a Venturi Device

The feeding of coarse particles (>0.5 mm diameter) directly into a riser operating at positive pressure is important for drying and pre-heating applications. The presence of the feeding device can lead to heterogeneity of drying and heating, and is the main factor responsible for pressure loss in short conveying systems. However, there is a lack of information concerning the axial and radial distributions of coarse particles in this type of configuration, despite the recent advances when dealing with fine particles (FCC catalyst). The present work therefore investigates a vertical venturi feeder with the conveying system operating in dilute-phase regime with 1 mm spherical glass particles. Experimental assays revealed the behavior of the mass flow rate of solids in the system, and pressure measurements were made along the riser in order to evaluate the accuracy of simulations. Euler-Euler simulations provided close estimation of the experimental pressure drop and the pressure drop according to distance in the linear region. Simulation of the fluid dynamics in the riser showed that solids clusters were formed at low concentrations near the feeding device, reflecting heterogeneity in the solid phase volume fraction.

A new measuring method for maximal length, width and thickness dimensions of coarse aggregates

In order to establish a new method for measuring the dimensions of coarse aggregates, five different-size flat and elongated (F&E) coarse aggregates were glued into two specimens by epoxy resin, respectively, and slice images were obtained by X-ray CT, then the aggregates were extracted by the fuzzy c-means clustering algorithm. Attributions of the particle on different cross-sections were determined by the ‘overlap area method’. And unified three-dimensional Cartesian coordinate system was established based on continuous slice images. The coefficient values of spherical harmonics descriptor representing particles surface profile were gained, then each scanned particle was represented by 60×120 discrete points conformably with spherical harmonics descriptor. The chord length and direction angles were determined by the calculation. With the major axis (L) and orthogonal axis (W and T), the calculated results were compared with those measured by caliper. It is concluded that the new L, W, and T dimension measuring method is able to take the place of the present manual measurement.

Coercivity of fractal aggregates formed by single-domain particles

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Near-Field Scattering Enhancement of Perylene Based Aggregates for Random Lasing

Strong near-field scattering enhancement (NFSE) of polyhedral oligomeric silsesquioxanes(POSS) nanoparticles (NPs) aggregates is found through physical simulation. An aggregation of N,N′-di-[3-(isobutyl polyhedral oligomeric silsesquioxanes) propyl] perylene diimide(DPP) which possesses POSS as scatteres experimentally performs strong NFSE, which confirms the physical simulation results. Moreover, coherent random laser is triggered from the DPP aggregates in carbon disulfide. It is the NFSE of POSS NPs connected to both ends of DPP through covalent bonds and the NFSE of their aggregation thanks to DPP’s aggregation that is responsible for the coherent random laser. So, this work develops a method to improve weak scattering of system through construction of molecules, and opens a road to a variety of novel interdisciplinary investigations, involving molecular designing for disordered photonics.

MICROSTRUCTURE OF AGGREGATES IN DISPERSIONS DESCRIBED IN TERMS OF RADIAL DISTRIBUTION FUNCTION

Following a sticky particle model and its computer simulation scheme proposed in the previous papers, the motions of particles in both 2-and 3-dimensional shear flow fields are simulated. At a steady state of clustering process, the radial distribution functions are calculated to precisely describe the microstructure of aggregates in dispersions, and the configuration of particles is displayed,which gives a direct view of microstructure. It is found that (1) the kind of the microstructure transforms from compact clusters to a loose network as the concentration of particles increases; (2) the microstructure is independent of shear rate which only dominates the size of clusters formed at steady state.

Application of Light Reflectance-Transmittance Measurement Method to Reconstruct Geometrical Morphology of Particle Fractal Aggregates

Particles,including soot,aerosol and ash,usually exist as fractal aggregates.The radiative properties of the particle fractal aggregates have a great influence on studying the light or heat radiative transfer in the particle medium.In the present work,the performance of the single-layer inversion model and the double-layer inversion model in reconstructing the geometric structure of particle fractal aggregates is studied based on the light reflectancetransmittance measurement method.An improved artificial fish-swarm algorithm(IAFSA)is proposed to solve the inverse problem.The result reveals that the accuracy of double-layer inversion model is more satisfactory as it can provide more uncorrelated information than the single-layer inversion model.Moreover,the developed IAFSA show higher accuracy and better robustness than the original artificial fish swarm algorithm(AFSA)for avoiding local optimization problems effectively.As a whole,the present work supplies a useful kind of measurement technology for predicting geometrical morphology of particle fractal aggregates.

Rheology of Cement Mortars with Crushed Fine Aggregates of Different Lithological Types

Crushed fine aggregates are widely used for full or partial replacement of natural sands in concretes. The crushed sands present different characteristics from the natural sand, especially if taking into account the content of microfine particle, the distribution of particle sizes, the shape features, besides the different lithological origin. From the rheological point of view, the crushed sands frequently provide mixtures with high yield stress, high viscosity, high cohesion and internal friction, which hinders its use in concrete. This study is focused on the evaluation of the rheological behavior of concrete mortar phase when using different lithological types of crushed sand in total replacement of natural sand. The lithological types surveyed were granite, calcitic limestone, dolomite limestone and mica schist. Each of these sand types was studied in two ways： in natura and with adjusted grading curve. The results show the best performance of calcitic limestone providing lower viscosities and lower yield stress in mortars.

Chloride diffusion in concrete with carbonated recycled coarse aggregates under biaxial compression

Chloride attack on concrete structures is affected by the complex stress state inside concrete,and the effect of recycled aggregates renders this process more complex.Enhancing the chloride resistance of recycled concrete in a complex environment via carbonization facilitates the popularization and application of recycled concrete and alleviates the greenhouse effect.In this study,the chloride ion diffusion and deformation properties of recycled concrete after carbonization are investigated using a chloride salt load-coupling device.The results obtained demonstrate that the chloride ion diffusivity of recycled concrete first decreases and then increases as the compressive load increases,which is consistent with the behavior of concrete,in that it first undergoes compressive deformation,followed by crack propagation.Carbonation enhances the performance of the recycled aggregates and reduces their porosity,thereby reducing the chloride diffusion coefficient of the recycled concrete under different compressive load combinations.The variation in the chloride ion diffusivity of the carbonized recycled aggregate concrete with the load is consistent with a theoretical formula.

Analysis of extinction characteristics of non-spherical biological particle aggregates [Invited]

In this study,a method was presented to accurately obtain the extinction characteristics of the non-spherical biological particle aggregates.Based on the multi-sphere particle model of non-spherical particles,a randomly oriented aggregation model was firstly built to construct the aggregates.The discrete-dipole approximation method was used to calculate the extinction characteristics of aggregates in the 3–14 μm waveband.The average mass extinction coefficients of three materials are 0.802 m~2/g,0.907 m~2/g,and 0.866 m~2/g in the 3–5 μm waveband and 0.590 m~2/g,0.402 m~2/g,and 0.523 m~2/g in the8–14 μm band,respectively.Smoke chamber experimental results are in good agreement with theoretical analyses.

Evaluation methods and indexes of morphological characteristics of coarse aggregates for road materials:A comprehensive review

The morphological characteristics of coarse aggregates, namely shape profile, angularity and surface texture, have a significant effect on the mechanical properties of asphalt mixtures. The identification methods and evaluation indexes of the morphological characteristics are crucial for the coarse aggregates. First, the visual identification technologies, including charged coupled device (CCD) image processing, X-ray tomography imaging and laser scanning technology, are summarized in term of the characteristics, research status and existing problems. Based on the deficiencies of visual identification technologies, it is proposed to improve the three-dimensional reconstruction of aggregate particles by increasing the number of two-dimensional projection directions or scanning sections. Moreover, the evaluation indexes of coarse aggregate morphology were summarized from the three aspects, namely shape profile, angularity and surface texture. It is found that evaluation of the indexes based on two-dimensional profile images or unrelated to pavement performance could not adequately evaluate the morphological characteristics of coarse aggregates. Therefore, the evaluation methods and indexes of coarse aggregate morphological characteristics have been recommended based on the performance of asphalt mixtures in this paper, which is helpful to establish a complete set of an evaluation system for coarse aggregate morphology.

Effects of coarse and fine aggregates on long-term mechanical properties of sea sand recycled aggregate concrete

Typical effects of coarse and fine aggregates on the long-term properties of sea sand recycled aggregate concrete(SSRAC)are analyzed by a series of axial compression tests.Two different types of fine(coarse)aggregates are considered:sea sand and river sand(natural and recycled coarse aggregates).Variations in SSRAC properties at different ages are investigated.A novel test system is developed via axial compression experiments and the digital image correlation method to obtain the deformation field and crack development of concrete.Supportive results show that the compressive strength of SSRAC increase with decreasing recycled coarse aggregate replacement percentage and increasing sea sand chloride ion content.The elastic modulus of SSRAC increases with age.However,the Poisson’s ratio reduces after 2 years.Typical axial stress-strain curves of SSRAC vary with age.Generally,the effect of coarse aggregates on the axial deformation of SSRAC is clear;however,the deformation differences between coarse aggregate and cement mortar reduce by adopting sea sand.The aggregate type changes the crack characteristics and propagation of SSRAC.Finally,an analytical expression is suggested to construct the long-term stress-strain curve of SSRAC.

CFD-DEM simulation of a pseudo-two-dimensional spouted bed comprising coarse particles

In the present study, computational fluid dynamics (CFD) and the discrete element method (DEM) are used in conjunction with the Eulerian-Lagrangian method to simulate a pseudo-two-dimensional spouted bed comprising coarse 6-mm particles. The open-source OpenFOAM code is used to solve the governing equations. The predicted vertical particle velocity along the bed axis, particle velocity profiles in the radial directi on, power spectral den sity, time-averaged particle velocity vectors, bed pressure drop, and solid flow pattern are evaluated and compared with existing experimental data. Good agreement is found between the CFD-DEM results and the measured data. It is also shown that the present CFD-DEM model accurately predicts the particle flow pattern throughout the bed. It is found that the drag force, solid stresses, and gravity play important roles in the CFD-DEM simulation of a spouted bed comprising coarse particles.

Effect of High Temperature Curing on the Frost Resistance of Recycled Aggregate Concrete and the Physical Properties of Second-Generation Recycled Coarse Aggregate under Freeze-Thaw Cycles

With the emphasis on environmental issues,the recycling of waste concrete,even recycled concrete,has become a hot spot in the field of architecture.But the repeated recycling of waste concrete used in harsh environments is still a complex problem.This paper discusses the durability and recyclability of recycled aggregate concrete(RAC)as a prefabricated material in the harsh environment,the effect of high-temperature curing(60℃,80℃,and 100℃)on the frost resistance of RAC and physical properties of the second generation recycled coarse aggregate(RCA_(2))of RAC after 300 freeze-thaw cycles were studied.The frost resistance of RAC was characterized by compressive strength,relative dynamic elastic modulus,and mass loss.As the physical properties of RCA_(2),the apparent density,water absorption,and crushing value were measured.And the SEM images of RAC after 300 freeze-thaw cycles were shown.The results indicated that the frost resistance of RAC cured at 80℃ for 7 days was comparable to that cured in the standard condition(cured for 28 days at 20℃±2℃ and 95%humidity),and the RAC cured at 100℃ was slightly worse.However,the frost resistance of RAC cured at 60℃ deteriorated seriously.The RAC cured at 80℃ for 7 days is the best.Whether after the freeze-thaw cycle or not,the RCA that curd at 60℃,80℃,and 100℃ for 7 days can also meet the requirements of Grade III RCA and be used as the aggregate of non-bearing part of prefabricated concrete components.RCA_(2) which is cured at 80℃ for 7 days had the best physical properties.

再生粗骨料混凝土应力-应变关系

再生粗骨料混凝土应力-应变关系是实现其材料到结构力学分析的桥梁纽带,成为再生粗骨料混凝土结构基础理论的基石。介绍了作者团队多年来在再生粗骨料混凝土应力-应变关系方面取得的研究进展:采用模型化再生粗骨料方法,研究了复杂界面过渡区对再生粗骨料混凝土破坏行为的影响,揭示了再生粗骨料混凝土细观损伤本质与演化机理;从静力作用到动力作用,系统地开展了不同工况下再生粗骨料混凝土应力-应变行为试验研究,探明了载荷条件对再生粗骨料混凝土应力与变形的影响规律并建立了相适应的力学与数学模型;进一步考虑再生粗骨料性能时空变异性,发现了再生粗骨料混凝土力学响应的概率分布特征,提出了再生粗骨料混凝土随机损伤本构关系;基于获得的本构模型,完成了再生粗骨料混凝土构件时变可靠度分析和结构动力非线性分析,为再生粗骨料混凝土在实际工程中的安全应用提供了理论支撑;提炼了相关研究结论并对未来研究工作进行了展望。