The effect of spin-1 impurities doping on the magnetic properties of a spin-3/2 Ising nanotube is investigated using Monte Carlo simulations within the Blume-Emery-Griffiths model in the presence of an external magnet...The effect of spin-1 impurities doping on the magnetic properties of a spin-3/2 Ising nanotube is investigated using Monte Carlo simulations within the Blume-Emery-Griffiths model in the presence of an external magnetic field. The thermal behaviors of the order parameters and different macroscopic instabilities as well as the hysteretic behavior of the material are examined in great detail as a function of the dopant density. It is found that the impurities concentration affects all the system magnetic properties generating for some specific values, compensation points and multi-cycle hysteresis. Doping conditions where the saturation/remanent magnetization and coercive field of the investigated material can be modified for permanent or soft magnets synthesis purpose are discussed.展开更多
The Ti-doped waveguide-type periodically poled LiNbO_(3)(PPLN)were fabricated and the dependence of domain wall velocity on an external field applied for domain inversion was investigated.The whole polarization revers...The Ti-doped waveguide-type periodically poled LiNbO_(3)(PPLN)were fabricated and the dependence of domain wall velocity on an external field applied for domain inversion was investigated.The whole polarization reversal process was computer-controlled to regulate domain wall expansion at a feedback time shorter than 5μs.The coercive voltage and several values of excess voltage were applied on 500μm-thick wafers serially connected to a 1-MOhm external resistor which had an effect of the poling current reduction,i.e.the deceleration of domain wall expansion.The domain wall velocity is sensitive to the poling voltage,precisely speaking,to the excess voltage.The domain wall velocities were 28.70,16.02 and 5.75μm·s^(-1)under poling field of 23.5,22.0 and 21.0 kV·mm^(-1),respectively.Moreover,average duty cycle of PPLN is about 49.93%.展开更多
Magnetic properties of composites prepared by coating lacquer containing neodymium iron boron (Nd-Fe-B) powders on rubberwood were characterized by vibrating sample magnetometry (VSM), magnetic moment measurements...Magnetic properties of composites prepared by coating lacquer containing neodymium iron boron (Nd-Fe-B) powders on rubberwood were characterized by vibrating sample magnetometry (VSM), magnetic moment measurements, and attraction tests with an iron-core solenoid. The Nd-Fe-B powders were recycled from electronic wastes by the ball-milling technique. Varying the milling time from 20 to 300 min, the magnetic squareness and the coercive field of the Nd-Fe-B powders were at the minimum when the powders were milled for 130 rain. It followed that the coercive field of the magnetic wood composites was increased with the milling time increasing from 130 to 300 min. For the magnetic wood composites using Nd-Fe-B obtained from the same milling time, the magnetic squareness and the coercive field were rather insensitive to the variation of Nd-Fe-B concentration in coating lacquer from 0.43 to 1.00 g/cm3. By contrast, the magnetization and magnetic moment were increased with the Nd-Fe-B concentration increasing. Furthermore, the electrical current in the solenoid required for the attraction of the magnetic wood composites was exponentially reduced with the increase in the amount of Nd-Fe-B used in the coating.展开更多
The Monte Carlo simulation is used to investigate the magnetic properties of ferromagnetic superlattices through the Ising model. The reduced critical temperatures of the ferromagnetic superlattices are studied each a...The Monte Carlo simulation is used to investigate the magnetic properties of ferromagnetic superlattices through the Ising model. The reduced critical temperatures of the ferromagnetic superlattices are studied each as a function of layer thickness for different values of exchange interaction. The exchange interaction in each layer within the interface and the crystal field in the unit cell are studied. The magnetic coercive fields and magnetization remnants are obtained for different values of exchange interaction, different values of temperature and crystal field with fixed values of physical parameters.展开更多
The [001]c-polarized(1-x)Pb(Mg1/3Nb2/3)O3–xPbTiO3(PMN-PT) single crystals are widely used in ultrasonic detection transducers and underwater acoustic sensors. However, the relatively small coercive field( 2 kV/cm) of...The [001]c-polarized(1-x)Pb(Mg1/3Nb2/3)O3–xPbTiO3(PMN-PT) single crystals are widely used in ultrasonic detection transducers and underwater acoustic sensors. However, the relatively small coercive field( 2 kV/cm) of such crystals restricts their application at high frequencies because the driving field will exceed the coercive field. The depolarization field can be considerably larger in an antiparallel direction than in a parallel direction with respect to polarization when the bipolar driving cycle starts. Thus, if the direction of the sine wave signal in the first half cycle is opposite to the polarization direction, then the depolarized domains can be repolarized in the second half of the sine cycle. However, if the direction of the sine wave signal in the first half of the cycle is along the polarization direction, then the change is negligible,and the domains switched in the second half of the sine cycle cannot be recovered. The design of electric driving method needs to allow the use of a large applied field to emit strong enough signals and produce good images. This phenomenon combined with the coercive field increases with the driving frequency, thereby making the PMN-PT single crystals usable for high-frequency applications. As such, the applied field can be considerably larger than the conventionally defined coercive field.展开更多
The magnetic properties of (Cox Fe1-x)A (Zn1-x Fe1+x)B O4 are studied using mean-field theory and the probability distribution law to obtain the saturation magnetization, the coercive field, the critical temperat...The magnetic properties of (Cox Fe1-x)A (Zn1-x Fe1+x)B O4 are studied using mean-field theory and the probability distribution law to obtain the saturation magnetization, the coercive field, the critical temperature, and the exchange interactions with different values of D (nm) and x. High-temperature series expansions (HTSEs) combined with the Pade approximant are used to calculate the critical temperature of (CoxFe1-x)A(Znl-xFe1+x)BO4, and the critical exponent associated with magnetic susceptibility is obtained.展开更多
Ferroelectric polymers,such as poly(vinylidene fluoride-trifluoroethylene)[P(VDF-TrFE)or PVTF]have attracted growing interest in developing flexible devices because of their excellent ferroelectricity and piezoelectri...Ferroelectric polymers,such as poly(vinylidene fluoride-trifluoroethylene)[P(VDF-TrFE)or PVTF]have attracted growing interest in developing flexible devices because of their excellent ferroelectricity and piezoelectricity.High coercive field(E c)inherent to PVTF for switching its polarization,however,is not beneficial for practical memory or sensor device application.Different strategies,including irradiation and interface control,have been thus developed to reduce E c.Despite many efforts,a facile approach to tailoring intrinsic E_(c) of PVTF has not been documented.In this work,an optically controlled E_(c) was reported,which is achieved for the first time by introducing photosensitive MAPbI3 nanocrystals into PVTF matrix.When exposed to the irradiation of 532 nm laser light,a decreased E_(c) of the composites can be achieved reversibly by increasing the light density.The decreased level of E_(c) increases as the MAPbI3 content enhanced,and a 10.7%reduction of E_(c) can be achieved in 15%(mass fraction)MAPbI3/PVTF samples.These results could be attributed to loading an internal stress on PVTF,which was generated by the photostriction of MAPbI3 nanocrystals.This explanation was further supported by in-situ XRD results under irradiation of 532 nm laser light.Our findings may offer the opportunity to optically modulate the ferroelectric properties of PVTF composites for optimized device performances.展开更多
Ferroelectric Ba0.65Sr0.35TiO3 (BST) thin films on the Pt/Ti/SiO2/Si substrate have been successfully prepared by sol-gel. Such films have approximately 300 nm thicknesses with a remnant polarization of about 2.95 ...Ferroelectric Ba0.65Sr0.35TiO3 (BST) thin films on the Pt/Ti/SiO2/Si substrate have been successfully prepared by sol-gel. Such films have approximately 300 nm thicknesses with a remnant polarization of about 2.95 μ℃/cm^2 and a coercive field of about 21.5 kV/cm. The investigations of X-ray diffraction and atomic force microscopy show that the BST films annealed at 650 ℃ exhibit a tetragonal structure and that the films dominantly consist of large column or grains of about 89 nm in diameter. The curves of the temperature dependence of dielectric coefficient in different frequencies display the curie transition at the temperature around 23 ℃. The dielectric loss tangent of BST thin fdms at 100 kHz is less than 0.04. As a result, the BST thin films are more applicable for fabrication of infrared detector compared with the BST thin films reported previously.展开更多
Two-dimensional(2D)ferroelectric materials with unique structure and extraordinary optoelectrical properties have attracted intensive research in the field of nanoelectronic and optoelectronic devices,such as optical ...Two-dimensional(2D)ferroelectric materials with unique structure and extraordinary optoelectrical properties have attracted intensive research in the field of nanoelectronic and optoelectronic devices,such as optical sensors,transistors,photovoltaics and non-volatile memory devices.However,the transition temperature of the reported ferroelectrics in 2D limit is generally low or slightly above room temperature,hampering their applications in high-temperature electronic devices.Here,we report the robust high-temperature ferroelectricity in 2D a-In2Se3,grown by chemical vapor depostion(CVD),exhibiting an out-of-plane spontaneous polarization reaching above 200℃.The polarization switching and ferroelectric domains are observed in In2Se;nanoflakes in a wide temperature range.The coercive field of the CVD grown ferroelectric layers ilustrates a room-temperature thickness dependency and increases drastically when the film thickness decreases;whereas there is no large variance in the coercive field at dfterent termperature from the samples with identical thickness.The results show the stable ferroelectricit of In2Se3 nanoflakes maintained at high temperature and open up the opportunities of 2D materials for novel applications in high-temperature nanoelectronic devices.展开更多
With the use of techniques of SawyerTower and Mertz method regularities of the origin of "fatigue"in thin ferroelectric films of lead titanate and lead zirconate titanate have been investigated in the field...With the use of techniques of SawyerTower and Mertz method regularities of the origin of "fatigue"in thin ferroelectric films of lead titanate and lead zirconate titanate have been investigated in the fields above coercive.We propose a model to explain the experimentally observed switching-dependent fatigue processes by the motion of charged dislocations in an applied external alternating electric field.展开更多
Binary piezoelectric crystal Pb(Mg_(1/3)Nb_(2/3))O_(3)–PbTiO_(3)(PMN–PT)has excellent dielectric and piezoelectric properties,which has led to the commercialization for medical ultrasound imaging.Recently,there is a...Binary piezoelectric crystal Pb(Mg_(1/3)Nb_(2/3))O_(3)–PbTiO_(3)(PMN–PT)has excellent dielectric and piezoelectric properties,which has led to the commercialization for medical ultrasound imaging.Recently,there is a growing demand for piezoelectric crystals with improved thermal and electrical properties.Ternary piezoelectric crystals Pb(In_(1/2)Nb_(1/2))O_(3)–Pb(Mg_(1/3)Nb_(2/3))O_(3)–PbTiO_(3)(PIN–PMN–PT)have increased depoling temperature and coercive field than binary PMN–PT.To better understand the ternary crystal system and improve crystal properties,we systematically investigated crystal growth of PIN–PMN–PT with modified Bridgman method.Like PMN–PT,PIN–PMN–PT crystals have excellent piezoelectric properties(e.g.,k_(33)0:87–0.92,d_(33)1000–2200 pm/V).Higher PIN content leads to40C increase in depoling temperature and more than doubling of coercive field(7.0 kV/cm).Such improvements are advantageous for applications where high temperature and/or high-drive are needed.展开更多
文摘The effect of spin-1 impurities doping on the magnetic properties of a spin-3/2 Ising nanotube is investigated using Monte Carlo simulations within the Blume-Emery-Griffiths model in the presence of an external magnetic field. The thermal behaviors of the order parameters and different macroscopic instabilities as well as the hysteretic behavior of the material are examined in great detail as a function of the dopant density. It is found that the impurities concentration affects all the system magnetic properties generating for some specific values, compensation points and multi-cycle hysteresis. Doping conditions where the saturation/remanent magnetization and coercive field of the investigated material can be modified for permanent or soft magnets synthesis purpose are discussed.
文摘The Ti-doped waveguide-type periodically poled LiNbO_(3)(PPLN)were fabricated and the dependence of domain wall velocity on an external field applied for domain inversion was investigated.The whole polarization reversal process was computer-controlled to regulate domain wall expansion at a feedback time shorter than 5μs.The coercive voltage and several values of excess voltage were applied on 500μm-thick wafers serially connected to a 1-MOhm external resistor which had an effect of the poling current reduction,i.e.the deceleration of domain wall expansion.The domain wall velocity is sensitive to the poling voltage,precisely speaking,to the excess voltage.The domain wall velocities were 28.70,16.02 and 5.75μm·s^(-1)under poling field of 23.5,22.0 and 21.0 kV·mm^(-1),respectively.Moreover,average duty cycle of PPLN is about 49.93%.
基金supported by Molecular Technology Research Unit, Walailak University and Department of Physics, Kasetsart University
文摘Magnetic properties of composites prepared by coating lacquer containing neodymium iron boron (Nd-Fe-B) powders on rubberwood were characterized by vibrating sample magnetometry (VSM), magnetic moment measurements, and attraction tests with an iron-core solenoid. The Nd-Fe-B powders were recycled from electronic wastes by the ball-milling technique. Varying the milling time from 20 to 300 min, the magnetic squareness and the coercive field of the Nd-Fe-B powders were at the minimum when the powders were milled for 130 rain. It followed that the coercive field of the magnetic wood composites was increased with the milling time increasing from 130 to 300 min. For the magnetic wood composites using Nd-Fe-B obtained from the same milling time, the magnetic squareness and the coercive field were rather insensitive to the variation of Nd-Fe-B concentration in coating lacquer from 0.43 to 1.00 g/cm3. By contrast, the magnetization and magnetic moment were increased with the Nd-Fe-B concentration increasing. Furthermore, the electrical current in the solenoid required for the attraction of the magnetic wood composites was exponentially reduced with the increase in the amount of Nd-Fe-B used in the coating.
文摘The Monte Carlo simulation is used to investigate the magnetic properties of ferromagnetic superlattices through the Ising model. The reduced critical temperatures of the ferromagnetic superlattices are studied each as a function of layer thickness for different values of exchange interaction. The exchange interaction in each layer within the interface and the crystal field in the unit cell are studied. The magnetic coercive fields and magnetization remnants are obtained for different values of exchange interaction, different values of temperature and crystal field with fixed values of physical parameters.
基金Project supported by the National Natural Science Foundation of China(Grant No.11674270)the Fundamental Research Funds for Xiamen University,China(Grant No.20720180113)+2 种基金the Education and Scientific Research Project for Young and Middle-aged Teachers of Fujian Province,China(Grant No.JAT170036)the Opening Fund of Acoustics Science and Technology Laboratory,China(Grant No.SSKF2018006)sponsored by the Education Department of Fujian Province,China for his study at the Pennsylvania State University(Grant No.2016071145)
文摘The [001]c-polarized(1-x)Pb(Mg1/3Nb2/3)O3–xPbTiO3(PMN-PT) single crystals are widely used in ultrasonic detection transducers and underwater acoustic sensors. However, the relatively small coercive field( 2 kV/cm) of such crystals restricts their application at high frequencies because the driving field will exceed the coercive field. The depolarization field can be considerably larger in an antiparallel direction than in a parallel direction with respect to polarization when the bipolar driving cycle starts. Thus, if the direction of the sine wave signal in the first half cycle is opposite to the polarization direction, then the depolarized domains can be repolarized in the second half of the sine cycle. However, if the direction of the sine wave signal in the first half of the cycle is along the polarization direction, then the change is negligible,and the domains switched in the second half of the sine cycle cannot be recovered. The design of electric driving method needs to allow the use of a large applied field to emit strong enough signals and produce good images. This phenomenon combined with the coercive field increases with the driving frequency, thereby making the PMN-PT single crystals usable for high-frequency applications. As such, the applied field can be considerably larger than the conventionally defined coercive field.
文摘The magnetic properties of (Cox Fe1-x)A (Zn1-x Fe1+x)B O4 are studied using mean-field theory and the probability distribution law to obtain the saturation magnetization, the coercive field, the critical temperature, and the exchange interactions with different values of D (nm) and x. High-temperature series expansions (HTSEs) combined with the Pade approximant are used to calculate the critical temperature of (CoxFe1-x)A(Znl-xFe1+x)BO4, and the critical exponent associated with magnetic susceptibility is obtained.
基金Natural Science Foundation of Zhejiang Province,China(No.LR21E020004)National Natural Science Foundation of China(No.U1909212)Project of the Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering,China(No.2021SX-FR007).
文摘Ferroelectric polymers,such as poly(vinylidene fluoride-trifluoroethylene)[P(VDF-TrFE)or PVTF]have attracted growing interest in developing flexible devices because of their excellent ferroelectricity and piezoelectricity.High coercive field(E c)inherent to PVTF for switching its polarization,however,is not beneficial for practical memory or sensor device application.Different strategies,including irradiation and interface control,have been thus developed to reduce E c.Despite many efforts,a facile approach to tailoring intrinsic E_(c) of PVTF has not been documented.In this work,an optically controlled E_(c) was reported,which is achieved for the first time by introducing photosensitive MAPbI3 nanocrystals into PVTF matrix.When exposed to the irradiation of 532 nm laser light,a decreased E_(c) of the composites can be achieved reversibly by increasing the light density.The decreased level of E_(c) increases as the MAPbI3 content enhanced,and a 10.7%reduction of E_(c) can be achieved in 15%(mass fraction)MAPbI3/PVTF samples.These results could be attributed to loading an internal stress on PVTF,which was generated by the photostriction of MAPbI3 nanocrystals.This explanation was further supported by in-situ XRD results under irradiation of 532 nm laser light.Our findings may offer the opportunity to optically modulate the ferroelectric properties of PVTF composites for optimized device performances.
文摘Ferroelectric Ba0.65Sr0.35TiO3 (BST) thin films on the Pt/Ti/SiO2/Si substrate have been successfully prepared by sol-gel. Such films have approximately 300 nm thicknesses with a remnant polarization of about 2.95 μ℃/cm^2 and a coercive field of about 21.5 kV/cm. The investigations of X-ray diffraction and atomic force microscopy show that the BST films annealed at 650 ℃ exhibit a tetragonal structure and that the films dominantly consist of large column or grains of about 89 nm in diameter. The curves of the temperature dependence of dielectric coefficient in different frequencies display the curie transition at the temperature around 23 ℃. The dielectric loss tangent of BST thin fdms at 100 kHz is less than 0.04. As a result, the BST thin films are more applicable for fabrication of infrared detector compared with the BST thin films reported previously.
基金the grant from Research Grants Council of Hong Kong(GRF No.PolyU 153033/17P).
文摘Two-dimensional(2D)ferroelectric materials with unique structure and extraordinary optoelectrical properties have attracted intensive research in the field of nanoelectronic and optoelectronic devices,such as optical sensors,transistors,photovoltaics and non-volatile memory devices.However,the transition temperature of the reported ferroelectrics in 2D limit is generally low or slightly above room temperature,hampering their applications in high-temperature electronic devices.Here,we report the robust high-temperature ferroelectricity in 2D a-In2Se3,grown by chemical vapor depostion(CVD),exhibiting an out-of-plane spontaneous polarization reaching above 200℃.The polarization switching and ferroelectric domains are observed in In2Se;nanoflakes in a wide temperature range.The coercive field of the CVD grown ferroelectric layers ilustrates a room-temperature thickness dependency and increases drastically when the film thickness decreases;whereas there is no large variance in the coercive field at dfterent termperature from the samples with identical thickness.The results show the stable ferroelectricit of In2Se3 nanoflakes maintained at high temperature and open up the opportunities of 2D materials for novel applications in high-temperature nanoelectronic devices.
文摘With the use of techniques of SawyerTower and Mertz method regularities of the origin of "fatigue"in thin ferroelectric films of lead titanate and lead zirconate titanate have been investigated in the fields above coercive.We propose a model to explain the experimentally observed switching-dependent fatigue processes by the motion of charged dislocations in an applied external alternating electric field.
基金supported by ONR contracts N00014-C and N00014-M,and HC-R&D fund-2001-13.
文摘Binary piezoelectric crystal Pb(Mg_(1/3)Nb_(2/3))O_(3)–PbTiO_(3)(PMN–PT)has excellent dielectric and piezoelectric properties,which has led to the commercialization for medical ultrasound imaging.Recently,there is a growing demand for piezoelectric crystals with improved thermal and electrical properties.Ternary piezoelectric crystals Pb(In_(1/2)Nb_(1/2))O_(3)–Pb(Mg_(1/3)Nb_(2/3))O_(3)–PbTiO_(3)(PIN–PMN–PT)have increased depoling temperature and coercive field than binary PMN–PT.To better understand the ternary crystal system and improve crystal properties,we systematically investigated crystal growth of PIN–PMN–PT with modified Bridgman method.Like PMN–PT,PIN–PMN–PT crystals have excellent piezoelectric properties(e.g.,k_(33)0:87–0.92,d_(33)1000–2200 pm/V).Higher PIN content leads to40C increase in depoling temperature and more than doubling of coercive field(7.0 kV/cm).Such improvements are advantageous for applications where high temperature and/or high-drive are needed.