Tunneling Electrons Triggered Energy Transfer between Coherently Coupled Donor-Acceptor Molecules

Energy transfer is ubiquitous in natural and artificial lightharvesting systems,and coherent energy transfer,a highly efficient energy transfer process,has been accepted to play a vital role in such systems.However,the energy oscillation of coherent energy transfer is exceedingly difficult to capture because of its evanescence due to the interaction with a thermal environment.Here a microscopic quantum model is used to study the time evolution of electrons triggered energy transfer between coherently coupled donoracceptor molecules in scanning tunneling microscope(STM).A series of topics in the plasmonic nanocavity(PNC)coupled donor-acceptor molecules system are discussed,including resonant and nonresonant coherent energy transfer,dephasing assisted energy transfer,PNC coupling strength dependent energy transfer,Fano resonance of coherently coupled donor-acceptor molecules,and polariton-mediated energy transfer.

Coherent Features of Resonance-Mediated Two-Photon Absorption Enhancement by Varying the Energy Level Structure,Laser Spectrum Bandwidth and Central Frequency

The femtosecond pulse shaping technique has been shown to be an effective method to control the multi-photon absorption by the light–matter interaction. Previous studies mainly focused on the quantum coherent control of the multi-photon absorption by the phase, amplitude and polarization modulation, but the coherent features of the multi-photon absorption depending on the energy level structure, the laser spectrum bandwidth and laser central frequency still lack in-depth systematic research. In this work, we further explore the coherent features of the resonance-mediated two-photon absorption in a rubidium atom by varying the energy level structure, spectrum bandwidth and central frequency of the femtosecond laser field. The theoretical results show that the change of the intermediate state detuning can effectively influence the enhancement of the near-resonant part, which further affects the transform-limited （TL）-normalized final state population maximum. Moreover, as the laser spectrum bandwidth increases, the TL-normalized final state population maximum can be effectively enhanced due to the increase of the enhancement in the near-resonant part, but the TL-normalized final state population maximum is constant by varying the laser central frequency. These studies can provide a clear physical picture for understanding the coherent features of the resonance-mediated two-photon absorption, and can also provide a theoretical guidance for the future applications.

Coherent and incoherent internal tides in the southern South China Sea

Coherent and incoherent internal tides(CITs and ICITs) in the southern South China Sea were investigated from two sets of _18-month mooring current records. The CITs were mainly composed of diurnal Q _1, O _1, P _1 and K _1 and semidiurnal M_2. The observed diurnal internal tides(ITs) were more coherent than the semidiurnal constituents. Coherent diurnal variance accounted for approximately 58% of the diurnal motion, whereas semidiurnal tides contained a much smaller fraction(35%) of coherent motion. The ICITs mainly consisted of motion at non-tidal harmonic frequencies around the tidal frequency, and showed clear intermittency. The modal decomposition of CITs and ICITs showed that CITs were dominated by mode-1, whereas mode-1 and higher modes in ICITs signals showed comparable amplitudes. CITs and ICITs accounted for approximately 64% and 36% of the total kinetic energy of internal tides, respectively.

Phonon-assisted excitation energy transfer in photosynthetic systems

The phonon-assisted process of energy transfer aiming at exploring the newly emerging frontier between biology and physics is an issue of central interest.This article shows the important role of the intramolecular vibrational modes for excitation energy transfer in the photosynthetic systems.Based on a dimer system consisting of a donor and an acceptor modeled by two two-level systems,in which one of them is coupled to a high-energy vibrational mode,we derive an effective Hamiltonian describing the vibration-assisted coherent energy transfer process in the polaron frame.The effective Hamiltonian reveals in the case that the vibrational mode dynamically matches the energy detuning between the donor and the acceptor,the original detuned energy transfer becomes resonant energy transfer.In addition,the population dynamics and coherence dynamics of the dimer system with and without vibration-assistance are investigated numerically.It is found that,the energy transfer efficiency and the transfer time depend heavily on the interaction strength of the donor and the high-energy vibrational mode,as well as the vibrational frequency.The numerical results also indicate that the initial state and dissipation rate of the vibrational mode have little influence on the dynamics of the dimer system.Results obtained in this article are not only helpful to understand the natural photosynthesis,but also offer an optimal design principle for artificial photosynthesis.

Stable optical vortices in nonlinear multicore fibers

The multicore fiber(MCF)is a physical system of high practical importance.In addition to standard exploitation,MCFs may support discrete vortices that carry orbital angular momentum suitable for spatial-division multiplexing in high-capacity fiber-optic communication systems.These discrete vortices may also be attractive for high-power laser applications.We present the conditions of existence,stability,and coherent propagation of such optical vortices for two practical MCF designs.Through optimization,we found stable discrete vortices that were capable of transferring high coherent power through the MCF.