The eutectic ionic liquid(EIL) tetraethyl ammonium bromide-malonic acid(TEAB-Mal) was synthesized, with its structure characterized by the FT-IR spectroscopy and the 1 H NMR spectrometry. The performance for removal o...The eutectic ionic liquid(EIL) tetraethyl ammonium bromide-malonic acid(TEAB-Mal) was synthesized, with its structure characterized by the FT-IR spectroscopy and the 1 H NMR spectrometry. The performance for removal of basic nitrogen compounds by EIL was studied using coker diesel as the feedstock. Experimental results showed that the EIL(TEAB-Mal) exhibited a good denitrogenation performance, leading to a 93.6% of basic N-removal efficiency under reaction conditions covering: a temperature of 30 °C, an EIL to oil mass ratio of 1:1, an extraction time of 30 min, and a settling time of 120 min, while the basic nitrogen content in diesel dropped from 580 μg/g to 37 μg/g. In addition, the efficiency for extraction of basic N-compounds could still reach 62.9% at an EIL/oil mass ratio of 1:7 after four recycles of the EIL.展开更多
An inexpensive coordinated ionic liquid NMP-0.5ZnCl_(2) was synthesized by reacting N-methyl-pyrrolidone with anhydrous ZnCl_(2),and its structure was characterized with FT-IR spectroscopy.The performance of IL for re...An inexpensive coordinated ionic liquid NMP-0.5ZnCl_(2) was synthesized by reacting N-methyl-pyrrolidone with anhydrous ZnCl_(2),and its structure was characterized with FT-IR spectroscopy.The performance of IL for removing basic nitrogen compounds from model oil containing quinoline and actual coker diesel was studied.Experimental results showed that the IL,NMP-0.5ZnCl_(2),exhibited a good denitrogenation performance,which can be attributed to its low viscosity and unoccupied orbitals of Zn ion,while obtaining a 99.68%quinoline removal efficiency under conditions covering a temperature of 50℃,an IL/model oil mass ratio of 1:2,and a reaction time of 30 min.In the case of coker diesel,above a 91%basic N-removal efficiency(with N-content reduced from 536μg/g to 47μg/g)was realized by the IL after 5-stage extraction.Moreover,the quinoline extraction efficiency could still reach 96.73%during four recycles of the IL.展开更多
以过氧化氢-有机酸体系作氧化剂,采用氧化反应与溶剂萃取相结合的方法,对焦化柴油进行了氧化脱氮研究。考察了不同的氧化体系、氧化温度、氧化时间、氧化剂油比和萃取剂、萃取温度、萃取时间、萃取剂油比对焦化柴油中氮化物脱除效果的...以过氧化氢-有机酸体系作氧化剂,采用氧化反应与溶剂萃取相结合的方法,对焦化柴油进行了氧化脱氮研究。考察了不同的氧化体系、氧化温度、氧化时间、氧化剂油比和萃取剂、萃取温度、萃取时间、萃取剂油比对焦化柴油中氮化物脱除效果的影响。结果表明,最适宜的氧化脱氮条件为:过氧化氢-甲酸作为氧化体系,氧化温度为70℃,氧化时间为1 m in,剂油体积比为0.24,V(过氧化氢)/V(有机酸)=0.5。萃取实验条件为:在室温条件下,萃取剂油比为0.8,搅拌5 m in。精制后,柴油回收率达93.33%,总氮脱除率为94.69%。展开更多
基金the financial support from the Doctoral Funds of Liaoning Provincial Natural Science Foundation(201601323)
文摘The eutectic ionic liquid(EIL) tetraethyl ammonium bromide-malonic acid(TEAB-Mal) was synthesized, with its structure characterized by the FT-IR spectroscopy and the 1 H NMR spectrometry. The performance for removal of basic nitrogen compounds by EIL was studied using coker diesel as the feedstock. Experimental results showed that the EIL(TEAB-Mal) exhibited a good denitrogenation performance, leading to a 93.6% of basic N-removal efficiency under reaction conditions covering: a temperature of 30 °C, an EIL to oil mass ratio of 1:1, an extraction time of 30 min, and a settling time of 120 min, while the basic nitrogen content in diesel dropped from 580 μg/g to 37 μg/g. In addition, the efficiency for extraction of basic N-compounds could still reach 62.9% at an EIL/oil mass ratio of 1:7 after four recycles of the EIL.
基金The authors are grateful for financial support from the Doctoral Funds of Liaoning Provincial Natural Science Foundation(201601323)the Research Startup Foundation of Liaoning Petrochemical University(2019xJJ-006).
文摘An inexpensive coordinated ionic liquid NMP-0.5ZnCl_(2) was synthesized by reacting N-methyl-pyrrolidone with anhydrous ZnCl_(2),and its structure was characterized with FT-IR spectroscopy.The performance of IL for removing basic nitrogen compounds from model oil containing quinoline and actual coker diesel was studied.Experimental results showed that the IL,NMP-0.5ZnCl_(2),exhibited a good denitrogenation performance,which can be attributed to its low viscosity and unoccupied orbitals of Zn ion,while obtaining a 99.68%quinoline removal efficiency under conditions covering a temperature of 50℃,an IL/model oil mass ratio of 1:2,and a reaction time of 30 min.In the case of coker diesel,above a 91%basic N-removal efficiency(with N-content reduced from 536μg/g to 47μg/g)was realized by the IL after 5-stage extraction.Moreover,the quinoline extraction efficiency could still reach 96.73%during four recycles of the IL.
文摘以过氧化氢-有机酸体系作氧化剂,采用氧化反应与溶剂萃取相结合的方法,对焦化柴油进行了氧化脱氮研究。考察了不同的氧化体系、氧化温度、氧化时间、氧化剂油比和萃取剂、萃取温度、萃取时间、萃取剂油比对焦化柴油中氮化物脱除效果的影响。结果表明,最适宜的氧化脱氮条件为:过氧化氢-甲酸作为氧化体系,氧化温度为70℃,氧化时间为1 m in,剂油体积比为0.24,V(过氧化氢)/V(有机酸)=0.5。萃取实验条件为:在室温条件下,萃取剂油比为0.8,搅拌5 m in。精制后,柴油回收率达93.33%,总氮脱除率为94.69%。
