The planetary boundary layer turbulence and moist convection parameterizations have been modified recently in the NASA Goddard Institute for Space Studies (GISS) Model E2 atmospheric general circulation model (GCM;...The planetary boundary layer turbulence and moist convection parameterizations have been modified recently in the NASA Goddard Institute for Space Studies (GISS) Model E2 atmospheric general circulation model (GCM; post-CMIP5, hereafter P5). In this study, single column model (SCM_P5) simulated cloud fractions (CFs), cloud liquid water paths (LWPs) and precipitation were compared with Atmospheric Radiation Measurement (ARM) Southern Great Plains (SGP) groundbased observations made during the period 2002-08. CMIP5 SCM simulations and GCM outputs over the ARM SGP region were also used in the comparison to identify whether the causes of cloud and precipitation biases resulted from either the physical parameterization or the dynamic scheme. The comparison showed that the CMIP5 SCM has difficulties in simulating the vertical structure and seasonal variation of low-level clouds. The new scheme implemented in the turbulence parameterization led to significantly improved cloud simulations in P5. It was found that the SCM is sensitive to the relaxation time scale. When the relaxation time increased from 3 to 24 h, SCM_P5-simulated CFs and LWPs showed a moderate increase (10%-20%) but precipitation increased significantly (56%), which agreed better with observations despite the less accurate atmospheric state. Annual averages among the GCM and SCM simulations were almost the same, but their respective seasonal variations were out of phase. This suggests that the same physical cloud parameterization can generate similar statistical results over a long time period, but different dynamics drive the differences in seasonal variations. This study can potentially provide guidance for the further development of the GISS model.展开更多
A single column model (SCM) is constructed by extracting the physical subroutines from the NCAR Community Climate Model version 1 (CCM1).Simulated data are generated by CCM1 and used to validate the SCM and to study t...A single column model (SCM) is constructed by extracting the physical subroutines from the NCAR Community Climate Model version 1 (CCM1).Simulated data are generated by CCM1 and used to validate the SCM and to study the sensitivity of the SCM to errors in its input data.It is found that the SCM temperature predictions are moderately sensitive to errors in the input horizontal temperature flux convergence and moisture flux convergence.Two types of error are concerned in this study,random errors due to insufficient data resolution,and errors due to insufficient data area coverage.While the first type of error can be reduced by filtering and/or increasing the data resolution,it is shown that the second type of error can be reduced by enlarging the data area coverage and using a suitable method to compute the input flux convergence terms.展开更多
It is presented that there is a pumping effect at its base in the development process of a cumulus.In the strongest stage of cumulus development,the pumping is mainly produced by the buoyance at the base,and may be ta...It is presented that there is a pumping effect at its base in the development process of a cumulus.In the strongest stage of cumulus development,the pumping is mainly produced by the buoyance at the base,and may be taken as the first approximation of the ascending speed at the base. The results of numerical calculations and simulations of four observed radar echoes show that as the first approximation,the height of air-mass cumulus may be simulated by Haltiner model in the absence of ob- served ascending speeds at the base,and the Haltiner model can be characterized by the sensitivity of the cumulus development to the virtual temperature excess over environment at the base.展开更多
A unique cyclonic static microbubble flotation column was developed for oily wastewater separation.The separation effciency was found to be highly dependent on gas holdup and bubble size distribution.By changing the c...A unique cyclonic static microbubble flotation column was developed for oily wastewater separation.The separation effciency was found to be highly dependent on gas holdup and bubble size distribution.By changing the circulation pressure,gas flow rate,frother concentration,the effect of operation parameters on gas holdup and oil removal effciency were attained.A mathematical modeling between the kinetic constant and the gas holdup was established for oily water separation process.The results show that higher gas holdup and smaller microbubble sizes are benefcial to improve oil removal effciency.展开更多
A single-column model is constructed based on parameterizations inherited from the Finite-volume/Spectral Atmospheric Model F/SAMIL and tested in simulations of tropical convective systems. Two representative convecti...A single-column model is constructed based on parameterizations inherited from the Finite-volume/Spectral Atmospheric Model F/SAMIL and tested in simulations of tropical convective systems. Two representative convection schemes are compared in terms of their performances on precipitation types, individual physical tendencies, and temperature and moisture fields. The main difference between the two selected schemes is in their representation of entraining/detraining process. The Tiedtke scheme assumes bulk entrainment, while the Zhang–Mc Farlane scheme parameterizes entrainment/detrainment rates under the spectrum concept. Large-scale forcing and verification data are taken from the GATE phase III field campaign, during which abundant convective events were observed. Given the same triggering function and closure assumption, results show that entrainment/detrainment representation remains the dominant factor on the simulation of cumulus mass flux and of temperature and moisture fields. By analyzing sources and sinks of heat and moisture, this study reveals how parameterization components compensate for each other and make model results insensitive to parameterization changes in certain fields, thus suggesting the need to treat parameterizations as systems rather than individual components.展开更多
The flow field of liquid phase (water) of agitated extraction columns is simulated with the help of computational fluid dynamics (CFD). Four kinds of Reynolds-averaged turbulence models, i.e. the standard k-ε model, ...The flow field of liquid phase (water) of agitated extraction columns is simulated with the help of computational fluid dynamics (CFD). Four kinds of Reynolds-averaged turbulence models, i.e. the standard k-ε model, the RNG (renormaiization group) k-ε model, the realizable k-ε model and the Reynolds stress model, are compared in detail in order to judge which is the best model in terms of the accuracy, less CPU time and memory required. The performance of the realizable k-ε model is obviously improved by reducing the model constant from c2 = 1.90 to c2 = 1.61. It is concluded that the improved realizable k-ε model is the optimal model.展开更多
The high degree of reversibility of heat integrated distillation column(HIDiC) has been thermodynamically interpreted by the entropy method. In this paper, a heat transfer model and a more universal method were propos...The high degree of reversibility of heat integrated distillation column(HIDiC) has been thermodynamically interpreted by the entropy method. In this paper, a heat transfer model and a more universal method were proposed, through which the overall heat transfer coefficient at different height of column under different operating conditions could be obtained before the experiment. Then the separation of a binary ethanol-water system was carried out experimentally as a case study to verify the heat transfer model and the aforementioned calculation method. The close results between the calculation, the simulation, and the experiments suggested that the proposed model and the calculation method in this paper were accurate and applicable. Meanwhile, it was demonstrated that the HIDiC shows obvious effect of reducing entropy increase and improving thermodynamic efficiency as compared to conventional distillation column.展开更多
To optimize industrial Fischer–Tropsch(FT) synthesis with the slurry bubble column reactor(SBCR) and ironbased catalyst, a comprehensive process model for FT synthesis that includes a detailed SBCR model, gas liquid ...To optimize industrial Fischer–Tropsch(FT) synthesis with the slurry bubble column reactor(SBCR) and ironbased catalyst, a comprehensive process model for FT synthesis that includes a detailed SBCR model, gas liquid separation model, simplified CO_2 removal model and tail gas cycle model was developed. An effective iteration algorithm was proposed to solve this process model, and the model was validated by industrial demonstration experiments data(SBCR with 5.8 m diameter and 30 m height), with a maximum relative error b 10% for predicting the SBCR performances. Subsequently, the proposed model was adopted to optimize the industrial SBCR performances simultaneously considering process and reactor parameters variations. The results show that C_(5+) yield increases as catalyst loading increases within 10–70 ton and syngas H_2/CO value decreases within1.3–1.6, but it doesn't increase obviously when the catalyst loading exceeds 45 ton(about 15 wt% concentration).Higher catalyst loading will result in higher difficulty for wax/catalyst separation and higher catalyst cost. Therefore, the catalyst loading(45 ton) is recommended for the industrial demonstration SBCR operation at syngas H_2/CO = 1.3, and the C_(5+) yield is about 402 ton" per day, which has an about 16% increase than the industrial demonstration run result.展开更多
Based on a series of previous studies, an experiment on the integral seismic behavior of a 1/3 scaled model of two-bay and three-story reinforced concrete frame with split columns at lower two stories is performed und...Based on a series of previous studies, an experiment on the integral seismic behavior of a 1/3 scaled model of two-bay and three-story reinforced concrete frame with split columns at lower two stories is performed under cyclic loading. The original columns at lower two stories of the model frame are short columns and they are replaced by the split columns. The hysteresis curves between the horizontal cyclic load and the lateral displacement at the top of the model frame, indicate that under the cyclic loading, the model frame undergoes the process of cracking, yielding, and maximum loading before being destroyed at the ultimate load. They also indicate that the model frame has better ductility, and the ratio of the ultimate displacement to the yielding displacement, reaches 6.0. The yielding process of the model frame shows that for the frame with split columns, plastic hinges are generated at the ends of beams and then the columns begin yielding while the frame still possesses the bearing and deformation capacity. The design idea of directly changing the short column to long one in the reinforced concrete frame may be realized by replacing the short column with the split one.展开更多
We present comparisons of the NO2 regional Chemical Transport Model (CTM) simulations over North-eastern North America during the time period from May to September, 1998 with hourly surface NO2 observations and the ...We present comparisons of the NO2 regional Chemical Transport Model (CTM) simulations over North-eastern North America during the time period from May to September, 1998 with hourly surface NO2 observations and the NO2 columns retrieved from the GOME (Global Ozone Monitoring Experiment) satellite instrument. The model calculations were performed using the Mesoscale Meteorological Model 5 (MM5), Sparse Matrix Operator Kernal Emissions (SMOKE), and Community Multiscale Air Quality (CMAQ) modeling systems, using the emission data from the National Emissions Inventory (NEI) databases of 1996 (U.S.) and 1995 (Canada). The major objectives were to assess the performance of the CMAQ model and the accuracy of the emissions inventories as they affected the simulations of this important short-lived atmospheric species. The modeled (NcMAQ) and measured (NGOME) NO2 column amounts, as well as their temporal variations, agreed reasonably well. The absolute differences (NcMAQ-NGOME) across the domain were between ±3.0×10^15 molecules cm^-2, but they were less than ±1.0×10^15 molecules cm^-2 over the majority (80%) of the domain studied. The overall correlation coefficient between the measurements and the simulations was 0.75. The differences were mainly ascribed to a combination of inaccurate emission data for the CTM and the uncertainties in the GOME retrievals. Of these, the former were the more easily identifiable.展开更多
Overall dispersed side volumetric mare transfer coeffcieats for protein and amino acids were measured in continuous countercurreat PEG4000/KHP aqueous two-phase systems in a 57 mm I.D. packed extraction column. A mode...Overall dispersed side volumetric mare transfer coeffcieats for protein and amino acids were measured in continuous countercurreat PEG4000/KHP aqueous two-phase systems in a 57 mm I.D. packed extraction column. A model for overall dispersed side volumetric mass transfer coefficients was derived by describing the motion of the drops based upon Navier-Stokes equation combined with the relationship between mass transfer coefficients and the drop velocity. The model provides good predictions and can be successfully used in aqueous two-phase extraction. The awrage relative deviation between calculated values and experimental date ranges from 8% to 14%.展开更多
Evaporating bubble column reactor (EBCR) is a kind of aerated reactor in which the reaction heat is removed by the evaporation of volatile reaction mixture. In this paper, a mathematical model that accounts for the ga...Evaporating bubble column reactor (EBCR) is a kind of aerated reactor in which the reaction heat is removed by the evaporation of volatile reaction mixture. In this paper, a mathematical model that accounts for the gas-liquid exothermic reaction and axial dispersions of both gas and liquid phase is employed to study the performance of EBCR for the process of p-xylene(PX) oxidation. The computational results show that there are remarkable concentration and temperature gradients in EBCR for high ratio of height to diameter (H/DT). The temperature is lower at the bottom of column and higher at the top, due to rapid evaporation induced by the feed gas near the bottom. The concentration profiles in the gas phase are more nonuniform than those (except PX) in the liquid phase, which causes more solvent burning consumption at high H/DT ratio. For p-xylene oxidation, theo ptimal H/DT is around 5.展开更多
The performance of different nonlinear modelling strategies to simulate the response of RC columns subjected to axial load combined with cyclic biaxial horizontal loading is compared. The models studied are classified...The performance of different nonlinear modelling strategies to simulate the response of RC columns subjected to axial load combined with cyclic biaxial horizontal loading is compared. The models studied are classified into two categories according to the nonlinearity distribution assumed in the elements: lumped-plasticity and distributed inelasticity. For this study, results of tests on 24 columns subjected to cyclic uniaxial and biaxial lateral displacements were numerically reproduced. The analyses show that the global envelope response is satisfactorily represented with the three modelling strategies, but significant differences were found in the strength degradation for higher drift demands and energy dissipation.展开更多
In this study,based on the Luo bubble coalescence model,a model correction factor C_e for pressures according to the literature experimental results was introduced in the bubble coalescence efficiency term.Then,a coup...In this study,based on the Luo bubble coalescence model,a model correction factor C_e for pressures according to the literature experimental results was introduced in the bubble coalescence efficiency term.Then,a coupled modified population balance model(PBM) with computational fluid dynamics(CFD) was used to simulate a high-pressure bubble column.The simulation results with and without C_e were compared with the experimental data.The modified CFD-PBM coupled model was used to investigate its applicability to broader experimental conditions.These results showed that the modified CFD-PBM coupled model can predict the hydrodynamic behaviors under various operating conditions.展开更多
In order to establish a restoring-force model for modified concrete columns with recycled aggregates concrete(RAC), cyclic loading tests were carried out on five concretes with RAC columns and ordinary concrete frame ...In order to establish a restoring-force model for modified concrete columns with recycled aggregates concrete(RAC), cyclic loading tests were carried out on five concretes with RAC columns and ordinary concrete frame columns under the combined influence with different admixtures and admixtures ratios(silica fume and hybrid fiber). The expressions for characteristic nodes of the skeleton curve were given by the analysis and numerical regression of the test results. In addition, the hysteretic rules of the restoring-force model and the expression for unloading stiffness were presented. Finally, we summed up the complete calculation method of the hysteretic restoring force, whose results were in good agreement with experiment. The results demonstrated that the proposed model could simulate and reflect the corresponding hysteretic behaviors, and the calculation method can provide the theoretical basis for the engineering application.展开更多
The dividing wall column(DWC) is considered as a major breakthrough in distillation technology and has good prospect of industrialization. Model predictive control(MPC) is an advanced control strategy that has acquire...The dividing wall column(DWC) is considered as a major breakthrough in distillation technology and has good prospect of industrialization. Model predictive control(MPC) is an advanced control strategy that has acquired extensive applications in various industries. In this study, MPC is applied to the process for separating ethanol,n-propanol, and n-butanol ternary mixture in a fully thermally coupled DWC. Both composition control and temperature inferential control are considered. The multiobjective genetic algorithm function "gamultiobj" in Matlab is used for the weight tuning of MPC. Comparisons are made between the control performances of MPC and PI strategies. Simulation results show that although both MPC and PI schemes can stabilize the DWC in case of feed disturbances, MPC generally behaves better than the PI strategy for both composition control and temperature inferential control, resulting in a more stable and superior performance with lower values of integral of squared error(ISE).展开更多
To investigate the bilateral shear strength of rectangular frame column subjected to oblique horizontal load, we presented a simplified space truss-arch model developed from unilateral truss-arch model. Main parameter...To investigate the bilateral shear strength of rectangular frame column subjected to oblique horizontal load, we presented a simplified space truss-arch model developed from unilateral truss-arch model. Main parameters in the new model were the cross-sectional area, transverse reinforcement raito, axial load, and material strength of the column. The reduction coefficient of concrete sterength owing to the severe cracking of column was also introduced in the model. Finally, 14 specimens under oblique horizontal load were tested to verified the feasibility and applicability of the space truss-arch model.展开更多
基金supported by the DOE ASR program(Grant No.DESC008468)
文摘The planetary boundary layer turbulence and moist convection parameterizations have been modified recently in the NASA Goddard Institute for Space Studies (GISS) Model E2 atmospheric general circulation model (GCM; post-CMIP5, hereafter P5). In this study, single column model (SCM_P5) simulated cloud fractions (CFs), cloud liquid water paths (LWPs) and precipitation were compared with Atmospheric Radiation Measurement (ARM) Southern Great Plains (SGP) groundbased observations made during the period 2002-08. CMIP5 SCM simulations and GCM outputs over the ARM SGP region were also used in the comparison to identify whether the causes of cloud and precipitation biases resulted from either the physical parameterization or the dynamic scheme. The comparison showed that the CMIP5 SCM has difficulties in simulating the vertical structure and seasonal variation of low-level clouds. The new scheme implemented in the turbulence parameterization led to significantly improved cloud simulations in P5. It was found that the SCM is sensitive to the relaxation time scale. When the relaxation time increased from 3 to 24 h, SCM_P5-simulated CFs and LWPs showed a moderate increase (10%-20%) but precipitation increased significantly (56%), which agreed better with observations despite the less accurate atmospheric state. Annual averages among the GCM and SCM simulations were almost the same, but their respective seasonal variations were out of phase. This suggests that the same physical cloud parameterization can generate similar statistical results over a long time period, but different dynamics drive the differences in seasonal variations. This study can potentially provide guidance for the further development of the GISS model.
文摘A single column model (SCM) is constructed by extracting the physical subroutines from the NCAR Community Climate Model version 1 (CCM1).Simulated data are generated by CCM1 and used to validate the SCM and to study the sensitivity of the SCM to errors in its input data.It is found that the SCM temperature predictions are moderately sensitive to errors in the input horizontal temperature flux convergence and moisture flux convergence.Two types of error are concerned in this study,random errors due to insufficient data resolution,and errors due to insufficient data area coverage.While the first type of error can be reduced by filtering and/or increasing the data resolution,it is shown that the second type of error can be reduced by enlarging the data area coverage and using a suitable method to compute the input flux convergence terms.
文摘It is presented that there is a pumping effect at its base in the development process of a cumulus.In the strongest stage of cumulus development,the pumping is mainly produced by the buoyance at the base,and may be taken as the first approximation of the ascending speed at the base. The results of numerical calculations and simulations of four observed radar echoes show that as the first approximation,the height of air-mass cumulus may be simulated by Haltiner model in the absence of ob- served ascending speeds at the base,and the Haltiner model can be characterized by the sensitivity of the cumulus development to the virtual temperature excess over environment at the base.
基金the National Natural Science Foundation of China(No.51104158)the Science and Technology Fund of China University of Mining & Technology (No.2011QNB08) for the financial support
文摘A unique cyclonic static microbubble flotation column was developed for oily wastewater separation.The separation effciency was found to be highly dependent on gas holdup and bubble size distribution.By changing the circulation pressure,gas flow rate,frother concentration,the effect of operation parameters on gas holdup and oil removal effciency were attained.A mathematical modeling between the kinetic constant and the gas holdup was established for oily water separation process.The results show that higher gas holdup and smaller microbubble sizes are benefcial to improve oil removal effciency.
基金jointly supported by the National Natural Science Foundation of China(41305102)the National Basic Research Program of China(2014CB441202,2013CB955803)
文摘A single-column model is constructed based on parameterizations inherited from the Finite-volume/Spectral Atmospheric Model F/SAMIL and tested in simulations of tropical convective systems. Two representative convection schemes are compared in terms of their performances on precipitation types, individual physical tendencies, and temperature and moisture fields. The main difference between the two selected schemes is in their representation of entraining/detraining process. The Tiedtke scheme assumes bulk entrainment, while the Zhang–Mc Farlane scheme parameterizes entrainment/detrainment rates under the spectrum concept. Large-scale forcing and verification data are taken from the GATE phase III field campaign, during which abundant convective events were observed. Given the same triggering function and closure assumption, results show that entrainment/detrainment representation remains the dominant factor on the simulation of cumulus mass flux and of temperature and moisture fields. By analyzing sources and sinks of heat and moisture, this study reveals how parameterization components compensate for each other and make model results insensitive to parameterization changes in certain fields, thus suggesting the need to treat parameterizations as systems rather than individual components.
文摘The flow field of liquid phase (water) of agitated extraction columns is simulated with the help of computational fluid dynamics (CFD). Four kinds of Reynolds-averaged turbulence models, i.e. the standard k-ε model, the RNG (renormaiization group) k-ε model, the realizable k-ε model and the Reynolds stress model, are compared in detail in order to judge which is the best model in terms of the accuracy, less CPU time and memory required. The performance of the realizable k-ε model is obviously improved by reducing the model constant from c2 = 1.90 to c2 = 1.61. It is concluded that the improved realizable k-ε model is the optimal model.
基金supported by the National Key Research and Development Program of China(2017YFB0602500)the Foundation for High Level Talents of Hebei (A2017002032).
文摘The high degree of reversibility of heat integrated distillation column(HIDiC) has been thermodynamically interpreted by the entropy method. In this paper, a heat transfer model and a more universal method were proposed, through which the overall heat transfer coefficient at different height of column under different operating conditions could be obtained before the experiment. Then the separation of a binary ethanol-water system was carried out experimentally as a case study to verify the heat transfer model and the aforementioned calculation method. The close results between the calculation, the simulation, and the experiments suggested that the proposed model and the calculation method in this paper were accurate and applicable. Meanwhile, it was demonstrated that the HIDiC shows obvious effect of reducing entropy increase and improving thermodynamic efficiency as compared to conventional distillation column.
基金Supported by the National Key R&D Program of China(2017YFB0602500)
文摘To optimize industrial Fischer–Tropsch(FT) synthesis with the slurry bubble column reactor(SBCR) and ironbased catalyst, a comprehensive process model for FT synthesis that includes a detailed SBCR model, gas liquid separation model, simplified CO_2 removal model and tail gas cycle model was developed. An effective iteration algorithm was proposed to solve this process model, and the model was validated by industrial demonstration experiments data(SBCR with 5.8 m diameter and 30 m height), with a maximum relative error b 10% for predicting the SBCR performances. Subsequently, the proposed model was adopted to optimize the industrial SBCR performances simultaneously considering process and reactor parameters variations. The results show that C_(5+) yield increases as catalyst loading increases within 10–70 ton and syngas H_2/CO value decreases within1.3–1.6, but it doesn't increase obviously when the catalyst loading exceeds 45 ton(about 15 wt% concentration).Higher catalyst loading will result in higher difficulty for wax/catalyst separation and higher catalyst cost. Therefore, the catalyst loading(45 ton) is recommended for the industrial demonstration SBCR operation at syngas H_2/CO = 1.3, and the C_(5+) yield is about 402 ton" per day, which has an about 16% increase than the industrial demonstration run result.
基金Supported by National Science Fund for Distinguished Young Scholars of China( No. 50425824
文摘Based on a series of previous studies, an experiment on the integral seismic behavior of a 1/3 scaled model of two-bay and three-story reinforced concrete frame with split columns at lower two stories is performed under cyclic loading. The original columns at lower two stories of the model frame are short columns and they are replaced by the split columns. The hysteresis curves between the horizontal cyclic load and the lateral displacement at the top of the model frame, indicate that under the cyclic loading, the model frame undergoes the process of cracking, yielding, and maximum loading before being destroyed at the ultimate load. They also indicate that the model frame has better ductility, and the ratio of the ultimate displacement to the yielding displacement, reaches 6.0. The yielding process of the model frame shows that for the frame with split columns, plastic hinges are generated at the ends of beams and then the columns begin yielding while the frame still possesses the bearing and deformation capacity. The design idea of directly changing the short column to long one in the reinforced concrete frame may be realized by replacing the short column with the split one.
文摘We present comparisons of the NO2 regional Chemical Transport Model (CTM) simulations over North-eastern North America during the time period from May to September, 1998 with hourly surface NO2 observations and the NO2 columns retrieved from the GOME (Global Ozone Monitoring Experiment) satellite instrument. The model calculations were performed using the Mesoscale Meteorological Model 5 (MM5), Sparse Matrix Operator Kernal Emissions (SMOKE), and Community Multiscale Air Quality (CMAQ) modeling systems, using the emission data from the National Emissions Inventory (NEI) databases of 1996 (U.S.) and 1995 (Canada). The major objectives were to assess the performance of the CMAQ model and the accuracy of the emissions inventories as they affected the simulations of this important short-lived atmospheric species. The modeled (NcMAQ) and measured (NGOME) NO2 column amounts, as well as their temporal variations, agreed reasonably well. The absolute differences (NcMAQ-NGOME) across the domain were between ±3.0×10^15 molecules cm^-2, but they were less than ±1.0×10^15 molecules cm^-2 over the majority (80%) of the domain studied. The overall correlation coefficient between the measurements and the simulations was 0.75. The differences were mainly ascribed to a combination of inaccurate emission data for the CTM and the uncertainties in the GOME retrievals. Of these, the former were the more easily identifiable.
基金Supported by the National Natural Science Foundation of China.
文摘Overall dispersed side volumetric mare transfer coeffcieats for protein and amino acids were measured in continuous countercurreat PEG4000/KHP aqueous two-phase systems in a 57 mm I.D. packed extraction column. A model for overall dispersed side volumetric mass transfer coefficients was derived by describing the motion of the drops based upon Navier-Stokes equation combined with the relationship between mass transfer coefficients and the drop velocity. The model provides good predictions and can be successfully used in aqueous two-phase extraction. The awrage relative deviation between calculated values and experimental date ranges from 8% to 14%.
基金Supported by the National Natural Science Foundation of China (No. 20076039) and SINOPEC.
文摘Evaporating bubble column reactor (EBCR) is a kind of aerated reactor in which the reaction heat is removed by the evaporation of volatile reaction mixture. In this paper, a mathematical model that accounts for the gas-liquid exothermic reaction and axial dispersions of both gas and liquid phase is employed to study the performance of EBCR for the process of p-xylene(PX) oxidation. The computational results show that there are remarkable concentration and temperature gradients in EBCR for high ratio of height to diameter (H/DT). The temperature is lower at the bottom of column and higher at the top, due to rapid evaporation induced by the feed gas near the bottom. The concentration profiles in the gas phase are more nonuniform than those (except PX) in the liquid phase, which causes more solvent burning consumption at high H/DT ratio. For p-xylene oxidation, theo ptimal H/DT is around 5.
基金Financial support provided by "FCT - Fundao para a Ciência e Tecnologia,"Portugal,through the research project PTDC/ECM/102221/2008
文摘The performance of different nonlinear modelling strategies to simulate the response of RC columns subjected to axial load combined with cyclic biaxial horizontal loading is compared. The models studied are classified into two categories according to the nonlinearity distribution assumed in the elements: lumped-plasticity and distributed inelasticity. For this study, results of tests on 24 columns subjected to cyclic uniaxial and biaxial lateral displacements were numerically reproduced. The analyses show that the global envelope response is satisfactorily represented with the three modelling strategies, but significant differences were found in the strength degradation for higher drift demands and energy dissipation.
基金Supported by the National Natural Science Foundation of China(91634101)The Project of Construction of Innovative TeamsTeacher Career Development for Universities and Colleges under Beijing Municipality(IDHT20180508)
文摘In this study,based on the Luo bubble coalescence model,a model correction factor C_e for pressures according to the literature experimental results was introduced in the bubble coalescence efficiency term.Then,a coupled modified population balance model(PBM) with computational fluid dynamics(CFD) was used to simulate a high-pressure bubble column.The simulation results with and without C_e were compared with the experimental data.The modified CFD-PBM coupled model was used to investigate its applicability to broader experimental conditions.These results showed that the modified CFD-PBM coupled model can predict the hydrodynamic behaviors under various operating conditions.
基金Project(51178388)supported by the National Natural Science Foundation of ChinaProject(2013SZS01-Z02)supported by Key Laboratory Fund of Shaanxi Province,China
文摘In order to establish a restoring-force model for modified concrete columns with recycled aggregates concrete(RAC), cyclic loading tests were carried out on five concretes with RAC columns and ordinary concrete frame columns under the combined influence with different admixtures and admixtures ratios(silica fume and hybrid fiber). The expressions for characteristic nodes of the skeleton curve were given by the analysis and numerical regression of the test results. In addition, the hysteretic rules of the restoring-force model and the expression for unloading stiffness were presented. Finally, we summed up the complete calculation method of the hysteretic restoring force, whose results were in good agreement with experiment. The results demonstrated that the proposed model could simulate and reflect the corresponding hysteretic behaviors, and the calculation method can provide the theoretical basis for the engineering application.
基金Supported by the National Natural Science Foundation of China(21676299,21476261and 21606255)
文摘The dividing wall column(DWC) is considered as a major breakthrough in distillation technology and has good prospect of industrialization. Model predictive control(MPC) is an advanced control strategy that has acquired extensive applications in various industries. In this study, MPC is applied to the process for separating ethanol,n-propanol, and n-butanol ternary mixture in a fully thermally coupled DWC. Both composition control and temperature inferential control are considered. The multiobjective genetic algorithm function "gamultiobj" in Matlab is used for the weight tuning of MPC. Comparisons are made between the control performances of MPC and PI strategies. Simulation results show that although both MPC and PI schemes can stabilize the DWC in case of feed disturbances, MPC generally behaves better than the PI strategy for both composition control and temperature inferential control, resulting in a more stable and superior performance with lower values of integral of squared error(ISE).
基金Funded by Natural Science Foundation of Henan Province Office of Education (No. 2009A560007)Doctor Foundation of Henan Polytechnic University (No. B2008-7)
文摘To investigate the bilateral shear strength of rectangular frame column subjected to oblique horizontal load, we presented a simplified space truss-arch model developed from unilateral truss-arch model. Main parameters in the new model were the cross-sectional area, transverse reinforcement raito, axial load, and material strength of the column. The reduction coefficient of concrete sterength owing to the severe cracking of column was also introduced in the model. Finally, 14 specimens under oblique horizontal load were tested to verified the feasibility and applicability of the space truss-arch model.