Featuring low density and high specific strength, magnesium(Mg) alloys have attracted wide interests in the fields of portable devices and automotive industry. However, the active chemical and electrochemical properti...Featuring low density and high specific strength, magnesium(Mg) alloys have attracted wide interests in the fields of portable devices and automotive industry. However, the active chemical and electrochemical properties make them susceptible to corrosion in humid, seawater, soil,and chemical medium. Various strategies have revealed certain merits of protecting Mg alloys. Therein, engineering self-repairing coatings is considered as an effective strategy, because they can enable the timely repair for damaged areas, which brings about long-term protection for Mg alloys. In this review, self-repairing coatings on Mg alloys are summarized from two aspects, namely shape restoring coatings and function restoring coatings. Shape restoring coatings benefit for swelling, shrinking, or reassociating reversible chemical bonds to return to the original state and morphology when coatings broken;function self-repairing coatings depend on the release of inhibitors to generate new passive layers on the damaged areas. With the advancement of coating research and to fulfill the demanding requirements of applications, it is an inevitable trend to develop coatings that can integrate multiple functions(such as stimulus response, self-repairing, corrosion warning,and so on). As a novel carrier and barrier, porous solids, especially covalent organic frameworks(COFs), have been respected as the future development of self-repairing coatings on Mg alloys, due to their unique, diverse structures and adjustable functions.展开更多
Titanium based IrO2 +Ta2O5 oxide anodes with different compositions and pyrolysis temperatures were prepared by termodecompoisition method. By using X-ray diffraction (XRD), the structure and texture coefficient of th...Titanium based IrO2 +Ta2O5 oxide anodes with different compositions and pyrolysis temperatures were prepared by termodecompoisition method. By using X-ray diffraction (XRD), the structure and texture coefficient of the coatings, TC(hkl), of IrO2 rutile crystal have been tested. It showed that, the crystallization processes of IrO2 and Ta2O5 in xIrO2 +(100-x) Ta2 O5 (x is in mol%) films affected and confined each other.In the mixed system, IrO2 rutile phase existed as a solid solution with Ta, and attained the maximum solubility when x=70mol%, i.e. for the coating of 70% IrO2 +Ta2O5.For the coatings of low iridium content or at low preparing tem pemture, (110) and (101) pwtered orientations were dominant. However, preferred growth of IrO2 weakened with increasing either iridium content or temperature. Three typical surface morphologies were observed by using scanning electron tnicroscopy(SEM). The crystallite size of the mixed oxide coatings were finest for the the film of 70%IrO2 +30%Ta2O5,and decreased with the pyrolysis tempemture. As the results of the finest crystallite segregating on sudece and the maxitnum solid solubility of Ir and Ta component in deposits, the coatings with the composition of 70%IrO2 +Ta2O5 prepared at 450℃ presented the mdrimutn electrocatalgtic activitg for O2 evolution in 0. 5M H2SO4 solution.UP to 550℃, Ti base suffered to oxidation resulting in decreasing anode conductivity,therefore, coatings performed a low activity.展开更多
SUS430 （16% - 17% （mass fraction） Cr） can be used as interconnects for solid oxide fuel cells （SOFCs） that operate at lower temperatures （ 〈 800 ℃ ）. However, oxidation of steel can occur readily at elevated...SUS430 （16% - 17% （mass fraction） Cr） can be used as interconnects for solid oxide fuel cells （SOFCs） that operate at lower temperatures （ 〈 800 ℃ ）. However, oxidation of steel can occur readily at elevated temperatures leading to the formation of Cr2O3 and spinel （Fe3O4） and thus greatly degrades the performance of the fuel cell. The aim of this work was to reduce oxide growth, in particular, the Cr2O3 phase, through the application of La0.8Sr0.2MnO3-δ （LSM2O） and La0.8Sr0.2FeO3-δ（LSF20） coatings by atmospheric plasma spraying technology （APS）. Oxide growth was characterized by using X-ray diffraction （XRD）, scanning electron microscopy （SEM） with an energy dispersive X-ray （EDX） analyzer. During oxidation of fifty 20 h cycles at 800 ℃ in air, the samples with coatings remained very stable, whereas significant spallation and weight loss were observed for the uncoated steel. LSF20 presents apparently advantages in reducing oxidation growth, interface resistance and inhibition of diffusion of chromium. After exposure in air at 800 ℃ for 1000 h, the interfacial resistance of LSF20-coated alloy is lowered by more than 23 times to that of LSM20-coated layer.展开更多
All-solid-state(ASS)Na-S batteries are promising for large-scale energy storage because of the incombustible solid electrolyte and avoiding the dissolution of intermediates.However,the poor contact between the active ...All-solid-state(ASS)Na-S batteries are promising for large-scale energy storage because of the incombustible solid electrolyte and avoiding the dissolution of intermediates.However,the poor contact between the active material and the solid electrolyte in the positive electrode leads to poor electrochemical performance.Here,we report an aqueous solution approach to fabricate Na3SbS4-coated SexS-based active materials for a Na-S battery working at room temperature.Compared with the Na3SbS4 and SexS mixed cathode,the coated cathode achieves significantly improved Na-ion diffusion kinetics and reduced impedance resistance.Additionally,the nanoparticle coating sustains the volume expansion of the cathode during cycling.The resulting batteries deliver an intensively enhanced specific capacity at various rates.Regardless of the mass loading,the Na3SbS4-coated cathode maintains a decent reversible capacity for the long-term discharge/charge cycling.The best battery achieves an initial discharge capacity of509 mAh g^-1 at a current density of 437.4 mA g^-1 and capacity retention of 98.9%for 100 cycles.To the best of our knowledge,this is one of the best room temperature ASS Na-S battery so far.This work demonstrates that Na3SbS4 is very promising for the cathode coating purpose for ASS Na-S batteries.展开更多
To improve the solid lubricity on the worn surface of frictional-pairs, a convenient and simple brush-painting technique was utilized to prepare the solid lubrication graphite coatings. The bonding between the coating...To improve the solid lubricity on the worn surface of frictional-pairs, a convenient and simple brush-painting technique was utilized to prepare the solid lubrication graphite coatings. The bonding between the coatings and substrate is good. To examine the influence of the different graphite contents on the tribological properties of the graphite coatings, the comparison experiments were carried out on the ring-on-block friction tester. The tribological results show a change law of saddle-shape between the tribological properties of graphite coatings and graphite content. When the amount of graphite is up to 28g, the tribological properties of graphite coating are the best. The excellent anti-friction of the graphite coating is associated with the close-packed hexagonal crystal structure of graphite.展开更多
Alumina coated LiNi1/3Mn1/3Co1/3O2 particles were obtained by a simple method of solid state reaction at room temperature. The reaction mechanism of solid state reaction at room temperature was investigated. The struc...Alumina coated LiNi1/3Mn1/3Co1/3O2 particles were obtained by a simple method of solid state reaction at room temperature. The reaction mechanism of solid state reaction at room temperature was investigated. The structure and morphology of the coating materials were investigated by XRD, SEM and TEM. The electrochemical performances of uncoated and Al2O3-coated LiNi1/3Co1/3Mn1/3O2 cathode materials were studied within a voltage window of 3.00?4.35 V at current density of 30 mA/g. SEM, TEM and EDS analytical results indicate that the surface of LiNi1/3Mn1/3Co1/3O2 particles is coated with very fine Al2O3 composite, which leads to the improved cycle ability though a slight decrease in the first discharge capacity is observed. It is proposed that surface treatment by solid state reaction at room temperature is a simple and effective method to improve the cycle performance of LiNi1/3Co1/3Mn1/3O2 particles.展开更多
Experiments on the solid-state reaction between iron ore particles and MgO were performed to investigate the coating mechanism of MgO on the iron ore particles＇ surface during fluidized bed reduction. MgO powders and...Experiments on the solid-state reaction between iron ore particles and MgO were performed to investigate the coating mechanism of MgO on the iron ore particles＇ surface during fluidized bed reduction. MgO powders and iron ore particles were mixed and compressed into briquettes and, subsequently, roasted at different temperatures and for different time periods. A Mg-containing layer was observed on the outer edge of the iron ore particles when the roasting temperature was greater than 1173 K. The concentration of Fe in the Mg-containing layer was evenly distributed and was approximately 10wt%, regardless of the temperature change. Boundary layers of Mg and Fe were observed outside of the iron ore particles. The change in concentration of Fe in the boundary layers was simulated using a gas–solid diffusion model, and the diffusion coefficients of Fe and Mg in these layers at different temperatures were calculated. The diffusion activation energies of Fe and Mg in the boundary layers in these experiments were evaluated to be approximately 176 and 172 k J/mol, respectively.展开更多
Solid contaminants in lubrication system will cause severe wear of sliding compo nents. In order to improve the wear resistance of the material in oil containing solid contaminants,the brush plated nano-Al2O3/Ni compo...Solid contaminants in lubrication system will cause severe wear of sliding compo nents. In order to improve the wear resistance of the material in oil containing solid contaminants,the brush plated nano-Al2O3/Ni composite coating was p repared and the influence of the sand content and sand size on the tribological property of the coating in oil containing solid contaminants was tested with bal l-on-disc tester. The results show that the wear volume increases with increas ing the sand content and sand size,and the wear resistance of the composite coa ting is 20% higher than that of the high-speed plain nickel coating. The main w ear mechanisms of the coatings are abrasive wear and adhesive wear. And due to t he nano-particle strengthening effect,the wear resistance of the composite coa ting is improved.展开更多
Surface sizing can improve the surface performances of paper. In this article we used surfacing sizing and ultra fine talcum powder to improve the quality of base paper. The results showed that the optimal formulation...Surface sizing can improve the surface performances of paper. In this article we used surfacing sizing and ultra fine talcum powder to improve the quality of base paper. The results showed that the optimal formulation is: sodium hexametaphosphate 0.4 parts, PC-01 25 parts and 100 parts ultra fine talcum powder. The solids content of coating is 18%. Surface sizing and low solids coating can improve brightness, opacity, IGT Pick resistance, and breaking length which were improved by 3.4%, 6.5%, 2.07m/sec and 700m separately than uncoated paper respectively. K and N ink absorption value was reduced from 62.1 to 34.6. The method can be used to produce base paper for art paper and ultra low weight coated paper (ULWC). It can reduce the cost of art paper.展开更多
LiNi0.8Co0.2O2 particles were modified by Co3（PO4）2 coating. The effects of the Co3（PO4）2 coating on the structure and electrochemical properties of the LiNi0.8Co0.2O2 cathode material were investigated. The Co3...LiNi0.8Co0.2O2 particles were modified by Co3（PO4）2 coating. The effects of the Co3（PO4）2 coating on the structure and electrochemical properties of the LiNi0.8Co0.2O2 cathode material were investigated. The Co3（PO4）2 coating forms a thin layer on the surface of the LiNi0.8Co0.2O2 material and a solid solution by interacting with the LiNi0.8Co0.2O2 core material during calcination at 700℃ for 4 h. Charge-discharge experiment results show that the Co3（PO4）2 coating improves the cycling stability of the LiNi0.8Co0.2O2 cathode material. The capacity retention of the pristine LiNi0.8Co0.2O2 cathode after 50 cycles is 83.6%, whereas it is 91.7% in the case of the LiNi0.8Co0.2O2 cathode coated with 1 wt.% Co3（PO4）2. Storage tests of the 4.35 V charged electrode at 60℃ after a month show that the Co3（POg）2-coated sample exhibits good storage properties compared with the pristine sample.展开更多
Cu-Mn_(3)O_(4)composite coating was prepared on the SUS 430 ferritic stainless steel by electrodeposition and then exposed in air at 800℃corresponding to the cathode atmosphere of solid oxide fuel cell(SOFC).A dual-l...Cu-Mn_(3)O_(4)composite coating was prepared on the SUS 430 ferritic stainless steel by electrodeposition and then exposed in air at 800℃corresponding to the cathode atmosphere of solid oxide fuel cell(SOFC).A dual-layer oxide structure mainly comprising an external layer of CuO followed by(Cu,Mn,Fe)_(3)O_(4)spinel and an internal layer of Cr-rich oxide was thermally developed on the coated steel.The scale area-specific resistances(ASRs)of the coated steels were lower than the scale ASR of the uncoated steel after identical thermal exposure.The external layer of CuO/(Cu,Mn,Fe)_(3)O_(4)spinel not only served as a barrier to reduce the growth rate of Cr-rich oxide internal layer and to suppress the outward diffusion of Cr,but also lowered the surface scale ASRs considerably.展开更多
Interconnector is a critical component to construct solid oxide cells (SOCs) stack. Oxidation of metallic interconnectors and Cr poisoning caused by oxidation are important factors that lead to long-term performance d...Interconnector is a critical component to construct solid oxide cells (SOCs) stack. Oxidation of metallic interconnectors and Cr poisoning caused by oxidation are important factors that lead to long-term performance degradation of SOCs. Coating on the interconnector surface is an important approach to inhibit the oxidation and Cr migration of the interconnector. Herein, (La0.75Sr0.25)0.95MnO3–δ (LSM) and Mn1.5Co1.5O4 (MCO) are used to fabricate the coatings of interconnector. Two advanced thermal spray technology, atmospheric plasma spraying (APS) and low-pressure plasma spray (LPPS), are adopted for the coating preparation. The electrochemical performance, rising and cooling cycle stability, and Cr diffusion inhibition performance of the coatings are tested and evaluated. The result indicates that MCO can generate more uniform and denser coatings than LSM. In addition, MCO coatings prepared by LPPS shows the best electrochemical performance, rising and cooling cycle stability, and Cr diffusion inhibition. The initial area specific resistance (ASR) is 0.0027 Ω·cm2 at 800 °C. After 4 cooling cycle tests, the ASR increases to 0.0032 Ω·cm2 but lower than other samples. Meanwhile, the relative intense of Cr at the interface of SUS430 with MCO coatings fabricated by LPPS is lower than that of MCO fabricated by APS after 4 rising and cooling cycle operations, showing more favorable Cr diffusion inhibition performance.展开更多
Ultra-high-temperature ceramic nanowires have shown increasing potential for use as thermal structural components.Herein,novel single-crystal Hf_(0.5)Ta_(0.5)C solid solution nanowires were synthesized and incorporate...Ultra-high-temperature ceramic nanowires have shown increasing potential for use as thermal structural components.Herein,novel single-crystal Hf_(0.5)Ta_(0.5)C solid solution nanowires were synthesized and incorporated with a HfC coating to construct a robust structure with Hf_(0.5)Ta_(0.5)C solid solution nanowires uniformly distributed and interconnected within the coating.The novel Hf_(0.5)Ta_(0.5)C solid solution nanowires could effectively hinder crack propagation through crack tip pinning and crack deflection.This mechanism substantially enhanced the elastic modulus and fracture toughness of the HfC coating by 53.29%and 59.67%,respectively.The toughened HfC coating displayed superior fracture toughness and good interfacial binding strength with the substrate to resist severe oxidation and scouring.Additionally,the high thermal conductivity of the toughened HfC coating promoted heat transmission.Thus,in comparison to the pure HfC coating,the toughened HfC coating displayed smaller mass and linear ablation rates of−0.35 mg·s^(−1)and−0.46μm·s^(−1),which decreased by 39.66%and 36.98%,respectively.Our work not only simultaneously enhances the mechanical properties and ablation resistance of HfC-coated carbon/carbon(C/C)composites but also provides novel prospects for advanced ultrahigh-temperature ceramic nanowires under extreme conditions.展开更多
基金the financial support from the National Natural Science Foundation of China (Nos.52204389,U19A2084 and 52234009)the National Key Research and Development Program (No.2022YFE0122000)Program for the Central University Youth Innovation Team。
文摘Featuring low density and high specific strength, magnesium(Mg) alloys have attracted wide interests in the fields of portable devices and automotive industry. However, the active chemical and electrochemical properties make them susceptible to corrosion in humid, seawater, soil,and chemical medium. Various strategies have revealed certain merits of protecting Mg alloys. Therein, engineering self-repairing coatings is considered as an effective strategy, because they can enable the timely repair for damaged areas, which brings about long-term protection for Mg alloys. In this review, self-repairing coatings on Mg alloys are summarized from two aspects, namely shape restoring coatings and function restoring coatings. Shape restoring coatings benefit for swelling, shrinking, or reassociating reversible chemical bonds to return to the original state and morphology when coatings broken;function self-repairing coatings depend on the release of inhibitors to generate new passive layers on the damaged areas. With the advancement of coating research and to fulfill the demanding requirements of applications, it is an inevitable trend to develop coatings that can integrate multiple functions(such as stimulus response, self-repairing, corrosion warning,and so on). As a novel carrier and barrier, porous solids, especially covalent organic frameworks(COFs), have been respected as the future development of self-repairing coatings on Mg alloys, due to their unique, diverse structures and adjustable functions.
文摘Titanium based IrO2 +Ta2O5 oxide anodes with different compositions and pyrolysis temperatures were prepared by termodecompoisition method. By using X-ray diffraction (XRD), the structure and texture coefficient of the coatings, TC(hkl), of IrO2 rutile crystal have been tested. It showed that, the crystallization processes of IrO2 and Ta2O5 in xIrO2 +(100-x) Ta2 O5 (x is in mol%) films affected and confined each other.In the mixed system, IrO2 rutile phase existed as a solid solution with Ta, and attained the maximum solubility when x=70mol%, i.e. for the coating of 70% IrO2 +Ta2O5.For the coatings of low iridium content or at low preparing tem pemture, (110) and (101) pwtered orientations were dominant. However, preferred growth of IrO2 weakened with increasing either iridium content or temperature. Three typical surface morphologies were observed by using scanning electron tnicroscopy(SEM). The crystallite size of the mixed oxide coatings were finest for the the film of 70%IrO2 +30%Ta2O5,and decreased with the pyrolysis tempemture. As the results of the finest crystallite segregating on sudece and the maxitnum solid solubility of Ir and Ta component in deposits, the coatings with the composition of 70%IrO2 +Ta2O5 prepared at 450℃ presented the mdrimutn electrocatalgtic activitg for O2 evolution in 0. 5M H2SO4 solution.UP to 550℃, Ti base suffered to oxidation resulting in decreasing anode conductivity,therefore, coatings performed a low activity.
文摘SUS430 （16% - 17% （mass fraction） Cr） can be used as interconnects for solid oxide fuel cells （SOFCs） that operate at lower temperatures （ 〈 800 ℃ ）. However, oxidation of steel can occur readily at elevated temperatures leading to the formation of Cr2O3 and spinel （Fe3O4） and thus greatly degrades the performance of the fuel cell. The aim of this work was to reduce oxide growth, in particular, the Cr2O3 phase, through the application of La0.8Sr0.2MnO3-δ （LSM2O） and La0.8Sr0.2FeO3-δ（LSF20） coatings by atmospheric plasma spraying technology （APS）. Oxide growth was characterized by using X-ray diffraction （XRD）, scanning electron microscopy （SEM） with an energy dispersive X-ray （EDX） analyzer. During oxidation of fifty 20 h cycles at 800 ℃ in air, the samples with coatings remained very stable, whereas significant spallation and weight loss were observed for the uncoated steel. LSF20 presents apparently advantages in reducing oxidation growth, interface resistance and inhibition of diffusion of chromium. After exposure in air at 800 ℃ for 1000 h, the interfacial resistance of LSF20-coated alloy is lowered by more than 23 times to that of LSM20-coated layer.
基金supported by the National Key R&D Program of China(grant no.2018YFB0104300)the Natural Science Foundation of Hebei Province(E2018203301)。
文摘All-solid-state(ASS)Na-S batteries are promising for large-scale energy storage because of the incombustible solid electrolyte and avoiding the dissolution of intermediates.However,the poor contact between the active material and the solid electrolyte in the positive electrode leads to poor electrochemical performance.Here,we report an aqueous solution approach to fabricate Na3SbS4-coated SexS-based active materials for a Na-S battery working at room temperature.Compared with the Na3SbS4 and SexS mixed cathode,the coated cathode achieves significantly improved Na-ion diffusion kinetics and reduced impedance resistance.Additionally,the nanoparticle coating sustains the volume expansion of the cathode during cycling.The resulting batteries deliver an intensively enhanced specific capacity at various rates.Regardless of the mass loading,the Na3SbS4-coated cathode maintains a decent reversible capacity for the long-term discharge/charge cycling.The best battery achieves an initial discharge capacity of509 mAh g^-1 at a current density of 437.4 mA g^-1 and capacity retention of 98.9%for 100 cycles.To the best of our knowledge,this is one of the best room temperature ASS Na-S battery so far.This work demonstrates that Na3SbS4 is very promising for the cathode coating purpose for ASS Na-S batteries.
文摘To improve the solid lubricity on the worn surface of frictional-pairs, a convenient and simple brush-painting technique was utilized to prepare the solid lubrication graphite coatings. The bonding between the coatings and substrate is good. To examine the influence of the different graphite contents on the tribological properties of the graphite coatings, the comparison experiments were carried out on the ring-on-block friction tester. The tribological results show a change law of saddle-shape between the tribological properties of graphite coatings and graphite content. When the amount of graphite is up to 28g, the tribological properties of graphite coating are the best. The excellent anti-friction of the graphite coating is associated with the close-packed hexagonal crystal structure of graphite.
基金Project(50604018) supported by the National Natural Science Foundation of China
文摘Alumina coated LiNi1/3Mn1/3Co1/3O2 particles were obtained by a simple method of solid state reaction at room temperature. The reaction mechanism of solid state reaction at room temperature was investigated. The structure and morphology of the coating materials were investigated by XRD, SEM and TEM. The electrochemical performances of uncoated and Al2O3-coated LiNi1/3Co1/3Mn1/3O2 cathode materials were studied within a voltage window of 3.00?4.35 V at current density of 30 mA/g. SEM, TEM and EDS analytical results indicate that the surface of LiNi1/3Mn1/3Co1/3O2 particles is coated with very fine Al2O3 composite, which leads to the improved cycle ability though a slight decrease in the first discharge capacity is observed. It is proposed that surface treatment by solid state reaction at room temperature is a simple and effective method to improve the cycle performance of LiNi1/3Co1/3Mn1/3O2 particles.
基金supported by the Fundamental Research Funds for the Central Universities (FRF-TP-15-009A2)the Project Funded by China Postdoctoral Science Foundation (2015M570931)+1 种基金the National Natural Science Fund Project of China (91534121)the National Major Scientific Instruments Special Plan (2011YQ12003907)
文摘Experiments on the solid-state reaction between iron ore particles and MgO were performed to investigate the coating mechanism of MgO on the iron ore particles＇ surface during fluidized bed reduction. MgO powders and iron ore particles were mixed and compressed into briquettes and, subsequently, roasted at different temperatures and for different time periods. A Mg-containing layer was observed on the outer edge of the iron ore particles when the roasting temperature was greater than 1173 K. The concentration of Fe in the Mg-containing layer was evenly distributed and was approximately 10wt%, regardless of the temperature change. Boundary layers of Mg and Fe were observed outside of the iron ore particles. The change in concentration of Fe in the boundary layers was simulated using a gas–solid diffusion model, and the diffusion coefficients of Fe and Mg in these layers at different temperatures were calculated. The diffusion activation energies of Fe and Mg in the boundary layers in these experiments were evaluated to be approximately 176 and 172 k J/mol, respectively.
文摘Solid contaminants in lubrication system will cause severe wear of sliding compo nents. In order to improve the wear resistance of the material in oil containing solid contaminants,the brush plated nano-Al2O3/Ni composite coating was p repared and the influence of the sand content and sand size on the tribological property of the coating in oil containing solid contaminants was tested with bal l-on-disc tester. The results show that the wear volume increases with increas ing the sand content and sand size,and the wear resistance of the composite coa ting is 20% higher than that of the high-speed plain nickel coating. The main w ear mechanisms of the coatings are abrasive wear and adhesive wear. And due to t he nano-particle strengthening effect,the wear resistance of the composite coa ting is improved.
文摘Surface sizing can improve the surface performances of paper. In this article we used surfacing sizing and ultra fine talcum powder to improve the quality of base paper. The results showed that the optimal formulation is: sodium hexametaphosphate 0.4 parts, PC-01 25 parts and 100 parts ultra fine talcum powder. The solids content of coating is 18%. Surface sizing and low solids coating can improve brightness, opacity, IGT Pick resistance, and breaking length which were improved by 3.4%, 6.5%, 2.07m/sec and 700m separately than uncoated paper respectively. K and N ink absorption value was reduced from 62.1 to 34.6. The method can be used to produce base paper for art paper and ultra low weight coated paper (ULWC). It can reduce the cost of art paper.
基金the National Natural Science Foundation of China (No. 50604018)
文摘LiNi0.8Co0.2O2 particles were modified by Co3（PO4）2 coating. The effects of the Co3（PO4）2 coating on the structure and electrochemical properties of the LiNi0.8Co0.2O2 cathode material were investigated. The Co3（PO4）2 coating forms a thin layer on the surface of the LiNi0.8Co0.2O2 material and a solid solution by interacting with the LiNi0.8Co0.2O2 core material during calcination at 700℃ for 4 h. Charge-discharge experiment results show that the Co3（PO4）2 coating improves the cycling stability of the LiNi0.8Co0.2O2 cathode material. The capacity retention of the pristine LiNi0.8Co0.2O2 cathode after 50 cycles is 83.6%, whereas it is 91.7% in the case of the LiNi0.8Co0.2O2 cathode coated with 1 wt.% Co3（PO4）2. Storage tests of the 4.35 V charged electrode at 60℃ after a month show that the Co3（POg）2-coated sample exhibits good storage properties compared with the pristine sample.
基金Funded by the Youth Science and Technology Talent Growth Project of Education Department of Guizhou Province(No.KY[2018]145)。
文摘Cu-Mn_(3)O_(4)composite coating was prepared on the SUS 430 ferritic stainless steel by electrodeposition and then exposed in air at 800℃corresponding to the cathode atmosphere of solid oxide fuel cell(SOFC).A dual-layer oxide structure mainly comprising an external layer of CuO followed by(Cu,Mn,Fe)_(3)O_(4)spinel and an internal layer of Cr-rich oxide was thermally developed on the coated steel.The scale area-specific resistances(ASRs)of the coated steels were lower than the scale ASR of the uncoated steel after identical thermal exposure.The external layer of CuO/(Cu,Mn,Fe)_(3)O_(4)spinel not only served as a barrier to reduce the growth rate of Cr-rich oxide internal layer and to suppress the outward diffusion of Cr,but also lowered the surface scale ASRs considerably.
文摘Interconnector is a critical component to construct solid oxide cells (SOCs) stack. Oxidation of metallic interconnectors and Cr poisoning caused by oxidation are important factors that lead to long-term performance degradation of SOCs. Coating on the interconnector surface is an important approach to inhibit the oxidation and Cr migration of the interconnector. Herein, (La0.75Sr0.25)0.95MnO3–δ (LSM) and Mn1.5Co1.5O4 (MCO) are used to fabricate the coatings of interconnector. Two advanced thermal spray technology, atmospheric plasma spraying (APS) and low-pressure plasma spray (LPPS), are adopted for the coating preparation. The electrochemical performance, rising and cooling cycle stability, and Cr diffusion inhibition performance of the coatings are tested and evaluated. The result indicates that MCO can generate more uniform and denser coatings than LSM. In addition, MCO coatings prepared by LPPS shows the best electrochemical performance, rising and cooling cycle stability, and Cr diffusion inhibition. The initial area specific resistance (ASR) is 0.0027 Ω·cm2 at 800 °C. After 4 cooling cycle tests, the ASR increases to 0.0032 Ω·cm2 but lower than other samples. Meanwhile, the relative intense of Cr at the interface of SUS430 with MCO coatings fabricated by LPPS is lower than that of MCO fabricated by APS after 4 rising and cooling cycle operations, showing more favorable Cr diffusion inhibition performance.
基金the National Key R&D Program of China(No.2021YFA0715803)the National Natural Science Foundation of China(Nos.52293373 and 52130205)+1 种基金the Joint Fund of Henan Province Science and Technology R&D Program(No.225200810002)the Fundamental Research Funds of Henan Academy of Sciences(No.240621040).
文摘Ultra-high-temperature ceramic nanowires have shown increasing potential for use as thermal structural components.Herein,novel single-crystal Hf_(0.5)Ta_(0.5)C solid solution nanowires were synthesized and incorporated with a HfC coating to construct a robust structure with Hf_(0.5)Ta_(0.5)C solid solution nanowires uniformly distributed and interconnected within the coating.The novel Hf_(0.5)Ta_(0.5)C solid solution nanowires could effectively hinder crack propagation through crack tip pinning and crack deflection.This mechanism substantially enhanced the elastic modulus and fracture toughness of the HfC coating by 53.29%and 59.67%,respectively.The toughened HfC coating displayed superior fracture toughness and good interfacial binding strength with the substrate to resist severe oxidation and scouring.Additionally,the high thermal conductivity of the toughened HfC coating promoted heat transmission.Thus,in comparison to the pure HfC coating,the toughened HfC coating displayed smaller mass and linear ablation rates of−0.35 mg·s^(−1)and−0.46μm·s^(−1),which decreased by 39.66%and 36.98%,respectively.Our work not only simultaneously enhances the mechanical properties and ablation resistance of HfC-coated carbon/carbon(C/C)composites but also provides novel prospects for advanced ultrahigh-temperature ceramic nanowires under extreme conditions.
