Rare earth elements（REEs） and major elements of 25 cobalt-rich crusts obtained from different depths of Mid-Pacific M seamount were analyzed using inductively coupled plasma-atomic emission spectrometer and gravimet...Rare earth elements（REEs） and major elements of 25 cobalt-rich crusts obtained from different depths of Mid-Pacific M seamount were analyzed using inductively coupled plasma-atomic emission spectrometer and gravimetric method.The results showed that they were hydrogenous crusts with average ∑REE content of 2084.69 μg/g and the light REE（LREE）/heavy REE（HREE） ratio of 4.84.The shale-normalized REE patterns showed positive Ce anomalies.The total content of strictly trivalent REEs increased with water depth.The Ce content and LREE/HREE ratios in Fe-Mn crusts above 2000 m were lower than those below 2000 m.The change in REE with water depth could be explained by two processes：adsorptive scavenging by setting matters and behaviors of REE in seawater.However, the Ce abundance took no obvious correlation with water depth reflects the constant Ce flux.The Ce in crusts existed mainly as Ce（IV）, implying that the oxidative-enriching process was controlled by kinetic factors.展开更多
The aim of this study is to apply the concept of functionally graded materials(FGMs) to cemented carbides and to develop high-performance rock drill buttons. Cobalt-gradient structure was introduced to the surface zon...The aim of this study is to apply the concept of functionally graded materials(FGMs) to cemented carbides and to develop high-performance rock drill buttons. Cobalt-gradient structure was introduced to the surface zone of the buttons by carburizing process. Finite element method and XRD measurement were used to decide the distribution of thermal residual stress. Constitutive parameters were determined by constraint factor. Numerical results show that residual stresses of gradient buttons mainly concentrate in cobalt-gradient zone. There is compressive stress in the surface zone and tensile stress in the cobalt-rich zone. The maximum value of surface compressive stress is 180 MPa for WC-6Co cemented carbides. And the numerical results agree with the results of XRD measurement.展开更多
目的探究在304LN不锈钢表面上激光沉积Stellite 6合金过程中的多元素传输机制。方法采用流体体积法VOF(Volume of Fluid),建立气-液两相传热传质激光沉积模型。模型中使用改进VOF法对熔池表面进行追踪,结合多组分传输模型与熔凝杠杆原则...目的探究在304LN不锈钢表面上激光沉积Stellite 6合金过程中的多元素传输机制。方法采用流体体积法VOF(Volume of Fluid),建立气-液两相传热传质激光沉积模型。模型中使用改进VOF法对熔池表面进行追踪,结合多组分传输模型与熔凝杠杆原则(Lever Rule),对异质材料熔覆界面的多元素传输进行模拟,采用扫描电子显微镜(SEM)与能谱仪(EDS)观察组织结构和元素分布,对比模拟结果分析多组沉积层宏观形貌和元素分布特征。结果沉积过程中,熔池的流动与材料导热对温度的传输起着重要作用,前端对流不断地将已熔化的基材金属运输至熔池中部,后端对流则将卷积的Fe元素和Co元素进一步混合。最终沉积层的宏观形貌平均误差为2.67%,主要元素Fe、Co、Cr的质量分数误差分别为0.64%、1.27%、0.31%。结论Fe元素浓度整体区域分布相对均匀,但在沉积层底部,Fe元素浓度迅速升高,Co元素浓度随沉积深度加深逐渐降低,Cr元素在沉积层中部富集的分布特性。该优化后的模型可以准确模拟异质合金沉积过程中的温度场、流场与质量传输过程。展开更多
基金supported by the National Natural Science Foundation of China(40704029 40376016)+1 种基金China International Science and Technology Cooperation Project (2006DFB21620)the Young People Marine Science Foundation of State Oceanic Administration (2005304)
文摘Rare earth elements（REEs） and major elements of 25 cobalt-rich crusts obtained from different depths of Mid-Pacific M seamount were analyzed using inductively coupled plasma-atomic emission spectrometer and gravimetric method.The results showed that they were hydrogenous crusts with average ∑REE content of 2084.69 μg/g and the light REE（LREE）/heavy REE（HREE） ratio of 4.84.The shale-normalized REE patterns showed positive Ce anomalies.The total content of strictly trivalent REEs increased with water depth.The Ce content and LREE/HREE ratios in Fe-Mn crusts above 2000 m were lower than those below 2000 m.The change in REE with water depth could be explained by two processes：adsorptive scavenging by setting matters and behaviors of REE in seawater.However, the Ce abundance took no obvious correlation with water depth reflects the constant Ce flux.The Ce in crusts existed mainly as Ce（IV）, implying that the oxidative-enriching process was controlled by kinetic factors.
基金Project(50323008) supported by the National Natural Science Foundation of China
文摘The aim of this study is to apply the concept of functionally graded materials(FGMs) to cemented carbides and to develop high-performance rock drill buttons. Cobalt-gradient structure was introduced to the surface zone of the buttons by carburizing process. Finite element method and XRD measurement were used to decide the distribution of thermal residual stress. Constitutive parameters were determined by constraint factor. Numerical results show that residual stresses of gradient buttons mainly concentrate in cobalt-gradient zone. There is compressive stress in the surface zone and tensile stress in the cobalt-rich zone. The maximum value of surface compressive stress is 180 MPa for WC-6Co cemented carbides. And the numerical results agree with the results of XRD measurement.
文摘目的探究在304LN不锈钢表面上激光沉积Stellite 6合金过程中的多元素传输机制。方法采用流体体积法VOF(Volume of Fluid),建立气-液两相传热传质激光沉积模型。模型中使用改进VOF法对熔池表面进行追踪,结合多组分传输模型与熔凝杠杆原则(Lever Rule),对异质材料熔覆界面的多元素传输进行模拟,采用扫描电子显微镜(SEM)与能谱仪(EDS)观察组织结构和元素分布,对比模拟结果分析多组沉积层宏观形貌和元素分布特征。结果沉积过程中,熔池的流动与材料导热对温度的传输起着重要作用,前端对流不断地将已熔化的基材金属运输至熔池中部,后端对流则将卷积的Fe元素和Co元素进一步混合。最终沉积层的宏观形貌平均误差为2.67%,主要元素Fe、Co、Cr的质量分数误差分别为0.64%、1.27%、0.31%。结论Fe元素浓度整体区域分布相对均匀,但在沉积层底部,Fe元素浓度迅速升高,Co元素浓度随沉积深度加深逐渐降低,Cr元素在沉积层中部富集的分布特性。该优化后的模型可以准确模拟异质合金沉积过程中的温度场、流场与质量传输过程。
