A global analysis of the ro-vibrational spectra of 19 bands in the comet-tail （A2Πi-X2Σ＋） system of the 12C16O＋ cation is presented, and the precise molecular constants of the vibrational levels involved are obt...A global analysis of the ro-vibrational spectra of 19 bands in the comet-tail （A2Πi-X2Σ＋） system of the 12C16O＋ cation is presented, and the precise molecular constants of the vibrational levels involved are obtained via a weighted nonlinear least-squares fitting procedure. Furthermore, the resultant precise equilibrium molecular constants enable us to achieve accurate Rydberg-Klein-Rees （RKR） potential curves for both the A and X states, yielding the accurate Franck-Condon factor and band origin of each band in this system.展开更多
基金the National Natural Science Foundation of China(Grant No.11034002)the State Key Development Program for Basic Research of China(Grant No.2011CB921602)+2 种基金the Natural Science Program of Nantong University,Chinathe State Key Laboratory of Precision Spectroscopy,ChinaQing Lan Project,China
文摘A global analysis of the ro-vibrational spectra of 19 bands in the comet-tail （A2Πi-X2Σ＋） system of the 12C16O＋ cation is presented, and the precise molecular constants of the vibrational levels involved are obtained via a weighted nonlinear least-squares fitting procedure. Furthermore, the resultant precise equilibrium molecular constants enable us to achieve accurate Rydberg-Klein-Rees （RKR） potential curves for both the A and X states, yielding the accurate Franck-Condon factor and band origin of each band in this system.
