In this paper,substantial domestic and foreign research results of microscopic shale reservoir space were systemically reviewed,the research history consisting of simple observation and qualitative classification,quan...In this paper,substantial domestic and foreign research results of microscopic shale reservoir space were systemically reviewed,the research history consisting of simple observation and qualitative classification,quantitative research,the combination of qualitative and quantitative research successively as well as the characteristics of each research stage were summarized.In addition,the current problems existing in the characterization methods of shale reservoir space were also analyzed.Furthermore,based on massive actual detection of typical core samples obtained from more than 50 global shale gas wells and relevant practical experience,a comprehensive characterization method of combining qualitative with the semiquantitative characterization was put forward.In detail,the indicators of the qualitative characterization include pore combination type and organic-matter microscopic morphology type,while the core elements of the semi-quantitative characterization include the percentage of the organic-matter area and the plane porosity of the pores of different types.Based on the reference of the naming and classification of rocks,the three-end-member diagram method was used to characterize microscopic shale reservoir space.This is achieved by plotting the three end-member diagram of 3 kinds of first-order critical reservoir spaces,i.e.,organic-matter pores,matrix pores,and micro-fractures,in order to intuitively present the features of the microscopic pore combination.Meanwhile,statistic histograms of organic-matter microscopic morphology type and the plane porosity of different types of pores were adopted to characterize the development degree of second-order pores quantitatively.By this comprehensive characterization method,the importance of both pore combination and the microscopic morphology of organic matter were emphasized,revealing the control of organic-matter microscopic morphology over the organic-matter pores.What is more,high-resolution FE-SEM was adopted to obtain semi-quantitative statistics results.In this way,the features of pore development and pore combination were quantified,not only reflecting the types and storage capacity of the microscopic shale reservoir space,but also presenting the hydrocarbongenerating potential of organic matter in shale.Therefore,the results of this research are capable of providing in-depth microscopic information for the assessment and exploration and development of shale gas resources.展开更多
以渤海SZ36-1油田油藏地质特征和流体性质为研究对象,以黏度和采收率为评价指标,开展了调驱剂、封窜剂和冷采剂筛选和基本性能评价,进行了调驱、封窜、冷采以及"调驱剂+冷采剂"和"封窜剂+冷采剂"段塞组合措施增油...以渤海SZ36-1油田油藏地质特征和流体性质为研究对象,以黏度和采收率为评价指标,开展了调驱剂、封窜剂和冷采剂筛选和基本性能评价,进行了调驱、封窜、冷采以及"调驱剂+冷采剂"和"封窜剂+冷采剂"段塞组合措施增油效果物理模拟。结果表明,封窜剂(改性淀粉类,主剂浓度80000 mg/L,辅剂浓度2150 mg/L)较调驱剂(Cr3+聚合物凝胶,聚合物浓度4000 mg/L,聚合物与Cr3+质量比180∶1)具有良好的抗稀释和抗剪切性,按油水体积比1∶5将冷采剂与原油混合后会形成油内相、水外相(O/W)乳状液,促使原油黏度降低(黏度为540 m Pa·s的模拟原油经冷采剂乳化后的黏度降为3.4 m Pa·s),渗流阻力减小。随岩心非均质性增强,水驱采收率减小,"调驱剂+冷采剂"和"封窜剂+冷采剂"段塞组合措施的增油效果提高,两个措施间采收率增幅差值增加,表明封窜剂转向作用效果增强,促使后续冷采剂更多地转向进入中低渗透层,原油降黏范围增加,作用效果增强。在高、中、低渗透率分别为6000×10-3、2000×10-3、200×10-3μm2的非均质岩心上,单独调驱、封窜和冷采、"调驱剂+冷采剂"和"封窜剂+冷采剂"段塞措施的提高采收率分别为25.5%、33.9%、6.1%、30.4%、39.9%,"封窜剂+冷采剂"复合段塞的液流转向效果较好,采收率增幅较大。展开更多
基金This study was supported by the National Scientific and Technological Major Special Project titled“Research on Evaluation Method and Exploration Technology on Shale Gas Resources”(2016ZX05034)“Shale Gas Basic Geological Survey Project in South China”(121201229000160021)initiated by CGSinter-governmental cooperation project titled“China-USA Cooperation Research Project of Carboniferous-Permian Shale Reservoir Evaluation Technology”(2017YFE0106300).
文摘In this paper,substantial domestic and foreign research results of microscopic shale reservoir space were systemically reviewed,the research history consisting of simple observation and qualitative classification,quantitative research,the combination of qualitative and quantitative research successively as well as the characteristics of each research stage were summarized.In addition,the current problems existing in the characterization methods of shale reservoir space were also analyzed.Furthermore,based on massive actual detection of typical core samples obtained from more than 50 global shale gas wells and relevant practical experience,a comprehensive characterization method of combining qualitative with the semiquantitative characterization was put forward.In detail,the indicators of the qualitative characterization include pore combination type and organic-matter microscopic morphology type,while the core elements of the semi-quantitative characterization include the percentage of the organic-matter area and the plane porosity of the pores of different types.Based on the reference of the naming and classification of rocks,the three-end-member diagram method was used to characterize microscopic shale reservoir space.This is achieved by plotting the three end-member diagram of 3 kinds of first-order critical reservoir spaces,i.e.,organic-matter pores,matrix pores,and micro-fractures,in order to intuitively present the features of the microscopic pore combination.Meanwhile,statistic histograms of organic-matter microscopic morphology type and the plane porosity of different types of pores were adopted to characterize the development degree of second-order pores quantitatively.By this comprehensive characterization method,the importance of both pore combination and the microscopic morphology of organic matter were emphasized,revealing the control of organic-matter microscopic morphology over the organic-matter pores.What is more,high-resolution FE-SEM was adopted to obtain semi-quantitative statistics results.In this way,the features of pore development and pore combination were quantified,not only reflecting the types and storage capacity of the microscopic shale reservoir space,but also presenting the hydrocarbongenerating potential of organic matter in shale.Therefore,the results of this research are capable of providing in-depth microscopic information for the assessment and exploration and development of shale gas resources.
文摘以渤海SZ36-1油田油藏地质特征和流体性质为研究对象,以黏度和采收率为评价指标,开展了调驱剂、封窜剂和冷采剂筛选和基本性能评价,进行了调驱、封窜、冷采以及"调驱剂+冷采剂"和"封窜剂+冷采剂"段塞组合措施增油效果物理模拟。结果表明,封窜剂(改性淀粉类,主剂浓度80000 mg/L,辅剂浓度2150 mg/L)较调驱剂(Cr3+聚合物凝胶,聚合物浓度4000 mg/L,聚合物与Cr3+质量比180∶1)具有良好的抗稀释和抗剪切性,按油水体积比1∶5将冷采剂与原油混合后会形成油内相、水外相(O/W)乳状液,促使原油黏度降低(黏度为540 m Pa·s的模拟原油经冷采剂乳化后的黏度降为3.4 m Pa·s),渗流阻力减小。随岩心非均质性增强,水驱采收率减小,"调驱剂+冷采剂"和"封窜剂+冷采剂"段塞组合措施的增油效果提高,两个措施间采收率增幅差值增加,表明封窜剂转向作用效果增强,促使后续冷采剂更多地转向进入中低渗透层,原油降黏范围增加,作用效果增强。在高、中、低渗透率分别为6000×10-3、2000×10-3、200×10-3μm2的非均质岩心上,单独调驱、封窜和冷采、"调驱剂+冷采剂"和"封窜剂+冷采剂"段塞措施的提高采收率分别为25.5%、33.9%、6.1%、30.4%、39.9%,"封窜剂+冷采剂"复合段塞的液流转向效果较好,采收率增幅较大。
