Evaluation of red soil-bentonite mixtures for compacted clay liners

Compacted clay liners are an integral part of the waste landfills,which are provided to contain the leachate within the landfills and protect the surrounding environment.Generally,locally available natural soils are used for the construction of compacted clay liners if they satisfy the design criteria.However,not all soils in their natural state satisfy all the design criteria for the liner materials.Thus,there is a definite need to modify the locally available natural soils by blending with bentonite to meet the required design criteria for the liners.In view of this,the present study evaluates the suitability of an Indian red soil enhanced with bentonite as a liner material.To achieve this,a series of experiments were carried out using locally available red soil and bentonite.First,the suitability of the red soil was evaluated as a liner material.The experimental results showed that the red soil met all the selection criteria stipulated by the Environmental Protection Agencies(EPAs)for the liners except the hydraulic conductivity criterion.Therefore,the red soil was mixed with bentonite contents of 10%,20%and 30%,and the red soil-bentonite mixtures were evaluated for their suitability for liners in their compacted state.Further,as the liners in the arid and semi-arid regions are subjected to moisture variations due to seasonal moisture fluctuations and other factors,the red soil-bentonite mixtures were subjected to wetdry cycles,and their suitability was evaluated after wet-dry cycles.The experimental results revealed that all the red soil-bentonite mixtures met the stipulated EPA criteria for the liners in the as-compacted state.However,the red soil-bentonite mixtures with 20%and 30%bentonite contents only satisfied the hydraulic conductivity requirement even after wet-dry cycles.The experimental findings were supplemented with the microstructural insights captured through digital camera images,scanning electron microscopy(SEM),and mercury intrusion porosimetry(MIP)studies.

Thermal fatigue and wear of compacted graphite iron brake discs with various thermomechanical properties

The increase in payload capacity of trucks has heightened the demand for cost-effective yet high performance brake discs.In this work,the thermal fatigue and wear of compacted graphite iron brake discs were investigated,aiming to provide an experimental foundation for achieving a balance between their thermal and mechanical properties.Compacted graphite iron brake discs with different tensile strengths,macrohardnesses,specific heat capacities and thermal diffusion coefficients were produced by changing the proportion and strength of ferrite.The peak temperature,pressure load and friction coefficient of compacted graphite iron brake discs were analyzed through inertia friction tests.The morphology of thermal cracks and 3D profiles of the worn surfaces were also discussed.It is found that the thermal fatigue of compacted graphite iron discs is determined by their thermal properties.A compacted graphite iron with the highest specific heat capacity and thermal diffusion coefficient exhibits optimal thermal fatigue resistance.Oxidization of the matrix at low temperatures significantly weakens the function of alloy strengthening in hindering the propagation of thermal cracks.Despite the reduced hardness,increasing the ferrite proportion can mitigate wear loss resulting from low disc temperatures and the absence of abrasive wear.

Feasibility of compacted attapulgite/diatomite amended clayey soils as gas barrier materials

Compacted clay liners are extensively used as barriers to control the upward diffusion of vapors of volatile or semi-volatile organic contaminants released from unsaturated contaminated soils at industrycontaminated sites.This study aimed to investigate the gas diffusion barrier performance of compacted clayey soils amended with three agents including attapulgite and diatomite individually,and attapulgite/diatomite mixture.The properties including water retention,volumetric shrinkage,gas diffusion,and unconfined compressive strength were evaluated through a series of laboratory tests of amended compacted clayey soils.The results demonstrate that the decrease in volume proportions of interaggregate pores leads to an increase in unconfined compressive strength(qu).Both hydrophilic groups and microstructures of attapulgite and diatomite result in an increase in water retention percent(Wt)of compacted clayey soil specimens after amendment regardless of the type of agent or initial water content(w0).Furthermore,the ratio of the gas diffusion coefficient(De)to the gas diffusion coefficient in the air(Da)was significantly reduced owing to a decrease in volume proportions of inter-aggregate pores,hydrophilic group,and microstructures of attapulgite and diatomite.Scanning electron microscope analyses revealed that rod-shaped attapulgite filled the inter-aggregate pores formed by clay particles,whereas the disc-shaped diatomite particles,characterized by micropores,failed to obstruct the interaggregate pores due to their larger particle size.Mercury intrusion porosimetry(MIP)analyses showed a reduction in pore volume in the inter-aggregate pores,leading to a reduction in the total pore volume for both the attapulgite and attapulgite/diatomite mixture amended clays,which is in accordance with the scanning electron microscope(SEM)results.The findings are pertinent to the practical application of compacted clay liners as gas barriers against the upward migration of volatile or semi-volatile organic contaminants at contaminated sites.

Research on Preparation and Electrochemical Performance of the High Compacted Density Ni-Co-Mn Ternary Cathode Materials

The high compacted density LiNi0.5-xCo0.2Mn0.3MgxO2 cathode material for lithium-ion batteries was synthesized by high temperature solid-state method, taking the Mg element as a doping element and the spherical Ni0.5Co0.2Mn0.3 (OH)2, Li2CO3 as raw materials. The effects of calcination temperature on the structure and properties of the products were investigated. The structure and morphology of cathode materials powder were analyzed by X-ray diffraction spectroscopy (XRD) and scanning electronmicroscopy (SEM). The electrochemical properties of the cathode materials were studied by charge-discharge test and cyclic properties test. The results show that LiNi0.4985Co0.2Mn0.3 Mg0.0015O2 cathode material prepared at calcination temperature 930°C has a good layered structure, and the compacted density of the electrode sheet is above 3.68 g/cm3. The discharge capacity retention rate is more than 97.5% after 100 cycles at a charge-discharge rate of 1C, displaying a good cyclic performance.

Effect of FeSi additive in dual-chamber sample cup on thermal analysis characteristic values and vermiculating rate of compacted graphite iron

Thermal analysis plays a key role in the online inspection of molten iron quality.Different solidification process of molten iron can be reflected by thermal analysis curves,and silicon is one of important elements affecting the solidification of molten iron.In this study,FeSi75 was added in one chamber of the dual-chamber sample cup,and the influences of FeSi75 additive on the characteristic values of thermal analysis curves and vermiculating rate were investigated.The results show that with the increase of FeSi75,the start temperature of austenite formation TALfirstly decreases and then increases,but the start temperature of eutectic growth TSEF,the lowest eutectic temperature TEU,temperature at maximum eutectic reaction rate TEM,and highest eutectic temperature TERkeep always an increase.The temperature at final solidification point TEShas little change.The FeSi75 additive has different influences on the vermiculating rate of molten iron with different vermiculation,and the vermiculating rate increases for lower vermiculation molten iron while decreases for higher one.According to the thermal analysis curves obtained by a dual-chamber sample cup with 0.30wt.%FeSi75 additive in one chamber,the vermiculating rate of molten iron can be evaluated by comparing the characteristic values of these curves.The time differenceΔtERcorresponding to the highest eutectic temperature TERhas a closer relationship with the vermiculating rate,and a parabolic regression curve between the time differenceΔtERand vermiculating rateηhas been obtained within the range of 65%to 95%,which is suitable for the qualified melt.

Anisotropic swelling pressures of compacted GMZ bentonite infiltrated with salt solutions

In the high-level radioactive waste(HLW)deep geological repository,bentonite is compacted uniaxially,and then arranged vertically in engineered barriers.The assembly scheme induces the initial anisotropy,and with hydration,it develops more evidently under chemical conditions.To investigate the anisotropic swelling of compacted Gaomiaozi(GMZ)bentonite and the further response to saline effects,a series of constant-volume swelling pressure tests were performed.Results showed that dry density enhanced the bentonite swelling and raised the final anisotropy,whereas saline inhibited the bentonite swelling but still promoted the final anisotropy.The final anisotropy coefficient(ratio of radial to axial pressure)obeyed the Boltzmann sigmoid attenuation function,decreasing with concentration and dry density,converging to a minimum value of 0.76.The staged evolution of anisotropy coefficient was discovered,that saline inhibited the rise of the anisotropy coefficient(Dd)in the isotropic process greater than the valley(d1)in the anisotropic process,leading to the final anisotropy increasing.The isotropic stage amplified the impact of soil structure rearrangement on the macro-swelling pressure values.Thus,a new method for predicting swelling pressures of compacted bentonite was proposed,by expanding the equations of Gouy-Chapman theory with a dissipative wedge term.An evolutionary function was constructed,revealing the correlation between the occurrence time and the pressure value due to the structure rearrangement and the former crystalline swelling.Accordingly,a design reference for dry density was given,based on the chemical conditions around the pre-site in Beishan,China.The anisotropy promoted by saline would cause a greater drop of radial pressure,making the previous threshold on axial swelling fail.

Water content and modulus relationship of a compacted unsaturated soil

In order to assess the performance of the embankment soil under various climate conditions during the period of service, the modulus behaviour of an unsaturated compacted soil is evaluated using the constant water content triaxial test. Since the water content measurement method is simple and economical and it is used widely in engineering, the soil suction is replaced by the water content and the relationship between the water content and the modulus is developed. The compacted samples are prepared with different compacted water contents, and samples with a similar water content subjected to drying or wetting procedures prior to the triaxial test are also investigated. The effect of the water content and the confining pressure on the modulus is analyzed. The results show that the modulus decreases with the increase in the water content and a power function can be proposed to quantitatively describe the relationship between the modulus and the water content in the range of the measured water content. The modulus increases with the increase in the confining pressure of the compacted soil. However, the effect of the water content on the modulus is more pronounced than that of the confining pressure. This research can be referenced for the compacted embankment soil assessment in-service period.

VITEK■ 2 Compact全自动微生物鉴定药敏分析仪虚拟仿真教学软件的开发与应用

文章主要介绍了VITEK■2 Compact全自动微生物鉴定药敏分析仪虚拟仿真教学软件的设计与开发,以及虚拟仿真融合线上线下混合教学模式在医学微生物检验实验教学中的应用。结果表明,该仿真教学软件的实际应用既有利于培养学生的实践操作能力及思维方式,又能弥补学校实训环境与临床实际不符的缺陷,为微生物检验实验教学质量的提升开辟新的思路。

Effects of alloy elements on ductility and thermal conductivity of compacted graphite iron

The infl uence of Si, Sn, Mo and Ni on the ductility and thermal conductivity of compacted graphite iron(CGI) was investigated. Metallographic observation and Differential Scanning Calorimetry(DSC) experiments were carried out to analyze the roles of various additions in the eutectoid reaction. The experimental results showed that the ductility of CGI is proportional to the ferrite fraction, so moderate Si content could dramatically improve the ductility by increasing the ferrite fraction. DSC measurements showed that Mo has moderate inhibition on eutectoid transformation during both the heating and cooling processes, while the sample without Sn obviously broadens the three-phase region. Vermicularity and ferrite are known to improve thermal conductivity, and the former plays a more important role. Besides, among the alloy elements investigated, Sn has the greatest negative effect on conductivity, followed by Ni and Mo having the smallest effects.

THE STRUCTURE CONTROL OF ALUMINUM FOAMS PRODUCED BY POWDER COMPACTED FOAMING PROCESS

A new technique, powder compact foaming process for the production of aluminumfoams has been studied in this article. According to this method, the aluminum pow-der is mixed with a powder foaming agent (TiH_2). Subsequent to mixing, the powderblend is hot compacted to obtain a dense semi--finished product. Upon heating to tem-peratures within the range of the melting point, the foaming agent decomposes to evolvegas and the semi--finished product expands into a porous cellular aluminum. Foamingprocess is the key in this method. Based on experiments, the foaming characteris-tics were mainly analyzed and discussed. Experiments show that the aluminum--foamwith closed pores and a uniform cell structure of high porosity can be obtained usingthis method by adjusting the foaming parameters: the content of foaming agent andfoaming temperature.

Saturated anisotropic hydraulic conductivity of a compacted lateritic soil

This study focuses on the saturated anisotropic hydraulic conductivity of a compacted lateritic clayey sandy soil. The effects of the molding water content and the confining stress on the anisotropic hydraulic conductivity are investigated. The hydraulic conductivity is measured with a flexible-wall permeameter. Samples are dynamically compacted into the three compaction states of a standard Proctor compaction curve： the dry branch, optimum water content and wet branch. Depending on the molding water content and confining stress, the hydraulic conductivity may increase or decrease. In addition, the results indicate that, when the samples are compacted to the optimum water content, lower hydraulic conductivity is obtained, except at a confining stress equal to 50 kPa. The increase of the confining stress decreases the hydraulic conductivity for each of the evaluated compaction states. In the wet branch, horizontal hy- draulic conductivity is about 8 times higher than the vertical value. The anisotropic hydraulic conduc- tivities of the dry and wet branches decrease when the confining stress increases, and the opposite is observed in the optimum water content state.

Study on mechanical properties of warm compacted iron-base materials

Mechanical properties of the warm compacted iron base powder metallurgy materials were compared with those of conventional cold compacted materials. Factors such as compaction temperature, lubricant concentration and lubricant′s property were studied. A lubricant for warm compaction powder metallurgy was developed. An iron based powder metallurgy material with a green density of 7.31 g/cm 3 (a relative density of 92.5%) can be obtained by pressing the powder at 700 MPa and 175 ℃. The sintered materials have a density of 7.2 g/cm 3, an elongation of 2.1% and a tensile strength of 751 MPa compared to 546 MPa using conventional cold compaction with the same lubricant and 655 MPa using warm compaction with other lubricant. Compact density and mechanical properties were influenced strongly by the compacting temperature. Although the best quality compacts can be obtained at 175 ℃, warm compaction within 165 to 185 ℃ can give high density compacts. Evidence shows that compact density depends on the friction coefficient of the lubricant.

Diffusion characteristics of HTO and 99TcO_4^- in compacted Gaomiaozi(GMZ) bentonite

The characteristics of diffusion are essential to the transport of radionuclides through buffer/backfill materials, such as bentonite, which are commonly found in waste repositories. This study used through-diffusion techniques to investigate the diffusion behavior of HTO and ^(99)TcO_4^- on GMZ bentonite of various densities. Diffusion rates were calculated by measuring the diffusion coefficients(De, Da), plotting breakthrough curves and interpreting experiment data. The apparent and effective diffusion coefficients of HTO ranged from(1.68 ± 0.40) 9 × 10^(-11) to(2.80 ± 0.62) 9 × 10^(-11) m^2/s and from(4.61 ±1.28) 9 × 10^(-12) to (16.2 ± 2.50) 9 × 10^(-12) m^2/s, respectively.The apparent and effective diffusion coefficients of^(99)TcO_4^-ranged from(5.26 ± 0.16) 9 × 10^-12to(7.78 ± 0.43) 9× 10^-12m^2/s and from(1.49 ± 0.002) 9 × 10^(-12) to(4.16 ±0.07) 9 × 10^(-12) m^2/s, respectively. The distribution coefficients of HTO and^(99)TcO_4^-ranged from(0.70 ± 0.12) 9× 10^(-2) to(1.36 ± 0.53) 9 × 10^(-2) mL/g and from(1.12 ±0.06) 9 × 10^(-2) to(5.79 ± 2.22) 9 × 10^(-2) mL/g, respectively.The Deand Kdvalues were shown to decrease with an increase in the bulk dry density of compacted bentonite. Our results show that HTO and ^(99)Tc could be considered nonsorbent radionuclides. The data obtained in this studyprovide a valuable reference for the safety assessment of waste repositories.

A reliable and consistent production technology for high volume compacted graphite iron castings

The demands for improved engine performance,fuel economy,durability,and lower emissions provide a continual challenge for engine designers.The use of Compacted Graphite Iron(CGI)has been established for successful high volume series production in the passenger vehicle,commercial vehicle and industrial power sectors over the last decade.The increased demand for CGI engine components provides new opportunities for the cast iron foundry industry to establish efficient and robust CGI volume production processes,in China and globally.The production window range for stable CGI is narrow and constantly moving.Therefore,any one step single addition of magnesium alloy and the inoculant cannot ensure a reliable and consistent production process for complicated CGI engine castings.The present paper introduces the SinterCast thermal analysis process control system that provides for the consistent production of CGI with low nodularity and reduced porosity,without risking the formation of flake graphite.The technology is currently being used in high volume Chinese foundry production.The Chinese foundry industry can develop complicated high demand CGI engine castings with the proper process control technology.

Analysis of density and mechanical properties of high velocity compacted iron powder

A new method for producing higher density PM parts, high velocity compaction （HVC）, was presented in the paper. Using water atomized pure iron powder without lubricant admixed as the staring material, ring samples were compacted by the technique. Scanning electron microscopy （SEM） and a computer controlled universal testing machine were used to investigate the morphologies and the mechanical properties of samples, respectively. The relationships among the impact velocity, the green density, the sintered density, the bending strength and the tensile strength were discussed, The results show that with increasing impact velocity, the green density and the bending strength increase gradually, so the sintered density does. In addition, the tensile strength of sintered material is improved continuously with the sintered density enhancing. In the study, the sintered density of 7.545 g/cm^3 and the tensile strength of 190 MPa are achieved at the optimal impact velocity of 9.8 m/s.

Compacted graphite iron-A material solution for modern diesel engine cylinder blocks and heads

The demands for improved fuel economy,performance and emissions continue to pose challenges for engine designers and the materials they choose. This is particularly true for modern diesel engines,where the primary path to achieving improved engine performance and emissions is to increase the Peak Firing Pressure in the combustion chamber. The resulting increase in thermal and mechanical loading has required a change from conventional grey cast iron to Compacted Graphite Iron (CGI) in order to satisfy durability requirements without increasing the size or the weight of the engines. With at least 75% higher tensile strength,45% higher stiffness and approximately double the fatigue strength of conventional grey cast iron,CGI satisfies durability requirements and also provides the dimensional stability required to meet emissions legislation throughout the life of the engine. Currently,there are no CGI diesel engines running on the roads in North America. This is set to change considerably as new commercial vehicle and pick-up SUV diesel engines are launched with CGI cylinder blocks in 2008 and 2009. These initial programs will provide over 2 million CGI diesel engines when ramped to mature volume,potentially accounting for 10%-15% of the North American passenger vehicle fleet within the next four years.

Influence of fading on characteristics of thermal analysis curve of compacted graphite iron

In general, during the production of compacted graphite iron (CGI), the active residual magnesium reduces and the effect of inoculation fades after magnesium treatment. In this paper, characteristics of the thermal analysis curve of CGI are compared with those of ductile iron and grey cast iron. The fading effect on the compacted graphite percentage and thermal analysis curve were also studied. Results indicate that the undercooling of CGI is as low as that of ductile iron, but CGI shows evident recalescence. In fading process, the magnesium element acts with oxygen. For a decrease in magnesium content, both the compacted graphite percentage and the austenitic liquidus temperature increase. The temperature of eutectic undercooling (TEU) decreases before the flake graphite appears. After that, TEU increases quickly, up to as high as 20℃, and then gradually decreases. The evolution of recalescence degree is opposite to that of TEU.

Experimental and FEM Study of Coated and Uncoated Tools Used for Dry Milling of Compacted Graphite Cast Iron

Compacted graphite cast iron （CG1） has been the material for high-power diesel engines recently, but its increased strength causes poor machinability. In this study, coated and uncoated carbide tools were used in dry milling experiment and FEM simulation to study the machinability of CGI and wear behaviour of tools. The experimental and FEM simulation results show that coated tool has great advantage in dry milling of CGI. SEM and EDS analysis of tool wear indicate the wear morphology and wear mechanism. Adhesive wear is the main mechanism to cause un- coated tool wear, while abrasive wear and delamination wear are the main mechanism to cause coated tool wear. Stress and temperature distribution in FEM simulation help to understand the wear mechanism including the reason for coat- ing peeled off.

Fluid solid coupling model based on endochronic damage for roller compacted concrete dam

According to the characteristics of thin-layer rolling and pouting construction technology and the complicated mechanical behavior of the roller compacted concrete dam （RCCD） construction interface, a constitutive model of endochronic damage was established based on the endochronic theory and damage mechanics. The proposed model abandons the traditional concept of elastic-plastic yield surface and can better reflect the real behavior of rolled control concrete. Basic equations were proposed for the fluid-solid coupling analysis, and the relationships among the corresponding key physical parameters were also put forward. One three-dimensional finite element method （FEM） program was obtained by studying the FEM type of the seepage-stress coupling intersection of the RCCD. The method was applied to an actual project, and the results show that the fluid-solid interaction influences dam deformation and dam abutment stability, which is in accordance with practice. Therefore, this model provides a new method for revealing the mechanical behavior of RCCD under the coupling field.

Modelling of compacted graphite cast iron solidification-Discussion of microstructure parameters

A melt maintained for hours in a press pour unit allowed the following changes over time from spheroidal graphite to compacted graphite iron by casting thermal cups at regular time intervals.This provided extensive experimental information for checking the possibility of simulating solidification of compacted graphite irons by means of a microstructure modelling approach.During solidification,compacted graphite develops very much as lamellar graphite but with much less branching.On this basis,a simulation of the thermal analysis records was developed which considers solidification proceeding in a pseudo binary Fe-C system.The simulated curves were compared with the experimental ones obtained from three representative alloys that cover the whole microstructure change during the holding of the melt.The most relevant result is that the parameter describing branching capability of graphite is the most important for reproducing the minimum eutectic temperature and the recalescence which are so characteristic of the solidification of compacted graphite cast irons.