Parallel back-building convective lines are often observed extending to the southwest of some mesoscale convective systems(MCSs)embedded in the mei-yu front in China.The convective lines with echo training behavior ca...Parallel back-building convective lines are often observed extending to the southwest of some mesoscale convective systems(MCSs)embedded in the mei-yu front in China.The convective lines with echo training behavior can quickly develop into a stronger convective group of echoes,resulting in locally heavy rainfall within the mei-yu front rainband.The initiation mechanism of the back-building convective lines is still unclear and is studied based on high-resolution numerical simulation of a case that occurred during 27−28 June 2013.In the present case,the new convection along the convective lines was found to be forced by nonuniform interaction between the cold outflow associated with the mei-yu front MCSs and the warm southerly airflow on the south side of the mei-yu front,which both are modified by local terrain.The mei-yu front MCSs evolved from the western to the eastern side of a basin surrounded by several mesoscale mountains and induced cold outflow centered over the eastern part of the basin.The strong southwest airflow ahead of the mei-yu front passed the Nanling Mountains and impacted the cold outflow within the basin.The nonuniform interaction led to the first stage of parallel convective line formation,in which the low mountains along the boundary of the two airflows enhanced the heterogeneity of their interaction.Subsequently,the convective group quickly developed from the first stage convective lines resulted in apparent precipitation cooling that enhanced the cold outflow and made the cold outflow a sharp southward windshift.The enhanced cold outflow pushed the warm southerly airflow southward and impacted the mountains on the southeast side of the basin,where the roughly parallel mountain valleys or gaps play a controlling role in a second stage formation of parallel convective lines.展开更多
The diphenyliodonium salt (DPIOC)/triethylamine (TEA) is used as photoinitiator for radical photopolymerization. It was found that a ground state CT complex formed between DPIOC as electron acceptor and TEA as electro...The diphenyliodonium salt (DPIOC)/triethylamine (TEA) is used as photoinitiator for radical photopolymerization. It was found that a ground state CT complex formed between DPIOC as electron acceptor and TEA as electron donor, which results in extending the photosensitivity range of DPIOC/TEA system up to above 500nm compared with DPIOC alone. The kinetic studies on photopolymerization of methyl methacrylate (MMA) were carried out in CH_3CN: H_2O (14: 1, v/v) mixture solution at 30℃ by dilatometer. The results obtained show that the polymerization rate (R_p) increases with increasing concentrations of DPIOC and TEA with exponent 0. 65 and 0. 62 respectively. The activation energy E_a and k_p/k_^(1/2) value were determined to be 4.1 Kcal mol^(-1) and 0.045 respectively. The other influence factors and reaction mechanism were also discussed.展开更多
The copolymerization process of triphenylmethyl methacrylate (TrMA) and methylmethacrylate (MMA) using chiral anionic complex initiator (-) SP-FlLi (Scheme 1) has beenstudied in toluene and THF, respectively. The copo...The copolymerization process of triphenylmethyl methacrylate (TrMA) and methylmethacrylate (MMA) using chiral anionic complex initiator (-) SP-FlLi (Scheme 1) has beenstudied in toluene and THF, respectively. The copolymer obtained in toluene possessed muchhigher specific rotation than that in THF. These copolymers have shown a tendency to a random and a like alternating structure, respectively.展开更多
Background:Based on the principle of“joint consultation,co-building,and sharing”,with the aim of creating an energetic new model of economic growth,the Belt and Road Initiative achieves connectivity and mutual benef...Background:Based on the principle of“joint consultation,co-building,and sharing”,with the aim of creating an energetic new model of economic growth,the Belt and Road Initiative achieves connectivity and mutual benefit.However,the degree of coordinated development of innovation subjects directly affects the improvement and optimization of the Belt and Road Initiative’s strategy implementation environment,and technology efficiency needs improvement.Methods:In this study,a data envelopment analysis model based on the environmental noise elimination algorithm(traditional Chinese medicine-Belt and Road Initiative)was used to identify the technical efficiency of the traditional Chinese medicine industry of Belt and Road Initiative by eliminating the impact of environmental factors.Results:Pure technical ineffectiveness,regional impact,and environmental factors represented by policy responses have a non-linear impact on technical efficiency.The overall technical efficiency of the traditional Chinese medicine industry in the countries along the route shows a trend of annual increases,technical efficiency and scale efficiency are relatively high,and operational efficiency is influenced by the degree of response of the countries along the route and its supporting policies.Conclusion:Pure technical inefficiency is the main factor affecting total technical loss.Geographical advantage is the key factor in operational efficiency.External environmental factors have a significant influence on the operational efficiency of the traditional Chinese medicine industry.展开更多
Neutral nickel sigma -acetylide complex [Ni(C=CPh)(2)(PBu3)(2)] is a novel initiator for the polymerization of styrene in CHCl3 over a range of polymerization temperature from 40 degreesC to 60 degreesC. The polystyre...Neutral nickel sigma -acetylide complex [Ni(C=CPh)(2)(PBu3)(2)] is a novel initiator for the polymerization of styrene in CHCl3 over a range of polymerization temperature from 40 degreesC to 60 degreesC. The polystyrene obtained was a syndio-rich atactic polymer and its weight-average molecular weight reached 279000. The mechanism of the polymerization was discussed and a radical mechanism was proposed.展开更多
CIP （complex initial permeability） spectra of PF （polycrystalline ferrite） are studied both as intrinsic and extrinsic properties. In the former case, main steps of modeling, based on effects coming from polycryst...CIP （complex initial permeability） spectra of PF （polycrystalline ferrite） are studied both as intrinsic and extrinsic properties. In the former case, main steps of modeling, based on effects coming from polycrystal grain sizes distribution and defects, are described. The obtained relations work well in practice for PF with more or less normal MS （microstructure） and no size effects. Besides, fundamental connection between parameters of CIP and MS is found. Another case--PF with possible size effects （MnZn-ferrites） are studied experimentally for different sizes of cores, unveiling the dependence of phenomena on： dimensions of cross-section, number of turns, width of nonmagnetic gap.展开更多
Two new complexes [Cu（dafo）2（en）]（ClO4）2·2H2O （en=NH2CH2CH2NH2） 1 and [Cu（dafo）2（dap）]（ClO4）2·2H2O [dap=NH2CH2CH（CH3）NH2] 2 （dafo=4,5-diazafluoren-9-one） have been synthesized and character...Two new complexes [Cu（dafo）2（en）]（ClO4）2·2H2O （en=NH2CH2CH2NH2） 1 and [Cu（dafo）2（dap）]（ClO4）2·2H2O [dap=NH2CH2CH（CH3）NH2] 2 （dafo=4,5-diazafluoren-9-one） have been synthesized and characterized by elemental analysis, IR and UV spectra. Meanwhile, the complex 1 has been characterized by single crystal X-ray diffraction analysis. The initial DNA binding interactions of the complexes 1 and 2 have been investigated by UV spectra, emission spectra and cyclic voltammogram. Concluding the results of three methods used to measure the interaction of complexes 1 and 2 with DNA, the action mode of the two complexes with DNA is intercalation, and character of ligands and steric effect may affect the interaction of the complexes with DNA.展开更多
本文利用WRF(Weather Research and Forecasting)模式耦合Noah陆面过程模式,对比研究了使用不同精度陆面资料:WRF默认陆面资料、中国1 km分辨率数字高程模型数据集、2006年MODIS(MODerate-resolution Imaging Spectroradiometer)土地利...本文利用WRF(Weather Research and Forecasting)模式耦合Noah陆面过程模式,对比研究了使用不同精度陆面资料:WRF默认陆面资料、中国1 km分辨率数字高程模型数据集、2006年MODIS(MODerate-resolution Imaging Spectroradiometer)土地利用和植被覆盖度资料,WRF模式对兰州地区冬季气象场模拟结果的差异。结果表明,近地面气温对陆面资料的精度非常敏感,而风场对陆面资料的精度不敏感,WRF模式对气温的模拟效果好于对风场模拟。采用高精度且时效性好的陆面资料后,WRF模拟的近地面气温准确率提高了15.8%,模拟的夜间气温改进幅度较白天大。陆面资料可影响整个边界层温度场分布,准确的陆面资料对提高WRF模式模拟近地面乃至整个边界层气象场至关重要。尽管风速模拟误差较大,但总体上WRF模式能较准确地模拟出研究区的风场演变特征。使用新的陆面资料后WRF模拟的风速误差略有减小,风向误差略有增加。干旱半干旱区冬季数值模拟需要注意土壤湿度初值和模式初始积分时刻对模拟结果的影响。展开更多
基金the National Key R&D Program of China(Grant No.2017YFC1501603)the Major Research Plan of the National Natural Science Foundation of China(Grant No.91937301)the National Natural Science Foundation of China(Grant Nos.41775054,41375061 and 40705019).
文摘Parallel back-building convective lines are often observed extending to the southwest of some mesoscale convective systems(MCSs)embedded in the mei-yu front in China.The convective lines with echo training behavior can quickly develop into a stronger convective group of echoes,resulting in locally heavy rainfall within the mei-yu front rainband.The initiation mechanism of the back-building convective lines is still unclear and is studied based on high-resolution numerical simulation of a case that occurred during 27−28 June 2013.In the present case,the new convection along the convective lines was found to be forced by nonuniform interaction between the cold outflow associated with the mei-yu front MCSs and the warm southerly airflow on the south side of the mei-yu front,which both are modified by local terrain.The mei-yu front MCSs evolved from the western to the eastern side of a basin surrounded by several mesoscale mountains and induced cold outflow centered over the eastern part of the basin.The strong southwest airflow ahead of the mei-yu front passed the Nanling Mountains and impacted the cold outflow within the basin.The nonuniform interaction led to the first stage of parallel convective line formation,in which the low mountains along the boundary of the two airflows enhanced the heterogeneity of their interaction.Subsequently,the convective group quickly developed from the first stage convective lines resulted in apparent precipitation cooling that enhanced the cold outflow and made the cold outflow a sharp southward windshift.The enhanced cold outflow pushed the warm southerly airflow southward and impacted the mountains on the southeast side of the basin,where the roughly parallel mountain valleys or gaps play a controlling role in a second stage formation of parallel convective lines.
文摘The diphenyliodonium salt (DPIOC)/triethylamine (TEA) is used as photoinitiator for radical photopolymerization. It was found that a ground state CT complex formed between DPIOC as electron acceptor and TEA as electron donor, which results in extending the photosensitivity range of DPIOC/TEA system up to above 500nm compared with DPIOC alone. The kinetic studies on photopolymerization of methyl methacrylate (MMA) were carried out in CH_3CN: H_2O (14: 1, v/v) mixture solution at 30℃ by dilatometer. The results obtained show that the polymerization rate (R_p) increases with increasing concentrations of DPIOC and TEA with exponent 0. 65 and 0. 62 respectively. The activation energy E_a and k_p/k_^(1/2) value were determined to be 4.1 Kcal mol^(-1) and 0.045 respectively. The other influence factors and reaction mechanism were also discussed.
文摘The copolymerization process of triphenylmethyl methacrylate (TrMA) and methylmethacrylate (MMA) using chiral anionic complex initiator (-) SP-FlLi (Scheme 1) has beenstudied in toluene and THF, respectively. The copolymer obtained in toluene possessed muchhigher specific rotation than that in THF. These copolymers have shown a tendency to a random and a like alternating structure, respectively.
文摘Background:Based on the principle of“joint consultation,co-building,and sharing”,with the aim of creating an energetic new model of economic growth,the Belt and Road Initiative achieves connectivity and mutual benefit.However,the degree of coordinated development of innovation subjects directly affects the improvement and optimization of the Belt and Road Initiative’s strategy implementation environment,and technology efficiency needs improvement.Methods:In this study,a data envelopment analysis model based on the environmental noise elimination algorithm(traditional Chinese medicine-Belt and Road Initiative)was used to identify the technical efficiency of the traditional Chinese medicine industry of Belt and Road Initiative by eliminating the impact of environmental factors.Results:Pure technical ineffectiveness,regional impact,and environmental factors represented by policy responses have a non-linear impact on technical efficiency.The overall technical efficiency of the traditional Chinese medicine industry in the countries along the route shows a trend of annual increases,technical efficiency and scale efficiency are relatively high,and operational efficiency is influenced by the degree of response of the countries along the route and its supporting policies.Conclusion:Pure technical inefficiency is the main factor affecting total technical loss.Geographical advantage is the key factor in operational efficiency.External environmental factors have a significant influence on the operational efficiency of the traditional Chinese medicine industry.
文摘Neutral nickel sigma -acetylide complex [Ni(C=CPh)(2)(PBu3)(2)] is a novel initiator for the polymerization of styrene in CHCl3 over a range of polymerization temperature from 40 degreesC to 60 degreesC. The polystyrene obtained was a syndio-rich atactic polymer and its weight-average molecular weight reached 279000. The mechanism of the polymerization was discussed and a radical mechanism was proposed.
文摘CIP （complex initial permeability） spectra of PF （polycrystalline ferrite） are studied both as intrinsic and extrinsic properties. In the former case, main steps of modeling, based on effects coming from polycrystal grain sizes distribution and defects, are described. The obtained relations work well in practice for PF with more or less normal MS （microstructure） and no size effects. Besides, fundamental connection between parameters of CIP and MS is found. Another case--PF with possible size effects （MnZn-ferrites） are studied experimentally for different sizes of cores, unveiling the dependence of phenomena on： dimensions of cross-section, number of turns, width of nonmagnetic gap.
基金Project supported by the Program for Changjiang Scholars and Innovative Research Team in University, PCSIRT （No. IRT 0559）, the National Natural Science Foundation of China （No. 20671076）, the Major State Basic Research Development Program of China （the 973 Program, No. 2003CB214606）, the Key Laboratory Research and Establishment Program of Shaanxi Education Section （No. 03JS006）, and the Special Foundation of Shaanxi Education Section （No. 04JK143）.
文摘Two new complexes [Cu（dafo）2（en）]（ClO4）2·2H2O （en=NH2CH2CH2NH2） 1 and [Cu（dafo）2（dap）]（ClO4）2·2H2O [dap=NH2CH2CH（CH3）NH2] 2 （dafo=4,5-diazafluoren-9-one） have been synthesized and characterized by elemental analysis, IR and UV spectra. Meanwhile, the complex 1 has been characterized by single crystal X-ray diffraction analysis. The initial DNA binding interactions of the complexes 1 and 2 have been investigated by UV spectra, emission spectra and cyclic voltammogram. Concluding the results of three methods used to measure the interaction of complexes 1 and 2 with DNA, the action mode of the two complexes with DNA is intercalation, and character of ligands and steric effect may affect the interaction of the complexes with DNA.
文摘本文利用WRF(Weather Research and Forecasting)模式耦合Noah陆面过程模式,对比研究了使用不同精度陆面资料:WRF默认陆面资料、中国1 km分辨率数字高程模型数据集、2006年MODIS(MODerate-resolution Imaging Spectroradiometer)土地利用和植被覆盖度资料,WRF模式对兰州地区冬季气象场模拟结果的差异。结果表明,近地面气温对陆面资料的精度非常敏感,而风场对陆面资料的精度不敏感,WRF模式对气温的模拟效果好于对风场模拟。采用高精度且时效性好的陆面资料后,WRF模拟的近地面气温准确率提高了15.8%,模拟的夜间气温改进幅度较白天大。陆面资料可影响整个边界层温度场分布,准确的陆面资料对提高WRF模式模拟近地面乃至整个边界层气象场至关重要。尽管风速模拟误差较大,但总体上WRF模式能较准确地模拟出研究区的风场演变特征。使用新的陆面资料后WRF模拟的风速误差略有减小,风向误差略有增加。干旱半干旱区冬季数值模拟需要注意土壤湿度初值和模式初始积分时刻对模拟结果的影响。
