Flow Regimes in Bubble Columns with and without Internals: A Review

Hydrodynamics characterization in terms offlow regime behavior is a crucial task to enhance the design of bubble column reactors and scaling up related methodologies.This review presents recent studies on the typicalflow regimes established in bubble columns.Some effort is also provided to introduce relevant definitions pertaining to thisfield,namely,that of“void fraction”and related(local,chordal,cross-sectional and volumetric)variants.Experimental studies involving different parameters that affect design and operating conditions are also discussed in detail.In the second part of the review,the attention is shifted to cases with internals of various types(perfo-rated plates,baffles,vibrating helical springs,mixers,and heat exchanger tubes)immersed in the bubble columns.It is shown that the presence of these elements has a limited influence on the global column hydrodynamics.However,they can make the homogeneousflow regime more stable in terms of transition gas velocity and transi-tion holdup value.The last section is used to highlight gaps which have not beenfilled yet and future directions of investigation.

Consolidation of high replacement ratio stone column-reinforced ground:Analytical solutions incorporating clogging effect

The utilization of stone columns has emerged as a popular ground improvement strategy,whereas the drainage performance can be adversely hampered by clogging effect.Despite the ample progress of calculation methods for the consolidation of stone column-improved ground,theoretical investigations into the clogging effect have not been thoroughly explored.Furthermore,it is imperative to involve the column consolidation deformation to mitigate computational error on the consolidation of composite ground with high replacement ratios.In this context,an analytical model accounting for the initial clogging and coupled time and depth-dependent clogging of stone columns is established.Then,the resulting governing equations and analytical solutions are obtained under a new flow continuity relationship to incorporate column consolidation deformation.The accuracy and reliability of the proposed model are illustrated by degradation analysis and case studies with good agreements.Subsequently,the computed results of the current study are juxtaposed against the existing models,and an in-depth assessment of the impacts of several crucial parameters on the consolidation behavior is conducted.The results reveal that ignoring column consolidation deformation leads to an overestimate of the consolidation rate,with maximum error reaching up to 16%as the replacement ratio increases.Furthermore,the initial clogging also has a significant influence on the consolidation performance.Additionally,the increment of depth and time-clogging factors a and b will induce a noticeable retardation of the consolidation process,particularly in the later stage.

Comparative impact behaviours of ultra high performance concrete columns reinforced with polypropylene vs steel fibres

Polypropylene(PP) fibres have primarily used to control shrinkage cracks or mitigate explosive spalling in concrete structures exposed to fire or subjected to impact/blast loads, with limited investigations on capacity improvement. This study unveils the possibility of using PP micro-fibres to improve the impact behaviour of fibre-reinforced ultra-high-performance concrete(FRUHPC) columns. Results show that the addition of fibres significantly improves the impact behaviour of FRUHPC columns by shifting the failure mechanism from brittle shear to favourable flexural failure. The addition of steel or PP fibres affected the impact responses differently. Steel fibres considerably increased the peak impact force(up to 18%) while PP micro-fibres slightly increased the peak(3%-4%). FRUHPC significantly reduced the maximum midheight displacement by up to 30%(under 20°impact) and substantially improved the displacement recovery by up to 100%(under 20° impact). FRUHPC with steel fibres significantly improved the energy absorption while those with PP micro-fibres reduced the energy absorption, which is different from the effect of PP-macro fibre reported in the literature. The optimal fibre content for micro-PP fibres is 1% due to its minimal fibre usage and low peak and residual displacement. This study highlights the potential of FRUHPC as a promising material for impact-resistant structures by creating a more favourable flexural failure mechanism, enhancing ductility and toughness under impact loading, and advancing the understanding of the role of fibres in structural performance.

Visual experimental study of nanofluids application to promote CO_(2) absorption in a bubble column

The addition of dispersed-phase nanoparticles in the liquid phase can enhance the gas-liquid transfer process as the suspended nanoparticles affect the transfer process inside the fluid through microdisturbance or micro-convection effects.In this article,a high-speed digital camera was used to visualize the bubble behavior of CO_(2) in pure water and nanofluids to examine the effects of CO_(2) gas flow rate,nanoparticle solid content and type on the bubble behavior in the fluids.The CO_(2) absorption performance in three water-based nanofluids were compared in a bubbler.And the mass transfer characteristics during CO_(2) bubble absorption and the reasons for the enhanced gas-liquid mass transfer effect of nanoparticles were analyzed.The results showed that the presence of nanoparticles affected the formation process of bubbles in the fluid,shortened the bubble detachment time,reduced the detachment diameter,effectively increased the gas-liquid contact area,and improved the bubbles detachment frequency.The system with MCM-41 corresponded to a higher overall mass transfer coefficient.Uncalined MCM-41 contained surfactant that enhanced foaming behavior in water.This prevented the transfer of CO_(2) to some extent,and the CO_(2) absorption by uncalined MCM-41/H_(2)O was 5.34%higher than that by pure water.Compared with SiO_(2) nanoparticles with the same particle size and the same composition,MCM-41 had a higher adsorption capacity and better hydrophilicity due to its larger specific surface area and rich porous structure,which was more favorable to accelerate the collision between nanoparticles and CO_(2) bubbles to cause micro-convection.Under the condition of 0.1%(mass)solid content,the enhancement of CO_(2) absorption process by MCM-41 nanoparticles was more significant and improved by 16.9%compared with pure water.

Hydrodynamic Performance of An Integrated System of Breakwater and A Multi-Chamber OWC Wave Energy Converter

A multi-chamber oscillating water column wave energy converter(OWC-WEC)integrated to a breakwater is investigated.The hydrodynamic characteristics of the device are analyzed using an analytical model based on the linear potential flow theory.A pneumatic model is employed to investigate the relationship between the air mass flux in the chamber and the turbine characteristics.The effects of chamber width,wall draft and wall thickness on the hydrodynamic performance of a dual-chamber OWC-WEC are investigated.The results demonstrate that the device,with a smaller front wall draft and a wider rear chamber exhibits a broader effective frequency bandwidth.The device with a chamber-width-ratio of 1:3 performs better in terms of power absorption.Additionally,results from the analysis of a triplechamber OWC-WEC demonstrate that reducing the front chamber width and increasing the rearward chamber width can improve the total performance of the device.Increasing the number of chambers from 1 to 2 or 3 can widen the effective frequency bandwidth.

A Two-Stage Scenario-Based Robust Optimization Model and a Column-Row Generation Method for Integrated Aircraft Maintenance-Routing and Crew Rostering

Motivated by a critical issue of airline planning process,this paper addresses a new two-stage scenario-based robust optimization in operational airline planning to cope with uncertainty and possible flight disruptions.Following the route network scheme and generated flight timetables,aircraft maintenance routing and crew scheduling are critical factors in airline planning and operations cost management.This study considers the simultaneous assignment of aircraft fleet and crew to the scheduled flight while satisfying a set of operational constraints,rules,and regulations.Considering multiple locations for airline maintenance and crew bases,we solve the problem of integrated Aircraft Maintenance Routing and Crew Rostering(AMRCR)to achieve the minimum airline cost.One real challenge to the efficiency of the planning results is the possible disruptions in the initial scheduled flights.Due to the fact that disruption scenarios are expressed discretely with a specified probability,and we provide adjustable decisions under disruption to deal with this disruption risk,we provide a Two-Stage Scenario-Based Robust Optimization(TSRO)model.In this model,here-and-now or first-stage variables are the initial resource assignment.Furthermore,to adapt itself to different disruption scenarios,the model considers some adjustable variables,such as the decision to cancel the flight in case of disruption,as wait-and-see or second-stage variables.Considering the complexity of integrated models,and the scenario-based decomposable structure of the TRSO model to solve it with better computational performance,we apply the column and row generation(CRG)method that iteratively considers the disruption scenarios.The numerical results confirm the applicability of the proposed TSRO model in providing the AMRCR problem with an integrated and robust solution with an acceptable level of computational tractability.To evaluate the proposed TSRO model,which solves the AMRCR problem in an integrated and robust manner,five Key Performance Indicators(KPIs)like Number of delayed/canceled flights,Average delay time,and Average profit are taken into account.As key results driven by conducting a case study,we show the proposed TSRO model has substantially improved the solutions at all indicators compared with those of the sequential/non-integrated and nominal/non-robust models.The simulated instances used to assess the performance of the proposed model and CRG method reveal that both CPLEX and the CRG method exhibit comparable and nearly optimal performance for small-scale problems.However,for large-scale instances the proposed TSRO model falls short in terms of computational efficiency.Conversely,the proposed CRG method is capable of significantly reducing computational time and the optimality gap to an acceptable level.

Experimental Study on the Axial Compression Performance of Bamboo Scrimber Columns Embedded with Steel Reinforcing Bars

In this paper,a new type of bamboo scrimber column embedded with steel bars(rebars)was proposed,and the compression performance was improved by pre-embedding rebars during the preparation of the columns.The effects of the slenderness ratio and the reinforcement ratio on the axial compression performance of reinforced bamboo scrimber columns were studied by axial compression tests on 28 specimens.The results showed that the increase in the slenderness ratio had a significant negative effect on the axial compression performance of the columns.When the slenderness ratio increased from 19.63 to 51.96,the failure mode changed from strength failure to buckling failure,and the maximum bearing capacity decreased by 43.03%.The axial compression performance of the reinforced bamboo scrimber columns did not significantly improve at a slenderness ratio of 19.63,but the opposite was true at slenderness ratios of 36.95 and 51.96.When the reinforcement ratio increased from 0%to 4.52%,the bearing capacity of those with a slenderness ratio of 51.96 increased by up to 16.99%,and the stiffness and ductility were also improved.Finally,based on existing specifications,two modification parameters,the overall elastic modulus Ec and the combined strength fcc,were introduced to establish a calculation method for the bearing capacity of the reinforced bamboo scrimber columns.The calculation results were compared with the test results,and the results showed that the proposed calculation models can more accurately predict the bearing capacity.

Numerical Analysis of Cold-Formed Thin-Walled Steel Short Columns with Pitting Corrosion during Bridge Construction

Pitting corrosion is harmful during bridge construction,which will lead to uneven roughness of steel surfaces and reduce the thickness of steel.Hence,the effect of pitting corrosion on the mechanical properties of cold-formed thin-walled steel stub columns is studied,and the empirical formulas are established through regression fitting to predict the ultimate load of web and flange under pitting corrosion.In detail,the failure modes and load-displacement curves of specimens with different locations,area ratios,and depths are obtained through a large number of non-linear finite element analysis.As for the specimens with pitting corrosion on the web,all the specimens are subject to local buckling failure,and the failure mode will not change with pitting corrosion,but the failure location will change with pitting corrosion location;the size,location,and area ratio of pitting corrosion have little influence on the ultimate load of cold-formed thin-walled steel short columns,but the loss rate of pitting corrosion section area has a greater impact on the ultimate bearing capacity.As for the specimen with flange pitting corrosion,the location and area ratio of pitting corrosion have less influence on the ultimate load of cold-formed thin-walled steel short columns,and the section area loss rate has greater influence on the ultimate bearing capacity;the impact of web pitting corrosion on the ultimate load is greater than that of flange pitting corrosion under the same condition of pitting corrosion section area.The prediction formulas of limit load which are suitable for pitting corrosion of web and flange are established,which can provide a reference for performance evaluation of corroded cold-formed thin-walled steel.

Comprehensive analysis of phenolic composition and antioxidant mechanisms in Gymnema sylvestre extracts using LC-MS and column chromatography

Recent studies have highlighted the potential of plant extracts as therapeutic agents for managing oxidative stress and related disorders.This study aims to elucidate the phenolic composition and antioxidant properties of Gymnema sylvestre extracts.Ethanolic reflux extraction followed by column chromatography was employed to isolate phenolic compounds.The total phenolic and flavonoid contents were quantified using the Folin–Ciocalteu and aluminum chloride colorimetric methods,respectively.Antioxidant activities were assessed by DPPH,ABTS scavenging assays and the ferric reducing antioxidant power(FRAP)assay.High-Performance Liquid Chromatography(HPLC)with a C18 column and Thermo TSQ Quantum Access Max(LC-MS)were used to determine the levels of gymnemic acid and identify other potential phenolic compounds.The analysis revealed significant antioxidant activities in the fractions.Fraction A showed the highest DPPH and ABTS scavenging activities,and Fraction C demonstrated the highest ferric reducing power.LC-MS analysis identified several phenolic compounds,indicating that these are major contributors to the antioxidant efficacy of the extract.This study provides a detailed phenolic profile and confirms the strong antioxidant potential of Gymnema sylvestre leaf extract,supporting its therapeutic use and further investigation.

An Affordable and Easily Accessible Approach for Acrylonitrile Monomer Purification through a Simple Column Technique

This manuscript presents a dataset detailing a method for purifying monomers. Purification plays a crucial role in every chemical process, as it leads to an improvement in product quality through the removal of impurities. The primary method for monomer purification, like acrylonitrile (AN), is the distillation technique. However, this technique is unsafe and hard to set up or handle. A straightforward, risk-free, low-cost method like the column technique resolves these issues. A simple column technique demonstrated the successful execution of purifying AN. Fourier transform infrared (FTIR) and nuclear magnetic resonance (NMR) analyses confirmed that AN was successfully purified, with purity reaching 99.8%. FTIR spectra revealed changes in the position and intensity of the stretching vibration peaks after purification. Also, the functional groups of the inhibitor monomethyl ether of hydroquinone (MeHQ) were undetected after purification. Furthermore, after purification, NMR spectra revealed the absence of aromatic protons and carbons associated with MeHQ. In conclusion, the column technique is a successful and inexpensive way to purify AN monomers. This makes it useful for a wide range of applications, especially in polymerization reactions where MeHQ needs to be removed to prevent self-polymerization during the initiation process.

Modelling and Sizing of a Floor Reinforced by Ballasted Columns Intended to Support a Tank

This work aims to study the modeling and sizing of a floor reinforced by ballasted columns. We are studying the system of reinforcement by ballasted columns because this technique is able to replace deep foundations that are technically difficult to realize and their cost is higher. The modelling and dimensioning of foundations on a ballasted column will be an important contribution to the state of the art of this method because it will highlight the mode of transfer of loads, and will expose the induced deformations by also allowing to verification criteria of bearing capacity and allowable settlement according to geometric information of the model. The columns on a substrate located at 9 m have a length of 9 m and a diameter of 40 cm and were obtained by incorporating ballast of granular class 0/31.5 of internal friction angle of 38˚ and a density weight of 21 kN/m3. The choice of this method is based on the geotechnical characteristics of the initial soil. Thus, identification and characterization tests were carried out to estimate the bearing capacity and the settlement giving respectively 125 kPa and 57 cm. These results show the ground does not have sufficient mechanical properties to withstand the loads transmitted by the tank. By adopting the reinforcement of the soil with ballasted columns, numerical calculations show that after applying a load equal to 265.1 KPa, 20 cm vertical settlement and 17 cm horizontal displacement were obtained. This is in the tolerable deformation range for our tank, namely, less than 20 cm. Analytically, in addition to reducing settlement, ballasted columns, Due to their high stiffness, they have effectively contributed to the increase of the permissible soil stress up to 257 kPa.

Simultaneous Adsorption of Aqueous Pb2+, Cu2+, Zn2+, and Cd2+ Using Surfactant-Modified and Unmodified Activated Carbon in a Fixed Bed Column

The goal of this work is to improve the simultaneous removal of Pb2+, Cu2+, Zn2+, and Cd2+ ions from synthetic wastewater in a fixed bed column by incorporating sodium dodecyl sulfate (SDS) onto the surface of activated carbon made from coconut shells. The activated carbons were characterized using Fourier transform infrared spectroscopy (FT-IR) and scanning electron microscopy-energy dispersive x-ray (SEM-EDX). The adsorption column dynamics were studied by varying the flow rates (5, 10 and 15 mL/min), bed heights (10, 15 and 20 cm), and initial concentrations (50, 150, and 250 mg/L). The activated carbon has a pore volume of 0.715 cm3/g and a BET-specific surface area of 1410 m2/g. Sodium dodecyl sulfate (SDS) surfactant incorporation onto the surface of the activated carbon enhances its capacity for simultaneous adsorption of Pb2+, Cu2+, Zn2+, and Cd2+ from the aqueous medium. The affinity of the heavy metals to both unmodified (AC) and modified (AC-SDS) activated carbons followed the order of Pb2+ > Cu2+ > Zn2+ > Cd2+. The dynamic adsorption of the column depends on the flow rate, bed height, initial metal concentration, and SDS surface modification. With a 5 mL/min flow rate, a 20 cm bed height, and a 50 mg/L initial metal concentration, a maximum break-through time of 150 minutes for the unmodified activated carbon (AC) and 180 minutes for the SDS-modified activated carbon (AC-SDS) was reached.

Nonlinear Time History Analysis for the Different Column Orientations under Seismic Wave Synthetic Approach

The significant impact of earthquakes on human lives and the built environment underscores the extensive human and economic losses caused by structural collapses. Over the years, researchers have focused on improving seismic design to mitigate earthquake-induced damages and enhance structural performance. In this study, a specific reinforced concrete (RC) frame structure at Kyungpook National University, designed for educational purposes, is analyzed as a representative case. Utilizing SAP 2000, the research conducts a nonlinear time history analysis to assess the structural performance under seismic conditions. The primary objective is to evaluate the influence of different column section designs, while maintaining identical column section areas, on structural behavior. The study employs two distinct seismic waves from Abeno (ABN) and Takatori (TKT) for the analysis, comparing the structural performance under varying seismic conditions. Key aspects examined include displacement, base shear force, base moment, joint radians, and layer displacement angle. This research is anticipated to serve as a valuable reference for seismic restraint reinforcement work on RC buildings, enriching the methods used for evaluating structures through nonlinear time history analysis based on the synthetic seismic wave approach.

Shortcut Procedure for Inverted Batch Distillation Column (I) Multicomponent Ideal System

Inverted batch distillation column(stripper) is opposed to a conventional batch distillation col-umn(rectifier). It has a storage vessel at the top and products leave the column at the bottom. The batch stripper is favourable to separate mixtures with a small amount of light components by removing the heavy components as bottom products. In this paper, we are presenting a shortcut procedure based on our earlier work for design and simulation of the inverted batch distillation column, which is equivalent to the Fenske-Underwood-Gilliland procedure for continuous distillation. Given a separation task, we propose to compute the minimum number of stages(Nbmin) and the minimum reboil ratio(Rbmin) required in a batch stripper,which are the stages and reboil ratio required in a hypothetical inverted batch distillation column operating in total reboil ratio or having an infinite number of stages, respectively. Then, it is shown that the performance of inverted batch columns with a finite number of stages and reboil ratios could be correlated in Gilliland coordinates with the minimum stages Nbmin and the minimum reboil ratio Rbmin.

A column system for modeling bentonite slurry infiltration in sands

Pressurized bentonite slurry is applied on a tunnel face to form a filter cake to stabilize the tunnel face when the slurryshield excavates through the sandy soil. Failure of the tunnel face may be caused by a high permeable filter cake, which commonlyhas a long penetration distance of slurry in sands. A column system with a height of 680 mm and a diameter of 300 mm was de-veloped to model pressurized slurry infiltration in sands. Pressure transducers were installed to estimate the hydraulic conductivityof the filter cake during slurry infiltration. The electrical conductivity of the leachate of collected samples was measured. Resultsshow that the majority of fine particles in slurry are within the range 100-300 mm into the sand specimen. The time for forming animpermeable filter cake is about 300 s, which indicates the impermeable filter cake is hard to form during the excavation.

Simulation Optimization and Experimental Study of Cross-Wall Adiabatic Dividing Wall Column Used to Separate Hexane-Heptane-Octane System

Through separation of the hexane-heptane–octane system in a cross-wall adiabatic dividing wall column, the effects of feed position, side-draw position, liquid split ratio, vapor split ratio and their interactions on the energy consumption were analyzed by Aspen Plus under the constant product purity, and the response surface model for the energy consumption was regressed. Based on the restriction on the optimal operating zone, the comparison of different combinations of surrogate models and optimization methods showed that, the combination of the Kriging model and multi-island genetic algorithm(Kriging-MIGA) had better prediction ability than the combination of the response surface model and partial derivative method(RSM-PD), and RSM-PD had better optimization effect than Kriging-MIGA. With a self-made cross-wall adiabatic dividing wall column, the temperature at measuring points and the energy consumption were measured during experiments, the comparison between measured values and simulated ones demonstrated that the optimized values of variables searched by RSM-PD and Kriging-MIGA could be both used as the optimum technological conditions since the experimental reliability was ensured, with the optimum technological conditions shown below: The feed position is 6, the side-draw position is 7, the combinations of liquid split ratio and vapor split ratio are [0.14, 0.5] and [0.16, 0.52], respectively. RSM-PD and Kriging-MIGA can provide the appropriate optimization methods for the dividing wall column.

Expert systems for HPLC in biochemistry—The knowledge base for selection of HPLC column system in the separation of amino acids, peptides and proteins

The strategy of expert system for high performance liquid chromatography was discussed, the attentions are mainly placed on the knowledge base for selection of column system, separation modes and detection modes in the analysis of amino acids, peptides and proteins.

Vibration analysis of damaged and undamaged steel structure systems: cantilever column and frame

This paper presents the experimental and numerical studies conducted on a steel column and a steel frame structure using free vibration analysis.The effects of damages on structures were investigated,which were simulated by introducing multiple cracks at different locations in the experimental and numerical models.The acceleration responses of the test models,were recorded through an accelerometer,and were used to calibrate the numerical models developed in finite element based software.Modal frequencies of damaged and undamaged structures were compared and analyzed,to derive relationships for damaged and undamaged structures’frequencies in terms of crack depth.It was found that,due to the presence of cracks,the mechanical properties of a structure changes,whereby,the modal frequencies decrease.An approximately linear trend was observed for the frequency decrease with the increase in crack depth,which was also confirmed by the numerical models.The derived relationships were extended to further develop a mechanics-based damage scale for steel structures,to help facilitate structural health monitoring and screening of vulnerable structures.

Responses of bacterial community to potential heap construction methods of fine-grained copper tailings in column bioleaching system

The column bioleaching of copper flotation tailings was comparatively investigated using layered heap construction method(LM),agglomerate heap construction method(AM),and pellets-sintering heap construction method(PM).The bacterial communities of free,attached,weakly-attached,and strongly-attached microbes in the later bioleaching stage were investigated.In AM group,the addition of lump sulphide ore resulted in the low leachate pH,high ferric iron concentration,and rapid microbial adsorption,which obtained the maximum copper extraction(60.1%)compared with LM(54.6%)and PM(43.9%)groups.The relative abundance of dominant genera and microbial communities of different microbiota underwent changes in three heap construction methods.The alpha-diversity indexes of attached,weakly-attached,and strongly-attached microbes were different,while no significant change was observed in free bacteria.The variation of whole bacterial community was significantly associated with solution pH,total iron,and ferric iron concentrations.Pearson correlation analysis and partial least square path model both indicated that attached bacteria made larger contribution to the copper extraction of tailings.

Measurement of Mass Transfer Coefficients and Their Modelling of Continuous Counter-Current Aqueous Two-Phase System in a Packed Extraction Column

Overall dispersed side volumetric mass transfer coefficients for protein and amino acids were measured in continuous countercurrent PEG4000/KHP aqueous two-phase systems in a 57mm I.D. packed extraction column. A model for overall dispersed side volumetric mass transfer coefficients was derived by describing the motion of the drops based upon Navier-Stokes equation combined with the relationship between mass transfer coefficients and the drop velocity. The model provides good predictions and can be successfully used in aqueous two-phase extraction. The average relative deviation between calculated values and experimental data ranges from 8% to 14%.