A novel method for the determination of cationic surfactant by laser thermal lens spectrometry was developed. It was based on the reaction between 1-hydroxy-2-(5-nitro-2-Pyri- dylazo)-8-aminonaphthalene-3,6-disulfoni...A novel method for the determination of cationic surfactant by laser thermal lens spectrometry was developed. It was based on the reaction between 1-hydroxy-2-(5-nitro-2-Pyri- dylazo)-8-aminonaphthalene-3,6-disulfonic acid (5-NO2-PAH) and cationic surfactant to form 1:2 ionic association complex in a weakly basic medium (pH 9.44). The determination conditions and the mechanism were discussed. The method has been applied to the analysis of wastewater and moat water samples.展开更多
Enhancing the dispersion and dissolution of substrate particles in substrate water suspension is a feasible way to improve steroid bioconversion. The aim of the present study is to investigate the effects of applying ...Enhancing the dispersion and dissolution of substrate particles in substrate water suspension is a feasible way to improve steroid bioconversion. The aim of the present study is to investigate the effects of applying surfactant to microbial conversion system on the dispersion, solubilization and in turn bioconversion of steroid substrate. The model system is hydroxylation of substrate 19α- 17α-epoxy- 4-pregnene- 3.2It-dine by microbial enzymes from Rhizopus nigricanl. The results show that the presence of substrate leads to an increase in critical micelle concentration （ CMC） of surfactant PSE compared with the normal CMC of PSE in aqueous solution. The grinding time during substrate suspension preparation affects the substrate aqueous solubility differently with the varied surfactant concentrations while barely making any difference in substrate solubility in the absence of surfactant. The properly prolonged grinding time can make up for the loss in substrate solubility arising from the reduction in surfactant concentration. The surfactant complexes composed of surfactants PSE and MGE at appropriate ratios are screened out with orthodoxy experiment method. the interaction between PSE and MGE exerts the most prominent effects on substrate bioconversion, and the surfactant complexes show more beneficial effects on steroid bioconversion than the surfactant PSE used alone.展开更多
Dual fluorescence and UV absorption of 2′-ethylhexyl 4-（N,N-dimethylamino）benzoate （EHDMAB） were investigated in cationic, non-ionic and anionic micelles. When EHDMAB was solubilized in different micelles, the UV...Dual fluorescence and UV absorption of 2′-ethylhexyl 4-（N,N-dimethylamino）benzoate （EHDMAB） were investigated in cationic, non-ionic and anionic micelles. When EHDMAB was solubilized in different micelles, the UV absorption of EHDMAB was enhanced. Twisted intramolecular charge transfer （TICT） emission with longer wavelength was observed in ionic micelles, whereas TICT emission with shorter wavelength was obtained in non-ionic micelles. In particular, dual fluorescence of EHDMAB was significantly quenched by the positively charged pyridinium ions arranged in the Stern layer of cationic micelles. UV radiation absorbed mainly decays via TICT emission and radiationless deactivation. The dimethylamino group of EHDMAB experiences different polar environments in ionic and non-ionic micelles according to the polarity dependence of TICT emission of EHDMAB in organic solvents. In terms of the molecular structures and sizes of EHDMAB and surfactants, each individual EHDMAB molecule should be buried in micelles with its dimethylamino group toward the polar head groups of different micelles and with its 2′-ethylhexyl chain toward the hydrophobic micellar core. Dynamic fluorescence quenching measurements of EHDMAB provide further support for the location of EHDMAB in different micelles.展开更多
为了满足低渗透储层水平井改造的需要,开发了一种梳形聚合物与表面活性剂胶束自组装复合压裂液体系。该体系不使用交联剂,不含水不溶物;80℃时,0.3%梳形聚合物CD-1与0.2%表面活性剂组成的自组装压裂液储能模量高达290 Pa,远大于耗能模量...为了满足低渗透储层水平井改造的需要,开发了一种梳形聚合物与表面活性剂胶束自组装复合压裂液体系。该体系不使用交联剂,不含水不溶物;80℃时,0.3%梳形聚合物CD-1与0.2%表面活性剂组成的自组装压裂液储能模量高达290 Pa,远大于耗能模量,表现出突出的黏弹特性。5 m3/min排量下压裂液的降阻率达到74.05%,具有突出的低摩阻特性。不同配方的自组装压裂液破胶液的表面张力都低于27 m N/m,界面张力低于0.8 m N/m,满足压裂液返排特性的要求。自组装压裂液对储层岩心平均伤害率18.04%,远小于瓜胶压裂液78.75%的水平。室内评价和现场试验施工都表明,自组装压裂液降阻率高,对地层伤害小,增产效果明显,同时证实了利用聚合物与表面活性剂胶束自组装形成结构携砂理论的正确性。该压裂液体系满足特殊结构井压裂改造要求,为特殊低渗透油气藏的开发提供了一种新的方法和手段。展开更多
A series of novel quaternary ammonium surfactants containing adamantane were designed and synthesized from 1-adamanta- necarboxylic acid. The structures of target surfactants were confirmed by 1H NMR, elements analysi...A series of novel quaternary ammonium surfactants containing adamantane were designed and synthesized from 1-adamanta- necarboxylic acid. The structures of target surfactants were confirmed by 1H NMR, elements analysis and FFIR. Surface properties of these surfactants were investigated. Due to the lipophilicity of adamantane, the critical micelle concentration （CMC） and C2o values of the synthesized quaternary ammonium surfactants are lower than that of conventional quaternary ammonium surfactants.展开更多
Preconcentration/separation of Co（II）, Fe（III）, Pb（II）, Cr（IIl）, Cu（II） and Cd（II） ions using bis（5-bromo- 2-hydroxy-benzaldehyde）-2-methy1-1,5-pentane diimine （BBHBPDI） on SDS coated alumina has been ...Preconcentration/separation of Co（II）, Fe（III）, Pb（II）, Cr（IIl）, Cu（II） and Cd（II） ions using bis（5-bromo- 2-hydroxy-benzaldehyde）-2-methy1-1,5-pentane diimine （BBHBPDI） on SDS coated alumina has been reported. The influences of the analytical parameters including pH, ligand and SDS amount, type and concentration of eluent and sample volume on metal ions recoveries were investigated. At optimum values of all variables the relative standard deviation are between 2.5-2.7 and preconcentration factor was 375, while recoveries for all understudy metal ions are higher than 95%, determination limits are between 1.5-2.7. The method has been successfully applied to determination of Co（II）, Fe（III）, Pb（II）, Cr（III）, Cu（II） and Cd（II） ions content in some real samples.展开更多
文摘A novel method for the determination of cationic surfactant by laser thermal lens spectrometry was developed. It was based on the reaction between 1-hydroxy-2-(5-nitro-2-Pyri- dylazo)-8-aminonaphthalene-3,6-disulfonic acid (5-NO2-PAH) and cationic surfactant to form 1:2 ionic association complex in a weakly basic medium (pH 9.44). The determination conditions and the mechanism were discussed. The method has been applied to the analysis of wastewater and moat water samples.
基金Supported by National Natural Science Foundation of China for Young Researchers ( No. 29606008) andTianjin Natural Science Foundation ( No. 993607111).
文摘Enhancing the dispersion and dissolution of substrate particles in substrate water suspension is a feasible way to improve steroid bioconversion. The aim of the present study is to investigate the effects of applying surfactant to microbial conversion system on the dispersion, solubilization and in turn bioconversion of steroid substrate. The model system is hydroxylation of substrate 19α- 17α-epoxy- 4-pregnene- 3.2It-dine by microbial enzymes from Rhizopus nigricanl. The results show that the presence of substrate leads to an increase in critical micelle concentration （ CMC） of surfactant PSE compared with the normal CMC of PSE in aqueous solution. The grinding time during substrate suspension preparation affects the substrate aqueous solubility differently with the varied surfactant concentrations while barely making any difference in substrate solubility in the absence of surfactant. The properly prolonged grinding time can make up for the loss in substrate solubility arising from the reduction in surfactant concentration. The surfactant complexes composed of surfactants PSE and MGE at appropriate ratios are screened out with orthodoxy experiment method. the interaction between PSE and MGE exerts the most prominent effects on substrate bioconversion, and the surfactant complexes show more beneficial effects on steroid bioconversion than the surfactant PSE used alone.
基金This work was supported by the National Natural Science Foundation of China （No.20335030） and the Innovation Foundation of Science and Technology （No.NWNU-KJCXGC-02-09）.
文摘Dual fluorescence and UV absorption of 2′-ethylhexyl 4-（N,N-dimethylamino）benzoate （EHDMAB） were investigated in cationic, non-ionic and anionic micelles. When EHDMAB was solubilized in different micelles, the UV absorption of EHDMAB was enhanced. Twisted intramolecular charge transfer （TICT） emission with longer wavelength was observed in ionic micelles, whereas TICT emission with shorter wavelength was obtained in non-ionic micelles. In particular, dual fluorescence of EHDMAB was significantly quenched by the positively charged pyridinium ions arranged in the Stern layer of cationic micelles. UV radiation absorbed mainly decays via TICT emission and radiationless deactivation. The dimethylamino group of EHDMAB experiences different polar environments in ionic and non-ionic micelles according to the polarity dependence of TICT emission of EHDMAB in organic solvents. In terms of the molecular structures and sizes of EHDMAB and surfactants, each individual EHDMAB molecule should be buried in micelles with its dimethylamino group toward the polar head groups of different micelles and with its 2′-ethylhexyl chain toward the hydrophobic micellar core. Dynamic fluorescence quenching measurements of EHDMAB provide further support for the location of EHDMAB in different micelles.
文摘为了满足低渗透储层水平井改造的需要,开发了一种梳形聚合物与表面活性剂胶束自组装复合压裂液体系。该体系不使用交联剂,不含水不溶物;80℃时,0.3%梳形聚合物CD-1与0.2%表面活性剂组成的自组装压裂液储能模量高达290 Pa,远大于耗能模量,表现出突出的黏弹特性。5 m3/min排量下压裂液的降阻率达到74.05%,具有突出的低摩阻特性。不同配方的自组装压裂液破胶液的表面张力都低于27 m N/m,界面张力低于0.8 m N/m,满足压裂液返排特性的要求。自组装压裂液对储层岩心平均伤害率18.04%,远小于瓜胶压裂液78.75%的水平。室内评价和现场试验施工都表明,自组装压裂液降阻率高,对地层伤害小,增产效果明显,同时证实了利用聚合物与表面活性剂胶束自组装形成结构携砂理论的正确性。该压裂液体系满足特殊结构井压裂改造要求,为特殊低渗透油气藏的开发提供了一种新的方法和手段。
基金support by the Major Program of Guangdong University of Technology (No.405095220)
文摘A series of novel quaternary ammonium surfactants containing adamantane were designed and synthesized from 1-adamanta- necarboxylic acid. The structures of target surfactants were confirmed by 1H NMR, elements analysis and FFIR. Surface properties of these surfactants were investigated. Due to the lipophilicity of adamantane, the critical micelle concentration （CMC） and C2o values of the synthesized quaternary ammonium surfactants are lower than that of conventional quaternary ammonium surfactants.
文摘Preconcentration/separation of Co（II）, Fe（III）, Pb（II）, Cr（IIl）, Cu（II） and Cd（II） ions using bis（5-bromo- 2-hydroxy-benzaldehyde）-2-methy1-1,5-pentane diimine （BBHBPDI） on SDS coated alumina has been reported. The influences of the analytical parameters including pH, ligand and SDS amount, type and concentration of eluent and sample volume on metal ions recoveries were investigated. At optimum values of all variables the relative standard deviation are between 2.5-2.7 and preconcentration factor was 375, while recoveries for all understudy metal ions are higher than 95%, determination limits are between 1.5-2.7. The method has been successfully applied to determination of Co（II）, Fe（III）, Pb（II）, Cr（III）, Cu（II） and Cd（II） ions content in some real samples.
